GB1007337A - Olefinic hydrocarbon polymer compositions - Google Patents

Olefinic hydrocarbon polymer compositions

Info

Publication number
GB1007337A
GB1007337A GB18414/62A GB1841462A GB1007337A GB 1007337 A GB1007337 A GB 1007337A GB 18414/62 A GB18414/62 A GB 18414/62A GB 1841462 A GB1841462 A GB 1841462A GB 1007337 A GB1007337 A GB 1007337A
Authority
GB
United Kingdom
Prior art keywords
methyl
copolymer
nickel
olefinic hydrocarbon
hydrocarbon polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18414/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1007337A publication Critical patent/GB1007337A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/928—Polyolefin fiber

Abstract

A dyeable polymer composition comprises a crystallizable olefinic hydrocarbon polymer, a carboxylic acid salt or chelate compound of nickel, cobalt, chromium, titanium, zirconium or mixed rare earth metals and a polymeric modifier selected from polyvinyl acetal, a homo- or copolymer of <FORM:1007337/C3/1> (where R is hydrogen or methyl and R1 is alkyl, alkoxyalkyl, cycloalkyl, aralkyl, alkaryl or aryl) or a vinyl pyridine, or a copolymer of an N-substituted acrylamide, vinyl acetate, ethyl fumarate or styrene. The olefinic hydrocarbon polymer may be a polymer of styrene, ethylene, propylene, butylene, 4-methyl-1-pentene or allyl benzene and the polymer may be in the form of a fibre, film or other shaped object. Preferably the metal chelate compound or carboxylic acid salt of the metal is incorporated into the polymeric modifier by rolling in a rubber mill or blending in a Banbury mixer. The resulting salt-containing modifier is then incorporated into the olefinic hydrocarbon polymer by mechanical blending followed by melt extrusion. In the examples crystalline polypropylene is the crystallizable olefinic hydrocarbon polymer employed. Cobaltous acetate tetrahydrate, nickel perlargonate, nickel stearate, nickel hexanoate perlargonate, cobalt perlargonate, cobalt tartrate, nickel adipate, the nickel chelate derivatives of 2,21-thiobis (4-t.-octyl-phenol), nickel acetate, cobalt 2-ethylhexanoate and chromic acid are the carboxylic acid salts or chelate compounds employed. Poly-(vinylbutyral), poly-(methyl-methacrylate), a methyl methacrylate/ethyl fumarate copolymer, poly - (n - butylmethacrylate), a methylmethacrylate/vinyl acetate copolymer, a methylmethacrylate(styrene copolymer, a methylmethacrylate/N,N-dimethylacrylamide copolymer, poly-(2-methyl-5-vinyl-pyridine) and an N-methylmethacrylamide/styrene copolymer are the polymeric modifiers employed in the examples. Specifications 716,564, 931,920, 968,389, 968,692 and 975,701 are referred to.ALSO:A polymer composition comprising a crystallizable olefinic hydrocarbon polymer, a carboxylic acid salt or chelate compound of nickel, cobalt, chromium, titanium, zirconium or mixed rare earth metals and a polymeric modifier which is a polyvinyl acetal, a homo- or copolymer of a vinyl pyridine or a monomer <FORM:1007337/D1-D2/1> where R is hydrogen or methyl and R1 is alkyl, alkoxyalkyl, cylcoalkyl, aralkyl, alkaryl or aryl, or a copolymer of an N-substituted acrylamide, vinyl acetate, ethyl fumarate or styrene, is dyed or printed with a dyestuff capable of undergoing chelation. The polymer composition to be dyed may be in the form of fibres, yarns, films or shaped objects. Suitable dyes are a -hydrokyanthraquinone compounds, ortho-hydroxyazo compounds and compounds having the formula <FORM:1007337/D1-D2/2> where A is a monocyclic benzene nucleus containing a <FORM:1007337/D1-D2/3> group where R is hydrogen, methyl or ethyl. In the examples the crystallizable olefinic hydrocarbon polymer is polypropylene and the dyes employed are 2-(4-acetamidophenylazo)-4-methyl phenol; 4-hydroxy-1-methyl-3-(m-nitrophenylazo)-carbostyril and 1-(4-hydroxyethylanilino)-4, 5-dihydroxy-8-nitroanthraquinone. Other dyes mentioned are 1-amino-4, 5-dihydroxy-2-methoxyanthraquinone and 1-(2-hydroxy-5-sulphonamidophenylazo)-2-hydroxynaphthalene. Specifications 716,564, 931,920, 968,389, 968,692 and 975,701 are referred to.
GB18414/62A 1961-05-15 1962-05-14 Olefinic hydrocarbon polymer compositions Expired GB1007337A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US109828A US3240552A (en) 1961-05-15 1961-05-15 Crystalline polymerized alpha-monoolefinic hydrocarbons containing an organic addition polymer and a metal compound to improve their dyeability

