GB1093917A - Removal of non-sugars from syrups comprising sugars - Google Patents
Removal of non-sugars from syrups comprising sugarsInfo
- Publication number
- GB1093917A GB1093917A GB3534165A GB3534165A GB1093917A GB 1093917 A GB1093917 A GB 1093917A GB 3534165 A GB3534165 A GB 3534165A GB 3534165 A GB3534165 A GB 3534165A GB 1093917 A GB1093917 A GB 1093917A
- Authority
- GB
- United Kingdom
- Prior art keywords
- precipitated
- flocculated
- syrups
- ions
- sugar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/005—Purification of sugar juices using chemicals not provided for in groups C13B20/02 - C13B20/14
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
Sedimental impurities and divalent metal cation impurities comprising both Ca and Mg are removed from sugar-cane syrups, e.g. low-grade mill syrups, by a process comprising the following steps:- (1) lowering the pH of the syrup to below 4, e.g. to about 3, by the addition of a selected acid capable of forming with Ca ions a salt insoluble in sugar solutions, (2) removing suspended solids comprising flocculated and precipitated material, (3) in the presence of orthophosphate and ammonium ions raising the pH to about 7 by the addition of a suitable base and (4) removing precipitated material. In step (2) sedimentable material is flocculated and calcium impurity is precipitated and in step (3) magnesium impurity is precipitated as magnesium ammonium phosphate. The removal of the flocculated and precipitated material from step (2) may be effected by a pressure filter or a continuously operating centrifuge suitable acids for use in step (1) are sulphuric and orthophosphoric acids or a mixture of sulphuric acid with a phosphate salt (e.g. superphosphate) may be used. If phosphoric acid has not been used in step (1) there must be a subsequent addition of phosphate ions, suitably after step (2). The base added in step (3) may be ammonium hydroxide or (if the Mg content is not high) a mixture of sodium carbonate and NH4OH. The purified syrup from step (4) may be further purified by passage through an ion exchange column.ALSO:Sedimental impurities and divalent metal cation impurities comprising both Ca and Mg are removed from sugar cane syrups, e.g. lowgrade mill syrups or low-grade invert syrups derived therefrom, by a process comprising the following steps:-(1) lowering the pH of the syrup to below 4, e.g. to about 3, by the addition of a selected acid capable of forming with Ca ions a salt insoluble in sugar solutions, (2) removing suspended solids comprising flocculated and precipitated material, (3) in the presence of orthophosphate and ammonium ions raising the pH to about 7 by the addition of a suitable base and (4) removing precipitated material. In step (2) sedimentable material is flocculated and calcium impurity is precipitated and in step (3) magnesium impurity is precipitated as magnesium ammonium phosphate. The removal of the flocculated and precipitated material from step (2) may be effected by a pressure filter or a continuously operating centrifuge. Suitable acids for use in step (1) are sulphuric and orthophosphoric acids or a mixture of sulphuric acid with a phosphate salt (e.g. superphosphate) may be used. If phosphoric acid has not been used in step (1) there must be a subsequent addition of phosphate ions, suitably after step (2). The base added in step (3) may be ammonium hydroxide or (if the Mg content is not high) a mixture of sodium carbonate and NH4OH. The sugar content of the treated syrup may be sucrose or invert sugar and inversion can be effected by heating the mixture in step (1) in a non-corrodible container. Alternatively, the inversion may be performed by invertase catalysis at a pH between 5 and 7, this inversion being conveniently carried out before step (1) at 60-65 DEG C. in a holding vessel fabricated of inexpensive material, e.g. mild steel. The purified syrup from step (4) may be further purified by passage through an ion-exchange column.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU48370/64A AU292702B2 (en) | 1964-08-20 | Removal of non - sugars from syrups comprising sugars | |
AU5422965 | 1965-01-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1093917A true GB1093917A (en) | 1967-12-06 |
Family
ID=25628220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3534165A Expired GB1093917A (en) | 1964-08-20 | 1965-08-18 | Removal of non-sugars from syrups comprising sugars |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1567250A1 (en) |
GB (1) | GB1093917A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2498787A4 (en) * | 2009-11-11 | 2015-07-29 | Carbo Ua Ltd | Compositions and processes for sugar treatment |
-
1965
- 1965-08-11 DE DE19651567250 patent/DE1567250A1/en active Pending
- 1965-08-18 GB GB3534165A patent/GB1093917A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2498787A4 (en) * | 2009-11-11 | 2015-07-29 | Carbo Ua Ltd | Compositions and processes for sugar treatment |
Also Published As
Publication number | Publication date |
---|---|
DE1567250A1 (en) | 1971-08-05 |
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