GB1054757A - - Google Patents
Info
- Publication number
- GB1054757A GB1054757A GB1054757DA GB1054757A GB 1054757 A GB1054757 A GB 1054757A GB 1054757D A GB1054757D A GB 1054757DA GB 1054757 A GB1054757 A GB 1054757A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polysiloxane
- carbon atoms
- acids
- peroxide
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/10—Block or graft copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Graft Or Block Polymers (AREA)
Abstract
1,054,757. Polysiloxane-unsaturated amide copolymer compositions. PITTSBURGH PLATE GLASS CO. March 26, 1964 [April 3, 1963], No. 13062/64. Headings C3P, C3R and C3T. A coating composition comprises (1) a copolymer of an unsaturated carboxylic acid amide having amide groups substituted by groups -CHR.OR 1 , where R is H or alkyl and R 1 is H or an organic radical, and (2) an organopolysiloxane of the average formula where R is an organic radical bound to silicon through a carbon atom, R<SP>1</SP> is hydrogen or an alkyl group of 1-20 carbon atoms, an aryl radical, or an acyl radical of 1-8 carbon atoms, n is 0À5-1À9, m is À01-2À5 and m+n is 0À51- 3À0. (1) is a copolymer with at least one other ethylenically unsaturated monomer. The composition preferably contains 1-40% of the polysiloxane and preferably also an alkyd resin, which preferably contains free hydroxy groups and constitutes 5-40% of the resin mixture, and which may be co-reacted with the polysiloxane. The alkylol groups in (1) are preferably at least 50% etherified. The resin (1) is obtained by reacting the unsaturated amide before or after polymerization with an aldehyde, and etherifying the alkylol groups so formed, if required. The ratio of aldehyde to amide group may be between 0À2 and 3À0 to 1, preferably about 2: 1, and the condensation catalyst may be e.g. maleic anhydride, oxalic, hydrochloric or sulphuric acid. Suitable amides are those of acrylic and methacrylic acids (preferred) and those of α-ethyl acrylic and crotonic acids, and the diamides of maleic, itaconic and fumaric acids, and maleuric acid and esters and N- carbamyl maleimide. Suitable aldehydes are formaldehyde (preferred), acetaldehyde, butyraldehyde and furfural. Suitable alcohols, for the etherification, are butanol (preferred) or any alkanol of up to 20 carbon atoms, benzyl alcohol, cyclohexanol, glycol monoethers and 3-chlorpropanol. Suitable ethylenic monomers include monoolefins, diolefins, halo-olefins, and unsaturated esters, acids and nitriles. Azo and peroxy catalysts for the polymerization include acetyl benzoyl peroxide, cyclohexanone peroxide, cyclohexyl hydroperoxide, cumene hydroperoxide, acetyl peroxide, lauroyl peroxide, benzoyl peroxide, methyl cyclohexyl hydroperoxide, di-t-butyl peroxide, peracetic acid, t-butyl permaleic acid and di-t-butyl diperphthalate, and p-methoxyphenyl diazothio-(2- naphthyl) ether and azobisisobutyronitrile. A chain modifying (" short stopping ' ) agent may be added, usually a mercaptan, possibly cyclopentadiene, allyl carbamate, or α-methylstyrene. In the organopolysiloxane, R may be an alkyl, cycloalkyl, aryl, aralkyl, alkaryl, alkenyl, cycloalkenyl, or alkenylaryl radical (examples given) or a halo, amino, hydroxy, cyano or sulphur-substituted hydrocarbon group, and R<SP>1</SP> may be an alkyl group of up to 20 carbon atoms or an aryl group, or an acyl group of 1-8 carbon atoms. The polysiloxane is produced by conventional methods. The alkyd resin may derive from e.g. phthalic, maleic, fumaric, isophthalic, succinic, adipic, azelaic and sebacic acids or their anhydrides, and e.g. glycrol, trimethylol ethane, pentaerythritol, sorbitol, mannitol, ethylene glycol, diethylene glycol and 2,3-butylene glycol. Suitable alkyd-modifying oils are soya, safflower, perilla, tung, oiticica, poppyseed, sunflower, coconut, babassu, tall, walnut and fish oils. Other materials which may be included in the composition are epoxy resins, e.g. polyglycidyl ethers of polyhydric compounds, epoxidized polyolefins and epoxidized aromatic compounds, phenol-aldehyde and aminoplast resins, nitrocellulose, solvents, plasticizers, anti-foaming agents, and anti-skinning agents. Pigments may be added, e.g. TiO 2 , carbon black, talc, barytes, chromates, Fe 2 O 3 , cadmium red and yellow, phthalocyanine blue and toluidine red. In examples, methylolated interpolymers of acrylamide, styrene, ethyl acrylate and optionally methacrylic acid are co-reacted with a polysiloxane, or mixed with a polysiloxane, or, in conjunction with an epoxy resin are mixed with polysiloxanes or polysiloxane-modified alkyd resins.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27020363A | 1963-04-03 | 1963-04-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1054757A true GB1054757A (en) |
Family
ID=23030342
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1054757D Active GB1054757A (en) | 1963-04-03 |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1494499C3 (en) |
GB (1) | GB1054757A (en) |
-
0
- GB GB1054757D patent/GB1054757A/en active Active
-
1964
- 1964-04-02 DE DE19641494499 patent/DE1494499C3/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1494499C3 (en) | 1973-11-15 |
DE1494499B2 (en) | 1973-04-19 |
DE1494499A1 (en) | 1969-12-11 |
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