GB1057090A - Amido-thiol-phosphoric acid esters - Google Patents
Amido-thiol-phosphoric acid estersInfo
- Publication number
- GB1057090A GB1057090A GB5182765A GB5182765A GB1057090A GB 1057090 A GB1057090 A GB 1057090A GB 5182765 A GB5182765 A GB 5182765A GB 5182765 A GB5182765 A GB 5182765A GB 1057090 A GB1057090 A GB 1057090A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compositions
- methyl
- formula
- amido
- thiol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 230000000361 pesticidal effect Effects 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 abstract 2
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000003139 biocide Substances 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- IIRVGTWONXBBAW-UHFFFAOYSA-M disodium;dioxido(oxo)phosphanium Chemical compound [Na+].[Na+].[O-][P+]([O-])=O IIRVGTWONXBBAW-UHFFFAOYSA-M 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000006072 paste Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2412—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of unsaturated acyclic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises compounds of the formula <FORM:1057090/C2/1> wherein R1 is methyl or ethyl, R2 and R3 are hydrogen or methyl, and R4 is propenyl or propynyl. The compounds are prepared by reacting an amido-O-alkyl-thiol phosphonic acid salt with a compound of formula R4-Hal, where Hal represents halogen, and they may be used in pesticidal compositions. The presence of solvents or diluents and the use of temperatures of 20 DEG to 100 DEG C. are preferred conditions for the preparation process. The phosphorus-containing starting materials are prepared by the hydrolysis of suitable O,O-dialkyl-thionophosphori acid amides using sodium hydroxide and the examples describe the preparation of (C2H5O)(H2N4)P(O)(SNa) and of (CH3O)(H2N)P(O)(SNa). The novel esters have pesticidal properties.ALSO:Pesticidal compositions comprise a compound of formula:- <FORM:1057090/A5-A6/1> where R1 is methyl or ethyl, R2 and R3 are hydrogen or methyl, and R4 is propenyl or propynyl, together with a solid or liquid diluent or carrier. The compositions may be in the form of solutions, emulsions, powders, pastes, or granules. Several solvents and carriers are specified. The compositions may also contain known biocides. The invention also comprises a method of combating pests by using these compositions or their active ingredient alone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF44972A DE1221633B (en) | 1965-01-15 | 1965-01-15 | Process for the preparation of amidothiolphosphoric acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1057090A true GB1057090A (en) | 1967-02-01 |
Family
ID=7100284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5182765A Expired GB1057090A (en) | 1965-01-15 | 1965-12-07 | Amido-thiol-phosphoric acid esters |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE674999A (en) |
| BR (1) | BR6676412D0 (en) |
| CH (1) | CH464196A (en) |
| DE (1) | DE1221633B (en) |
| DK (1) | DK118930B (en) |
| FR (1) | FR1487325A (en) |
| GB (1) | GB1057090A (en) |
| IL (1) | IL24740A (en) |
| NL (1) | NL148901C (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE581598A (en) * | 1958-08-12 |
-
1965
- 1965-01-15 DE DEF44972A patent/DE1221633B/en active Granted
- 1965-12-03 CH CH1669165A patent/CH464196A/en unknown
- 1965-12-06 IL IL2474065A patent/IL24740A/en unknown
- 1965-12-07 GB GB5182765A patent/GB1057090A/en not_active Expired
-
1966
- 1966-01-12 BE BE674999D patent/BE674999A/xx unknown
- 1966-01-13 NL NL6600465A patent/NL148901C/en active
- 1966-01-14 BR BR17641266A patent/BR6676412D0/en unknown
- 1966-01-14 FR FR45922A patent/FR1487325A/en not_active Expired
- 1966-01-14 DK DK22666A patent/DK118930B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1221633C2 (en) | 1967-02-02 |
| DE1221633B (en) | 1966-07-28 |
| NL6600465A (en) | 1966-07-18 |
| FR1487325A (en) | 1967-10-12 |
| CH464196A (en) | 1968-10-31 |
| BR6676412D0 (en) | 1973-11-29 |
| BE674999A (en) | 1966-05-03 |
| NL148901C (en) | 1976-03-15 |
| IL24740A (en) | 1969-07-30 |
| DK118930B (en) | 1970-10-19 |
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