Publications (1)

Publication Number Publication Date
GB1007337A true GB1007337A (en) 1965-10-13

Family

ID=22329774

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18414/62A Expired GB1007337A (en) 1961-05-15 1962-05-14 Olefinic hydrocarbon polymer compositions

Country Status (3)

Country Link
US (1) US3240552A (en)
DE (1) DE1247011B (en)
GB (1) GB1007337A (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL296819A (en) * 1962-08-20
DE1544345A1 (en) * 1963-02-28 1969-07-10 Allied Chem Process for the preparation of new benzothiazolyl monoazo dyes
GB1052969A (en) * 1963-12-23
US3410799A (en) * 1964-01-06 1968-11-12 Exxon Research Engineering Co Dyeable polymers
NL127902C (en) * 1964-02-21
US3376251A (en) * 1965-03-01 1968-04-02 Dow Chemical Co Metal containing olefin polymers having improved color
US3454512A (en) * 1965-12-22 1969-07-08 Chemcell 1963 Ltd Dyeable compositions comprising polypropylene,polyamide and ethylene copolymer
US3464943A (en) * 1967-09-28 1969-09-02 Eastman Kodak Co Stabilizing polyolefins with certainnickel and hydroxybenzotriazole compounds
US4490494A (en) * 1971-12-13 1984-12-25 Phillips Petroleum Company Dyeable polymer alloy fibers containing a polymeric dye-receptor and a metal salt of a carboxylic acid
JPS512346B2 (en) * 1972-12-28 1976-01-24
CA1096533A (en) * 1975-06-16 1981-02-24 William H. Harrop Process for improving the processability of polyolefins, improved polyolefin compositions, and modifier compositions
US4083683A (en) * 1977-03-11 1978-04-11 American Color & Chemical Corporation Metal-containing polypropylene dyed with 1,4-bis-(2'-methyl-6'-ethylanilino)anthraquinone
JP3115934B2 (en) * 1992-03-16 2000-12-11 協和化学工業株式会社 Flame retardant aid, flame retardant and flame retardant resin composition
US5446112A (en) * 1993-09-22 1995-08-29 General Electric Company Melt process for the synthesis of tin(II) terephthalate
US20070044255A1 (en) * 2005-08-25 2007-03-01 Mohawk Brands, Inc. Increasing receptivity for acid dyes
EP2441793B1 (en) * 2010-10-13 2018-08-15 Treofan Germany GmbH & Co.KG Highly active beta-nucleation additive for polypropylene

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE557717A (en) *
US2628214A (en) * 1945-10-27 1953-02-10 Du Pont Curing of polyethylenes
US2571683A (en) * 1950-04-13 1951-10-16 Eastman Kodak Co Mixtures comprising polyacrylonitrile and a polyvinyl acetal
DE1010697B (en) * 1952-09-04 1957-06-19 Hoechst Ag Process for the production of fibers and surface structures from aqueous solutions of polyvinyl alcohol
NL83376C (en) * 1953-07-31
NL92954C (en) * 1954-12-16
US2927904A (en) * 1956-11-19 1960-03-08 Phillips Petroleum Co Method of foaming blend of crystalline 1-olefin polymer and rubber and product obtained thereof
BE564276A (en) * 1957-01-26
US2984634A (en) * 1957-01-30 1961-05-16 Eastman Kodak Co Crystalline polymerized monoolefinic hydrocarbons containing metal salt of carboxylic acid
FR1235806A (en) * 1957-01-30 1960-07-08 Eastman Kodak Co Process for improving the dyeing properties of a crystallizable polymeric hydrocarbon and new products obtained
GB834160A (en) * 1957-04-10 1960-05-04 Gen Aniline & Film Corp Pigment composition
US3003845A (en) * 1958-04-01 1961-10-10 Dow Chemical Co Dye-receptive polymer compositions of fiber-forming polymers and crosslinked n-vinyl - 3 - morpholinone copolymers, preparation thereof and articles resulting therefrom
NL126684C (en) * 1959-08-03
US3156743A (en) * 1959-12-21 1964-11-10 Eastman Kodak Co Dyeable polypropylene fibers containing acrylate and methacrylate units in polymeric form

Also Published As

Publication number Publication date
US3240552A (en) 1966-03-15
DE1247011B (en) 1967-08-10

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