GB1103284A - New copolymers and cosmetics applications thereof - Google Patents

New copolymers and cosmetics applications thereof

Info

Publication number
GB1103284A
GB1103284A GB867866A GB867866A GB1103284A GB 1103284 A GB1103284 A GB 1103284A GB 867866 A GB867866 A GB 867866A GB 867866 A GB867866 A GB 867866A GB 1103284 A GB1103284 A GB 1103284A
Authority
GB
United Kingdom
Prior art keywords
methyl
butyl
formula
isopropyl
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB867866A
Inventor
Andre Viout
Regine Pasero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7787A external-priority patent/FR1472926A/en
Application filed by LOreal SA filed Critical LOreal SA
Publication of GB1103284A publication Critical patent/GB1103284A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention comprises copolymers of (a) vinyl acetate, (b) crotonic acid and (c) at least one acrylic or methacrylic ester of the formula <FORM:1103284/C3/1> where R represents hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of formula <FORM:1103284/C3/2> where R11 is ethyl, isopropyl, butyl, isobutyl or chloroethyl, and salts of these copolymers. The copolymers preferably contain 75 to 85% by weight of vinyl acetate, 5 to 15% by weight of crotonic acid and 5 to 15% by weight of component (c). Suitable salts include those with ammonia, monoethanolamine, monoethylamine, dimethylamine, diethylamine, aminoethylamine, ethanolamine, monoisopropanolamine, 2 - amino - 2 - methyl - propanol - 1, or 2 - amino - 2 - methyl - propanediol - 1,3. Solutions of the salts, preferably in the form of aerosol lacquers, may be used as cosmetics. The aerosol lacquer may contain alcohol and a propellant gas preferably a halogenated hydrocarbon.ALSO:Aerosol compositions comprise solutions of salts of copolymers of (a) vinyl acetate; (b) crotonic acid; and (c) at least one acrylic or methacrylic ester of the formula <FORM:1103284/C4-C5/1> where R is hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of the formula CH2 = CH-O-R11, where R11 is ethyl, isopropyl butyl, isobutyl or chloroethyl. The aerosol lacquers are used as cosmetic products and also contain alcohols and propellant gas. Preferred alcohols are anhydrous ethanol or isopropanol and preferred propellant gases are halogenated hydrocarbons. In examples fluorinated hydrocarbons, butyl phthalate, ethyl alcohol, isopropyl palmitate, triethylene glycol, water and isopropyl myristate are used.ALSO:Hair lacquers and lotions comprise solutions of salts of copolymers of (a) vinyl acetate, (b) crotonic acid and (c) at least one acrylic or methacrylic ester of the formula <FORM:1103284/A5-A6/1> where R is hydrogen or methyl and R1 is methyl, butyl, ethylhexyl, butoxyethyl or lauryl or alkyl vinyl ether of the formula CH2=CH-O-R11 where R11 is ethyl, isopropyl, butyl, isobutyl or chloroethyl. The products are preferably in the form of aerosol lacquers which preferably include alcohols and propellant gases. Preferred alcohols are anhydrous ethanol or isopropanol and preferred propellant gases are halogenated hydrocarbons. In Examples fluorinated hydrocarbons, butyl pthalate, ethyl alcohol, isopropyl palmitate, triethylene glycol, water and isopropyl myristate are used. Conventional cosmetics additives, e.g. plastisizers, perfumes and dyestuffs may also be incorporated.
GB867866A 1965-03-03 1966-02-28 New copolymers and cosmetics applications thereof Expired GB1103284A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7787A FR1472926A (en) 1965-03-03 1965-03-03 New copolymers and applications of these copolymers to cosmetics
FR47441A FR92221E (en) 1965-03-03 1966-01-27 New copolymers and applications of these copolymers to cosmetics

Publications (1)

Publication Number Publication Date
GB1103284A true GB1103284A (en) 1968-02-14

Family

ID=26162272

Family Applications (1)

Application Number Title Priority Date Filing Date
GB867866A Expired GB1103284A (en) 1965-03-03 1966-02-28 New copolymers and cosmetics applications thereof

Country Status (6)

Country Link
BE (1) BE677267A (en)
CH (2) CH466504A (en)
DE (1) DE1645082B2 (en)
FR (1) FR92221E (en)
GB (1) GB1103284A (en)
NL (1) NL6602661A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2029696A1 (en) * 1969-01-30 1970-10-23 Chandor Sa
GB2006233A (en) * 1977-10-20 1979-05-02 Wacker Chemie Gmbh Aqueous vinyl acetate copolymer dispersions for use as binders for non-woven materials
CN106046236A (en) * 2016-08-16 2016-10-26 天津辛德玛悬浮剂有限公司 High-alcoholysis-degree polyvinyl alcohol being hydrolysable at room temperature and preparation method thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1001790A (en) * 1970-12-14 1976-12-14 Daniel J. Kay Aerosol compositions
US3946035A (en) * 1972-06-29 1976-03-23 L'oreal Anti-inflammatory polymers, pharmaceutical compositions containing the same and process for producing said polymers
DE2453655C2 (en) * 1974-11-12 1982-09-16 Wacker-Chemie GmbH, 8000 München Copolymers of vinyl acetate, maleic acid diesters of primary, straight-chain, aliphatic alcohols with 8 and / or 10 carbon atoms, unsaturated esters with a hydrophilic group and crotonic acid
DE69322062T2 (en) * 1992-07-16 1999-07-15 National Starch And Chemical Investment Holding Corp., Wilmington, Del. EMULSION POLYMERS AND THEIR USE IN HAIR-TENSIONING PREPARATIONS
US5620683A (en) * 1995-09-13 1997-04-15 National Starch And Chemical Investment Holding Corporation Aqueous, acrylic hair fixatives and methods of making same
US5686062A (en) * 1995-12-29 1997-11-11 National Starch And Chemical Investment Holding Corporation Acrylic hair fixatives and methods of making same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2029696A1 (en) * 1969-01-30 1970-10-23 Chandor Sa
GB2006233A (en) * 1977-10-20 1979-05-02 Wacker Chemie Gmbh Aqueous vinyl acetate copolymer dispersions for use as binders for non-woven materials
CN106046236A (en) * 2016-08-16 2016-10-26 天津辛德玛悬浮剂有限公司 High-alcoholysis-degree polyvinyl alcohol being hydrolysable at room temperature and preparation method thereof

Also Published As

Publication number Publication date
CH461109A (en) 1968-08-15
BE677267A (en) 1966-09-02
FR92221E (en) 1968-10-11
DE1645082A1 (en) 1970-07-16
NL6602661A (en) 1966-09-05
DE1645082B2 (en) 1973-04-12
CH466504A (en) 1968-12-15

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