GB1087337A - Alkylbenzene sulphonate detergent compositions - Google Patents
Alkylbenzene sulphonate detergent compositionsInfo
- Publication number
- GB1087337A GB1087337A GB10707/65A GB1070765A GB1087337A GB 1087337 A GB1087337 A GB 1087337A GB 10707/65 A GB10707/65 A GB 10707/65A GB 1070765 A GB1070765 A GB 1070765A GB 1087337 A GB1087337 A GB 1087337A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenylalkanes
- sulphonates
- chains
- alkylbenzene
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A detergent composition comprises a mixture of alkylbenzenesulphonates [e.g. of Li, Na, K, NH3, Ca, Mg, NH2C2H4OH or N(C2 H4OH)3] in which the alkylbenzene portion has an average mol. wt. 250-270, the alkyl groups are linear and contain at least 85% C12- 14 and at least 10% each C12, C13 and C14 chains, the sulphonates having at least 37% 5-(or higher) phenylalkanes and at most 27% 2-phenylalkanes. Other ingredients specified are Na2SO4, Na2CO3, K2CO3, Na4P2O7, Na3PO4, Na5P3O10, K5\P3O10, (NaPO3)6, Na- and K-silicates (e.g. Na2O + 1-3 SiO2), Nacarboxymethylcellulose, persulphates, perborates, percarbonates, lauric or coconut diethanolamide, monoethanolamide, isopropanolamide and their oxyethylated derivatives, lauryl and cetyl alcohols, dodecyldimethylamine oxide, Na- and K-xylene- and toluene-sulphonates, C8- 20 alkyl sulphates and sulphonates, sulphated alkylphenol- and alkanol-ethylene oxide condensates, polyethylene glycol ethers and esters, polyvinyl alcohol, Na salt of 85:15 tallow-coconut fatty acids, silica, trichlorocyanuric acid, chlorinated Na3PO4 and oxalic acid. A suitable starting material is an unbranched C11- 15 paraffin mixture, containing 34% C12, 43% C13 and 17% C14, prepared by selective absorption on molecular sieves of kerosene, followed by fractionation of the desorbed linear hydrocarbon. The product is monohalogenated and reacted with benzene (+ AlCl/HCl). The undesired 2-phenylalkane is separated by distillation from the desired 5-(or higher)phenylalkane and recycled to the alkylation reactor. The alkylation of benzene with alphaolefins having at least 85% C12- 14 chains, in presence of HF, is also mentioned.ALSO:The invention comprises a mixture of alkyl-benzenesulphonates [e.g. of Li, Na, K, NH3, Ca, Mg, NH2C2H4OH or N(C2H4OH)3] i which the alkylbenzene portion has an average mol. wt. 250-270, the alkyl groups are linear and contain at least 85% C12- 14 and at least 10% each C12, C13 and C14 chains, the sulphonates having at least 37% 5 (or higher)-phenylalkanes and at most 27% 2-phenylalkanes. The alkylbenzene having the specified properties is sulphonated by a standard procedure. A suitable starting material is an unbranched C11- 15 paraffin mixture containing 34% C12, 43% C13 and 17% C14, which is monohalogenated by reaction with one third mol. Cl2 to give internally chlorinated hydrocarbons.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US361289A US3320174A (en) | 1964-04-20 | 1964-04-20 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1087337A true GB1087337A (en) | 1967-10-18 |
Family
ID=23421431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB10707/65A Expired GB1087337A (en) | 1964-04-20 | 1965-03-12 | Alkylbenzene sulphonate detergent compositions |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3320174A (en) |
