GB1107292A - The preparation of ªŠ-caprolactone - Google Patents
The preparation of ªŠ-caprolactoneInfo
- Publication number
- GB1107292A GB1107292A GB445566A GB445566A GB1107292A GB 1107292 A GB1107292 A GB 1107292A GB 445566 A GB445566 A GB 445566A GB 445566 A GB445566 A GB 445566A GB 1107292 A GB1107292 A GB 1107292A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cyclohexanone
- benzoic acid
- caprolactone
- oxidation zone
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 6
- 230000003647 oxidation Effects 0.000 abstract 4
- 238000007254 oxidation reaction Methods 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- 239000005711 Benzoic acid Substances 0.000 abstract 3
- 235000010233 benzoic acid Nutrition 0.000 abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052790 beryllium Inorganic materials 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- -1 e.g. Co Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyrane Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6501332A NL6501332A (enrdf_load_stackoverflow) | 1965-02-03 | 1965-02-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1107292A true GB1107292A (en) | 1968-03-27 |
Family
ID=19792261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB445566A Expired GB1107292A (en) | 1965-02-03 | 1966-02-01 | The preparation of ªŠ-caprolactone |
Country Status (7)
| Country | Link |
|---|---|
| AT (1) | AT266809B (enrdf_load_stackoverflow) |
| BE (1) | BE675886A (enrdf_load_stackoverflow) |
| CH (1) | CH474504A (enrdf_load_stackoverflow) |
| ES (1) | ES322527A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1107292A (enrdf_load_stackoverflow) |
| IL (1) | IL25068A (enrdf_load_stackoverflow) |
| NL (1) | NL6501332A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0569098A3 (en) * | 1992-05-07 | 1994-02-09 | Dsm N.V. | Conversion of cycloalkanone into lactone |
| CN115445601A (zh) * | 2022-08-15 | 2022-12-09 | 南京工业大学 | 一种负载型SiO2@MxOy-TiO2催化剂及其制备方法和应用 |
-
1965
- 1965-02-03 NL NL6501332A patent/NL6501332A/xx unknown
-
1966
- 1966-01-30 IL IL2506866A patent/IL25068A/xx unknown
- 1966-02-01 AT AT89466A patent/AT266809B/de active
- 1966-02-01 BE BE675886D patent/BE675886A/xx unknown
- 1966-02-01 CH CH135166A patent/CH474504A/de not_active IP Right Cessation
- 1966-02-01 GB GB445566A patent/GB1107292A/en not_active Expired
- 1966-02-02 ES ES0322527A patent/ES322527A1/es not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0569098A3 (en) * | 1992-05-07 | 1994-02-09 | Dsm N.V. | Conversion of cycloalkanone into lactone |
| CN115445601A (zh) * | 2022-08-15 | 2022-12-09 | 南京工业大学 | 一种负载型SiO2@MxOy-TiO2催化剂及其制备方法和应用 |
| CN115445601B (zh) * | 2022-08-15 | 2023-12-29 | 南京工业大学 | 一种负载型SiO2@MxOy-TiO2催化剂及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE675886A (enrdf_load_stackoverflow) | 1966-08-01 |
| NL6501332A (enrdf_load_stackoverflow) | 1966-08-04 |
| CH474504A (de) | 1969-06-30 |
| IL25068A (en) | 1969-05-28 |
| ES322527A1 (es) | 1966-11-16 |
| AT266809B (de) | 1968-12-10 |
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