FR3137089A1 - PROCESS FOR RECOVERY OF HEAVY BY-PRODUCTS FROM THE MANUFACTURING OF ACRYLIC ACID - Google Patents

Abstract

The present invention relates to a process for the regeneration, by thermal cracking, of acrylic acid (AA), from heavy by-products (residues called LAA) resulting from an AA production unit, with a view to their recycling in the acrylic acid production workshop. This process consists of two stages: hydrolysis carried out in batches, and cracking carried out continuously, and improves the current performance of cracking installations. FIGURE 1

Description

PROCESS FOR RECOVERY OF HEAVY BY-PRODUCTS FROM THE MANUFACTURING OF ACRYLIC ACID FIELD OF THE INVENTION

The present invention relates to a process for the regeneration, by thermal cracking, of acrylic acid (AA), from heavy by-products (residues called LAA) resulting from an AA production unit, with a view to their recycling in the acrylic acid production workshop. This process consists of two stages: hydrolysis carried out in batches, and cracking carried out continuously, and improves the current performance of cracking installations.

TECHNICAL BACKGROUND

Under the effect of temperature during the distillation stages, the manufacture of acrylic acid is accompanied by the formation of heavy compounds, derived from the addition of compounds with nucleophilic properties on the double bond of unsaturated carbonyl monomers, by reaction of Michael. “Heavy” compounds are those whose boiling point is higher than that of the acrylic monomer produced.

In the case of an AA production unit, this essentially involves:

- addition derivatives of acrylic acid on the double bond of another acrylic acid molecule: 3-acryloxypropionic acid also called "dimeric acrylic acid" or "AA dimer";

- addition derivatives of acrylic acid on the double bond on an AA dimer molecule, to form the "AA trimer" and other oligomers formed by successive additions of acrylic acid on the double bonds of the previous AA oligomers, and

- carboxylic acid addition derivatives formed as by-products of acrylic acid or water on the double bond of AA or the oligomers mentioned above.

The recovery of recoverable monomers from heavy compounds derived from Michael is difficult in the case of heavy compounds coming from an AA production unit. Indeed, during the thermal cracking process which regenerates acrylic acid, which is distilled and upgraded, there remains a residue whose viscosity increases sharply when high cracking yields are sought, to the point where it can no longer be used. extracted from the cracking reactor.

The main limiting factor in the effectiveness of the regeneration of compounds derived from the Michael reaction contained in the heavy flows from the AA workshops is the increase in the viscosity of the heavy residue obtained at the bottom of the cracker, when the fraction rich in acrylic monomers was vaporized.

The vaporization of light compounds during cracking causes a concentration of heavy products in the residue stream, and an increase in the viscosity of this stream. However, the residue must remain sufficiently fluid after cooling to be transported and then treated for destruction.

In the case where there is a production of light esters (methyl acrylate (MA) or ethyl acrylate (EA)) near the AA production unit, co-cracking of the respective heavy ones can improve the situation, by making the cracked residue more fluid. The proposed solution makes it possible to recover the maximum AA per cracking operation while managing the viscosity of the residue formed without being dependent on another production unit.

Thus, in document EP 717 031, it was shown that it is possible to improve the efficiency of the recovery of these noble recoverable products, if the cracking is carried out from a mixture of heavy substances coming from a AA production unit and an acrylic ester (EA) production unit, compared to the individual cracking of the heavy streams of these units. The effect of adding heavies from ester units (LEA) to heavies from an AA unit (LAA) is to decrease the viscosity of the final residue. The cracking reaction is carried out using mixtures with a heavy AA/heavy ester ratio of 9/1 to 1/9, at a temperature of 180 to 220°C, under atmospheric pressure, during a residence time of 0.5 to 1/9. 3 hours. In this process, the cracking and vaporization of the light compounds generated are carried out in a reactor, then the generated gas flow is sent to a distillation column and finally the bottom flow of the distillation column is recycled into the reactor. On the other hand, the light fraction obtained by cracking mainly consists of AA and ester acrylic monomers, which are particularly sensitive to polymerization, the distillation step must necessarily be carried out under reduced pressure, so as to reduce the temperature, to avoid the formation of polymer in the column. Furthermore, the rectification plates of the distillation column cause the effective separation of the polymerization inhibitors entrained in the gas mixture, which flow back towards the bottom of the column, and therefore, it is necessary to introduce fresh polymerization inhibitors in column head, to avoid the formation of polymers in the upper part of the column.

