FR3136166A1 - Process for cosmetic treatment of hair, comprising multiple application of a composition comprising particular amino acids and hydroxy carboxylic acids - Google Patents

Abstract

The present invention relates to a method for cosmetic treatment of hair, comprising at least two successive steps of application of a cosmetic composition comprising: - one or more compounds of the amino acid type, present in a total content of at least 0.5% by weight relative to the total weight of the composition, and - one or more hydroxylated (poly) carboxylic acids, comprising 2 to 8 carbon atoms, and/or their salts, present in a total content of at least 0.5% in weight relative to the total weight of the composition.

Description

Process for cosmetic treatment of hair, comprising multiple application of a composition comprising particular amino acids and hydroxy carboxylic acids

The present invention relates to a method of cosmetic treatment of hair, comprising at least two successive steps of application of a composition comprising one or more compounds of the amino acid type and one or more particular hydroxy carboxylic acids.

Consumers around the world generally find themselves in contact with a wide variety of water sources which have an impact on hair, particularly on its cosmetic properties and/or the performance of hair products.

So-called mineral waters contain, for example, variable quantities of minerals present in the form of dissolved ions such as calcite (present in the form of calcium), dolomite (present in the form of calcium and magnesium), magnetite (present in the form of iron ) and chalcanthite (present in the form of copper). So-called hard water is also concentrated in minerals such as calcium and magnesium and swimming pool water is concentrated in copper salts from algaecides used in the treatment of swimming pools.

Hair has a strong tendency to absorb these minerals and/or their metallic salts because of the presence on their surface of anionic functions which correspond in particular to the sulfonic or carboxylic functions of keratin. Furthermore, the isoelectric point of the hair is generally described between 3.2 and 4. As a result, in everyday life, the pH of the water applied to the hair is greater than such values, which leads to a fiber negatively charged.

Minerals, often versatile cations, will therefore be attracted and captured by this negatively charged fiber by forming chemical bonds which prevent their release by conventional hair treatment processes. This results in a possible accumulation of minerals on the hair over time. Such fixation depends not only on the hardness of the water, the frequency and/or duration of exposure of the hair to the water in question but also on the nature and length of the hair (in particular porosity and load) as well as than their damaged state.

The accumulation of these minerals and/or their metallic salts can cause modifications to the hair fiber and, in particular, a more or less marked modification of the cosmetic properties of the hair. Thus an accumulation of calcium and magnesium can lead to dry hair, lacking shine, while an accumulation of copper can lead to greening of the hair.

In addition, the accumulation of metal salts (iron, copper, for example) can accelerate damage to hair because they catalyze redox reactions and generate HO° hydroxyl radicals that can be harmful to the keratin fiber, including low levels.

This can result in photo-degradation of the fiber, lightening of the fiber, as well as an alteration of the properties of the hair, which can lead to premature breakage of the hair; These phenomena are particularly observed during the subsequent use of lightening products or coloring products.

In other words, hair can become less resistant, more weakened, or even break more easily, or even lose its shine, due to the accumulation of minerals and/or their metallic salts.

There is therefore a real need to have a means to combat the accumulation of metal ions, from minerals and metal salts dissolved in water, or even to allow them to be extracted from keratin fibers, in order to limit their negative impacts and overcome all of the disadvantages mentioned above.

The implementation of the composition described below, repeatedly, makes it possible to achieve this goal.

The subject of the present invention is therefore a method of cosmetic treatment of hair, comprising at least two successive stages of application of a cosmetic composition comprising:

- one or more compounds of the amino acid type, present in a total content of at least 0.5% by weight relative to the total weight of the composition, and

- one or more hydroxylated (poly)carboxylic acids, comprising 2 to 8 carbon atoms, and/or their salts, present in a total content of at least 0.5% by weight relative to the total weight of the composition.

It has been found that the process according to the invention makes it possible to improve the resistance to breakage of the hair, to strengthen the hair and also to significantly limit its reduction or loss of shine, undesirable effects likely to be caused by the presence of metal ions, in particular copper or calcium, within said fibers.

After implementation of the process, the fibers are reinforced, said reinforcement being improved progressively with successive applications of the composition.

It has also been noted that the composition used in the context of the invention makes it possible to provide conditioning properties to the hair, in particular a smooth feel, softness, shine and easier detangling, while providing strength, body and mass effect to the hair.

The method according to the invention is particularly suitable for sensitized, weakened and/or damaged hair, in particular following physical treatments (repeated brushing) and/or chemical treatments, for example coloring, bleaching, perming and/or straightening.