| BE (1) | BE662407A (en) |
| CH (1) | CH481213A (en) |
| DE (1) | DE1281087B (en) |
| DK (1) | DK117311B (en) |
| ES (1) | ES310058A1 (en) |
| GB (1) | GB1087337A (en) |
| NL (1) | NL6504957A (en) |
| OA (1) | OA01693A (en) |
| SE (1) | SE303168B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000037775A1 (en) * | 1998-12-22 | 2000-06-29 | Chevron U.S.A. Inc. | Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3433846A (en) * | 1964-05-07 | 1969-03-18 | Chevron Res | Biodegradable detergent alkylate having improved detergent properties |
| US3342888A (en) * | 1965-02-17 | 1967-09-19 | Atlantic Refining Co | Production of low 2-phenyl isomer content monoalkylbenzene fractions |
| US3391210A (en) * | 1965-02-17 | 1968-07-02 | Continental Oil Co | Process for the preparation of detergent alkylate |
| US3352933A (en) * | 1965-12-07 | 1967-11-14 | Atlantic Refining Co | Isomerization of 2-phenyl alkanes |
| US3538006A (en) * | 1966-07-27 | 1970-11-03 | Witco Chemical Corp | Emulsion cleaner |
| US3639291A (en) * | 1969-08-25 | 1972-02-01 | Monsanto Co | Surfactant composition and liquid detergent formulations containing same |
| US3970596A (en) * | 1973-11-26 | 1976-07-20 | Colgate-Palmolive Company | Non-gelling alpha-olefin sulfonate liquid detergent |
| US3951879A (en) * | 1973-12-14 | 1976-04-20 | Colgate-Palmolive Company | Detergent that reduces electrostatic cling of synthetic fabrics |
| US4162236A (en) * | 1978-01-05 | 1979-07-24 | Monsanto Company | Detergent compositions containing mixtures of alkylbenzene sulfonates as the detergent active |
| US4486329A (en) * | 1983-10-17 | 1984-12-04 | Colgate-Palmolive Company | Liquid all-purpose cleaner |
| US4842767A (en) * | 1986-09-10 | 1989-06-27 | Colgate-Palmolive Company | Heavy duty built aqueous liquid detergent composition containing stabilized enzymes |
| US5236614A (en) | 1990-09-25 | 1993-08-17 | Colgate-Palmolive Company | Stable microemulsion disinfecting detergent composition |
| US6147246A (en) * | 1999-12-23 | 2000-11-14 | Condea Vista Company | Process for preparing alkoxylated dialkyl carbonate compounds |
| DE10246139A1 (en) * | 2002-10-01 | 2004-04-15 | Basf Ag | Alkylglycidol carbonates as co-surfactants |
| DE10246140A1 (en) * | 2002-10-01 | 2004-04-15 | Basf Ag | Reaction products of 2-propylheptanol with 1-halogen-2,3-epoxypropanes and 1-hydroxy-2,3-epoxypropane |
| US6669929B1 (en) * | 2002-12-30 | 2003-12-30 | Colgate Palmolive Company | Dentifrice containing functional film flakes |
| US7087567B2 (en) * | 2003-04-14 | 2006-08-08 | Colgate-Palmolive Company | Antibacterial light duty liquid cleaning composition |
| US6908890B2 (en) * | 2003-05-19 | 2005-06-21 | Colgate-Palmolive Company | Pearlescent solution |
| US20050020465A1 (en) * | 2003-07-23 | 2005-01-27 | Colgate-Palmolive Company | Liquid dish cleaning compositions |
| US7033986B2 (en) * | 2003-08-28 | 2006-04-25 | Colgate-Palmolive Company | Liquid dish cleaning compositions comprising a mixture of alkyl benzene sulfonates and alkyl ether sulfates |
| US6974790B2 (en) * | 2003-11-06 | 2005-12-13 | Colgate-Palmolive Company | Cleaning compositions in the form of a tablet |
| ES2396144T3 (en) | 2005-04-21 | 2013-02-19 | Colgate-Palmolive Company | Liquid detergent composition |
