GB1025569A - Phosphorus-containing cyclic acetals and mercaptals - Google Patents
Phosphorus-containing cyclic acetals and mercaptalsInfo
- Publication number
- GB1025569A GB1025569A GB21743/63A GB2174363A GB1025569A GB 1025569 A GB1025569 A GB 1025569A GB 21743/63 A GB21743/63 A GB 21743/63A GB 2174363 A GB2174363 A GB 2174363A GB 1025569 A GB1025569 A GB 1025569A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- mercaptals
- phosphorus
- containing cyclic
- cyclic acetals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 cyclic acetals Chemical class 0.000 title abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002903 organophosphorus compounds Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
- C07F9/655345—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
- C07F9/655363—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a six-membered ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/08—Systemic pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises compounds of formula <FORM:1025569/C2/1> where R and R1 are C1- 8 alkyl, R2 i H or C1- 5 alkyl, R3 is CH2 or C=O, n is 1 or 2, X is oxygen or sulphur (same or different), Y is C1- 3 alkylene, phenylene or carbethoxymethylene. They are prepared by reacting (RO)(R1O)P (X)XYC(O)R2 with HXR3(CH2)nXH. O,O - Diethyl - 5 - [1 - carbethoxy - 2 - oxopropyl-1] phosphorothioate is prepared by reacting (C2H5O)2P(O)(SK) with C2H5OC(O)CH ClC(3)CH3.ALSO:Pesticidal compositions comprise organophosphorus compounds of formula <FORM:1025569/A5-A6/1> where R and R1 are C1-8 alkyl, R2 is H or C1-5 alkyl, R3 is CH2 or C = 0,n is 1 or 2, X (same or different) is D or S, Y is C1-3 alkylene, phenylene or carbethoxymethylene. Aqueous dispersions, emulsions, wettable powders, dusts and vapours are specified.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202686A US3247223A (en) | 1962-06-15 | 1962-06-15 | Cyclic mercaptals |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1025569A true GB1025569A (en) | 1966-04-14 |
Family
ID=22750868
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21743/63A Expired GB1025569A (en) | 1962-06-15 | 1963-05-30 | Phosphorus-containing cyclic acetals and mercaptals |
Country Status (6)
Country | Link |
---|---|
US (1) | US3247223A (en) |
BE (1) | BE633592A (en) |
BR (1) | BR6349862D0 (en) |
CH (2) | CH428764A (en) |
GB (1) | GB1025569A (en) |
NL (1) | NL294012A (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3317561A (en) * | 1963-05-29 | 1967-05-02 | American Cyanamid Co | New heterocyclic organo-phosphate compounds |
US3427147A (en) * | 1966-08-15 | 1969-02-11 | Olin Mathieson | Iminodioxolanes as herbicides |
CA1058192A (en) * | 1972-11-03 | 1979-07-10 | Ciba-Geigy Ag | Esters |
US4237056A (en) * | 1979-07-26 | 1980-12-02 | Velsicol Chemical Corporation | Cyclic acetal-methyl-carbamoyl-methyl esters of phosphonic and phosphoric acid |
US4314840A (en) * | 1979-07-26 | 1982-02-09 | Velsicol Chemical Corporation | Cyclic acetal-methyl-carbamoyl-methyl esters of phosphonic and phosphoric acids, as herbicides |
US4230720A (en) * | 1979-07-30 | 1980-10-28 | Stauffer Chemical Company | Heterocyclic dithiophosphates or phosphonates as insecticides and acaricides |
US4216222A (en) * | 1979-07-30 | 1980-08-05 | Stauffer Chemical Company | Alkyl or alkoxy-O-alkyl-S-[N-(2-alkyl, phenyl or vinyl-1,3-dioxolan-4-yl) methylaminoacetyl] dithiophosphates or phosphonates as insecticides and acaricides |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2701253A (en) * | 1955-02-01 | Substituted dithiolanes | ||
NL86689C (en) * | 1951-04-20 | 1900-01-01 | ||
US2789124A (en) * | 1951-07-02 | 1957-04-16 | Allied Chem & Dye Corp | Organic phosphate compounds and method of preparation and use thereof |
US2920997A (en) * | 1955-02-14 | 1960-01-12 | Pittsburgh Coke And Chemical C | Fungicidal composition of a hydantoin selected from the group consisting of 5, 5 polymethylene and 5, 5 diaryl, and 5, 5 aryl, alky hydantion |
US2815350A (en) * | 1955-08-30 | 1957-12-03 | Hercules Powder Co Ltd | Method of preparing organic dithiophosphoric acid compounds |
US2853416A (en) * | 1955-09-19 | 1958-09-23 | Gen Aniline & Film Corp | Method of protecting plants by applying a pesticidal amount of a polyvinylpyrrolidone-iodine adduct |
US3053852A (en) * | 1958-08-21 | 1962-09-11 | Eastman Kodak Co | Phosphorothiolothionates derived from vinylene carbonate and vinylene sulfite |
US3071594A (en) * | 1960-07-23 | 1963-01-01 | Bayer Ag | Thiophosphoric acid esters and processes for their production |
-
0
- BE BE633592D patent/BE633592A/xx unknown
- NL NL294012D patent/NL294012A/xx unknown
-
1962
- 1962-06-15 US US202686A patent/US3247223A/en not_active Expired - Lifetime
-
1963
- 1963-05-30 GB GB21743/63A patent/GB1025569A/en not_active Expired
- 1963-06-13 CH CH738263A patent/CH428764A/en unknown
- 1963-06-13 CH CH1710966A patent/CH430320A/en unknown
- 1963-06-14 BR BR149862/63A patent/BR6349862D0/en unknown
Also Published As
Publication number | Publication date |
---|---|
BR6349862D0 (en) | 1973-06-26 |
CH430320A (en) | 1967-02-15 |
CH428764A (en) | 1967-01-31 |
BE633592A (en) | |
NL294012A (en) | |
US3247223A (en) | 1966-04-19 |
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