GB1001458A - Catalysts for isocyanate reactions - Google Patents
Catalysts for isocyanate reactionsInfo
- Publication number
- GB1001458A GB1001458A GB4546362A GB4546362A GB1001458A GB 1001458 A GB1001458 A GB 1001458A GB 4546362 A GB4546362 A GB 4546362A GB 4546362 A GB4546362 A GB 4546362A GB 1001458 A GB1001458 A GB 1001458A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphonium
- iodide
- organic metal
- active hydrogen
- quaternary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The reaction between a polyisocyanate or polyisothiocyanate and a compound containing active hydrogen is catalysed by a mixture of a quaternary ammonium, quaternary phosphonium or ternary sulphonium salt of a strong acid and an organic metal compound of the type used as catalyst in polyurethane manufacture, the said quaternary or ternary salt and the said organic metal compound both being used in an amount of from 0.05 to 5% by weight of the compound containing active hydrogen. Compounds specified are tri-n-butyl methyl phosphonium iodide, triphenyl methyl phosphonium iodide, thio-(tetrabutyl phosphonium) sulphate, tetrabutyl phosphonium chloride, N,N-dimethylpiperidinium iodide, tetrakis (hydroxymethyl) phosphonium chloride, phenyl-ethylcyclo-tetramethylene phosphonium iodide, N-allyl - N - ethylpiperidinium bromide and trimethylsulphonium iodide. Organic metal compounds are: stannous octoate, zinc octoate, lead octoate and dibutyl tin dilaurate. Conventional organic polyisocyanates are listed. The active hydrogen-containing group may be hydroxyl, carboxylic acid, amide, urethane or urea groups. Cellular and non-cellular polyurethanes may be produced from polyesters, polyesteramides or polyethers. In Example (2), a solution containing a methyl phenylsiloxane, stannous octoate and tolylene diisocyanate was added to a mixture of N-allyl N-ethylpiperidinium bromide, water and a linear polypropylene glycol of MW 2000 to obtain a cellular polyurethane.ALSO:The reaction between an organic polyisocyanate or polyisothiocyanate and a compound containing active hydrogen is catalysed by a mixture of a quaternary ammonium quaternary phosphonium or ternary sulphonium part of a strong acid and an organic metal compound of the type used as catalyst in polyurethane manufacture, the said quaternary or ternary salt and the said organic metal compound both being used in an amount of from 0.05% to 5% by weight of the compound containing active hydrogen. Compounds specified are tri-n-butylmethyl phosphonium iodide, triphenyl-methyl phosphonium iodide, bis-(tetrabutyl phosphonium) sulphate, tetrabutyl phosphonium chloride, N,N-dimethylpiperidinium iodide, tetrakis(hydroxymethyl) phosphonium chloride, phenylethyl - cyclo - tetramethylene phosphonium iodide, N-allyl-N ethyl piperidinium bromide and trimethylsulphonium iodide. Organic metal compounds may be stannous octoate, zinc octoate, lead octoate, and dibutyltin dilaurate. The active hydrogen-containing group may be: hydroxyl, carboxylic acid, amide, urethane or urea groups. In an Example (1) the reaction between dry sec.-butanol and a mixture of tolylene diisocyanates to form a mixture of tolylene bis-(sec.-butyl carbamates) was catalysed by different catalyst mixtures. In comparison examples the reaction was repeated with no catalyst and with the ternary or quaternary salts but omitting the organic metal compounds.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4546362A GB1001458A (en) | 1962-12-03 | 1962-12-03 | Catalysts for isocyanate reactions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4546362A GB1001458A (en) | 1962-12-03 | 1962-12-03 | Catalysts for isocyanate reactions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1001458A true GB1001458A (en) | 1965-08-18 |
Family
ID=10437300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4546362A Expired GB1001458A (en) | 1962-12-03 | 1962-12-03 | Catalysts for isocyanate reactions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1001458A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2392715A1 (en) * | 1977-05-31 | 1978-12-29 | Stauffer Chemical Co | ENCAPSULATION PROCESS INVOLVING PHASE TRANSFER CATALYSTS |
CN114164063A (en) * | 2021-12-16 | 2022-03-11 | 万华化学集团股份有限公司 | Chemical cleaning agent for scaling substance of isocyanate heat exchanger, preparation method and application |
US11390774B2 (en) | 2015-09-11 | 2022-07-19 | Ppg Industries Ohio, Inc. | Curable coating compositions containing poly activated methylene resins and polyisocyanates |
CN114957590A (en) * | 2022-06-29 | 2022-08-30 | 合肥安邦化工有限公司 | Water-based isocyanate derivative crosslinking agent and preparation method thereof |
CN115141335A (en) * | 2021-03-30 | 2022-10-04 | 万华化学集团股份有限公司 | Preparation method of low-viscosity polyisocyanate composition |
-
1962
- 1962-12-03 GB GB4546362A patent/GB1001458A/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2392715A1 (en) * | 1977-05-31 | 1978-12-29 | Stauffer Chemical Co | ENCAPSULATION PROCESS INVOLVING PHASE TRANSFER CATALYSTS |
US11390774B2 (en) | 2015-09-11 | 2022-07-19 | Ppg Industries Ohio, Inc. | Curable coating compositions containing poly activated methylene resins and polyisocyanates |
CN115141335A (en) * | 2021-03-30 | 2022-10-04 | 万华化学集团股份有限公司 | Preparation method of low-viscosity polyisocyanate composition |
CN115141335B (en) * | 2021-03-30 | 2023-08-11 | 万华化学集团股份有限公司 | Preparation method of low-viscosity polyisocyanate composition |
CN114164063A (en) * | 2021-12-16 | 2022-03-11 | 万华化学集团股份有限公司 | Chemical cleaning agent for scaling substance of isocyanate heat exchanger, preparation method and application |
CN114164063B (en) * | 2021-12-16 | 2023-08-11 | 万华化学集团股份有限公司 | Chemical cleaning agent for scaling substances of isocyanate heat exchanger, and preparation method and application thereof |
CN114957590A (en) * | 2022-06-29 | 2022-08-30 | 合肥安邦化工有限公司 | Water-based isocyanate derivative crosslinking agent and preparation method thereof |
CN114957590B (en) * | 2022-06-29 | 2023-05-05 | 合肥安邦化工有限公司 | Water-based isocyanate derivative cross-linking agent and preparation method thereof |
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