GB1107236A - Thermosetting aminoplast resins - Google Patents
Thermosetting aminoplast resinsInfo
- Publication number
- GB1107236A GB1107236A GB5343366A GB5343366A GB1107236A GB 1107236 A GB1107236 A GB 1107236A GB 5343366 A GB5343366 A GB 5343366A GB 5343366 A GB5343366 A GB 5343366A GB 1107236 A GB1107236 A GB 1107236A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aldehyde
- crotonaldehyde
- baking
- cured
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Paints Or Removers (AREA)
Abstract
Thermosetting resins are prepared by condensing 1-2 moles of an imidazolidin-2-one of the formula <FORM:1107236/C3/1> with 1 mole of an a ,b -unsaturated aldehyde: R3-CH=CH-CHO in an acid medium. R1 and R2 are H or C1-C18 alkyl radicals and R3 is a C1-C18 alkyl radical. As an example N,N1-ethylene urea are condensed with crotonaldehyde in butanol containing hydrochloric acid. The minimum pH of the reactants may be 2 and reaction may take place at 30-100 DEG C. Part (e.g. 5-25 mole per cent) of the unsaturated aldehyde may be replaced by a saturated aldehyde, e.g. lauric aldehyde. The resins of the invention may be blended with a plasticizing (e.g. castor oil modified) alkyd resin to obtain surface coatings which may be cured by baking at an elevated temperature (e.g. at 150 DEG C. for 30 minutes).ALSO:A coating composition comprising, in solution in n-butanol, a mixture of an aminoplast obtained by condensing ethylene urea with crotonaldehyde and an oil-modified alkyd resin is coated onto phosphated steel. The coating is cured by baking at 150 DEG C for 30 minutes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5343366A GB1107236A (en) | 1966-11-29 | 1966-11-29 | Thermosetting aminoplast resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5343366A GB1107236A (en) | 1966-11-29 | 1966-11-29 | Thermosetting aminoplast resins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1107236A true GB1107236A (en) | 1968-03-27 |
Family
ID=10467790
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5343366A Expired GB1107236A (en) | 1966-11-29 | 1966-11-29 | Thermosetting aminoplast resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1107236A (en) |
-
1966
- 1966-11-29 GB GB5343366A patent/GB1107236A/en not_active Expired
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