GB1018553A - Process for the preparation of purified sucrose esters and products obtained thereby - Google Patents

Process for the preparation of purified sucrose esters and products obtained thereby

Info

Publication number
GB1018553A
GB1018553A GB31504/62A GB3150462A GB1018553A GB 1018553 A GB1018553 A GB 1018553A GB 31504/62 A GB31504/62 A GB 31504/62A GB 3150462 A GB3150462 A GB 3150462A GB 1018553 A GB1018553 A GB 1018553A
Authority
GB
United Kingdom
Prior art keywords
sucrose
esters
sucrose esters
solvent
mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31504/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ledoga SpA
Original Assignee
Ledoga SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ledoga SpA filed Critical Ledoga SpA
Publication of GB1018553A publication Critical patent/GB1018553A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
    • C07H13/06—Fatty acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Saccharide Compounds (AREA)

Abstract

Sucrose esters, obtained by the interesterification of sucrose with a C1- 8 alkyl ester of a C6- 30 aliphatic acid or a glycerol ester of such aliphatic acids in the presence of a basic catalyst and an organic solvent, are purified by a process comprising (i) evaporating off the reaction solvent, (ii) dissolving the residue in an ethyl alkanoate, containing 2-6 carbon atoms, at 60-90 DEG C., (iii) extracting this solution 2-3 times at 60-90 DEG C. with a volume of water equal to about 10-20% of the initial volume, and separating an aqueous phase containing unreacted sucrose, (iv) cooling the water-saturated organic layer to 0-30 DEG C. to form two phases, the organic phase containing unreacted alkyl esters of the aliphatic acids and unreacted or partially reacted glycerides, (v) separating the aqueous phase which contains the sucrose esters, (vi) extracting said sucrose esters with a mixture of butanol and cyclohexane, or with butanol alone, (vii) washing resulting organic solution with water and NaCl solution and (viii) evaporating to dryness to obtain the sucrose esters in high purity. The preferred ester solvent is ethyl acetate. According to the proportions of the reactants in the interestification, mono- or poly-sucrose esters are obtained. The usual interesterification solvent is dimethyl formamide. The examples relate to sucrose-monolaurate, -monopalmitate, -mono-undecenoate-dimyristate and to mono-esters derived from the acids of coconut, palm, ox tallow and rape-seed oils.
GB31504/62A 1961-09-12 1962-08-16 Process for the preparation of purified sucrose esters and products obtained thereby Expired GB1018553A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1646861 1961-09-12

Publications (1)

Publication Number Publication Date
GB1018553A true GB1018553A (en) 1966-01-26

Family

ID=11148892

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31504/62A Expired GB1018553A (en) 1961-09-12 1962-08-16 Process for the preparation of purified sucrose esters and products obtained thereby

Country Status (5)

Country Link
US (1) US3249600A (en)
BR (1) BR6242818D0 (en)
CH (1) CH423742A (en)
ES (1) ES280733A1 (en)
GB (1) GB1018553A (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2004899C2 (en) * 1969-02-05 1984-07-26 Dai-Ichi Kogyo Seiyaku Co.,Ltd., Kyoto Process for the separation of impurities from sucrose fatty acid ester raw products
WO1980002156A1 (en) * 1979-04-05 1980-10-16 Mitsui Toatsu Chemicals Process for purifying sugar fatty acid ester
US4683299A (en) * 1984-08-10 1987-07-28 Nebraska Department Of Economic Development Sugar esters and an improved anhydrous method of manufacture
US4710567A (en) * 1984-08-10 1987-12-01 Nebraska Department Of Economic Development, State Of Nebraska Separation and purification of sugar esters synthesized from both aqueous and nonaqueous systems
US5017398A (en) * 1987-04-10 1991-05-21 The Procter & Gamble Company Improved margarine compositions/containing solid sucrose polyesters
US4797300A (en) * 1987-04-10 1989-01-10 The Procter & Gamble Company Compositions containing novel solid, nondigestible, fat-like compounds
US4942054A (en) * 1987-05-13 1990-07-17 Curtice-Burns, Inc. Process for producing low calorie foods from alkyl glycoside fatty acid polyesters
US5550220A (en) * 1987-05-13 1996-08-27 Curtice-Burns, Inc. Alkyl glycoside fatty acid polyester fat substitute food compositions and process to produce the same
US6077556A (en) * 1989-04-10 2000-06-20 The Procter & Gamble Company Solid, nondigestible, fat-like compounds

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1054981B (en) * 1959-04-16 Procter & Gamble Process for the production of fatty acid esters of non-reducing oligosaccharides

Also Published As

Publication number Publication date
BR6242818D0 (en) 1973-05-24
CH423742A (en) 1966-11-15
ES280733A1 (en) 1963-02-01
US3249600A (en) 1966-05-03

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