GB1085160A - Stoving lacquers - Google Patents

Stoving lacquers

Info

Publication number
GB1085160A
GB1085160A GB4950765A GB4950765A GB1085160A GB 1085160 A GB1085160 A GB 1085160A GB 4950765 A GB4950765 A GB 4950765A GB 4950765 A GB4950765 A GB 4950765A GB 1085160 A GB1085160 A GB 1085160A
Authority
GB
United Kingdom
Prior art keywords
aminotriazine
butanol
per mol
resin
used per
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4950765A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beck Koller and Company England Ltd
Original Assignee
Beck Koller and Company England Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1965R0039984 external-priority patent/DE1595225B2/en
Priority claimed from DE1965R0039985 external-priority patent/DE1519327B2/en
Application filed by Beck Koller and Company England Ltd filed Critical Beck Koller and Company England Ltd
Publication of GB1085160A publication Critical patent/GB1085160A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40Chemically modified polycondensates
    • C08G12/42Chemically modified polycondensates by etherifying
    • C08G12/424Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds
    • C08G12/425Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds based on triazines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32Modified amine-aldehyde condensates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

A stoving lacquer comprises a compound containing epoxy groups and/or an epoxy resin and a thermosetting butanol etherified amino-triazine-formaldehyde condensation product which is prepared from butanol, HOHO and/or a compound which yields HOHO under reaction conditions (e.g. paraformaldehyde) and an aminotriazine of general formula <FORM:1085160/C3/1> in which R is NH2, a substituted NH2 group, or an alkyl, aryl, acyl or hydroxyl group. The reactants are initially heated either individually or in admixture in the presence of weak acids and are then condensed by further heating during which any water formed is removed by cyclic distillation. 3.5 to 6.5 mols of butanol may be used per mol of aminotriazine. Either n-butanol or a 50:50 mixture of n- and isobutanol may be used. 3.5 to 6 moles of paraformaldehyde may be used per mol. of aminotriazine. From 0.5 to 5 ml of acetic acid may be used per mol of aminotriazine, to provide the weakly acidic medium. The initial reflux stage may last from 30 minutes to 5 hrs. and the cyclic distillation from 2 to 7 hrs. The resin is substantially free of uncombined HCHO. The lacquer may contain from 10-70% by weight of aminotriazine resin and 90-30% by weight of epoxy resin and/or compound containing epoxide groups. A suitable epoxy resin has an epoxy equivalent of 1550-2000 and a Duran softening point of 114-125 DEG C.
GB4950765A 1965-02-12 1965-11-22 Stoving lacquers Expired GB1085160A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DER0039987 1965-02-12
DE1965R0039984 DE1595225B2 (en) 1965-02-24 1965-02-24 PROCESS FOR THE MANUFACTURING OF HEAT-CURABLE, BUTANOL-ETHERIZED EPOXY RESIN COMPATIBLE MELAMINE FORMALDEHYDE RESINS AND THEIR USE
DE1965R0039985 DE1519327B2 (en) 1965-02-24 1965-02-24 HIGHLY RESISTANT STOVE ENAMELS ON THE BASIS OF COMPOUNDS CONTAINING EPOXY GROUPS OR MELAMINE-FORMALDEHYDE RESINS ETHED WITH BUTYL ALCOHOLS

Publications (1)

Publication Number Publication Date
GB1085160A true GB1085160A (en) 1967-09-27

Family

ID=27212172

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4950765A Expired GB1085160A (en) 1965-02-12 1965-11-22 Stoving lacquers

Country Status (1)

Country Link
GB (1) GB1085160A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0001049A1 (en) * 1977-08-23 1979-03-21 Lentia Gesellschaft mit beschränkter Haftung Method for the manufacture of stably storable non-yellowing stoving enamels

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0001049A1 (en) * 1977-08-23 1979-03-21 Lentia Gesellschaft mit beschränkter Haftung Method for the manufacture of stably storable non-yellowing stoving enamels

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