Therefore, we must separate the reaction stages, carried out under higher pressure, and the distillation stages, carried out under reduced pressure. The installation for carrying out the process must therefore be equipped with a reactor and a condenser at the top, operated at the same pressure, and a distillation column operated at reduced pressure, supplied with the condensed product, and comprising a boiler at the bottom, and at the top a condenser, reflux equipment and a supply of inhibitors. This device is complicated and expensive.

Furthermore, the co-cracking of heavy AAs mixed with heavy EAs causes operating constraints. Indeed, when the ester unit is stopped, the cracking operation must be stopped. This causes economic losses.

In other cases, the AA heavies are thermally cracked discontinuously without adding ester heavies and generate an extremely viscous residue, which limits the performance of this cracking and causes problems in terms of storage and processing. transfer of residues.

To overcome the problem linked to viscosity, it is also known to add a solvent to the heavy AA cracking residue.

EP 3255030 teaches the addition of higher alcohols during cleavage of the residue, the maleic anhydride present in the residue being converted to maleic acid esters which are less susceptible to polymerization.

US 6414183 teaches the dilution of the discarded residue with solvents such as acetic acid, water and methanol.

WO 2021/224044 describes a process for decomposing Michael adducts of acrylic acid, by dilution in a solvent 1 having a boiling point at 1013 hPa of at least 170°C and a solubility in water at 25°C of at least 20 g per 100 g of water, said solvent being chosen from alcohols such as ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol and 2-ethoxyethanol, carboxamides such as N,N-dimethylacetamide, N-methylacetamide and N,N-dimethylformamide, sulfoxides such as dimethylsulfoxide, and sulfones such as sulfolane.

However, this solution has several disadvantages, such as the generation of waste to burn, if it is not an internal flow, or the provision of additional equipment for producing the mixture. In addition, most of these solvents generate nitrogen or sulfur derivatives during burning.

Consequently, there is a need to improve the regeneration yield, by thermal cracking, of heavy compounds originating only from AA units.

The invention relates to a process for regenerating a mixture of heavy by-products from an acrylic acid (LAA) production unit, said process comprising the following steps:

1. introducing said heavy by-products with water into a hydrolyzer and subjecting them to batch hydrolysis, the water:LAA mass ratio ranging from 0.1 to 1.3 (limits inclusive) for a period of 1 to 10 h , preferably from 1 to 5 hours, leading to obtaining a mixture of hydrolyzed products,
2. injecting said mixture of hydrolyzed products into a reactor and subjecting it to continuous thermal cracking producing a gaseous overhead stream containing acrylic acid and water and a bottom stream (residue) concentrated in heavy products,
3. recover a lighter fraction rich in AA and water that can be recycled at different points in the process,
4. recover said residue for disposal treatment.

According to various embodiments, said method comprises the following characters, where appropriate

combined.

According to one embodiment, the pressure in the hydrolyzer varies between 0.1 and 2 MPa, preferably between 0.5 and 1.5 MPa.

According to one embodiment, the temperature in the hydrolyzer varies between 80 and 200°C, preferably between 150 and 200°C.

According to one embodiment, the cracking temperature is between 140 and 260°C, preferably between 160 and 210°C.

According to one embodiment, the residence time of the reaction mixture in the cracking reactor is between 0.5h and 10h, preferably between 1h and 2h.

According to one embodiment, the thermal cracking reaction takes place at atmospheric pressure or under light pressure (maximum 0.2 MPa).

According to one embodiment, the reactor bottom flow (residue) obtained at the end of the thermal cracking operation has a dynamic viscosity less than 1 Pa.s, measured at a temperature of 100°C for example at using a Brookfield “CAP 1000+” cone-plane type viscometer.

According to one embodiment, the thermal cracking reaction takes place in the absence of catalyst.

The present invention makes it possible to overcome the disadvantages of the state of the art. It makes it possible to recover the maximum amount of AA per cracking operation, while managing the viscosity of the residue formed without being dependent on another production unit. This is accomplished through the combination of a hydrolysis step of heavy by-products coming from an acrylic acid production unit, and a thermal cracking step of the hydrolyzed products.

The main advantages of the process according to the invention are:

• A simple and inexpensive process in terms of investment since it practically only requires additional equipment (the hydrolyzer) compared to the cracking stage alone.

• A process to reduce releases by reducing the quantity of cracking residue.

• A less viscous residue compared to cracking without hydrolysis step.

• The cracking stage does not depend on other units (notably esters).

• Hydrolysis also makes it possible to avoid special treatment of residues to ensure their evacuation such as the addition of solvent for example to fluidize them.

