GB1006745A - Process for forming a hydrogen rich synthesis gas - Google Patents
Process for forming a hydrogen rich synthesis gasInfo
- Publication number
- GB1006745A GB1006745A GB21989/64A GB2198964A GB1006745A GB 1006745 A GB1006745 A GB 1006745A GB 21989/64 A GB21989/64 A GB 21989/64A GB 2198964 A GB2198964 A GB 2198964A GB 1006745 A GB1006745 A GB 1006745A
- Authority
- GB
- United Kingdom
- Prior art keywords
- steam
- naphtha
- mixture
- passed
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/388—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the heat being generated by superheated steam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/26—Fuel gas
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
<PICT:1006745/C4-C5/1> Hydrogen-rich synthesis gas containing principally H2, CO, CO2 and steam is produced by continuous steam reforming of naphtha wherein naphtha preheated to a temperature below 1000 DEG F. (540 DEG C.), preferably 400-800 DEG F., is mixed with steam preheated to at least 1000 DEG F., preferably 1500-1800 DEG F., at a steam-carbon ratio between 2 and 6 : 1, preferably 5-6 : 1, to form a mixture at least 1000 DEG F., preferably 1400-1700 DEG F., the mixture is allowed to react for up to 1 second, preferably 0.05-0.33 second, and the partially reacted mixture is passed at a linear velocity of at least 5 ft./sec., preferably 10-30 ft./sec., into an externally heated reforming catalyst of supported nickel or cobalt maintained at a temperature of at least 1400 DEG F. (760 DEG C.). A pressure of 1-22 atmos. may be used. Preferably the partially reacted gas mixture is divided into a plurality of separate streams and passed downwardly through a vertically disposed bed of catalyst so that local depression of temperature is avoided and the deposition of free carbon and formation of lower hydrocarbons does not occur. In the Figure, vaporized liquid naphtha, 3, steam 4, and optionally CO2 5, are mixed, passed through initial reaction zone 8 in less than 1 second, and passed into catalytic reformer 10; 10 comprises catalyst beds 12 in reformer tubes 11 which are heated by combustion of fluid hydrocarbon 13 in air 14. The reformed gas product is withdrawn at 16 and has a typical analysis 72.4% H2, 14.7% CO2, 11.5% CO, 1.0% methane. Pure hydrogen may be obtained by oxidation of CO and removal of CO2 with hot K2CO3. Examples describe the production of gas of 70% H2 content and to the formation of methanol synthesis gas from an initial mixture containing naphtha, steam and CO2. The naphtha feed had an initial boiling point of 130 DEG F., and end-pt. of 380 DEG F., specific gravity at 60 DEG F. of 0.725 and a sulphur content of 4 p.p.m.ALSO:<PICT:1006745/C1/1> Hydrogen-rich synthesis gas containing principally H2, CO, CO2 and steam is produced by continuous steam reforming of naphtha wherein naphtha preheated to a temperature below 1000 DEG F. (540 DEG C.) is mixed with steam pre-heated to at least 1000 DEG F., at a steam-carbon ratio between 2 : 1 and 6 : 1 to form a mixture at 1000 DEG F. at least, the mixture is allowed to react for up to 1 second and is then passed at a linear velocity of at least 5 feet/second into an externally heated reforming catalyst of supported nickel or cobalt maintained at 1400 DEG F. (760 DEG C.) at least; 1-22 atmospheres pressure may be employed. In the Figure vaporized liquid naphtha 3, steam 4, and optionally CO2 5, are mixed and passed consecutively into initial reaction zone 8 and catalytic reformer 10, the latter comprising catalyst beds 12 in reformer tubes 11, heated by combustion of fluid hydrocarbon 13 in air 14. The reformed gas product typically analyses 72.4% H2, 14.7% CO2, 11.5% CO, 1.0% CH4. Pure hydrogen is obtained by oxidizing CO to CO2 and absorbing the latter in hot K2CO3.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US285672A US3351563A (en) | 1963-06-05 | 1963-06-05 | Production of hydrogen-rich synthesis gas |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1006745A true GB1006745A (en) | 1965-10-06 |
