GB1052241A - - Google Patents

Info

Publication number
GB1052241A
GB1052241A GB1052241DA GB1052241A GB 1052241 A GB1052241 A GB 1052241A GB 1052241D A GB1052241D A GB 1052241DA GB 1052241 A GB1052241 A GB 1052241A
Authority
GB
United Kingdom
Prior art keywords
methacrylate
copolymer
methacrylic acid
polymer
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication date
Publication of GB1052241A publication Critical patent/GB1052241A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
    • C08F261/06—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/005—Processes for mixing polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
    • C08J3/11—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids from solid polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1,052,241. Polymer dispersions; unsaturated polymers. IMPERIAL CHEMICAL INDUSTRIES. May 29, 1963 [June 22, 1962], No. 24216/62. Addition to 941,305. Headings C3G. C3P and C3R. Stable dispersions of synthetic polymers in organic liquids are made by polymerizing ethylenic monomer in an organic liquid which is a solvent for the monomer but not for the resulting polymer and which contains a graft copolymer made by graft polymerizing an ethylenic monomer with a polymer which contains a copolymerizable unsaturated group, the grafted chain being of different polarity from that of the preformed polymer chain, one chain of the graft copolymer being solvated by the organic liquid and the other chain being not solvated by the organic liquid and becoming associated with the disperse polymer, the molecular weight of the non-solvated chain being at least 2000 and 0À1-10 times the molecular weight of the solvated chain which is at least 5000. Preferably the graft copolymer precursor containing unsaturated groups is dissolved in an appropriate organic solvent, and the polymer dispersion-forming monomer is then polymerized in the solution of the precursor polymer, thereby simultaneously forming the graft copolymer and the dispersed polymer. Alternatively, the grafting monomer and the polymer dispersion-forming monomer, may be different. Exemplified unsaturated precursor polymers are made by reacting: ( 1 ) methacrylyl chloride with a lauryl methacrylatepropylene glycol monomethacrylate, (2 and 3) methacrylic acid with a lauryl methacrylateglycidyl methacrylate copolymers, (4 and 5) maleic anhydride and monomethyl itaconate with a tert. butyl methacrylate-propylene glycol monomethacrylate copolymer, (6) allylamine with a tert. butyl methacrylate-methacrylyl chloride copolymer, (7) allyl isocyanate with a tert. butyl methacrylate-ethylene glycol monomethyacrylate copolymer, (8) allyl glycidyl ether with a tert. butyl methacrylate-methacrylic acid copolymer, (9) methacrylic acid with a tert. butyl methacrylate-glycidyl methacrylate copolymer, (10) ethyl acrylate with an ethylene oxide-propylene oxide block copolymer, (11 and 12) acrylic acid with 2-ethylhexyl acrylate-glycidyl methacrylate and cetyl methacrylate-glycidyl methacrylate copolymers, (13) ethyl acrylate with a vinyl toluene-vinyl acetate copolymer, (14) methacrylyl chloride and poly (propylene glycol monomethacrylate), (15) methacrylic acid and a methylmethacrylate. glycidyl methacrylate copolymer, (16) vinyl chloride and a hydrolysed vinyl toluene-vinyl acetate copolymer, (17) methacrylic acid and a lauryl methacrylate-glycidyl methacrylate copolymer, (18) acrylic acid and a lauryl methacrylate-n-octyl methacrylate-glycidyl methacrylate copolymer, (19 and 20) glycidyl methacrylate and lauryl methacrylate-methacrylic acid copolymers, and (21) methacrylic acid and a methyl methacrylate-glycidyl methacrylate copolymer. The precursor polymers are grafted with unsaturated monomers either prior to or during the formation of polymer dispersions by the polymerization in organic liquids of (22 and 23) methyl methacrylate, ethoxyethyl methacrylate and methacrylic acid, (24, 30, 35, 38, 39 and 53) methyl methacrylate, (25, 28, 37, 52, 54, 55 and 58) methyl methacrylate and methacrylic acid, (26) methyl and n-butyl methacrylates, (29) acrylonitrile, ethoxyethyl methacrylate and acrylic acid, (31) acrylic acid and acrylonitrile, (32) hydroxyethyl and hydroxypropyl methacrylates and methacrylic acid, (33) acrylonitrile and n-butyl methacrylate, (34, 40-45 and 65) vinyl chloride, (36) methyl methacrylate, methacrylic acid and ethyl acrylate, (46) vinylidene chloride and methyl acrylate, (47 and 62) vinyl acetate, (48) vinyl chloroacetate, (49 and 50) styrene, (51) styrene, ethyl acrylate and acrylonitrile, (56) acrylonitrile, (57) acrylic acid, (59) methyl methacrylate, ethoxthyl acrylate and acryileyc acid, (60) vinyl stearate, acrylonitrile and acrylamide, (61) styrene and acrylonitrile, (63) vinyl acetate and monomethyl maleate, and (64) vinyl chloroacetate and monomethyl maleate.
GB1052241D 1958-11-05 Expired GB1052241A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB35503/58A GB941305A (en) 1958-11-05 1958-11-05 Polymer dispersions
GB1505159 1959-05-01
GB2421662 1962-06-22

