GB1067546A - Improvements in or relating to polyesters and polyurethanes - Google Patents

Improvements in or relating to polyesters and polyurethanes

Info

Publication number
GB1067546A
GB1067546A GB4259164A GB4259164A GB1067546A GB 1067546 A GB1067546 A GB 1067546A GB 4259164 A GB4259164 A GB 4259164A GB 4259164 A GB4259164 A GB 4259164A GB 1067546 A GB1067546 A GB 1067546A
Authority
GB
United Kingdom
Prior art keywords
bis
diol
hydroxyethyloxamido
oxamide
finely
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4259164A
Inventor
Andre Louis Armand Rio
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of GB1067546A publication Critical patent/GB1067546A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G85/00—General processes for preparing compounds provided for in this subclass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3825—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing amide groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6856—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A polyurethane or polyester is prepared by reacting either an organic diisocyanate or terephthaloyl chloride respectively with a suspension of a finely-divided diol in an inert liquid organic diluent in which both diol and polyurethane or polyester (as the case may be) are insoluble but the organic diisocyanate or terephthaloyl chloride (as the case may be) is soluble. The diluent may be diphenyl oxide, decahydronaphthalene or di-(a -methyl benzyl)-oxide. The diol may be an oxamide diol of formula HO(CH2)nNHCOXCONH(CH2)nOH, where n is 2-6, X is a single bond or <FORM:1067546/C3/1> or a group of formula -CONHY-NHCO-, where Y is -(CH2)m-, where m is 2 to 6 or <FORM:1067546/C3/2> where Z is -CH2-, -SO2- or -PO(CH3)-. When the diol is solid at the reaction temperature it is employed in finely divided form and is kept in suspension in the inert diluent. When the diol or final polycondensate is a liquid at the reaction temperature it may be kept in finely-divided form by vigorous stirring. The polycondensation may be carried out under pressure. In Examples (1), (3), (4), (5), (6), (7), (8), (9), (10) and (11) N,N1-bis-(b -hydroxyethyl) oxamide, 1,6 - bis - (b - hydroxyethyloxamido) hexane, N,N1 - bis - (g - hydroxypropyl) oxamide, bis - p,p1 - (hydroxyethyloxamido) diphenylmethane, bis - N,N1 - (b - hydroxyethyloxamido) piperazine, methyl bis-(m-b -hydroxyethyloxamido) phosphine oxide and bis-p,p1-(b -hydroxyethyloxamido) diphenylsulphone were reacted with either 1: 6-diisocyanatohexane or diphenylmethane 4,41-diisocyanate or in Example (2) with terephthaloyl chloride.
GB4259164A 1963-10-22 1964-10-19 Improvements in or relating to polyesters and polyurethanes Expired GB1067546A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR951372A FR1380681A (en) 1963-10-22 1963-10-22 Polycondensation in suspension

Publications (1)

Publication Number Publication Date
GB1067546A true GB1067546A (en) 1967-05-03

Family

ID=8814896

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4259164A Expired GB1067546A (en) 1963-10-22 1964-10-19 Improvements in or relating to polyesters and polyurethanes

Country Status (4)

Country Link
BE (1) BE654667A (en)
CH (2) CH433741A (en)
FR (1) FR1380681A (en)
GB (1) GB1067546A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170083603A (en) * 2014-11-14 2017-07-18 헌츠만 페트로케미칼 엘엘씨 Comb polyurethane dispaersants
CN112094401A (en) * 2020-09-27 2020-12-18 江南大学 Degradable polyester and preparation method and application thereof
CN112608460A (en) * 2020-09-27 2021-04-06 江南大学 Polyglycolic acid material and preparation method and application thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1373531A (en) * 1971-03-30 1974-11-13 Ici Ltd Process for the preparation of polymer dispersions
IE38152B1 (en) * 1972-06-16 1978-01-04 Usm Corp Improvements in or relating to methods of making polyurethane powder

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170083603A (en) * 2014-11-14 2017-07-18 헌츠만 페트로케미칼 엘엘씨 Comb polyurethane dispaersants
CN107075106A (en) * 2014-11-14 2017-08-18 亨斯迈石油化学有限责任公司 Combed polyurethane dispersant
EP3218423A4 (en) * 2014-11-14 2018-06-20 Huntsman Petrochemical LLC Comb polyurethane dispersants
CN107075106B (en) * 2014-11-14 2020-01-21 亨斯迈石油化学有限责任公司 Comb type polyurethane dispersant
CN112094401A (en) * 2020-09-27 2020-12-18 江南大学 Degradable polyester and preparation method and application thereof
CN112608460A (en) * 2020-09-27 2021-04-06 江南大学 Polyglycolic acid material and preparation method and application thereof
CN112094401B (en) * 2020-09-27 2021-10-19 江南大学 Degradable polyester and preparation method and application thereof
CN112608460B (en) * 2020-09-27 2022-01-11 江南大学 Polyglycolic acid material and preparation method and application thereof

Also Published As

Publication number Publication date
FR1380681A (en) 1964-12-04
BE654667A (en)
CH433741A (en) 1967-04-15
CH434748A (en) 1967-04-30

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