GB1083516A - Improvements relating to condensation products of higher unsaturated hydroxy fatty acids with polymerizalbe unsaturated compounds - Google Patents
Improvements relating to condensation products of higher unsaturated hydroxy fatty acids with polymerizalbe unsaturated compoundsInfo
- Publication number
- GB1083516A GB1083516A GB868066A GB868066A GB1083516A GB 1083516 A GB1083516 A GB 1083516A GB 868066 A GB868066 A GB 868066A GB 868066 A GB868066 A GB 868066A GB 1083516 A GB1083516 A GB 1083516A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fatty acids
- acid
- unsaturated
- cyclic compound
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F242/00—Copolymers of drying oils with other monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
Abstract
Condensation polymers of C15- 25 unsaturated hydroxy fatty acids or their esters with cyclic unsaturated compounds which contain either at least two conjugated double bonds (one of which may be in an aromatic ring) or at least one double bond and an activated single bond conjugated therewith are produced by heating 0.5-20 moles of the cyclic compound with 1 mole of the fatty acid or ester, with optionally other fatty acids or their esters, to a temperature of 50-200 DEG C. in the presence of a Lewis acid as catalyst, water being evolved during the polymerization. The cyclic compound may be cyclopentadiene, styrene, indene, acenaphthylene, cumarone, pinene or a mixture of cumarone and indene. The fatty acid or ester may be ricinoleic acid or its methyl ester or castor oil fatty acid methyl ester. The reactants may be heated in the presence of an inert solvent, e.g. xylene, which forms an azeotropic mixture with water. The catalyst may be an acid-activated bleaching earth. Up to half of the cyclic compound may be present at the start of the reaction and the rest added during the reaction.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH0055337 | 1965-03-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1083516A true GB1083516A (en) | 1967-09-13 |
Family
ID=7159004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB868066A Expired GB1083516A (en) | 1965-03-01 | 1966-02-28 | Improvements relating to condensation products of higher unsaturated hydroxy fatty acids with polymerizalbe unsaturated compounds |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE676736A (en) |
DE (1) | DE1570740A1 (en) |
GB (1) | GB1083516A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758096A1 (en) * | 1994-04-28 | 1997-02-12 | Kureha Kagaku Kogyo Kabushiki Kaisha | Synthetic resin lens and process for producing the same |
US6211315B1 (en) * | 1998-11-12 | 2001-04-03 | Iowa State University Research Foundation, Inc. | Lewis acid-catalyzed polymerization of biological oils and resulting polymeric materials |
-
1965
- 1965-03-01 DE DE19651570740 patent/DE1570740A1/en active Pending
-
1966
- 1966-02-18 BE BE676736D patent/BE676736A/xx unknown
- 1966-02-28 GB GB868066A patent/GB1083516A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758096A1 (en) * | 1994-04-28 | 1997-02-12 | Kureha Kagaku Kogyo Kabushiki Kaisha | Synthetic resin lens and process for producing the same |
EP0758096A4 (en) * | 1994-04-28 | 1997-11-05 | Kureha Chemical Ind Co Ltd | Synthetic resin lens and process for producing the same |
US6211315B1 (en) * | 1998-11-12 | 2001-04-03 | Iowa State University Research Foundation, Inc. | Lewis acid-catalyzed polymerization of biological oils and resulting polymeric materials |
Also Published As
Publication number | Publication date |
---|---|
DE1570740A1 (en) | 1970-03-05 |
BE676736A (en) | 1966-07-18 |
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