It is also particularly suitable for the cosmetic treatment of hair loaded with metals, in particular loaded with metals at levels of at least 100 ppm, better still at least 200 ppm; in particular loaded with copper, in particular at contents of at least 100 ppm, better still at least 200 ppm and/or loaded with calcium, notably at contents of at least 4000 ppm, better still at least 10,000 ppm.

The hair treatment process according to the invention comprises at least two successive steps consisting of applying the composition as defined above to the hair.

In other words, the composition is applied to the hair several times in succession, that is to say that the steps of applying the composition according to the invention follow each other with or without an intermediate rinsing step.

Preferably, the process according to the invention involves a step of rinsing the hair at least between two successive steps of applying the composition.

The exposure time of the composition according to the invention on the hair can vary between a few seconds (10 seconds for example) and a few minutes (5 to 60 minutes for example), preferably between 1 and 30 minutes, better still between 2 and 15 minutes.

Application to the hair can be carried out for example using a comb, a brush, using a brush or with the fingers.

Between each successive application step of the composition, the hair can be rinsed and/or can be dried.

Rinsing can be done with water or shampoo, after a possible exposure time. The hair can then be dried, possibly washed using a standard shampoo and then dried.

The rinsing step can also be followed by a drying step, for example at room temperature (25°C) or at a temperature above 40°C. Preferably, the hair is dried, in addition to heat, with a flow of air. During drying, a mechanical action on the strands can be exerted such as combing, brushing, running fingers. The drying step of the process of the invention can be implemented with a helmet, a hair dryer, a straightener. When the drying step is carried out with a helmet or a hair dryer, the drying temperature is between 40 and 110°C, preferably between 50 and 90°C. When the drying step is carried out with a hair straightener, the drying temperature is between 110 and 220°C, preferably between 130 and 200°C.

The hair treatment process according to the invention may comprise more than two successive steps of application of the composition as defined above to the hair, for example at least 3 successive steps, or even at least 4 successive steps. These successive applications can also be implemented over several weeks, or even several months.

The time between each application step can advantageously be between 1 and several days, for example 1 to 7 days which corresponds to a weekly application of the composition, or between 2 to 4 days, which corresponds to a bi-application. weekly composition.

In what follows, and unless otherwise indicated, the limits of a domain of values are included in this domain, in particular in the expressions “between” and “ranging from… to…”.

Furthermore, the expression “at least one” used in this description is equivalent to the expression “one or more” and can be substituted for it.

Amino acid compounds

The composition used in the context of the present invention comprises one or more compounds of the amino acid type.

By compound of amino acid type is meant for the purposes of the present invention an organic compound comprising one or more carboxylic acid and/or sulfonic acid functions, and one or more amine functions, the amine function(s) being able to be intra-cyclic, optionally under form of salt.

Preferably, the amino acid type compound(s) are chosen from amino acid type compounds comprising only one or more carboxylic acid functions (therefore not comprising a sulfonic acid function) and/or their salts. Said compounds are also called compounds of the amino carboxylic acid type and are particularly preferred.

Preferably, the composition according to the present invention comprises one or more compounds of the amino acid type chosen from the compounds corresponding to formula (I) below and/or their salts.

Amino acid type compounds can therefore correspond to formula (I):

in which p is an integer equal to 1 or 2, it being understood that:
- when p = 1, R forms with the nitrogen atom a saturated heterocycle comprising from 5 to 8 members, preferably 5 members, this cycle possibly being substituted by one or more groups chosen from hydroxyl or (C ₁ -C ₄ ) alkyl;
- when p = 2, R represents a hydrogen atom or a (C ₁ -C ₁₂ ) alkyl group, preferably (C ₁ -C ₄ ) alkyl, linear or branched, saturated, optionally interrupted by one or more heteroatoms or groups chosen from –S–, –NH– or –C(NH)– and/or optionally substituted by one or more groups chosen from hydroxyl (OH), amino (NH2), -SH, -COOH, -CONH2 or –NH –C(NH)–NH ₂ .

Preferably, when p = 1, R forms with the nitrogen atom a saturated heterocycle comprising 5 members, this cycle not being substituted.

Preferably, p=2.

Preferably, when p = 2, R represents a hydrogen atom or a (C1-C4) alkyl group, linear or branched, saturated, optionally interrupted by an –S– heteroatom and/or optionally substituted by one or two selected groups among hydroxyl, amino or –NH–C(NH)–NH2.

Preferably, p=2 and R represents a hydrogen atom.

The amino acid type compounds can also be a salt of a compound of formula (I).

