GB1049216A - Improvements in or relating to the preparation of hydrides of phosphorous, arsenic and antimony - Google Patents
Improvements in or relating to the preparation of hydrides of phosphorous, arsenic and antimonyInfo
- Publication number
- GB1049216A GB1049216A GB22466/65A GB2246665A GB1049216A GB 1049216 A GB1049216 A GB 1049216A GB 22466/65 A GB22466/65 A GB 22466/65A GB 2246665 A GB2246665 A GB 2246665A GB 1049216 A GB1049216 A GB 1049216A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrides
- arsenic
- antimony
- phosphorous
- relating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052787 antimony Inorganic materials 0.000 title abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052785 arsenic Inorganic materials 0.000 title abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title abstract 2
- 150000004678 hydrides Chemical class 0.000 title abstract 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 title 1
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 abstract 3
- 229910000103 lithium hydride Inorganic materials 0.000 abstract 3
- 239000000843 powder Substances 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 239000012159 carrier gas Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
Hydrides of phosphorus, arsenic and antimony are prepared by reacting a gaseous halide of the element with lithium hydride powder at 100-250 DEG C. The halide may be mixed with an inert carrier gas, e.g. nitrogen or argon and the lithium hydride powder may be mixed with an inert solid, e.g. powdered quartz, sand, NaCl or KCl. The lithium hydride powder and inert solid if present may be agitated vigorously during the reaction.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1964S0091250 DE1467153A1 (en) | 1964-05-27 | 1964-05-27 | Manufacture of hydrides of the elements of main group V of the periodic table |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1049216A true GB1049216A (en) | 1966-11-23 |
Family
ID=7516378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22466/65A Expired GB1049216A (en) | 1964-05-27 | 1965-05-26 | Improvements in or relating to the preparation of hydrides of phosphorous, arsenic and antimony |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3428428A (en) |
| BE (1) | BE664520A (en) |
| CH (1) | CH448978A (en) |
| DE (1) | DE1467153A1 (en) |
| FR (1) | FR1435442A (en) |
| GB (1) | GB1049216A (en) |
| NL (1) | NL6504634A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4318890A (en) * | 1978-10-02 | 1982-03-09 | Monahan Daniel E | Reactor for generating granular metal hydride |
| US5156827A (en) * | 1989-03-14 | 1992-10-20 | Advanced Technology Materials, Inc. | Apparatus, process, and composition for in-situ generation of polyhydridic compounds of group iv-vi elements |
| US5664427A (en) * | 1989-03-08 | 1997-09-09 | Rocky Research | Rapid sorption cooling or freezing appliance |
| US5441716A (en) * | 1989-03-08 | 1995-08-15 | Rocky Research | Method and apparatus for achieving high reaction rates |
| US5598721A (en) | 1989-03-08 | 1997-02-04 | Rocky Research | Heating and air conditioning systems incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5628205A (en) * | 1989-03-08 | 1997-05-13 | Rocky Research | Refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates |
| DK0462226T3 (en) * | 1989-03-08 | 1995-07-10 | Rocky Research | Process and apparatus for achieving high reaction rates in solid-state gas reactor systems |
| US5545800A (en) * | 1994-07-21 | 1996-08-13 | Regents Of The University Of California | Clean process to destroy arsenic-containing organic compounds with recovery of arsenic |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2474021A (en) * | 1948-01-17 | 1949-06-21 | Du Pont | Production of metal compounds |
| US3188173A (en) * | 1953-08-06 | 1965-06-08 | British Titan Products | Process for the production of oxides of al, si and ti |
| NL277704A (en) * | 1961-04-27 | |||
| US3382048A (en) * | 1965-03-18 | 1968-05-07 | John E. Lindberg Jr. | Method of pretreating metallic hydrides |
-
1964
- 1964-05-27 DE DE1964S0091250 patent/DE1467153A1/en active Pending
-
1965
- 1965-04-12 NL NL6504634A patent/NL6504634A/xx unknown
- 1965-04-22 CH CH556165A patent/CH448978A/en unknown
- 1965-05-26 BE BE664520D patent/BE664520A/xx unknown
- 1965-05-26 GB GB22466/65A patent/GB1049216A/en not_active Expired
- 1965-05-26 FR FR18568A patent/FR1435442A/en not_active Expired
- 1965-05-27 US US459182A patent/US3428428A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CH448978A (en) | 1967-12-31 |
| US3428428A (en) | 1969-02-18 |
| FR1435442A (en) | 1966-04-15 |
| NL6504634A (en) | 1965-11-29 |
| BE664520A (en) | 1965-09-16 |
| DE1467153A1 (en) | 1969-08-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX9602906A (en) | Metal complexes for use as gas generants. | |
| MX9800736A (en) | Metal complexes for use as gas generants. | |
| GB1049216A (en) | Improvements in or relating to the preparation of hydrides of phosphorous, arsenic and antimony | |
| ES489170A1 (en) | Process for preparing stabilized, ammonium nitrate containing granules | |
| GB1406002A (en) | Pyrotechnic compositions for gas generation | |
| Simon et al. | Neoarchean reworking of TTG-like crust in the southernmost portion of the São Francisco Craton: U-Pb zircon dating and geochemical evidence from the São Tiago Batholith | |
| GB1252497A (en) | ||
| Levason et al. | Chromium (III) complexes of polydentate and macrocyclic selenoethers—synthesis, spectroscopic and exafs studies | |
| El-Sonbati | Polymer complexes. Part XVI. Structural chemistry of poly-(5-vinylsalicylidene) aniline complexes | |
| GB1127221A (en) | Prevention of hydrogen embrittlement in oxygen-bearing copper | |
| GB1475672A (en) | Perchlorate complexes | |
| SE7711593L (en) | MELT GRANULATED FERROCHROME AND METHOD OF PREPARING THIS | |
| GB1357504A (en) | Electric batteries | |
| AU498342B2 (en) | Boron alloyed iron powder | |
| ES454033A1 (en) | Process for the manufacture of hexamethyldisilazane | |
| Norman | A new general method for the synthesis of unsubstituted phosphino-silanes and-germanes | |
| Lehmann et al. | Lithium aluminates, 2: Li 5 AlO 4(Chemical reactions of lithium aluminates) | |
| URRUTIA | The homogeneous gas phase decomposition of hydrazine by singular perturbation methods | |
| Fronczek et al. | Actinide metallocarbaborane complex: synthesis and X-ray structure determination of the bis [η 5-(3)-1, 2-dicarbollyl] dichlorouranium (IV) dianion | |
| Ibers | The relativistic X-ray form factor for mercury | |
| GB1420051A (en) | Chalcogenide glasses | |
| BOLDYREV et al. | Study of the thermal decomposition of ammonium perchlorate and polystyrene-based mixed solid fuel using a time of flight mass-spectrometer(High temperature decomposition kinetics in vacuum of mixed ammonium perchlorate-polystyrene solid fuel, using time of flight mass spectrometer) | |
| KOEHNE et al. | Development and application of plasma sources for plasma chemical reactions | |
| US3205239A (en) | Sodium decaborane-tetrahydrofuran adduct and method for preparing same | |
| GB1297569A (en) |