• An increase in the recovery yield of noble products from the heavy Michael derivatives present in the heavy streams of the AA workshops by pushing the cracking reaction further, the viscosity limit of the residue being reached later compared to a solution without hydrolysis.

FIGURES

There schematically represents an embodiment of an installation according to the invention.

DESCRIPTION OF MODES OF CARRYING OUT THE INVENTION

The invention is now described in more detail and in a non-limiting manner in the description which follows.

The term “heavy by-products from an acrylic acid production unit” includes:

• addition derivatives of acrylic acid on the double bond of another acrylic acid molecule: 3-acryloxypropionic acid also called “acrylic acid dimer” or “dimer AA”;

• addition derivatives of acrylic acid on the double bond on an AA dimer molecule, to form the “AA trimer” and other oligomers formed by successive additions of acrylic acid on the double bonds of the previous AA oligomers;

• carboxylic acid addition derivatives formed as by-products of acrylic acid (for example acetic acid) or water on the double bond of AA or the oligomers mentioned above.

The term “hydrolyzer” refers to a reactor in which the hydrolysis reaction of the mixture of water and heavy AA can take place. This reactor can be heated and hold pressure. This can be a conventional stirred type reactor, or in a heat exchanger.

The invention is based on a continuous thermal cracking process, coupled with a batch hydrolysis operation carried out beforehand on heavy by-products from an AA production unit.

It is possible to regenerate the acrylic monomers involved in the Michael addition derivatives by carrying out hydrolysis of the oligomers prior to the heat treatment step. This hydrolysis reaction forms hydroxypropionic acid (HPA), thermally crackable into acrylic acid. Hydrolysis reduces the oligomer chains, which makes the residue less viscous.

Hydrolysis in batch mode is carried out under a pressure ranging from 0.1 to 2 MPa.

The efficiency of regeneration (expressed in the form of the cracking yield) essentially depends on:

• a/ parameters for hydrolysis: temperature and pressure, hydrolysis residence time and the Water/Heavy AA ratio, and
• b/ parameters for cracking: temperature and heat treatment residence time.

The increase in these last two parameters (b/) tends to improve the regeneration yield, but this is done at the expense of an increase in the viscosity of the cracked residue.

Cracking performance is characterized by two values:

• the TRU or useful recovery rate: this is the quantity of acrylic acid recovered after cracking reduced to the quantity of heavy AA which feeds the cracker:

TRU = AA mass recovered / Heavy AA cracker feed

• the cracking rate or yield: this is the quantity of acrylic acid recovered after cracking reduced to the sum of the recoverable compounds in the cracker feed (acrylic acid (AA), acrylic acid dimers (AA2) and hydroxypropionic acid (HPA)).

According to the embodiment of the process represented in , the flow containing the said heavy by-products coming from the acrylic acid production workshop (LAA) and water are introduced together or separately into the reactor R1. The LAA stream is rich in heavy Michael addition compounds generated during the acrylic acid synthesis and purification steps, and also contains other heavy compounds accumulated during the synthesis and purification processes, particularly inhibitors. polymerization.

The mixture (1) containing the heavy acrylic acid compounds and water is heated to the temperature required to carry out the hydrolysis of the Michael addition derivatives into lighter compounds. Stream (2) is recovered after the hydrolysis step is completed. It is then introduced continuously into a second reactor R2 where it is heated to the temperature required to carry out the cracking of the Michael addition derivatives into lighter compounds which are extracted in the form of a gaseous mixture (3) at the top of the reactor. reactor.

This vapor flow rich in acrylic acid and containing some heavy compounds, including inhibitors in low concentrations, is advantageously recycled in the acrylic acid production process, either directly in vapor form, or after total condensation in an E1 flow exchanger. (4).

According to one embodiment, at least one polymerization inhibitor is introduced at the level of the condenser E1. These inhibitors are chosen from polymerization inhibitors known to those skilled in the art: phenolic derivatives such as hydroquinone and its derivatives such as hydroquinone methyl ether, 2,6-di-terbutyl-4- methyl phenol (BHT), and 2,4-dimethyl-6-terbutyl phenol (Topanol A), phenothiazine and its derivatives, manganese salts, such as manganese acetate, salts of thiocarbamic or dithiocarbamic acid , such as metallic thiocarbamates and dithiocarbamates, such as copper di-n-butyldithiocarbamate, N-oxyl compounds, such as 4-hydroxy-2,2,6,6-tetramethyl piperidinoxyl (4-OH-TEMPO), compounds with nitroso groups, such as N-nitroso phenyl hydroxylamine and its ammonium salts, amino compounds such as paraphenylenediamine derivatives or a mixture of these inhibitors.

