GB1105481A - Improvements relating to surface coatings - Google Patents

Improvements relating to surface coatings

Info

Publication number
GB1105481A
GB1105481A GB20980/63A GB2098063A GB1105481A GB 1105481 A GB1105481 A GB 1105481A GB 20980/63 A GB20980/63 A GB 20980/63A GB 2098063 A GB2098063 A GB 2098063A GB 1105481 A GB1105481 A GB 1105481A
Authority
GB
United Kingdom
Prior art keywords
composition
rubber
polyamine
graft polymer
natural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20980/63A
Inventor
John Liberty Smith
Anthony Geoffrey Marriott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Co Ltd
Original Assignee
Dunlop Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dunlop Co Ltd filed Critical Dunlop Co Ltd
Priority to GB20980/63A priority Critical patent/GB1105481A/en
Priority to US368349A priority patent/US3377194A/en
Priority to FR975773A priority patent/FR1397666A/en
Priority to DE1964D0044526 priority patent/DE1470789B1/en
Priority to BE648384A priority patent/BE648384A/xx
Priority to GB41666/65A priority patent/GB1149246A/en
Priority to US579828A priority patent/US3475197A/en
Priority to FR77982A priority patent/FR91072E/en
Priority to BE687646D priority patent/BE687646A/xx
Publication of GB1105481A publication Critical patent/GB1105481A/en
Priority to MY197031A priority patent/MY7000031A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/58—No clear coat specified
    • B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/58—No clear coat specified
    • B05D7/587—No clear coat specified some layers being coated "wet-on-wet", the others not
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/04—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to rubbers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/904—Artificial leather
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31826—Of natural rubber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31826—Of natural rubber
    • Y10T428/31833—Next to aldehyde or ketone condensation product or addition polymer from unsaturated monomers
    • Y10T428/31837—Including polyene monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31826—Of natural rubber
    • Y10T428/31841—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31884—Regenerated or modified cellulose
    • Y10T428/31891—Where addition polymer is an ester or halide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2041—Two or more non-extruded coatings or impregnations
    • Y10T442/2098—At least two coatings or impregnations of different chemical composition

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

A coating composition comprises a graft polymer of a vinyl monomer and a natural or synthetic rubber. The graft polymer may be formed from a vinyl ester, vinylidene compound, alkyl methacrylate or acrylate, acrylonitrile, acrylamide, vinyl pyridine or styrene and a rubber in the form of a latex or aqueous dispersion, e.g. natural rubber, polybutadiene, or a copolymer of butadiene with styrene, acrylonitrile or methylisopropenyl ketone. The graft polymer may be prepared by polymerization initiated by a benzoyl peroxide/polyamine, tertiary butyl hydroperoxide/polyamine or a cumene hydroperoxide/polyamine, e.g. tetraethylene pentamine or ethylene diamine, system, or ionizing radiation. In Example II the graft polymer is produced in the presence of casein.ALSO:A coating for a surface consisting at least in part of a natural or synthetic rubber composition comprises an interlayer of a composition of a graft polymer of a vinyl monomer and a natural or synthetic rubber and an outer layer of an aqueous polymeric composition. The outer layer may be an acrylic polymer composition or a nitrocellulose composition. The graft polymer may be formed from a vinyl ester, vinylidene compound, alkyl methacrylate or acrylate, acrylonitrile, acrylamide, vinyl pyridine or styrene, and a rubber in the form of a latex or an aqueous dispersion, e.g. natural rubber, polybutadiene or a copolymer of butadiene with styrene, acrylonitrile or methylisopropenyl ketone. The acrylic polymer composition may comprise a polymer of methyl methacrylate with one or more different monomers, e.g. ethyl acrylate, or a terpolymer of methyl methacrylate, ethyl acrylate, and butyl hexyl acrylate or methacrylic acid. The surface may be that of a leather-like sheet material or a textile web such as a consolidated mat of interpenetrated crimped continuous fibres, e.g. nylon, which may have a layer of nonwoven staple fibres, e.g. of polypropylene, needled on to at least one surface, or a woven fabric bonded to one surface and a surface layer of resinous or elastomeric composition on the surface remote from the mat, bonded or reinforced with natural or synthetic rubber composition, e.g. polyurethane rubber, butyl rubber, polychloroprene, and copolymers of butadiene with styrene or acrylonitrile. The graft polymer may be prepared by polymerisation initiated by a benzoyl peroxide/polyamine, a tertiary butyl hydroperoxide/polyamine system, a cumene hydroperoxide/polyamine, e.g. tetraethylene pentamine or ethylene diamine, system, or ionizing radiation.
GB20980/63A 1963-05-25 1963-05-25 Improvements relating to surface coatings Expired GB1105481A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB20980/63A GB1105481A (en) 1963-05-25 1963-05-25 Improvements relating to surface coatings
US368349A US3377194A (en) 1963-05-25 1964-05-18 Coatings for surfaces consisting at least in part of a rubber composition
FR975773A FR1397666A (en) 1963-05-25 1964-05-25 Improvements to leather-like surface coverings formed, at least in part, of rubber
DE1964D0044526 DE1470789B1 (en) 1963-05-25 1964-05-25 Process for the production of laminated bodies
BE648384A BE648384A (en) 1963-05-25 1964-05-25
GB41666/65A GB1149246A (en) 1963-05-25 1965-09-30 Method for coating surfaces
US579828A US3475197A (en) 1963-05-25 1966-09-16 Method for coating surfaces comprising a rubber composition
FR77982A FR91072E (en) 1963-05-25 1966-09-28 Improvements to leather-like surface coverings formed, at least in part, of rubber
BE687646D BE687646A (en) 1963-05-25 1966-09-30
MY197031A MY7000031A (en) 1963-05-25 1970-12-31 Improvems relating to surface coatings