Family
ID=23095238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21989/64A Expired GB1006745A (en) | 1963-06-05 | 1964-05-27 | Process for forming a hydrogen rich synthesis gas |
Country Status (7)
Country | Link |
---|---|
US (1) | US3351563A (en) |
JP (1) | JPS4822597B1 (en) |
BE (1) | BE648834A (en) |
DE (1) | DE1467004A1 (en) |
ES (1) | ES300406A1 (en) |
GB (1) | GB1006745A (en) |
NL (1) | NL6406292A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0069830A1 (en) * | 1981-04-15 | 1983-01-19 | Union Carbide Corporation | Process for heat carrier generation |
WO1986005769A1 (en) * | 1985-03-25 | 1986-10-09 | Josef Hubert Schick | Process for the production of heat energy from synthetic gas |
GB2388118A (en) * | 2002-04-09 | 2003-11-05 | Chevron Usa Inc | Converting CO2 in natural gas to syngas using hydroge from naphtha reforming |
GB2388117A (en) * | 2002-04-09 | 2003-11-05 | Chevron Usa Inc | Production of additional syngas by CO2 recycling and naphtha reforming |
RU2455226C2 (en) * | 2006-09-08 | 2012-07-10 | Гелато Корпорейшн Н.В. | Method of producing synthetic gas |
CN112850643A (en) * | 2021-01-29 | 2021-05-28 | 天津闪速炼铁技术有限公司 | High-efficiency carbon dioxide conversion method |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3531267A (en) * | 1965-06-17 | 1970-09-29 | Chevron Res | Process for manufacturing fuel gas and synthesis gas |
GB2072216A (en) * | 1980-03-18 | 1981-09-30 | British Gas Corp | Treatment of hydrocarbon feedstocks |
WO2009086407A2 (en) | 2007-12-28 | 2009-07-09 | Greatpoint Energy, Inc. | Steam generating slurry gasifier for the catalytic gasification of a carbonaceous feedstock |
US8361428B2 (en) | 2008-02-29 | 2013-01-29 | Greatpoint Energy, Inc. | Reduced carbon footprint steam generation processes |
US8286901B2 (en) | 2008-02-29 | 2012-10-16 | Greatpoint Energy, Inc. | Coal compositions for catalytic gasification |
US8652222B2 (en) | 2008-02-29 | 2014-02-18 | Greatpoint Energy, Inc. | Biomass compositions for catalytic gasification |
WO2009111345A2 (en) | 2008-02-29 | 2009-09-11 | Greatpoint Energy, Inc. | Catalytic gasification particulate compositions |
WO2009111342A2 (en) | 2008-02-29 | 2009-09-11 | Greatpoint Energy, Inc | Carbonaceous fines recycle |
US8297542B2 (en) | 2008-02-29 | 2012-10-30 | Greatpoint Energy, Inc. | Coal compositions for catalytic gasification |
US8647402B2 (en) | 2008-09-19 | 2014-02-11 | Greatpoint Energy, Inc. | Processes for gasification of a carbonaceous feedstock |
CN102159687B (en) | 2008-09-19 | 2016-06-08 | 格雷特波因特能源公司 | Use the gasification process of charcoal methanation catalyst |
AU2009293087B2 (en) | 2008-09-19 | 2012-11-15 | Sure Champion Investment Limited | Processes for gasification of a carbonaceous feedstock |
EP2370549A1 (en) | 2008-12-30 | 2011-10-05 | Greatpoint Energy, Inc. | Processes for preparing a catalyzed coal particulate |
KR101290453B1 (en) | 2008-12-30 | 2013-07-29 | 그레이트포인트 에너지, 인크. | Processes for preparing a catalyzed carbonaceous particulate |
CN104119956B (en) | 2009-05-13 | 2016-05-11 | 格雷特波因特能源公司 | The hydrogenation methanation method of carbon raw material |
CN102459525B (en) | 2009-05-13 | 2016-09-21 | 格雷特波因特能源公司 | The method carrying out the hydrogenation methanation of carbon raw material |
