GB1093804A - Method for preparing expandable thermoplastic polymer particles containing a volatileluid foaming agent symmetrically encapsulated therein - Google Patents
Method for preparing expandable thermoplastic polymer particles containing a volatileluid foaming agent symmetrically encapsulated thereinInfo
- Publication number
- GB1093804A GB1093804A GB37866A GB37866A GB1093804A GB 1093804 A GB1093804 A GB 1093804A GB 37866 A GB37866 A GB 37866A GB 37866 A GB37866 A GB 37866A GB 1093804 A GB1093804 A GB 1093804A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monomer
- soluble
- foaming agent
- sodium
- activator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004088 foaming agent Substances 0.000 title abstract 3
- 239000002245 particle Substances 0.000 title abstract 2
- 229920001169 thermoplastic Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000012190 activator Substances 0.000 abstract 3
- 239000003638 chemical reducing agent Substances 0.000 abstract 3
- 239000002609 medium Substances 0.000 abstract 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 abstract 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 abstract 1
- ISRGONDNXBCDBM-UHFFFAOYSA-N 2-chlorostyrene Chemical compound ClC1=CC=CC=C1C=C ISRGONDNXBCDBM-UHFFFAOYSA-N 0.000 abstract 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004285 Potassium sulphite Substances 0.000 abstract 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 abstract 1
- 125000005595 acetylacetonate group Chemical group 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- LVGQIQHJMRUCRM-UHFFFAOYSA-L calcium bisulfite Chemical compound [Ca+2].OS([O-])=O.OS([O-])=O LVGQIQHJMRUCRM-UHFFFAOYSA-L 0.000 abstract 1
- 235000010260 calcium hydrogen sulphite Nutrition 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 229960002887 deanol Drugs 0.000 abstract 1
- 239000012972 dimethylethanolamine Substances 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910001448 ferrous ion Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- VLAGSAGYAIGJSU-UHFFFAOYSA-N hexanoyl hexaneperoxoate Chemical class CCCCCC(=O)OOC(=O)CCCCC VLAGSAGYAIGJSU-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 125000005474 octanoate group Chemical group 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 abstract 1
- 235000019252 potassium sulphite Nutrition 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 abstract 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 abstract 1
- 235000010262 sodium metabisulphite Nutrition 0.000 abstract 1
- 239000004296 sodium metabisulphite Substances 0.000 abstract 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42484265A | 1965-01-11 | 1965-01-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1093804A true GB1093804A (en) | 1967-12-06 |
Family
ID=23684092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB37866A Expired GB1093804A (en) | 1965-01-11 | 1966-01-04 | Method for preparing expandable thermoplastic polymer particles containing a volatileluid foaming agent symmetrically encapsulated therein |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE674949A (enExample) |
| BR (1) | BR6676354D0 (enExample) |
| DE (1) | DE1570485A1 (enExample) |
| DK (1) | DK121976B (enExample) |
| GB (1) | GB1093804A (enExample) |
| NL (1) | NL148080B (enExample) |
| NO (1) | NO124541B (enExample) |
| SE (1) | SE345464B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9493625B2 (en) | 2013-09-26 | 2016-11-15 | Sekisui Chemical Co., Ltd. | Thermally expanding microcapsules |
-
1965
- 1965-12-02 DE DE19651570485 patent/DE1570485A1/de active Pending
-
1966
- 1966-01-04 GB GB37866A patent/GB1093804A/en not_active Expired
- 1966-01-10 NL NL6600284A patent/NL148080B/xx unknown
- 1966-01-10 SE SE25766A patent/SE345464B/xx unknown
- 1966-01-10 NO NO16118866A patent/NO124541B/no unknown
- 1966-01-11 BR BR17635466A patent/BR6676354D0/pt unknown
- 1966-01-11 DK DK13766A patent/DK121976B/da unknown
- 1966-01-11 BE BE674949D patent/BE674949A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9493625B2 (en) | 2013-09-26 | 2016-11-15 | Sekisui Chemical Co., Ltd. | Thermally expanding microcapsules |
Also Published As
| Publication number | Publication date |
|---|---|
| BR6676354D0 (pt) | 1973-12-26 |
| NL148080B (nl) | 1975-12-15 |
| SE345464B (enExample) | 1972-05-29 |
| DK121976B (da) | 1971-12-27 |
| NO124541B (enExample) | 1972-05-02 |
| BE674949A (enExample) | 1966-07-11 |
| DE1570485A1 (de) | 1969-12-11 |
| NL6600284A (enExample) | 1966-07-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1044680A (en) | Expandable thermoplastic polymer particles containing volatile fluid foaming agent and method of making the same | |
| KR920018122A (ko) | 발포 아크릴계 중합체 조성물 | |
| EP0017086A1 (en) | Expandable thermoplastic polymer beads and process for their production | |
| GB1101984A (en) | Polymer dispersions | |
| GB1091449A (en) | A process for the production of thermoplastic moulding compositions | |
| GB1036744A (en) | Method for manufacture of acrylonitrile-butadiene-aromatic vinyl resinous compositions | |
| US3324052A (en) | Production of suspension polymers | |
| GB1121116A (en) | Transparent graft interpolymers and their production | |
| GB1093804A (en) | Method for preparing expandable thermoplastic polymer particles containing a volatileluid foaming agent symmetrically encapsulated therein | |
| US3505253A (en) | Expandable alkenyl aromatic polymers containing incorporated expandable alkenyl aromatic polymers and polysiloxane | |
| GB1389115A (en) | Graft copolymer and composition thereof | |
| US3635852A (en) | Process of making a general purpose expandable alkenyl aromatic polymer containing di-alkyl polysiloxane internally | |
| GB1104926A (en) | Production of foamable resins | |
| KR910007990A (ko) | 그라프트제가 혼입된 고무-보강 중합체 조성물 | |
| GB817656A (en) | Method and agent for making cellular vinyl aromatic polymers | |
| GB1270632A (en) | Preparation of organic polymer particles and aqueous dispersions thereof | |
| JPS5611929A (en) | Foaming styrene resin particle | |
| GB820930A (en) | Improvements in or relating to polymeric material | |
| JPS5611930A (en) | Foaming styrene resin particle | |
| GB1297105A (enExample) | ||
| US3349046A (en) | Microporous plastic sheet material and method of making same | |
| GB847602A (en) | Process of polymerisation | |
| GB1063422A (en) | Process for the production of polyvinyl chloride compositions having high impact strength and compositions obtained thereby | |
| GB801399A (en) | Method of enlarging solid cross-linked polymer bodies | |
| JPS55123631A (en) | Production of foaming thermoplastic resin particle |