GB1092492A - Process for the preparation of tertiary phosphines - Google Patents
Process for the preparation of tertiary phosphinesInfo
- Publication number
- GB1092492A GB1092492A GB25273/66A GB2527366A GB1092492A GB 1092492 A GB1092492 A GB 1092492A GB 25273/66 A GB25273/66 A GB 25273/66A GB 2527366 A GB2527366 A GB 2527366A GB 1092492 A GB1092492 A GB 1092492A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphine
- aliphatic
- carried out
- reaction
- tertiary phosphines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003003 phosphines Chemical group 0.000 title abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229940100198 alkylating agent Drugs 0.000 abstract 3
- 239000002168 alkylating agent Substances 0.000 abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 abstract 2
- -1 from NaI Chemical compound 0.000 abstract 2
- 101100305864 Alteromonas mediterranea (strain DSM 17117 / CIP 110805 / LMG 28347 / Deep ecotype) rph2 gene Proteins 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 101100135363 Yarrowia lipolytica (strain CLIB 122 / E 150) RIM101 gene Proteins 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010494 dissociation reaction Methods 0.000 abstract 1
- 230000005593 dissociations Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 1
- 229940006461 iodide ion Drugs 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229940050176 methyl chloride Drugs 0.000 abstract 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5407—Acyclic saturated phosphonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US461669A US3389183A (en) | 1965-06-07 | 1965-06-07 | Process for the preparation of tertiary phosphines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1092492A true GB1092492A (en) | 1967-11-29 |
Family
ID=42830244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25273/66A Expired GB1092492A (en) | 1965-06-07 | 1966-06-07 | Process for the preparation of tertiary phosphines |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3389183A (en:Method) |
| BE (1) | BE682132A (en:Method) |
| DE (1) | DE1257143B (en:Method) |
| FR (1) | FR1482434A (en:Method) |
| GB (1) | GB1092492A (en:Method) |
| NL (1) | NL6607892A (en:Method) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3459808A (en) * | 1966-06-24 | 1969-08-05 | Procter & Gamble | Process for the preparation of phosphonium salts and phosphine oxides starting with aluminum trialkyl |
| DE2407461C2 (de) * | 1974-02-16 | 1983-03-03 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Alkylphosphinen |
| CH616688A5 (en:Method) * | 1974-12-05 | 1980-04-15 | Hoechst Ag | |
| FR2472575B1 (fr) * | 1979-12-28 | 1985-10-04 | Poudres & Explosifs Ste Nale | Procede de synthese d'oxydes de phosphines tertiaires et nouveaux oxydes de phosphines tertiaires |
| CA2054546A1 (en) * | 1991-10-30 | 1993-05-01 | Colleen E. Micklethwaite | Method of preparing a phosphine compound |
| WO2007016264A2 (en) * | 2005-07-29 | 2007-02-08 | Trustees Of Dartmouth College | Method for enantioselective synthesis of phosphorus-stereogenic phosphines |
-
1965
- 1965-06-07 US US461669A patent/US3389183A/en not_active Expired - Lifetime
-
1966
- 1966-06-04 DE DEP39621A patent/DE1257143B/de active Pending
- 1966-06-06 FR FR64335A patent/FR1482434A/fr not_active Expired
- 1966-06-06 BE BE682132D patent/BE682132A/xx unknown
- 1966-06-07 GB GB25273/66A patent/GB1092492A/en not_active Expired
- 1966-06-07 NL NL6607892A patent/NL6607892A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE682132A (en:Method) | 1966-12-06 |
| US3389183A (en) | 1968-06-18 |
| DE1257143B (de) | 1967-12-28 |
| NL6607892A (en:Method) | 1966-12-08 |
| FR1482434A (fr) | 1967-05-26 |
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