AU2010310846B2 (en) | 2009-10-19 | 2013-05-30 | Greatpoint Energy, Inc. | Integrated enhanced oil recovery process |
CN102597417B (en) | 2009-10-19 | 2014-10-01 | 格雷特波因特能源公司 | Integrated enhanced oil recovery process |
AU2010339952B8 (en) | 2009-12-17 | 2013-12-19 | Greatpoint Energy, Inc. | Integrated enhanced oil recovery process |
WO2011106285A1 (en) | 2010-02-23 | 2011-09-01 | Greatpoint Energy, Inc. | Integrated hydromethanation fuel cell power generation |
US8652696B2 (en) | 2010-03-08 | 2014-02-18 | Greatpoint Energy, Inc. | Integrated hydromethanation fuel cell power generation |
US8557878B2 (en) | 2010-04-26 | 2013-10-15 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with vanadium recovery |
KR101506381B1 (en) * | 2010-05-28 | 2015-03-26 | 그레이트포인트 에너지, 인크. | Conversion of liquid heavy hydrocarbon feedstocks to gaseous products |
KR101424941B1 (en) | 2010-08-18 | 2014-08-01 | 그레이트포인트 에너지, 인크. | Hydromethanation of carbonaceous feedstock |
CA2815243A1 (en) | 2010-11-01 | 2012-05-10 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock |
US9115324B2 (en) | 2011-02-10 | 2015-08-25 | Expander Energy Inc. | Enhancement of Fischer-Tropsch process for hydrocarbon fuel formulation |
US8648121B2 (en) | 2011-02-23 | 2014-02-11 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with nickel recovery |
US9169443B2 (en) | 2011-04-20 | 2015-10-27 | Expander Energy Inc. | Process for heavy oil and bitumen upgrading |
US9156691B2 (en) | 2011-04-20 | 2015-10-13 | Expander Energy Inc. | Process for co-producing commercially valuable products from byproducts of heavy oil and bitumen upgrading process |
WO2012166879A1 (en) | 2011-06-03 | 2012-12-06 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock |
EP2753596B1 (en) | 2011-09-08 | 2019-05-01 | Expander Energy Inc. | Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment |
US8889746B2 (en) | 2011-09-08 | 2014-11-18 | Expander Energy Inc. | Enhancement of Fischer-Tropsch process for hydrocarbon fuel formulation in a GTL environment |
US9315452B2 (en) | 2011-09-08 | 2016-04-19 | Expander Energy Inc. | Process for co-producing commercially valuable products from byproducts of fischer-tropsch process for hydrocarbon fuel formulation in a GTL environment |
US9012524B2 (en) | 2011-10-06 | 2015-04-21 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock |
CA2776369C (en) | 2012-05-09 | 2014-01-21 | Steve Kresnyak | Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment |
US9273260B2 (en) | 2012-10-01 | 2016-03-01 | Greatpoint Energy, Inc. | Agglomerated particulate low-rank coal feedstock and uses thereof |
CN104704204B (en) | 2012-10-01 | 2017-03-08 | 格雷特波因特能源公司 | Method for producing steam from original low rank coal raw material |
WO2014055349A1 (en) | 2012-10-01 | 2014-04-10 | Greatpoint Energy, Inc. | Agglomerated particulate low-rank coal feedstock and uses thereof |
US9034058B2 (en) | 2012-10-01 | 2015-05-19 | Greatpoint Energy, Inc. | Agglomerated particulate low-rank coal feedstock and uses thereof |
US9266730B2 (en) | 2013-03-13 | 2016-02-23 | Expander Energy Inc. | Partial upgrading process for heavy oil and bitumen |
CA2818322C (en) | 2013-05-24 | 2015-03-10 | Expander Energy Inc. | Refinery process for heavy oil and bitumen |
US9595726B2 (en) * | 2014-01-07 | 2017-03-14 | Advanced Cooling Technologies, Inc. | Fuel reforming system and process |
US10557391B1 (en) | 2017-05-18 | 2020-02-11 | Advanced Cooling Technologies, Inc. | Incineration system and process |
US10464872B1 (en) | 2018-07-31 | 2019-11-05 | Greatpoint Energy, Inc. | Catalytic gasification to produce methanol |