These salts include salts with organic or mineral bases, for example salts of alkali metals, such as lithium, sodium, potassium salts; alkaline earth metal salts such as magnesium salts, calcium salts and zinc salts.

The amino acid type compounds can be in the form of an optical isomer of L, D or DL configuration, preferably of L configuration.

As examples according to the present invention of compounds in the form of an optical isomer of L configuration, mention may be made of L-proline, L-methionine, L-serine, L-arginine and L-lysine. .

Preferably, the amino acid type compound(s) according to the invention are chosen from glycine, proline, methionine, serine, arginine, lysine, their salts (in particular of alkali or alkaline earth metals, or of zinc) and their mixtures.

Preferably, the amino acid type compound(s) according to the invention are chosen from glycine, proline, methionine, serine, arginine, their salts and their mixtures.

Even better, the amino acid type compound is chosen from glycine, its salts (in particular of alkali or alkaline earth metals, or of zinc) and their mixtures.

As glycine salts according to the present invention, mention may be made of sodium glycinate, zinc glycinate, calcium glycinate, magnesium glycinate, manganese glycinate and potassium glycinate, preferably sodium glycinate and potassium glycinate.

Preferably, the amino acid compound is glycine.

The total content of amino acid type compound(s) present in the composition according to the invention is at least 0.5% by weight relative to the total weight of the composition. This content can range from 0.5 to 10% by weight, in particular from 0.7 to 8% by weight, better still from 0.8 to 7% by weight relative to the total weight of the composition.

In particular, the total content of compound(s) of the amino carboxylic acid type in the composition according to the invention can range from 0.5 to 10% by weight, in particular from 0.7 to 8% by weight, better still from 0.8 at 7% by weight, relative to the total weight of the composition.

Better, the total content of compound(s) of amino acid type chosen from glycine, proline, methionine, serine, arginine, lysine, their salts and their mixtures, in the composition according to the invention can range from 0.5 to 10% by weight, in particular 0.7 to 8% by weight, better still 0.8 to 7% by weight, relative to the total weight of the composition.

Very particularly, the total content of compound(s) of amino acid type chosen from glycine, its salts and their mixtures, in the composition according to the invention can range from 0.5 to 10% by weight, in particular from 0.7 to 8% by weight, better 0.8 to 7% by weight, relative to the total weight of the composition.

Even better, the glycine content in the composition according to the invention can range from 0.5 to 10% by weight, in particular from 0.7 to 8% by weight, better still from 0.8 to 7% by weight, relative to to the total weight of the composition.

Hydroxy(poly)carboxylic acids

The composition used according to the invention also comprises one or more hydroxylated (poly)carboxylic acids, comprising 2 to 8 carbon atoms, and/or their salts.

These (poly) acids are different from the amino acid type compounds previously described.

Said (poly) acids comprise at least one COOH group (in acidic or salified form); they can include several, in particular at least 2 COOH groups (in acidic or salified form), better still 2 or 3 COOH groups (in acidic or salified form).

They also include at least one OH group, but can include several, in particular 2 to 3 OH groups.

Preferably, they comprise a total of 4 to 6 carbon atoms and their hydrocarbon chain is saturated and linear.

Advantageously, the hydroxylated (poly) carboxylic acids and/or their salts comprise a total of 4 to 6 carbon atoms, 1 to 3 OH groups and 2 to 3 COOH groups (in acidic or salified form).

The salts of these (poly) acids include salts with organic or mineral bases, for example salts of alkali metals, such as lithium, sodium, potassium salts; alkaline earth metal salts such as magnesium salts, calcium salts and zinc salts. Alkaline or alkaline earth metal salts are preferred, and in particular sodium salts.

Preferably, the (poly) hydroxylated carboxylic acids or their salts are chosen from alpha hydroxy acids and their salts, and in particular from lactic, glycolic, tartaric or citric acids, and their salts in particular from alkali or alkaline earth metals. ; very particularly citric acid and/or tartaric acid as well as their salts, in particular of alkali or alkaline earth metals such as sodium citrate and/or sodium tartrate; even better citric acid or its salts, in particular of alkali or alkaline earth metals such as sodium citrate.

The total content of (poly) hydroxylated carboxylic acids comprising a total of 2 to 8 carbon atoms, and/or their salts, present in the composition according to the invention is at least 0.5% by weight relative to the total weight. of the composition. This content can range from 0.5 to 10% by weight, in particular from 1 to 8% by weight, better still from 1.5 to 6% by weight, relative to the total weight of the composition.

