GB1046575A - Graft polymers of chlorinated ethylene polymers - Google Patents
Graft polymers of chlorinated ethylene polymersInfo
- Publication number
- GB1046575A GB1046575A GB1856665A GB1856665A GB1046575A GB 1046575 A GB1046575 A GB 1046575A GB 1856665 A GB1856665 A GB 1856665A GB 1856665 A GB1856665 A GB 1856665A GB 1046575 A GB1046575 A GB 1046575A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chlorinated polyethylene
- polymers
- solvent
- aqueous suspension
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000578 graft copolymer Polymers 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 title 1
- 239000004709 Chlorinated polyethylene Substances 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000007900 aqueous suspension Substances 0.000 abstract 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 230000004913 activation Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical class CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Graft polymers are made by heating chlorinated polyethylene which has sites thereon activated for free-radical polymerization with at least 5% by weight of a vinylidene monomer in a liquid reaction medium. The activation of the chlorinated polyethylene may be effected by chlorinating polyethylene in the presence of oxygen or hydrogen peroxide, or by ozonizing chlorinated polyethylene. Monomers specified are styrene, methyl, ethyl, hydroxyethyl and glycidylmethacrylates, acrylonitrile, acrylamide, n-octyl acrylate and divinylbenzene. Polymerization may be carried out in aqueous suspension or in solution, e.g. in toluene. When polymerizing in aqueous suspension it is preferred to have present a solvent, e.g. methanol, which is a non-solvent for the chlorinated polyethylene, thereby minimizing the formation of vinylidene monomer homopolymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36430464A | 1964-05-01 | 1964-05-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1046575A true GB1046575A (en) | 1966-10-26 |
Family
ID=23433918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1856665A Expired GB1046575A (en) | 1964-05-01 | 1965-05-03 | Graft polymers of chlorinated ethylene polymers |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS503357B1 (en) |
| BE (1) | BE663290A (en) |
| DE (1) | DE1570204A1 (en) |
| GB (1) | GB1046575A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001788A1 (en) * | 1977-10-27 | 1979-05-16 | Hoechst Aktiengesellschaft | Use of thermoplastic masses based on chlorinated polyolefins for the manufacture of medical devices and medical devices obtained thereby |
| EP0016493A1 (en) * | 1979-03-05 | 1980-10-01 | Uniroyal, Inc. | Copolymer elastomer with improved heat and oil resistance based on modified chlorinated polyethylene |
| CN112920413A (en) * | 2021-01-29 | 2021-06-08 | 常州爱特恩新材料科技有限公司 | Ionomer type grafted multifunctional material, preparation method thereof and application thereof in PVC (polyvinyl chloride) |
| CN114213591A (en) * | 2022-02-24 | 2022-03-22 | 山东三义集团股份有限公司 | Chlorinated polyethylene graft copolymer and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4477633A (en) * | 1983-12-15 | 1984-10-16 | E. I. Dupont De Nemours And Company | Simultaneously chlorinating and grafting a cure site onto polyethylene in an aqueous suspension |
-
1965
- 1965-04-30 BE BE663290D patent/BE663290A/xx unknown
- 1965-05-01 JP JP2562565A patent/JPS503357B1/ja active Pending
- 1965-05-03 GB GB1856665A patent/GB1046575A/en not_active Expired
- 1965-05-03 DE DE19651570204 patent/DE1570204A1/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001788A1 (en) * | 1977-10-27 | 1979-05-16 | Hoechst Aktiengesellschaft | Use of thermoplastic masses based on chlorinated polyolefins for the manufacture of medical devices and medical devices obtained thereby |
| EP0016493A1 (en) * | 1979-03-05 | 1980-10-01 | Uniroyal, Inc. | Copolymer elastomer with improved heat and oil resistance based on modified chlorinated polyethylene |
| CN112920413A (en) * | 2021-01-29 | 2021-06-08 | 常州爱特恩新材料科技有限公司 | Ionomer type grafted multifunctional material, preparation method thereof and application thereof in PVC (polyvinyl chloride) |
| CN112920413B (en) * | 2021-01-29 | 2022-02-22 | 常州爱特恩新材料科技有限公司 | Ionomer type grafted multifunctional material, preparation method thereof and application thereof in PVC (polyvinyl chloride) |
| CN114213591A (en) * | 2022-02-24 | 2022-03-22 | 山东三义集团股份有限公司 | Chlorinated polyethylene graft copolymer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1570204A1 (en) | 1970-02-05 |
| BE663290A (en) | 1965-08-17 |
| JPS503357B1 (en) | 1975-02-03 |
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