Publications (1)

Publication Number Publication Date
GB1052241A true GB1052241A (en) 1900-01-01

Family

ID=27257207

Family Applications (3)

Application Number Title Priority Date Filing Date
GB1052241D Expired GB1052241A (en) 1958-11-05
GB35503/58A Expired GB941305A (en) 1958-11-05 1958-11-05 Polymer dispersions
GB13193/61A Expired GB1017931A (en) 1958-11-05 1961-04-12 Dispersion polymerisation

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB35503/58A Expired GB941305A (en) 1958-11-05 1958-11-05 Polymer dispersions
GB13193/61A Expired GB1017931A (en) 1958-11-05 1961-04-12 Dispersion polymerisation

Country Status (9)

Country Link
BE (3) BE584369A (en)
CH (2) CH392873A (en)
DE (2) DE1570771C3 (en)
FR (2) FR1244568A (en)
GB (3) GB941305A (en)
LU (2) LU43943A1 (en)
MY (2) MY6400071A (en)
NL (8) NL112597C (en)
SE (1) SE310063B (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2114773A1 (en) * 1971-03-26 1972-09-28 Hunt Chem Corp Philip A Liquid electrostatographic developer - contg film forming fixing agen solvent solid dispersant etc
DE1719427A1 (en) * 1966-11-25 1973-05-30 Dulux Australia Ltd DISPERSIONS
US3846828A (en) * 1973-04-04 1974-11-05 Dow Chemical Co High solids content vinylidene chloride polymer dispersions in strongly hydrogen bonded dispersing media and process of preparation thereof
US3931432A (en) * 1973-01-04 1976-01-06 Imperial Chemical Industries Limited Printing process
US3950284A (en) 1973-07-28 1976-04-13 Toray Industries, Inc. Polymer dispersed liquid
EP0001489A2 (en) * 1977-10-12 1979-04-18 Imperial Chemical Industries Plc Preparation of sterically stabilised aqueous polymer dispersions
US4180489A (en) * 1977-04-25 1979-12-25 Imperial Chemical Industries Limited Coating composition
US4206099A (en) 1977-04-25 1980-06-03 Imperial Chemical Industries Limited Autoxidizable coating compositions
US4232135A (en) 1978-01-10 1980-11-04 Imperial Chemical Industries Limited Coating compositions
US4242249A (en) 1979-04-03 1980-12-30 Union Carbide Corporation Polymer/polyols via non-aqueous dispersion stabilizers
US4294735A (en) 1977-04-25 1981-10-13 Imperial Chemical Industries Limited Coating compositions
EP0038127A1 (en) * 1980-04-14 1981-10-21 Imperial Chemical Industries Plc Multi-layer coating process involving use of aqueous basecoat composition containing crosslinked polymer microparticles and having a pseudoplastic or thixotropic character
US4350780A (en) 1979-04-03 1982-09-21 Union Carbide Corporation Polyurethanes made with polymer/polyols prepared via preformed stabilizers
GB2120259A (en) * 1979-08-10 1983-11-30 Coopervision Preparation of non-cross-linked polymers and moulding process therefor
GB2161170A (en) * 1984-07-06 1986-01-08 Ricoh Kk Production of polymer particles
GB2207681A (en) * 1987-07-28 1989-02-08 Kansai Paint Co Ltd Dispersion of reactive polymer particles
US4985490A (en) * 1989-04-12 1991-01-15 Bayer Aktiengesellschaft Method of direct manufacture of pigmented polyurethane powder

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1122397A (en) * 1964-08-04 1968-08-07 Ici Ltd Polymer dispersion and dispersants
GB1156652A (en) * 1965-06-10 1969-07-02 Ici Ltd Coated Particles
GB1157630A (en) * 1965-07-29 1969-07-09 Ici Ltd Polymer Dispersions
US3753760A (en) * 1970-01-30 1973-08-21 Hunt P Liquid electrostatic development using an amphipathic molecule
US4098980A (en) 1976-06-24 1978-07-04 The Goodyear Tire & Rubber Company Non-aqueous dispersion polymerization of conjugated diolefins
US4453261A (en) * 1979-06-18 1984-06-05 Imperial Chemical Industries Plc Manufacture of aqueous polymer dispersions and coating compositions derived from them
US4252710A (en) * 1979-08-02 1981-02-24 Exxon Research & Engineering Co. Stabilized slurries of isoolefin polymers
EP0031997B2 (en) * 1979-12-21 1988-09-14 Imperial Chemical Industries Plc Polymerisation process for production of polymer microparticles of high refractive index and coating compositions containing them
DE3207292A1 (en) * 1982-03-01 1983-09-08 Röhm GmbH, 6100 Darmstadt CONCENTRATED EMULSIONS OF OLEFIN COPOLYMERS
DE3207291A1 (en) * 1982-03-01 1983-09-08 Röhm GmbH, 6100 Darmstadt CONCENTRATED EMULSIONS OF OLEFIN COPOLYMERS
US5331035A (en) * 1992-12-22 1994-07-19 Bridgestone Corporation Process for the preparation of in situ dispersion of copolymers
FR2710646B1 (en) * 1993-10-01 1995-12-22 Lvmh Rech Stable microdispersions and microgels based on acrylic polymers, process for obtaining them and compositions, in particular cosmetic, containing them.
WO2005021666A1 (en) * 2003-08-27 2005-03-10 Cytec Surface Specialties, S.A. Radiation-curable compositions for pigmented inks
FR2937645B1 (en) 2008-10-24 2010-12-17 Oreal FLEXIBLE PARTICLE DISPERSION OF POLYMER, COSMETIC COMPOSITION COMPRISING SAME, AND PROCESS FOR COSMETIC TREATMENT
CN110903436B (en) * 2019-12-04 2022-09-09 东胜化学(上海)有限公司 Solution containing self-extinction acrylic polymer particles and preparation method thereof

