GB1095849A - Process for the production of cyclobutane-1,2-dinitrile - Google Patents
Process for the production of cyclobutane-1,2-dinitrileInfo
- Publication number
- GB1095849A GB1095849A GB54181/66A GB5418166A GB1095849A GB 1095849 A GB1095849 A GB 1095849A GB 54181/66 A GB54181/66 A GB 54181/66A GB 5418166 A GB5418166 A GB 5418166A GB 1095849 A GB1095849 A GB 1095849A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dinitrile
- cyclobutane
- benzaldehyde
- photo
- pyrone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cyclobutane-1,2-dinitrile is produced by irradiating acrylonitrile, with or without the addition of a polymerization inhibitor or a neutral solvent, with visible light and/or U.V. light and separating the cyclobutane-1,2-dinitrile from the resulting mixture there being added to the acrylonitrile as photo-sensitizer benzaldehyde or a derivative thereof, or g -pyrone or its homologues or benzo derivatives. The photo-sensitizer may be a benzaldehyde of the general formula <FORM:1095849/C2/1> in which R1 and R2 are the same or different and each represents hydrogen or a halogen or an alkyl, aryl, cyano or ester group. Preferred photo-sensitizers are p-tolualdehyde, p - bromo-benzaldehyde, 2,6 - dimethyl - g - pyrone and xanthone.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB54181/66A GB1095849A (en) | 1966-12-02 | 1966-12-02 | Process for the production of cyclobutane-1,2-dinitrile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB54181/66A GB1095849A (en) | 1966-12-02 | 1966-12-02 | Process for the production of cyclobutane-1,2-dinitrile |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1095849A true GB1095849A (en) | 1967-12-20 |
Family
ID=10470185
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB54181/66A Expired GB1095849A (en) | 1966-12-02 | 1966-12-02 | Process for the production of cyclobutane-1,2-dinitrile |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1095849A (en) |
-
1966
- 1966-12-02 GB GB54181/66A patent/GB1095849A/en not_active Expired
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