GB1075754A - Improvements in or relating to stiffening materials for footwear - Google Patents
Improvements in or relating to stiffening materials for footwearInfo
- Publication number
- GB1075754A GB1075754A GB33673/64A GB3367364A GB1075754A GB 1075754 A GB1075754 A GB 1075754A GB 33673/64 A GB33673/64 A GB 33673/64A GB 3367364 A GB3367364 A GB 3367364A GB 1075754 A GB1075754 A GB 1075754A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stiffening material
- stiffening
- synthetic resin
- adhesive
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
- A43B23/16—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/245—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using natural fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08J2361/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Moulded and stiffened articles, particularly footwear and parts of footwear, are made by incorporating in a normally flexible article a stiffening material at the location where moulding and stiffening is required, the stiffening material comprising a woven or nonwoven cloth e.g. of cotton, or sheet of fibrous material carrying a blend of a urea-formaldehyde synthetic resin and a thermoplastic synthetic resin, applying heat to the article at the location where moulding is required to render the thermoplastic component pliable and moulding the article in the desired form and finally curing the article in that form. The cloth or sheet of fibrous material may be impregnated or coated on one or both sides with the blend of synthetic resins, or may be coated on one side with the urea-formaldehyde synthetic resin and on the other side with the thermoplastic synthetic resin. The stiffening material may also carry a suitable catalyst for promoting the curing of the urea-formaldehyde resin. The catalyst may be selected from organic acids, inorganic salts which react acid in solution, and ammonium salts which produce acid by reaction with the formaldehyde present in the resin. An amount of urea may be added to the catalyst in order to retain its action to suit different production rate requirements. The stiffening material may have a coating e.g. applied by brushing, spraying or dipping, on one or both sides, of a suitable adhesive for adhesively bonding the stiffening material to the article, such as the lining or upper material, or both, of footwear. The adhesive may be a thermoplastic adhesive capable of forming a solution or emulsion in water and may be an acrylic base adhesive. The stiffening material may have a coating on one or both sides of a mixture of an adhesive and a catalyst comprising 100 parts by weight of a 50% acrylic adhesive solution and 10 parts by weight of ammonium chloride. A suitable compatible plasticiser e.g. glycerol, dibutyl-phthalate, may be incorporated in the blend of synthetic resins carried by the stiffening material to prevent hardening and/or embrittlement. The thermoplastic synthetic resin may be polyvinyl acetate resin which may have a softening point well above atmospheric temperature but below the temperature at which the stiffening material is to be moulded. The stiffening material may carry a blend of synthetic resin comprising 70 parts by weight of a 70% urea-formaldehyde solution and 30 parts by weight of a 60% polyvinyl acetate emulsion. The stiffening material is inserted between the lining and upper of a part of footwear at the location where stiffening is required.ALSO:Moulded and stiffened articles, particularly footwear and parts of footwear, are made by incorporating in a normally flexible article a stiffening material at the location where moulding and stiffening is required, the stiffening material comprising a woven or nonwoven cloth, e.g. of cotton, or sheet of fibrous material carrying a blend of a urea-formaldehyde synthetic resin and a thermoplastic synthetic resin, applying heat to the article at the location where moulding is required to render the thermoplastic component pliable and moulding the articles in the desired form and finally curing the article in that form. The cloth or sheet of fibrous material may be impregnated or coated on one or both sides with the blend of synthetic resins, or may be coated on one side with the urea-formaldehyde synthetic resin and on the other side with the thermoplastic synthetic resin. The stiffening material may also carry a suitable catalyst for promoting the curing of the urea-formaldehyde resin. The catalyst may be selected from organic acids, inorganic salts which react acid in solution, and ammonium salts which produce acid by reaction with the formaldehyde present in the resin. An amount of urea may be added to the catalyst in order to retain its action to suit different production rate requirements. The stiffening material may have a coating e.g. applied by brushing, spraying or dipping, on one or both sides, of a suitable adhesive for adhesively bonding the stiffening material to the article, such as the lining or upper material, or both, of footwear. The adhesive may be a thermoplastic adhesive capable of forming a solution or emulsion in water and may be an acrylic base adhesive. The stiffening material may have a coating on one or both sides of a mixture of an adhesive and a catalyst comprising 100 parts by weight of a 50% acrylic adhesive solution and 10 parts by weight of ammonium chloride. A suitable compatible plasticiser, e.g. glycerol, dibutylphthalate, may be incorporated in the blend of synthetic resins carried by the stiffening material to prevent hardening and/or embrittlement. The thermoplastic synthetic resin may be polyvinyl acetate resin which may have a softening point well above atmospheric temperature but below the temperature at which the stiffening material is to be moulded. The stiffening material may carry a blend of synthetic resin comprising 70 parts by weight of a 70% urea-formaldehyde solution and 30 parts by weight of a 60% polyvinyl acetate emulsion. The stiffening material is inserted between the lining and upper of a part of footwear at the location where stiffening is required.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB33673/64A GB1075754A (en) | 1964-08-18 | 1964-08-18 | Improvements in or relating to stiffening materials for footwear |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB33673/64A GB1075754A (en) | 1964-08-18 | 1964-08-18 | Improvements in or relating to stiffening materials for footwear |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1075754A true GB1075754A (en) | 1967-07-12 |
Family
ID=10355950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33673/64A Expired GB1075754A (en) | 1964-08-18 | 1964-08-18 | Improvements in or relating to stiffening materials for footwear |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1075754A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006015331A1 (en) * | 2004-07-30 | 2006-02-09 | Hexion Specialty Chemicals, Inc. | Polymerization-enhancing composition for urea-formaldehyde resins, method of manufacture, method of use, and articles formed therefrom |
-
1964
- 1964-08-18 GB GB33673/64A patent/GB1075754A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006015331A1 (en) * | 2004-07-30 | 2006-02-09 | Hexion Specialty Chemicals, Inc. | Polymerization-enhancing composition for urea-formaldehyde resins, method of manufacture, method of use, and articles formed therefrom |
AU2005267775B2 (en) * | 2004-07-30 | 2011-03-31 | Hexion Inc. | Polymerization-enhancing composition for urea-formaldehyde resins, method of manufacture, method of use, and articles formed therefrom |
CN1993397B (en) * | 2004-07-30 | 2012-04-25 | 迈图专业化学股份有限公司 | Polymerization-enhancing composition for urea-formaldehyde resins, method of manufacture, method of use, and articles formed therefrom |
US8252864B2 (en) | 2004-07-30 | 2012-08-28 | Momentive Specialty Chemicals Inc. | Polymerization-enhancing composition for urea-formaldehyde resins, method of manufacture, method of use, and articles formed therefrom |
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