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1719427A1 (en) * 1966-11-25 1973-05-30 Dulux Australia Ltd DISPERSIONS
DE2114773A1 (en) * 1971-03-26 1972-09-28 Hunt Chem Corp Philip A Liquid electrostatographic developer - contg film forming fixing agen solvent solid dispersant etc
US3931432A (en) * 1973-01-04 1976-01-06 Imperial Chemical Industries Limited Printing process
US3846828A (en) * 1973-04-04 1974-11-05 Dow Chemical Co High solids content vinylidene chloride polymer dispersions in strongly hydrogen bonded dispersing media and process of preparation thereof
US3950284A (en) 1973-07-28 1976-04-13 Toray Industries, Inc. Polymer dispersed liquid
US4294735A (en) 1977-04-25 1981-10-13 Imperial Chemical Industries Limited Coating compositions
US4180489A (en) * 1977-04-25 1979-12-25 Imperial Chemical Industries Limited Coating composition
US4206099A (en) 1977-04-25 1980-06-03 Imperial Chemical Industries Limited Autoxidizable coating compositions
EP0001489A2 (en) * 1977-10-12 1979-04-18 Imperial Chemical Industries Plc Preparation of sterically stabilised aqueous polymer dispersions
EP0001489A3 (en) * 1977-10-12 1979-06-13 Imperial Chemical Industries Limited Preparation of sterically stabilised aqueous polymer dispersions
US4209435A (en) 1977-10-12 1980-06-24 Ici Ltd Dispersion preparation
US4232135A (en) 1978-01-10 1980-11-04 Imperial Chemical Industries Limited Coating compositions
US4242249A (en) 1979-04-03 1980-12-30 Union Carbide Corporation Polymer/polyols via non-aqueous dispersion stabilizers
US4350780A (en) 1979-04-03 1982-09-21 Union Carbide Corporation Polyurethanes made with polymer/polyols prepared via preformed stabilizers
GB2120259A (en) * 1979-08-10 1983-11-30 Coopervision Preparation of non-cross-linked polymers and moulding process therefor
EP0038127A1 (en) * 1980-04-14 1981-10-21 Imperial Chemical Industries Plc Multi-layer coating process involving use of aqueous basecoat composition containing crosslinked polymer microparticles and having a pseudoplastic or thixotropic character
GB2161170A (en) * 1984-07-06 1986-01-08 Ricoh Kk Production of polymer particles
GB2207681A (en) * 1987-07-28 1989-02-08 Kansai Paint Co Ltd Dispersion of reactive polymer particles
GB2207681B (en) * 1987-07-28 1991-02-06 Kansai Paint Co Ltd Dispersion of reactive polymer particles
US4985490A (en) * 1989-04-12 1991-01-15 Bayer Aktiengesellschaft Method of direct manufacture of pigmented polyurethane powder

Also Published As

Publication number Publication date
NL295760A (en) 1900-01-01
NL294396A (en) 1900-01-01
FR1365607A (en) 1964-07-03
MY6400071A (en) 1964-12-31
BE584369A (en) 1900-01-01
MY6700095A (en) 1967-12-31
SE310063B (en) 1969-04-14
FR1244568A (en) 1960-10-28
GB941305A (en) 1963-11-06
BE633840A (en) 1900-01-01
DE1520119B2 (en) 1980-03-06
DE1570771B2 (en) 1974-09-05
GB1017931A (en) 1966-01-26
NL112597C (en) 1900-01-01
NL277174A (en) 1900-01-01
LU37864A1 (en) 1900-01-01
CH392873A (en) 1965-05-31
NL244968A (en) 1900-01-01
DE1520119C3 (en) 1980-10-30
DE1520119A1 (en) 1969-07-10
NL124341C (en) 1900-01-01
LU43943A1 (en) 1963-09-20
CH456942A (en) 1968-05-31
BE616314A (en) 1900-01-01
NL126614C (en) 1900-01-01
DE1570771C3 (en) 1975-05-07
NL295759A (en) 1900-01-01
DE1570771A1 (en) 1969-12-11

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