GB1025693A - Process for the production of poly-addition products from bisketones and compounds with reactive hydrogen - Google Patents

Process for the production of poly-addition products from bisketones and compounds with reactive hydrogen

Info

Publication number
GB1025693A
GB1025693A GB629/63A GB62963A GB1025693A GB 1025693 A GB1025693 A GB 1025693A GB 629/63 A GB629/63 A GB 629/63A GB 62963 A GB62963 A GB 62963A GB 1025693 A GB1025693 A GB 1025693A
Authority
GB
United Kingdom
Prior art keywords
copolymers
adduct
compounds
pyridine
reactive hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB629/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of GB1025693A publication Critical patent/GB1025693A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/87—Preparation of ketenes or dimeric ketenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/88—Ketenes; Dimeric ketenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Polyaddition compounds are prepared by reacting high molecular weight compounds having reactive hydrogen atoms with an adduct of a bisketene with pyridine and/or a derivative of pyridine. From 50 to 1% of the adduct may be used. Specified reactive hydrogen containing compounds are polyethers from ethylene oxide and/or propylene oxide, tetrahydrofurane polymers, polythioethers from thioglycol and glycol with hydroxyl terminal groups, polyformaldehyde, polyacrolein, linear polyesters from saturated and/or unsaturated dicarboxylic acids, e.g. adipic, phthalic, tetrahydrophthalic, tetrachlorophthalic, hexachloroendomethylene - tetrahydrophthalic, fumaric and maleic acids and anhydrides and diols, e.g. ethylene glycol, diethylene glycol, propanediol and epoxides, or from dicarboxylic acids and diols or polyols such as trimethylolpropane, glycerin and pentaerythritol, polymers and copolymers having carboxylic groups from acrylic or fumaric acids, copolymers of endomethylene tetrahydrobenzyl alcohol, partially or completely saponified homopolymers or copolymers of vinyl acetate and/or vinylidene carbonate, saponified maleic anhydride/olefin copolymer, copolymers from the hydrolysis of vinyl phthalimide and disubstituted acid amides as well as polymerizable monomer solvents, e.g. styrene, methyl methacrylate and dialkyl phthalate in which case a polymerization catalyst, e.g. organic peroxides and/or azobis-isobutyronitrile is also present. Solvents and diluents, e.g. liquid hydrocarbons, chlorohydrocarbons, ketones, ethers and esters, may be present or absent as may dyes, fillers, stabilizers, extenders, elastifiers, foam-forming substances and fire-proofing materials. In Examples (1) polyethylene oxide of molecular weight 1000 is heated at 70 DEG C. with 0.1 mole of cyclohexane-bisketene-pyridine adduct, (2) the reaction product of polyvinyl-idene carbonate and lauryloxy-propylamine containing the grouping. <FORM:1025693/C3/1> is dissolved in methyl ethyl ketone and heated with xylylene-bis-methylketene-quinoline adduct.
GB629/63A 1962-01-08 1963-01-07 Process for the production of poly-addition products from bisketones and compounds with reactive hydrogen Expired GB1025693A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC25929A DE1156562B (en) 1962-01-08 1962-01-08 Process for the preparation of polyadducts from bisketene and compounds with active hydrogen

Publications (1)

Publication Number Publication Date
GB1025693A true GB1025693A (en) 1966-04-14

Family

ID=7017997

Family Applications (1)

Application Number Title Priority Date Filing Date
GB629/63A Expired GB1025693A (en) 1962-01-08 1963-01-07 Process for the production of poly-addition products from bisketones and compounds with reactive hydrogen

Country Status (3)

Country Link
DE (1) DE1156562B (en)
FR (1) FR1345334A (en)
GB (1) GB1025693A (en)

Also Published As

Publication number Publication date
DE1156562B (en) 1963-10-31
FR1345334A (en) 1963-12-06

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