| ES2375500T3 (en) | 2006-04-21 | 2012-03-01 | Colgate-Palmolive Company | COMPOSITION FOR VISIBILITY AND IMPACT OF SUSPENDED MATERIALS. |
| MX2009006393A (en) | 2006-12-15 | 2009-09-02 | Colgate Palmolive Co | Liquid detergent composition. |
| EP2245128B1 (en) * | 2007-12-18 | 2014-05-21 | Colgate-Palmolive Company | Degreasing all purpose cleaning compositions and methods |
| US8282743B2 (en) | 2007-12-18 | 2012-10-09 | Colgate-Palmolive Company | Alkaline cleaning compositions |
| AR072859A1 (en) | 2008-05-23 | 2010-09-29 | Colgate Palmolive Co | CLEANING LIQUID METHODS AND COMPOSITIONS |
| AR071894A1 (en) | 2008-05-23 | 2010-07-21 | Colgate Palmolive Co | MULTI PURPOSE CLEANING COMPOSITIONS |
| MY155216A (en) | 2008-05-23 | 2015-09-30 | Colgate Palmolive Co | Liquid cleaning compositions and manufacture |
| WO2010126742A1 (en) | 2009-05-01 | 2010-11-04 | Colgate-Palmolive Company | Liquid cleaning composition with films |
| MX2013006650A (en) | 2010-12-13 | 2013-08-01 | Colgate Palmolive Co | Dilutable concentrated cleaning composition. |
| CA2818719C (en) | 2010-12-13 | 2015-11-24 | Colgate-Palmolive Company | Dilutable concentrated cleaning composition |
| MX357477B (en) | 2011-06-22 | 2018-07-11 | Colgate Palmolive Co | Choline salt cleaning compositions. |
| MX342215B (en) | 2011-06-22 | 2016-09-21 | Colgate Palmolive Co | Liquid salt cleaning compositions. |
| ES2617492T3 (en) | 2012-12-19 | 2017-06-19 | Colgate-Palmolive Company | Antiperspirant products with protein and antiperspirant salts |
| AU2012397269B2 (en) | 2012-12-19 | 2015-10-29 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor|comprising zinc amino acid halides |
| CN108186382A (en) | 2012-12-19 | 2018-06-22 | 高露洁-棕榄公司 | Zinc and amino-acids halide complex and cysteine |
| AU2012397259B2 (en) | 2012-12-19 | 2015-09-17 | Colgate-Palmolive Company | Zinc-lysine complex |
| US9925130B2 (en) | 2012-12-19 | 2018-03-27 | Colgate-Palmolive Company | Composition with zinc amino acid/trimethylglycine halide precursors |
| US9675823B2 (en) | 2012-12-19 | 2017-06-13 | Colgate-Palmolive Company | Two component compositions containing zinc amino acid halide complexes and cysteine |
| US9750670B2 (en) | 2012-12-19 | 2017-09-05 | Colgate-Palmolive Company | Zinc amino acid complex with cysteine |
| US9504858B2 (en) | 2012-12-19 | 2016-11-29 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
| BR112015014758B1 (en) | 2012-12-19 | 2019-04-09 | Colgate-Palmolive Company | ORAL CARE PRODUCTS UNDERSTANDING ZINC OXIDE AND TRIMETHYLGLYCIN |
| AU2012397265B2 (en) | 2012-12-19 | 2016-02-25 | Colgate-Palmolive Company | Oral gel comprising zinc - amino acid complex |
| RU2648513C2 (en) | 2012-12-19 | 2018-03-26 | Колгейт-Палмолив Компани | Zinc amino acid halide mouthwash |
| KR20150097494A (en) | 2012-12-19 | 2015-08-26 | 콜게이트-파아므올리브캄파니 | Oral care products comprising a tetrabasic zinc - amino acid - halide complex |
| US10188112B2 (en) | 2012-12-19 | 2019-01-29 | Colgate-Palmolive Company | Personal cleansing compositions containing zinc amino acid/trimethylglycine halide |
| AU2012397268B2 (en) | 2012-12-19 | 2015-09-24 | Colgate-Palmolive Company | Oral care products comprising tetrabasic zinc chloride and trimethylglycine |
| CA2892175C (en) | 2012-12-19 | 2019-10-15 | Colgate-Palmolive Company | Zinc amino acid/trimethylglycine halide |
