GB1021887A - Coating compositions for paper - Google Patents
Coating compositions for paperInfo
- Publication number
- GB1021887A GB1021887A GB4807262A GB4807262A GB1021887A GB 1021887 A GB1021887 A GB 1021887A GB 4807262 A GB4807262 A GB 4807262A GB 4807262 A GB4807262 A GB 4807262A GB 1021887 A GB1021887 A GB 1021887A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- water
- compounds
- acrylic
- weight per
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/50—Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
- C08L89/005—Casein
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Compositions for coating paper comprise an alkaline casein solution and a polymer dispersion obtained by emulsion polymerization of a mixture of 90 to 99.9 weight per cent of one or more water-insoluble saponifiable ethylenically unsaturated compounds and 10 to 0.1 weight per cent of one or more ethylenically unsaturated compounds which yield water-soluble polymers, at a pH of 3 to 6.5 in the presence of 0.3 to 5 weight per cent based on the monomers of one or more alkali metal or ammonium salts of sulphuric acid half esters of reaction products of ethylene oxide and/or propylene oxide with compounds containing hydroxyl, carboxyl, amide or imide groups, any adjustment of pH to a value above 6.5 being effected only after polymerization is completed. Specified watersoluble monomers are acrylic, methacrylic, maleic, fumaric, a -ethylacrylic, crotonic, a -chloracrylic and vinyl sulphonic acids, acrylamide, methacrylamide, vinyl lactams such as N-vinyl pyrrolidone, C-vinyl amines, N-vinyl amines and salts thereof. Specified saponifiable compounds are vinyl acetate, vinyl propionate, acrylic and methacrylic esters of alcohols containing 1 to 4 carbon atoms, maleic and itaconic esters and N,N-dibutylacrylamide. The monomer mixture may also comprise minor proportions of unsaponifiable compounds such as vinyl ethers, vinyl halides, vinylidene halides, butadiene, isoprene and styrene; and water soluble compounds which yield water-insoluble polymers, e.g. acrylonitrile, methacrylonitrile and acrolein. The emulsifiers may be derived from fatty alcohols, fatty acids, resin acids, amides and imides of carboxylic and sulphonic acids, alkyl phenols and alkyl naphthols, and may be used alone or together with other emulsifiers and stabilizers, e.g. alkali metal and ammonium salts of carboxylic and sulphonic acids or sulphuric acid half esters, polyvinyl alcohol, polyvinyl pyrrolidone and polyacrylamide. amide. The casein may be dissolved in aqueous ammonia, ethanolamine or caustic soda. The coating compositions may also contain soya bean meal, starches, water-soluble cellulose derivatives, dispersing agents, optical brighteners, dyes and pigments, e.g. kaolin, barium sulphate, calcium carbonate, titanium dioxide and calcium sulphoaluminate. Examples describe (1) the preparation of a dispersion by copolymerizing sodium vinyl sulphonate, acrylic acid, vinyl propionate and n-butyl acrylate in the presence of potassium persulphate and the sodium sulphate half ester of an ethylene oxide-iso-octylphenol condensate; and coating compositions comprising caustic soda solubilized casein, kaolin and aqueous dispersions prepared as in Example (1) of copolymers of sodium vinyl sulphonate and acrylic acid with (1) vinyl propionate and n-butyl acrylate, (2 and 3) vinyl propionate and (4) isobutyl acrylate and t.-butyl acrylate.ALSO:Paper may be coated with compositions comprising an alkaline casein solution and a polymer dispersion obtained by emulsion polymerization of a mixture of 90-99,9 weight per cent of one or more water-insoluble saponifiable ethylenically unsaturated compounds and 10-0,1 weight per cent of one or more ethylenically unsaturated compounds which yield water-soluble polymers, at a pH of 3-6,5 in the presence of 0,3-5 weight per cent based on the monomers of one or more alkali metal or ammonium salts of sulphuric acid half esters of reaction products of ethylene oxide and/or propylene oxide with compounds containing hydroxyl, carboxyl, amide or imide groups, any adjustment of pH to a value above 6,5 being