GB1049842A - Cellulosic webs - Google Patents
Cellulosic websInfo
- Publication number
- GB1049842A GB1049842A GB472865A GB472865A GB1049842A GB 1049842 A GB1049842 A GB 1049842A GB 472865 A GB472865 A GB 472865A GB 472865 A GB472865 A GB 472865A GB 1049842 A GB1049842 A GB 1049842A
- Authority
- GB
- United Kingdom
- Prior art keywords
- binder
- fibres
- liquid
- ethylene
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/18—Highly hydrated, swollen or fibrillatable fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/35—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The fibres in a web of cellulosic fibres are swollen by at least 50% by volume and are bound together by a binder of tensile modulus (by A.S. T.M. D882-61T) of 106 to 1011 dynes/cm2, distributed in isotropic microcellular configuration in the web. Such a product may be made from an aqueous slurry of fibres by laying the fibres into a sheet by paper-making methods, wet-pressing and then removing remaining water by solvent-exchange techniques so that the fibres remain in their swollen condition. The sheet is then impregnated with a solution or dispersion of a suitable binder in a solvent that is a swelling agent for or inert towards the fibres and the binder coagulated by immersion in a liquid that is miscible with this solvent but is not a solvent for the binder and is inert towards the fibres. The sheets are then dried. Swelling agents referred to are dimethylacetamide, dimethylformamide, dimethylsulphoxide, formamide, ethylene glycol, methyl alcohol, furfuryl alcohol, water and aqueous solutions of the hydroxides of sodium, potassium and lithium. The swelling liquid must be removed without loss of swelling, e.g. by displacement by an inert liquid which is miscible with water and may be then evaporated. If the displacing liquid has an affinity for water it may itself be displaced in turn by a liquid that has not. Liquids referred to for the first displacement are acetone, methyl ethyl ketone, tetrahydrofuran and dioxane, and for the second benzene and xylene. The swelling liquid or displacing liquid may be still present in the web when the binder is applied, or the solvent for the binder may itself serve as the swelling agent. The binder may be a polymer of acrylic or methacrylic acid or an ester thereof, of a vinyl ester, of a vinyl or vinylidene halide, of 2-chlorobutadiene, 2-3-chlorobutadiene, trichlorethylene, tetrafluorethylene or chlorotrifluorethylene, of styrene, an alkylstyrene or a halostyrene, of ethylene, propylene or butene, of vinyl-carbazole, N-vinylformamide, vinyl-pyrrolidone, acrylonitrile or vinylidene cyanide, of styrene-sulphonic, boronic or phosphoric acid, of formaldehyde, acetaldehyde, crotonaldehyde or acrolein, or of copolymers of these monomers with one another or with other monomers such as butadiene, isobutylene, isoprene, maleates, fumarates, maleic, fumaric and itaconic acids, alkyl glycidyl ether, glycidyl acrylate and methacrylate, alkyl vinyl ethers, ethylene oxide, propylene oxide, butylene oxide, cyclohexene epoxide, tetrahydrofuran, sulphur dioxide and carbon monoxide, or chemically modified polymers such as halogenated polyethylene, hydrolysed polyvinyl acetate, halogenated polyethers, halogenated copolymer of ethylene and propylene, chlorosulphonated polyolefines, halogenated or hydrolysed copolymer of ethylene and vinyl acetate, hydrogenated ethylene/carbon monoxide polymers, polyepoxides modified by hydrolysis, amination or phosphonation, polyesters, polyamides, condensation polymers of diisocyanates and glycols, dimercaptans, diamines or polyethers, or graft or block polymers, or starch, casein, gutta percha, gum acacia, guar gum or gum arabic, or hydroxyethyl-, cyanoethyl-, aminoethyl-or carboxymethyl-cellulose, starch or protein. After impregnation, the sheet may be calendered or embossed, or heated to crosslink or otherwise alter the binder. Plasticizers, polymer-curing agents, dyes, pigments and surfactants may be included. The products are normally water-impermeable, but may be made water-absorptive by treatment with surfactants.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34223164A | 1964-02-03 | 1964-02-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1049842A true GB1049842A (en) | 1966-11-30 |
Family
ID=23340925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB472865A Expired GB1049842A (en) | 1964-02-03 | 1965-02-03 | Cellulosic webs |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH446874A (en) |
DE (1) | DE1546431A1 (en) |
GB (1) | GB1049842A (en) |
NL (1) | NL6501300A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001049933A2 (en) * | 1999-12-30 | 2001-07-12 | Sca Hygiene Products Gmbh | A method of applying treatment chemicals to a fiber-based planar product and products obtained by said method |
-
1965
- 1965-02-02 NL NL6501300A patent/NL6501300A/xx unknown
- 1965-02-02 DE DE19651546431 patent/DE1546431A1/en active Pending
- 1965-02-03 CH CH147465A patent/CH446874A/en unknown
- 1965-02-03 GB GB472865A patent/GB1049842A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001049933A2 (en) * | 1999-12-30 | 2001-07-12 | Sca Hygiene Products Gmbh | A method of applying treatment chemicals to a fiber-based planar product and products obtained by said method |
WO2001049933A3 (en) * | 1999-12-30 | 2001-11-15 | Sca Hygiene Prod Gmbh | A method of applying treatment chemicals to a fiber-based planar product and products obtained by said method |
Also Published As
Publication number | Publication date |
---|---|
NL6501300A (en) | 1965-08-04 |
CH446874A (en) | 1967-11-15 |
DE1546431A1 (en) | 1970-07-30 |
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