GB1063172A - Improvements relating to blends of olefin polymers and waxes - Google Patents
Improvements relating to blends of olefin polymers and waxesInfo
- Publication number
- GB1063172A GB1063172A GB2243965A GB2243965A GB1063172A GB 1063172 A GB1063172 A GB 1063172A GB 2243965 A GB2243965 A GB 2243965A GB 2243965 A GB2243965 A GB 2243965A GB 1063172 A GB1063172 A GB 1063172A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polybutene
- earth metal
- paraffins
- mixture
- blends
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 229920000098 polyolefin Polymers 0.000 title 1
- 239000001993 wax Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 4
- 229920001748 polybutylene Polymers 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000012169 petroleum derived wax Substances 0.000 abstract 2
- 235000019381 petroleum wax Nutrition 0.000 abstract 2
- 125000003367 polycyclic group Chemical group 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical group CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 239000004200 microcrystalline wax Substances 0.000 abstract 1
- 235000019808 microcrystalline wax Nutrition 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 235000019809 paraffin wax Nutrition 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
- C09D191/08—Mineral waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Blends of polybutene-1 and a petroleum wax are obtained by mixing butene-1, a petroleum wax and a catalytic amount of a catalyst formed by mixing a compound of a metal of Group IVb, Vb, VIb or VIII, Large's Table, or manganese with an organometallic compound of an alkali metal, an alkaline earth metal, zinc, an earth metal or a rare earth metal, and heating the resulting mixture to a temperature of 50 DEG to 160 DEG C. under a pressure from atmospheric to 17.5 kg./cm.2. Excess catalyst is preferably removed from the polymerization mixture by adding water, the amount being insufficient to wet the polybutene-1 was blend, and then removing the catalyst residues, e.g. by filtration. Paraffin waxes, e.g. mixtures of essentially straight chain hydrocarbons or intermediate fractions containing straight chain n - paraffins, isoparaffins, polycyclic paraffins and aromatics or the micro-crystalline waxes consisting of a mixture of isoparaffins, polycyclic paraffins and aromatics, may be used. The molecular weight of the polybutene-1 can be controlled by varying the polymerization temperature, adding zinc diethyl or adding hydrogen. In the examples the catalysts employed are titanium trichloride with either diethyl aluminium chloride or triethyl aluminium.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37036664A | 1964-05-26 | 1964-05-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1063172A true GB1063172A (en) | 1967-03-30 |
Family
ID=23459324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2243965A Expired GB1063172A (en) | 1964-05-26 | 1965-05-26 | Improvements relating to blends of olefin polymers and waxes |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE664472A (en) |
| FR (1) | FR1438679A (en) |
| GB (1) | GB1063172A (en) |
| NL (1) | NL6506656A (en) |
-
1965
- 1965-05-25 FR FR18393A patent/FR1438679A/en not_active Expired
- 1965-05-25 NL NL6506656A patent/NL6506656A/xx unknown
- 1965-05-25 BE BE664472D patent/BE664472A/xx unknown
- 1965-05-26 GB GB2243965A patent/GB1063172A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE664472A (en) | 1965-09-16 |
| FR1438679A (en) | 1966-05-13 |
| NL6506656A (en) | 1965-11-29 |
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