US10344231B1 (en) | 2018-10-26 | 2019-07-09 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with improved carbon utilization |
US10435637B1 (en) | 2018-12-18 | 2019-10-08 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation |
US10618818B1 (en) | 2019-03-22 | 2020-04-14 | Sure Champion Investment Limited | Catalytic gasification to produce ammonia and urea |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL34213C (en) * | 1931-01-17 | |||
US2524840A (en) * | 1945-02-06 | 1950-10-10 | Hercules Powder Co Ltd | Hydrogen production |
US2550742A (en) * | 1946-06-28 | 1951-05-01 | Standard Oil Dev Co | Conversion of hydrocarbon gases to hydrogen and carbon monoxide |
NL69139C (en) * | 1947-06-17 | |||
US2579843A (en) * | 1947-12-10 | 1951-12-25 | Method foe the manufacture of | |
FR1073309A (en) * | 1951-05-04 | 1954-09-23 | Azote & Prod Chim | Improvements in processes for the production of hydrogen by catalytic reduction of water vapor using hydrocarbons |
US2940840A (en) * | 1956-12-31 | 1960-06-14 | Hercules Powder Co Ltd | Hydrocarbon conversion process |
NL285248A (en) * | 1961-12-20 | 1900-01-01 |
-
1963
- 1963-06-05 US US285672A patent/US3351563A/en not_active Expired - Lifetime
-
1964
- 1964-05-27 GB GB21989/64A patent/GB1006745A/en not_active Expired
- 1964-05-30 ES ES300406A patent/ES300406A1/en not_active Expired
- 1964-06-03 DE DE19641467004 patent/DE1467004A1/en active Pending
- 1964-06-04 NL NL6406292A patent/NL6406292A/xx unknown
- 1964-06-04 BE BE648834D patent/BE648834A/xx unknown
- 1964-06-05 JP JP39031735A patent/JPS4822597B1/ja active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0069830A1 (en) * | 1981-04-15 | 1983-01-19 | Union Carbide Corporation | Process for heat carrier generation |
WO1986005769A1 (en) * | 1985-03-25 | 1986-10-09 | Josef Hubert Schick | Process for the production of heat energy from synthetic gas |
GB2388118A (en) * | 2002-04-09 | 2003-11-05 | Chevron Usa Inc | Converting CO2 in natural gas to syngas using hydroge from naphtha reforming |
GB2388117A (en) * | 2002-04-09 | 2003-11-05 | Chevron Usa Inc | Production of additional syngas by CO2 recycling and naphtha reforming |
US6693138B2 (en) | 2002-04-09 | 2004-02-17 | Chevron U.S.A. Inc. | Reduction of carbon dioxide emissions from Fischer-Tropsch GTL facility by aromatics production |
GB2388118B (en) * | 2002-04-09 | 2004-06-16 | Chevron Usa Inc | Reducing CO2 levels in CO2-rich natural gases converted into liquid fuels |
GB2388117B (en) * | 2002-04-09 | 2004-06-23 | Chevron Usa Inc | Reduction of carbon dioxide emissions from Fischer-Tropsch GTL facility by aromatics production |
US6846404B2 (en) | 2002-04-09 | 2005-01-25 | Chevron U.S.A. Inc. | Reducing CO2 levels in CO2-rich natural gases converted into liquid fuels |
AU2003203442B2 (en) * | 2002-04-09 | 2008-11-20 | Chevron U.S.A. Inc. | Reduction of carbon dioxide emissions from Fischer-Tropsch GTL facility by aromatics production |
RU2455226C2 (en) * | 2006-09-08 | 2012-07-10 | Гелато Корпорейшн Н.В. | Method of producing synthetic gas |
US8507566B2 (en) | 2006-09-08 | 2013-08-13 | Gelato Corporation N.V. | Process for the preparation of synthesis gas |
CN112850643A (en) * | 2021-01-29 | 2021-05-28 | 天津闪速炼铁技术有限公司 | High-efficiency carbon dioxide conversion method |
Also Published As
Publication number | Publication date |
---|---|
JPS4822597B1 (en) | 1973-07-06 |
BE648834A (en) | 1964-12-04 |
ES300406A1 (en) | 1964-11-16 |
US3351563A (en) | 1967-11-07 |
NL6406292A (en) | 1964-12-07 |
DE1467004A1 (en) | 1968-12-19 |
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