GB1021388A - New plastisols and organosols - Google Patents
New plastisols and organosolsInfo
- Publication number
- GB1021388A GB1021388A GB14465A GB14465A GB1021388A GB 1021388 A GB1021388 A GB 1021388A GB 14465 A GB14465 A GB 14465A GB 14465 A GB14465 A GB 14465A GB 1021388 A GB1021388 A GB 1021388A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phthalate
- chlorallyl
- vinyl
- ethylhexyl
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Plastisols and organosols comprise a pulverulent, halogen-containing vinyl polymer, a polymerizable plasticizer in which said polymer is substantially insoluble at room temperature, a polymerization catalyst and a stabilizer for the vinyl polymer, said plasticizer consisting at least in part of a compound of formula <FORM:1021388/C3/1> where R is an aliphatic, cycloaliphatic, araliphatic or aromatic residue. Specified polymers are polyvinyl chloride, copolymers of vinyl chloride with vinyl acetate, maleic anhydride, ethylene, acrylonitrile, vinylidene chloride or acrylic acid esters, chlorinated polyvinyl chloride and partially hydrolysed copolymers of vinyl chloride with vinyl acetate or vinyl acetals. In the plasticizers R may be a residue of 2-chlorallyl,allyl, methyl, ethyl, propyl, butyl, amyl, hexyl, octyl, lauryl, stearyl, oleyl, cyclohexyl or benzyl alcohols. Other plasticizers, e.g. dioctyl phthalate, diallyl phthalate, dibutyl sebacate and dibutyl adipate. Many suitable catalysts are listed, including hydrazine derivatives, tetraethyl lead, azodiisobutyronitrile, acyl and halogenated acyl peroxides, hydrocarbon peroxides and hydroperoxides, peracids, persalts and peresters. Many suitable stabilizers are listed, including calcium, strontium, barium, cadmium and lead soaps, basic lead salts, organotin salts and mono- and polyepoxides. Adhesion to substrates may be improved by adding basic substances, e.g. basic lead salts and alkaline earth metal hydroxides. The compositions may also contain fillers and pigments e.g. titanium dioxide, iron oxide, vegetable fillers and reinforcing agents, and solvents, e.g. acetone, tetrahydrofuran, cyclohexanone, toluene and xylene, and may be used for coating and cementing metals, wood, ceramics, textiles of polyamide or polyeste fibres, and making laminates, printing inks, putties and dipping, casting and potting resins. Examples describe compositions comprising polyvinyl chloride and (1) bis-(2-chlorallyl) phthalate, di-n-octyl phthalate, titanium dioxide, tertiary butyl perbenzoate, as stabilizer a mixture of basic lead carbonate and dibasic lead phthalate, barium (cadmium palmitate or dibutyl tin maleate, and optionally calcium hydroxide; (2) bis-(2-chlorallyl) phthalate, 2-ethylhexyl 2-chlorallyl phthalate and/or di-2-ethylhexyl phthalate, titanium dioxide, tertiary butyl perbenzoate, calcium hydroxide and barium/cadmium palmitate or epoxy resin; (5) bis-(2-chlorallyl) phthalate, 2-ethylhexyl 2-chlorallyl phthalate, di-2-ethylhexyl phthalate, chromium oxide, tertiary butyl perbenzoate, barium/cadmium palmitate and calcium hydroxide; together with (3) isophorone and toluene; and (4) butanol, amyl alcohol and decalin.ALSO:Substrates may be coated with plastisols and organosols comprising a pulverulent, halogen-containing vinyl polymer, a polymerizable plasticizer of formula <FORM:1021388/B1-B2/1> where R is an aliphatic, cycloaliphatic, araliphatic or aromatic residue, in which the polymer is substantially insoluble at room temperature, a polymerization catalyst and a stabilizer for the vinyl polymer. The compositions may be used for coating metals, e.g. iron, copper, and brass, wood, ceramics and textiles of polyamide or polyester fibre. Specified polymers are polyvinyl chloride, copolymers of vinyl chloride with vinyl acetate, maleic anhydride, ethylene, acrylonitrile, vinylidene chloride and acrylic esters, chlorinated polyvinyl chloride and hydrolysed copolymers of vinyl chloride with vinyl acetate or vinyl acetals. R may be 2-chlorallyl, allyl, methyl, ethyl, propyl, butyl, amyl, hexyl, octyl, lauryl, stearyl, oleyl, cyclohexyl or benzyl. The compositions may also contain conventional plasticizers, pigments and fillers, and adhesion to the substrates may be improved by incorporating basic substances, e.g. basic lead salts and alkaline earth metal hydroxides. Many suitable catalysts, stabilizers and solvents are listed and in examples iron strips are coated by spraying with organol compositions comprising polyvinyl chloride, di-2-ethylhexyl phthalate, 2-ethylhexyl 2-chlorallyl phthalate, chrome oxide green, t.butyl perbenzoate, barium/cadmium palmitate, calcium hydroxide, and (3) bis(2-chlorallyl)-phthalate, isophorone and toluene, and (4) bis-(2-chlorallyl) isophthalate, butanol, pentanol and decalin.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH25364A CH427257A (en) | 1964-01-10 | 1964-01-10 | New plastisols and organosols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1021388A true GB1021388A (en) | 1966-03-02 |
Family
ID=4182786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14465A Expired GB1021388A (en) | 1964-01-10 | 1965-01-01 | New plastisols and organosols |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE658085A (en) |
CH (1) | CH427257A (en) |
FR (1) | FR1425580A (en) |
GB (1) | GB1021388A (en) |
NL (1) | NL6500207A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3281975A4 (en) * | 2015-04-06 | 2018-03-28 | LG Chem, Ltd. | Resin composition comprising plasticizer composition, and preparation method therefor |
-
1964
- 1964-01-10 CH CH25364A patent/CH427257A/en unknown
- 1964-12-31 FR FR509A patent/FR1425580A/en not_active Expired
-
1965
- 1965-01-01 GB GB14465A patent/GB1021388A/en not_active Expired
- 1965-01-08 BE BE658085A patent/BE658085A/xx unknown
- 1965-01-08 NL NL6500207A patent/NL6500207A/xx unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3281975A4 (en) * | 2015-04-06 | 2018-03-28 | LG Chem, Ltd. | Resin composition comprising plasticizer composition, and preparation method therefor |
US20180291179A1 (en) * | 2015-04-06 | 2018-10-11 | Lg Chem, Ltd. | Resin composition including plasticizer composition, and methods for preparing the same |
US10259929B2 (en) | 2015-04-06 | 2019-04-16 | Lg Chem, Ltd. | Resin composition including plasticizer composition, and methods for preparing the same |
Also Published As
Publication number | Publication date |
---|---|
NL6500207A (en) | 1965-07-12 |
FR1425580A (en) | 1966-01-24 |
CH427257A (en) | 1966-12-31 |
BE658085A (en) | 1965-07-08 |
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