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB20980/63A GB1105481A (en) 1963-05-25 1963-05-25 Improvements relating to surface coatings
GB41666/65A GB1149246A (en) 1963-05-25 1965-09-30 Method for coating surfaces

Publications (1)

Publication Number Publication Date
GB1105481A true GB1105481A (en) 1968-03-06

Family

ID=61628002

Family Applications (2)

Application Number Title Priority Date Filing Date
GB20980/63A Expired GB1105481A (en) 1963-05-25 1963-05-25 Improvements relating to surface coatings
GB41666/65A Expired GB1149246A (en) 1963-05-25 1965-09-30 Method for coating surfaces

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB41666/65A Expired GB1149246A (en) 1963-05-25 1965-09-30 Method for coating surfaces

Country Status (6)

Country Link
US (2) US3377194A (en)
BE (2) BE648384A (en)
DE (1) DE1470789B1 (en)
FR (1) FR1397666A (en)
GB (2) GB1105481A (en)
MY (1) MY7000031A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1105481A (en) * 1963-05-25 1968-03-06 Dunlop Co Ltd Improvements relating to surface coatings
JP2582771B2 (en) * 1987-04-07 1997-02-19 三井石油化学工業株式会社 Thermoplastic elastomer laminated leather
US5240767A (en) * 1990-02-10 1993-08-31 Dynic Corporation Nonwoven fabrics for printing
US5458953A (en) * 1991-09-12 1995-10-17 Mannington Mills, Inc. Resilient floor covering and method of making same

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3125462A (en) * 1964-03-17 Textile fabrics treated with ethylene-
US2422550A (en) * 1942-10-20 1947-06-17 Du Pont Polymerization of vinyl compounds with rubber
US2697048A (en) * 1952-06-11 1954-12-14 Kendall & Co Flexible leatherlike sheet material
DE975459C (en) * 1954-01-19 1961-11-30 Degussa Process for the production of an artificial leather that is dry to the touch
US2806824A (en) * 1954-02-03 1957-09-17 Goodrich Co B F Composition of matter for making golf ball covers
DE1073197B (en) * 1955-06-28 1960-01-14
BE552579A (en) * 1955-11-15
US2978785A (en) * 1956-03-05 1961-04-11 Celanese Corp Bonded batting, or non-woven fabric
US2973284A (en) * 1957-04-30 1961-02-28 Goodrich Co B F Leather-like material
NL251498A (en) * 1959-05-13 1900-01-01
US3026293A (en) * 1959-08-06 1962-03-20 Eastman Kodak Co Acrylamidic graft copolymers and their preparation
GB911211A (en) * 1960-07-19 1962-11-21 Du Pont Pyroxylin-coated sheet material
US3143522A (en) * 1961-05-19 1964-08-04 Firestone Tire & Rubber Co Method of grafting styrene onto butadiene-styrene polymer
GB1105481A (en) * 1963-05-25 1968-03-06 Dunlop Co Ltd Improvements relating to surface coatings

Also Published As

Publication number Publication date
US3377194A (en) 1968-04-09
BE648384A (en) 1964-09-16
BE687646A (en) 1967-03-01
GB1149246A (en) 1969-04-16
MY7000031A (en) 1970-12-31
US3475197A (en) 1969-10-28
DE1470789B1 (en) 1970-07-09
FR1397666A (en) 1965-04-30

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