GB1027149A - Preparation of synthetic resins - Google Patents

Preparation of synthetic resins

Info

Publication number
GB1027149A
GB1027149A GB4176563A GB4176563A GB1027149A GB 1027149 A GB1027149 A GB 1027149A GB 4176563 A GB4176563 A GB 4176563A GB 4176563 A GB4176563 A GB 4176563A GB 1027149 A GB1027149 A GB 1027149A
Authority
GB
United Kingdom
Prior art keywords
polymerization
styrene
added
preparation
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4176563A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beck & Co GmbH
Original Assignee
Beck & Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beck & Co GmbH filed Critical Beck & Co GmbH
Publication of GB1027149A publication Critical patent/GB1027149A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/123—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/137—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C08G18/4233—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups derived from polymerised higher fatty acids or alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C08G18/683—Unsaturated polyesters containing cyclic groups
    • C08G18/686—Unsaturated polyesters containing cyclic groups containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The improvement in or modification of the process claimed in Specification 896,396, wherein (i) a product obtained by the polymerization of a monomeric unsaturated fatty acid containing more than 7 C under conditions such that the free carboxyl group of the monomer is preserved, or an alkyl or glycol ester of such a polymerization product forms at least part of the fatty acid component used in the preparation of the component A1; and/or (ii) such a polymerization product or an alkyl or glycol ester thereof is used to replace at least a part of the fatty acid glyceride in the preparation of the component A-2. The polymerization products are derived from thermal or catalytic polymerization of monomeric unsaturated fatty acids to form di-, tri- and polymeric compounds and may contain residues of monomeric vinyl compounds, e.g. styrene which are copolymerized simultaneously. In Example (1) maleic anhydride, phthalic anhydride, n-hexanol and triethanolamine were first reacted at 130-140 DEG C. and then ethylene glycol, benzoic acid, azelaic acid, dimerized linoleic acid dimethyl ester and trimerized linoleic acid trimethyl ester and diterkiarybutyl-p-cresol as inhibitor were added and condensation carried out. A solution of the product in styrene was added to a complex isocyanate solution (prepared from styrene, tolylene diisocyanate, benzoquinone, dry castor oil, dry boleko oil and a mixture of hexane triol and 2-ethylhexane 1,3-diol) and diethylaniline in vinyltoluene and dibenzoyl peroxide and dimethylphthalate added. The mass was allowed to solidify overnight and then heated gently up to 120 DEG C. to obtain golden brown mass.
GB4176563A 1962-10-24 1963-10-23 Preparation of synthetic resins Expired GB1027149A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB69355A DE1200530B (en) 1962-10-24 1962-10-24 Process for the production of elastic to tough plastics with shaping

Publications (1)

Publication Number Publication Date
GB1027149A true GB1027149A (en) 1966-04-27

Family

ID=6976252

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4176563A Expired GB1027149A (en) 1962-10-24 1963-10-23 Preparation of synthetic resins

Country Status (2)

Country Link
DE (1) DE1200530B (en)
GB (1) GB1027149A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5385788A (en) * 1990-07-13 1995-01-31 Coates Brothers Plc Polyesters
WO2014029975A2 (en) * 2012-08-23 2014-02-27 Croda International Plc Polyurethanes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5385788A (en) * 1990-07-13 1995-01-31 Coates Brothers Plc Polyesters
WO2014029975A2 (en) * 2012-08-23 2014-02-27 Croda International Plc Polyurethanes
WO2014029975A3 (en) * 2012-08-23 2014-05-15 Croda International Plc Polyurethanes
US9815939B2 (en) 2012-08-23 2017-11-14 Croda International Plc Polyurethanes

Also Published As

Publication number Publication date
DE1200530B (en) 1965-09-09

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