The residue flow recovered at the bottom of the reactor (5) is cooled, then eliminated in the form of a liquid of moderate viscosity, so that it can be transported without difficulty by pump, for example to a storage or processing unit. incineration.

EXAMPLES

The following examples illustrate the invention without limiting it.

The exhaustion rate is defined by the ratio of distillate mass/heavy mass. In the case of adding water, this rate becomes the “corrected exhaustion rate” by subtracting this mass of water from the quantity of distillate.

Example 1: Batch hydrolysis and continuous cracking (according to the invention)

The assembly used for the hydrolysis operation consists of an HC 276 laboratory autoclave reactor capable of holding a maximum pressure of 80 bar @ 250°C, AmAr brand, equipped with an internal stirrer, a pressure gauge, a nitrogen inlet, a plunging temperature probe and a regulated external electric heating mantle. Its useful volume is 450 ml.

The mixture to be hydrolyzed is introduced into the reactor then the reactor is closed using a jaw system to make it watertight. A nitrogen pipe connecting the reactor allows it to be placed under a pressure of 6 bars before the temperature rises. The mixture is then heated to a temperature of 150°C for 1 hour. The pressure read on the pressure gauge increases to 12 bars. Once hydrolysis is complete, the mixture is discharged via the bottom valve after cooling to room temperature.

The assembly used for the cracking operation consists of a 500ml double-jacketed glass reactor equipped with a stirrer, a temperature probe immersed in the liquid phase, a vertical pipe in the upper part, for the the extraction of vapors, a lateral tap allowing a constant level to be obtained and the evacuation of the cracked residue and a condenser. The previously hydrolyzed mixture is introduced continuously into the reactor then heated to the desired temperature. The liquid (distillate) is collected in a receiving flask and analyzed. The residue evacuated by overflow is collected in a receiving bottle.

Duration of the trial: 61 hours

Hydrolysis: T = 150°C, residence time: 1 hour, P = 1.2 MPa, water/heavy ratio AA = 0.5

Cracking: T = 168°C, atmospheric pressure, residence time: 4h, water/heavy ratio AA = 0.5

- TRU = 61%

- Corrected exhaustion rate = 66.5%

- Viscosity 0.437 Pa.s.

Example 2: Continuous cracking without hydrolysis (comparative)

Test duration: 58 hours

Cracking: T= 193°C, residence time: 4 hours, atmospheric pressure, water/heavy ratio AA = 0.5

- TRU = 55.0%

- Exhaustion rate = 62.15%

- Viscosity = 2.361 Pa.s.

Comparison of Example 1 with the comparative example (Example 2) demonstrates that cracking can be done at a lower temperature in the case where the stream to be cracked has been previously hydrolyzed. In addition, the viscosity of the residue is lower.

Claims (8)

Process for regenerating heavy by-products from an acrylic acid production unit (LAA), said process comprising the following steps:

1. introducing said heavy by-products with water into a hydrolyzer and subjecting them to batch hydrolysis, the water:LAA ratio ranging from 0.1 to 1.3 for a period of 1 to 10 h, preferably 1 at 5 a.m., leading to obtaining a mixture of hydrolyzed products,
2. injecting said mixture of hydrolyzed products into a reactor and subjecting it to continuous thermal cracking producing a gaseous overhead stream containing acrylic acid and water and a bottom stream (residue) concentrated in heavy products,
3. recover a lighter fraction rich in AA and water which can be recycled at different points in the process,
4. recovering said residue for disposal treatment.

Method according to claim 1, in which step i) is carried out at a pressure of between 0.1 and 2 MPa, preferably between 0.5 and 1.5 MPa. Process according to one of claims 1 and 2, in which the hydrolysis temperature is between 80 and 200°C, preferably between 150 and 200°C. Process according to one of Claims 1 to 3, in which the cracking temperature is between 140 and 260°C, preferably between 160 and 210°C. Process according to one of claims 1 to 4, in which the residence time of the reaction mixture in the cracking reactor is between 0.5h and 10h, preferably between 1h and 2h. Method according to one of claims 1 to 4, in which the reactor bottom flow (residue) obtained at the end of the thermal cracking operation has a dynamic viscosity measured at 100°C of less than 1 Pa.s. Method according to one of the preceding claims in which at least one polymerization inhibitor is introduced at the level of the condenser E1. Process according to one of claims 1 to 7 in which the thermal cracking reaction takes place in the absence of catalyst.