| WO2014098826A1 (en) | 2012-12-19 | 2014-06-26 | Colgate-Palmolive Company | Oral care compositions comprising zinc amino acid halides |
| US9498421B2 (en) | 2012-12-19 | 2016-11-22 | Colgate-Palmolive Company | Two component compositions containing tetrabasic zinc-amino acid halide complexes and cysteine |
| WO2017010971A1 (en) | 2015-07-10 | 2017-01-19 | Colgate-Palmolive Company | Cleaning compositions and methods for enhancing fragrance performance |
| MX2019007634A (en) | 2016-12-27 | 2019-09-06 | Colgate Palmolive Co | Cleaning compositions and methods for modifying turbidity. |
| BR112019012557B1 (en) | 2016-12-27 | 2023-04-25 | Colgate-Palmolive Company | CLEANSING COMPOSITION AND METHOD OF PREPARATION OF CLEANING COMPOSITION WITH ENHANCED FRAGRANCE PERFORMANCE |
| MX2021006836A (en) | 2018-12-14 | 2021-07-02 | Colgate Palmolive Co | Personal care compositions. |
| AU2018455659A1 (en) | 2018-12-27 | 2021-07-01 | Colgate-Palmolive Company | Home care compositions |
| CN114667337A (en) | 2019-12-05 | 2022-06-24 | 宝洁公司 | Cleaning composition |
| US11485940B2 (en) | 2019-12-05 | 2022-11-01 | The Procter & Gamble Company | Method of making a cleaning composition |
| CN115418646B (en) * | 2022-08-12 | 2023-10-10 | 国网浙江省电力有限公司电力科学研究院 | Steel surface cleaning agent and preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2712530A (en) * | 1950-03-31 | 1955-07-05 | Exxon Research Engineering Co | Sulfonate detergent blend |
| US2944028A (en) * | 1956-09-12 | 1960-07-05 | California Research Corp | Sulfonate detergent compositions |
| FR1272254A (en) * | 1959-10-26 | 1961-09-22 | Colgate Palmolive Co | Detergent bar |
| US3169987A (en) * | 1960-12-30 | 1965-02-16 | Universal Oil Prod Co | Alkaryl sulfonate production via n-olefin isomerization |
-
1964
- 1964-04-20 US US361289A patent/US3320174A/en not_active Expired - Lifetime
-
1965
- 1965-03-03 ES ES0310058A patent/ES310058A1/en not_active Expired
- 1965-03-10 DE DEC35269A patent/DE1281087B/en active Pending
- 1965-03-11 SE SE3220/65A patent/SE303168B/xx unknown
- 1965-03-12 CH CH346465A patent/CH481213A/en not_active IP Right Cessation
- 1965-03-12 GB GB10707/65A patent/GB1087337A/en not_active Expired
- 1965-04-12 BE BE662407D patent/BE662407A/xx unknown
- 1965-04-15 OA OA51591A patent/OA01693A/en unknown
- 1965-04-20 DK DK198265AA patent/DK117311B/en unknown
- 1965-04-20 NL NL6504957A patent/NL6504957A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000037775A1 (en) * | 1998-12-22 | 2000-06-29 | Chevron U.S.A. Inc. | Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins |
| US6269881B1 (en) | 1998-12-22 | 2001-08-07 | Chevron U.S.A. Inc | Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins and the alpha-olefin compositions |
| CN1306145C (en) * | 1998-12-22 | 2007-03-21 | 切夫里昂奥罗尼特有限责任公司 | Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins |
Also Published As
| Publication number | Publication date |
|---|---|
| ES310058A1 (en) | 1965-06-01 |
| US3320174A (en) | 1967-05-16 |
| DK117311B (en) | 1970-04-13 |
| BE662407A (en) | 1965-08-02 |
| SE303168B (en) | 1968-08-19 |
| NL6504957A (en) | 1965-10-21 |
| DE1281087B (en) | 1968-10-24 |
| CH481213A (en) | 1969-11-15 |
| OA01693A (en) | 1969-12-15 |
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