GB1052584A - - Google Patents

Info

Publication number
GB1052584A
GB1052584A GB2458765A GB2458765A GB1052584A GB 1052584 A GB1052584 A GB 1052584A GB 2458765 A GB2458765 A GB 2458765A GB 2458765 A GB2458765 A GB 2458765A GB 1052584 A GB1052584 A GB 1052584A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
hydrogen
pressure
amide
cyclohexenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2458765A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1052584A publication Critical patent/GB1052584A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,052,584. Cyclohexenes. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. June 10, 1965 [June 12, 1964 (2)], No. 24587/65. Heading C5E. Cyclohexenes are obtained from benzene or an alkyl or cycloalkyl derivative by reaction in the liquid phase at 30-180‹ C. with sodium, potassium, rubidium or caesium and a compound of the formula RNH 2 in which R is hydrogen or alkyl and recovering the alkali metal from the amide formed. The alkali metal is preferably recovered by heating with hydrogen to 375-800‹ C., the hydrogen pressure or partial pressure being 10-150% of the dissociation pressure of the amide at the temperature used. Ammonia is the preferred amide used in a molar ratio to hydrocarbon of 3-100: 1. The alkali metal is added in amounts of 1-10 atoms per molecule of hydrocarbon. Pressures of 2-300 atmospheres, e.g. autogenous pressure, are used to maintain the liquid phase.
GB2458765A 1964-06-12 1965-06-10 Expired GB1052584A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37484364A 1964-06-12 1964-06-12
US374837A US3258329A (en) 1964-06-12 1964-06-12 Alkali metal recovery from alkali metal amides

Publications (1)

Publication Number Publication Date
GB1052584A true GB1052584A (en) 1966-12-30

Family

ID=27006782

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2458765A Expired GB1052584A (en) 1964-06-12 1965-06-10

Country Status (6)

Country Link
US (1) US3258329A (en)
BE (1) BE665232A (en)
DE (1) DE1493059A1 (en)
FR (1) FR1445767A (en)
GB (1) GB1052584A (en)
NL (1) NL6507378A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1081628B (en) * 1977-07-27 1985-05-21 Snam Progetti PROCESS FOR THE HYDROGENATION OF AROMATIC SUBSTRATES AND MEANS SUITABLE FOR THE PURPOSE
JPS56150049A (en) * 1980-04-21 1981-11-20 Nippon Kasei Kk Production of d-2-amino-2- 1,4-cyclohexadienyl acetic acid

Also Published As

Publication number Publication date
BE665232A (en) 1965-12-10
NL6507378A (en) 1965-12-13
DE1493059A1 (en) 1968-12-19
FR1445767A (en) 1966-07-15
US3258329A (en) 1966-06-28

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