GB1107236A - Thermosetting aminoplast resins - Google Patents

Thermosetting aminoplast resins

Info

Publication number
GB1107236A
GB1107236A GB5343366A GB5343366A GB1107236A GB 1107236 A GB1107236 A GB 1107236A GB 5343366 A GB5343366 A GB 5343366A GB 5343366 A GB5343366 A GB 5343366A GB 1107236 A GB1107236 A GB 1107236A
Authority
GB
United Kingdom
Prior art keywords
aldehyde
crotonaldehyde
baking
cured
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5343366A
Inventor
John Frederick Marsh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB5343366A priority Critical patent/GB1107236A/en
Publication of GB1107236A publication Critical patent/GB1107236A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/26Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Paints Or Removers (AREA)

Abstract

Thermosetting resins are prepared by condensing 1-2 moles of an imidazolidin-2-one of the formula <FORM:1107236/C3/1> with 1 mole of an a ,b -unsaturated aldehyde: R3-CH=CH-CHO in an acid medium. R1 and R2 are H or C1-C18 alkyl radicals and R3 is a C1-C18 alkyl radical. As an example N,N1-ethylene urea are condensed with crotonaldehyde in butanol containing hydrochloric acid. The minimum pH of the reactants may be 2 and reaction may take place at 30-100 DEG C. Part (e.g. 5-25 mole per cent) of the unsaturated aldehyde may be replaced by a saturated aldehyde, e.g. lauric aldehyde. The resins of the invention may be blended with a plasticizing (e.g. castor oil modified) alkyd resin to obtain surface coatings which may be cured by baking at an elevated temperature (e.g. at 150 DEG C. for 30 minutes).ALSO:A coating composition comprising, in solution in n-butanol, a mixture of an aminoplast obtained by condensing ethylene urea with crotonaldehyde and an oil-modified alkyd resin is coated onto phosphated steel. The coating is cured by baking at 150 DEG C for 30 minutes.
GB5343366A 1966-11-29 1966-11-29 Thermosetting aminoplast resins Expired GB1107236A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB5343366A GB1107236A (en) 1966-11-29 1966-11-29 Thermosetting aminoplast resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5343366A GB1107236A (en) 1966-11-29 1966-11-29 Thermosetting aminoplast resins

Publications (1)

Publication Number Publication Date
GB1107236A true GB1107236A (en) 1968-03-27

Family

ID=10467790

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5343366A Expired GB1107236A (en) 1966-11-29 1966-11-29 Thermosetting aminoplast resins

Country Status (1)

Country Link
GB (1) GB1107236A (en)

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