effected after polymerization is completed. The compositions may also comprise soya bean meal, starches, water-soluble cellulose derivatives, dispersing agents, optical brighteners, dyes and pigments, e.g. kaolin, barium sulphate, calcium carbonate, titanium dioxide and calcium sulphoaluminate. Specified monomers yielding water-soluble polymers are acrylic, methacrylic, maleic, fumaric, a -ethyl acrylic, crotonic, a -chloracrylic and vinyl sulphonic acids, acrylamide, methacrylamide, N-vinyl pyrrolidone, C-vinyl pyridines, N-vinyl pyridines and salts thereof. Specified saponifiable compounds are vinyl acetate, vinyl propionate, acrylic and methacrylic esters of alcohols containing 1-4 carbon atoms, maleic and itaconic esters and N,N-dibutylacrylamide. The monomer mixture may also comprise minor proportions of unsaponifiable compounds such as vinyl ethers, vinyl halides, vinylidene halides, butadiene, isoprene and styrene; and water-soluble compounds yielding water-insoluble polymers, e.g. acrylonitrile, methacrylonitrile and acrolein. The casein may be dissolved in aqueous ammonia, ethanolamine or caustic soda. Examples describe the coating of paper with compositions comprising caustic soda solubilized casein, kaolin and dispersions of copolymers of sodium vinyl sulphonate and acrylic acid with (1) vinyl propionate and n-butyl acrylate, (2 and 3) vinyl propionate and (4) isobutyl acrylate and t.butyl acrylate, prepared in the presence of the sodium sulphate half ester of an isooctyl phenol-ethylene oxide condensate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB65331A DE1197743B (en) | 1961-12-23 | 1961-12-23 | Paper coating slips |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1021887A true GB1021887A (en) | 1966-03-09 |
Family
ID=6974735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4807262A Expired GB1021887A (en) | 1961-12-23 | 1962-12-20 | Coating compositions for paper |
Country Status (5)
Country | Link |
---|---|
AT (1) | AT238949B (en) |
BE (1) | BE626416A (en) |
CH (1) | CH459742A (en) |
DE (1) | DE1197743B (en) |
GB (1) | GB1021887A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2006233A (en) * | 1977-10-20 | 1979-05-02 | Wacker Chemie Gmbh | Aqueous vinyl acetate copolymer dispersions for use as binders for non-woven materials |
US4495029A (en) * | 1979-03-24 | 1985-01-22 | Feldmuhle Aktiengesellschaft | Process for the preparation of coated paper and cardboard and coating materials for the performance of the process |
WO1999029779A1 (en) * | 1997-12-10 | 1999-06-17 | Fausto De Donato | Composition for bleaching woodpulp and process for its production |
US6974852B2 (en) | 1997-02-14 | 2005-12-13 | Basf Aktiengesellschaft | Emulsifier system for aqueous emulsion polymerization |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7701688A (en) * | 1977-02-17 | 1978-08-21 | Scholten Honig Research Nv | PROCESS FOR PREPARING FLOATING MASSES FOR PAPER WITH VINYL ACETATE COPOLYMER DISPERSIONS AS BINDING AGENTS. |
-
0
- BE BE626416D patent/BE626416A/xx unknown
-
1961
- 1961-12-23 DE DEB65331A patent/DE1197743B/en active Pending
-
1962
- 1962-11-26 CH CH1384262A patent/CH459742A/en unknown
- 1962-12-19 AT AT992962A patent/AT238949B/en active
- 1962-12-20 GB GB4807262A patent/GB1021887A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2006233A (en) * | 1977-10-20 | 1979-05-02 | Wacker Chemie Gmbh | Aqueous vinyl acetate copolymer dispersions for use as binders for non-woven materials |
US4495029A (en) * | 1979-03-24 | 1985-01-22 | Feldmuhle Aktiengesellschaft | Process for the preparation of coated paper and cardboard and coating materials for the performance of the process |
US6974852B2 (en) | 1997-02-14 | 2005-12-13 | Basf Aktiengesellschaft | Emulsifier system for aqueous emulsion polymerization |
WO1999029779A1 (en) * | 1997-12-10 | 1999-06-17 | Fausto De Donato | Composition for bleaching woodpulp and process for its production |
Also Published As
Publication number | Publication date |
---|---|
AT238949B (en) | 1965-03-10 |
DE1197743B (en) | 1965-07-29 |
CH459742A (en) | 1968-07-15 |
BE626416A (en) |
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