GB1041014A - Preparation of expandable thermoplastic particles - Google Patents
Preparation of expandable thermoplastic particlesInfo
- Publication number
- GB1041014A GB1041014A GB1222963A GB1222963A GB1041014A GB 1041014 A GB1041014 A GB 1041014A GB 1222963 A GB1222963 A GB 1222963A GB 1222963 A GB1222963 A GB 1222963A GB 1041014 A GB1041014 A GB 1041014A
- Authority
- GB
- United Kingdom
- Prior art keywords
- blowing agent
- thermoplastic
- low
- wax
- polythene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
Abstract
A blowing agent is uniformly distributed throughout a particulate thermoplastic mass by maintaining the thermoplastic in contact with the blowing agent and a low M.W. material solid at 25 DEG C., the mixture meanwhile being heated to a temperature at which the low M.W. material is fluid, but which is not above the sintering temperature of the thermoplastic and is below the decomposition temperature of the blowing agent, so that the thermoplastic is coated with the other materials, the coating then being allowed to solidify. The low M.W. material may be molten or in solution. 0.1-5% of the blowing agent and 0.1-10% of the low M.W. material may be used. Articles, e.g. wire insulation, shock absorbers, packing material and laminates may be formed from the product at a temperature at which the blowing agent decomposes. Two types of low M.W. materials are specified: (a) Polymers of ethylene, propylene and butene and copolymers of these with styrene and acrylates of 3500-12,000 M.W., prepared either from the monomers or by pyrolysis at 300-600 DEG C. of higher molecular weight polymers. (b) Waxy materials of melting point 25-150 DEG C., insoluble in water, at least partially soluble in alcohol and ether and completely soluble in oils, fats and hydrocarbon solvents. Type (b) is exemplified by petroleum, paraffin and microcrystalline waxes, spermaceti, beeswax, Chinese insect wax, ozokerite, montan, ceresin, carnauba wax, japan wax, bayberry wax and candelilla wax, jojoba wax. Mixtures of low molecular weight materials may be used. Blowing agents specified are carbonates, azo compounds, N-nitroso compounds, sulphonyl hydrazides, aryoyl azides, N-nitro-N1 - cyclohexyl - urea, N,N1 - dinitroethylene urea, nitroguanadine, nitrobiuret, N,N1-dinitro - N,N1 - dimethyl - oxamide, N - nitrophthalimide, N - nitrosuccimide, N,N1 - dinitroso - N,N1 - diacetyl - ethylenediamine and N-nitroxazolidone. Four types of thermoplastics are specified: (i) polymers and copolymers of olefinically unsaturated compounds, e.g. hydrocarbons, dienes, mono and dicarboxylic acids, amides and esters, including glycidyl methacrylate, halides, nitriles, silanes and phosphonates, (ii) polymers derived from ethylene oxide, (iii) condensates of bisphenols with carbonate precursors, e.g. 2,2-bis-(4-hydroxyphenol) propane and dialkyl or diaryl esters of carbonic acid or phosgene; (iv) condensates of bisphenols with epihalohydrins. The thermoplastics may contain as additives fillers, extenders, opacifiers, modifiers and stabilizers. In Examples (1)-(6) low M.W. polythene (1)-(5) or paraffin wax (6) was added to a mixture of polypropylene (1), (4), polyisobutylene (1), polyvinyl chloride (2), polyethylene (3) or 2,2-bis-(4 - hydroxyphenyl) propane / epichlorohydrin condensate (6) and 1,11-azo-bisformamide (1), (3)-(6) or N,N1 - dimethyl - N,N1 - dinitroso-terephthalimide (2) and oxanilide (1), tribasic lead sulphate (2), dioctyl phthalate (2), hydrolysed clay (2) and CaCO3 (2). The mixture was then melted and cooled to solidify. In Examples (13)-(15) the reactants were as in Example (1), but (13) the blowing agent in molten polythene was added to the thermoplastic, (14) the blowing agent and polythene dissolved in toluene were added to the thermoplastic and (15) the polythene dissolved in toluene was added to the blowing agent and the thermoplastic.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18457262A | 1962-04-02 | 1962-04-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1041014A true GB1041014A (en) | 1966-09-01 |
Family
ID=22677456
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1222963A Expired GB1041014A (en) | 1962-04-02 | 1963-03-28 | Preparation of expandable thermoplastic particles |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE630359A (en) |
GB (1) | GB1041014A (en) |
NL (1) | NL291028A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3509247A (en) * | 1967-09-11 | 1970-04-28 | Anaconda Wire & Cable Co | Extrusion method |
US3528841A (en) * | 1967-11-15 | 1970-09-15 | Nat Distillers Chem Corp | Method for reducing tackiness of polymer pellets |
-
0
- NL NL291028D patent/NL291028A/xx unknown
- BE BE630359D patent/BE630359A/xx unknown
-
1963
- 1963-03-28 GB GB1222963A patent/GB1041014A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3509247A (en) * | 1967-09-11 | 1970-04-28 | Anaconda Wire & Cable Co | Extrusion method |
US3528841A (en) * | 1967-11-15 | 1970-09-15 | Nat Distillers Chem Corp | Method for reducing tackiness of polymer pellets |
Also Published As
Publication number | Publication date |
---|---|
NL291028A (en) | |
BE630359A (en) |
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