GB1090753A - Improvements in or relating to anaerobic curing compositions - Google Patents

Improvements in or relating to anaerobic curing compositions

Info

Publication number
GB1090753A
GB1090753A GB26798/63A GB2679863A GB1090753A GB 1090753 A GB1090753 A GB 1090753A GB 26798/63 A GB26798/63 A GB 26798/63A GB 2679863 A GB2679863 A GB 2679863A GB 1090753 A GB1090753 A GB 1090753A
Authority
GB
United Kingdom
Prior art keywords
glycol
butyl
peroxide
dimethyl
compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26798/63A
Inventor
Peter Bosworth
Brian Vyse
John Swire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion UK Ltd
Original Assignee
Borden Chemical UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borden Chemical UK Ltd filed Critical Borden Chemical UK Ltd
Priority to GB26798/63A priority Critical patent/GB1090753A/en
Priority to ES0301618A priority patent/ES301618A1/en
Priority to FR980566A priority patent/FR1404000A/en
Priority to BE650086A priority patent/BE650086A/xx
Priority to CH875264A priority patent/CH422331A/en
Priority to NL6407641A priority patent/NL6407641A/xx
Priority to GB3189264A priority patent/GB1094853A/en
Priority to CH1082165A priority patent/CH440694A/en
Priority to FR27035A priority patent/FR92901E/en
Priority to BE667954D priority patent/BE667954A/xx
Priority to NL6510189A priority patent/NL6510189A/xx
Priority to GB163/66A priority patent/GB1161661A/en
Priority to FR89465A priority patent/FR93063E/en
Priority to BE692031D priority patent/BE692031A/xx
Priority to NL6700089A priority patent/NL6700089A/xx
Priority to BE692865D priority patent/BE692865A/fr
Publication of GB1090753A publication Critical patent/GB1090753A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A composition having anaerobic curing properties comprises a monomer (or a partial polymer thereof) of the formula <FORM:1090753/C3/1> wherein R is -H, -CH3, -C2H5, -CH2OH or <FORM:1090753/C3/2> R1 is -H, -Cl, -CH3 or -C2H5; R11 is -H, -OH or <FORM:1090753/C3/3> x and y are integers, each equal to at least 1 and n is 0 or 1, an organic peroxide (other than a hydroperoxide) having a half-life (as defined) greater than 5 hours at 100 DEG C. and a tertiary amine. Monomers specified are diacrylates and dimethacrylates of diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, diglycerol and di-(pentamethylene) glycol, and the tetramethacrylate of diglycerol; esters of monoalkylene glycols may also be used and also glycol esters of acids such as ethacrylic or chloroacrylic acid. Suitable peroxides include 2,5 - dimethyl - 2,5 - di - (t - butyl peroxy)-hexane, di-t-butyl peroxide, dihexylene glycol proxide, t-butyl-cumyl peroxide, methyl isobutyl ketone peroxide, t-butyl peracetate and t-butyl perbenzoate. Tertiary amines specified are N,N - dimethyl - p - toluidine, N,N - dimethylaniline, tri-n-butylamine, triethylamine and 2-diethylamino-ethanol. Other components may be included in the compositions, e.g. plasticizer solvents for the peroxides such as dimethyl phthalate; thickening agents such as polystyrene, polymethyl methacrylate, poly-n-butyl methacrylate, polyester resins; fillers such as silica, montmorillonite clay, bentonite; pigments and dyestuffs such as anthraquinone dyestuffs; traces of catalytic metals, such as Fe, Co, Mn; inhibitors such as hydroquinone. The compositions are suitable for bonding metal surfaces, particularly in systems such as nuts and bolts.
GB26798/63A 1963-07-05 1963-07-05 Improvements in or relating to anaerobic curing compositions Expired GB1090753A (en)

Priority Applications (16)

Application Number Priority Date Filing Date Title
GB26798/63A GB1090753A (en) 1963-07-05 1963-07-05 Improvements in or relating to anaerobic curing compositions
ES0301618A ES301618A1 (en) 1963-07-05 1964-07-02 Procedure for joining surfaces, especially metallic. (Machine-translation by Google Translate, not legally binding)
FR980566A FR1404000A (en) 1963-07-05 1964-07-03 Composition curing under anaerobic conditions
BE650086A BE650086A (en) 1963-07-05 1964-07-03
CH875264A CH422331A (en) 1963-07-05 1964-07-03 Composition curing in the absence of air
NL6407641A NL6407641A (en) 1963-07-05 1964-07-06
GB3189264A GB1094853A (en) 1963-07-05 1964-08-05 Improvements in or relating to compositions curing rapidly under anaerobic conditions
CH1082165A CH440694A (en) 1963-07-05 1965-08-02 Sticky composition
FR27035A FR92901E (en) 1963-07-05 1965-08-03 Composition curing under anaerobic conditions.
BE667954D BE667954A (en) 1963-07-05 1965-08-05
NL6510189A NL6510189A (en) 1963-07-05 1965-08-05
GB163/66A GB1161661A (en) 1963-07-05 1966-01-03 Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions
FR89465A FR93063E (en) 1963-07-05 1966-12-30 Composition curing under anaerobic conditions.
BE692031D BE692031A (en) 1963-07-05 1966-12-30
NL6700089A NL6700089A (en) 1963-07-05 1967-01-03
BE692865D BE692865A (en) 1963-07-05 1967-01-19

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB26798/63A GB1090753A (en) 1963-07-05 1963-07-05 Improvements in or relating to anaerobic curing compositions

Publications (1)

Publication Number Publication Date
GB1090753A true GB1090753A (en) 1967-11-15

Family

ID=10249396

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26798/63A Expired GB1090753A (en) 1963-07-05 1963-07-05 Improvements in or relating to anaerobic curing compositions

Country Status (6)

Country Link
BE (1) BE650086A (en)
CH (1) CH422331A (en)
ES (1) ES301618A1 (en)
FR (1) FR1404000A (en)
GB (1) GB1090753A (en)
NL (1) NL6407641A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2711748A1 (en) * 1977-03-17 1978-09-21 Bostik Gmbh ANAEROBICLY CURING ADHESIVE COMPOUND AND METHOD OF JOINING SURFACES USING THIS ADHESIVE COMPOUND

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2338598T3 (en) * 1997-07-03 2010-05-10 Henkel Loctite Corporation ANAEROBIC ADHESIVE COMPOSITIONS OF HIGH TEMPERATURE CONTROLLED RESISTANCE IN NORMAL ENVIRONMENTAL CONDITIONS.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2711748A1 (en) * 1977-03-17 1978-09-21 Bostik Gmbh ANAEROBICLY CURING ADHESIVE COMPOUND AND METHOD OF JOINING SURFACES USING THIS ADHESIVE COMPOUND

Also Published As

Publication number Publication date
ES301618A1 (en) 1965-01-16
FR1404000A (en) 1965-06-25
CH422331A (en) 1966-10-15
NL6407641A (en) 1965-01-06
BE650086A (en) 1965-01-04

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