In particular, the total content of (poly) hydroxylated carboxylic acids comprising a total of 4 to 6 carbon atoms, 1 to 3 OH groups and 2 or 3 COOH groups, or their salts, present in the composition according to the invention can range from 0.5 to 10% by weight, in particular from 1 to 8% by weight, better still from 1.5 to 6% by weight, relative to the total weight of the composition.

Very particularly, the total content of (poly) hydroxylated carboxylic acids chosen from lactic, glycolic, tartaric or citric acids, and their salts in particular of alkali or alkaline earth metals, in the composition according to the invention can range from 0.5 at 10% by weight, in particular from 1 to 8% by weight, better still from 1.5 to 6% by weight, relative to the total weight of the composition.

Even better, the content of citric acid and/or its salts in the composition according to the invention can range from 0.5 to 10% by weight, in particular from 1 to 8% by weight, better still from 1.5 to 6% by weight. weight, relative to the total weight of the composition.

Associative polymer

The composition used according to the invention may optionally comprise one or more associative polymers. Preferably, the associative polymers are nonionic.

For the purposes of the present invention, the term "polymer" means any compound resulting from polycondensation polymerization or radical polymerization of monomers of which at least one is different from an alkylene oxide and a monofunctional compound of formula RX, R designating a C ₁₀ -C ₃₀ alkyl or alkenyl group, optionally hydroxylated, and X designating a carboxylic acid, amine, amide, hydroxyl, ester group. In particular, all compounds resulting solely from the simple condensation of an alkylene oxide on a fatty alcohol, a fatty ester, a fatty acid, a fatty amide, a fatty amine are excluded.

For the purposes of the present invention, the term "associative polymer" means an amphiphilic polymer capable, in an aqueous medium, of reversibly associating with itself or with other molecules. It generally includes in its chemical structure, at least one hydrophilic zone, or group, and at least one hydrophobic zone, or group.

The associative polymers according to the invention are polymers comprising at least one fatty chain comprising 8 to 30 carbon atoms and whose molecules are capable, in the formulation medium, of associating with each other or with molecules of other compounds. Preferably, the fatty chain contains 10 to 30 carbon atoms.

A particular case of associative polymers are amphiphilic polymers, that is to say polymers comprising one or more hydrophilic parts or groups which make them soluble in water and one or more hydrophobic zones or groups (comprising at least one chain fatty) by which polymers interact and come together with each other or with other molecules.

By "hydrophobic group" is meant a group or polymer with a hydrocarbon chain, saturated or not, linear or branched which may contain one or more heteroatoms such as P, O, N, S, or a radical with a perfluorinated or silicone chain. When it designates a hydrocarbon group, the hydrophobic group comprises at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms and preferably from 18 to 30 carbon atoms. Preferably, the hydrophobic hydrocarbon group comes from a monofunctional compound. For example, the hydrophobic group can come from a fatty alcohol such as stearyl alcohol, dodecyl alcohol, decyl alcohol or from a polyalkylenated fatty alcohol such as steareth-100. It can also designate a hydrocarbon polymer such as for example polybutadiene.

By “fatty chain” within the meaning of the present invention is meant an alkyl or alkenyl chain, linear or branched, comprising at least 8 carbon atoms, preferably from 8 to 30 carbon atoms, and better still from 10 to 22 atoms. of carbon.

By “fatty” compound, such as for example a fatty alcohol, a fatty acid or a fatty amide, is meant within the meaning of the present invention, a compound comprising in its main chain at least one hydrocarbon chain, saturated or unsaturated, such as alkyl or alkenyl, comprising at least 8 carbon atoms, preferably from 8 to 30 carbon atoms, and better still from 10 to 22 carbon atoms.

Among the anionic associative polymers, we can in particular cite:

- (A) those comprising at least one hydrophilic unit and at least one fatty chain allyl ether unit; and more particularly those:
the hydrophilic unit of which is constituted by an ethylenically unsaturated anionic monomer, more particularly still by a vinyl carboxylic acid and very particularly by an acrylic acid or a methacrylic acid or mixtures thereof; And
whose fatty chain allyl ether unit corresponds to the monomer of formula (I') following: CH ₂ =C(R')-CH ₂ OB _n R
in which R' denotes H or CH ₃ , B denotes the ethyleneoxy radical, n ranges from 0 to 100, and R denotes a hydrocarbon radical chosen from alkyl, arylalkyl, aryl, alkylaryl and cycloalkyl radicals, comprising from 8 to 30 atoms of carbon, preferably 10 to 24, and even more particularly 12 to 18 carbon atoms. Preferably, R' denotes H, n = 10 and R denotes a stearyl radical (C ₁₈ ).

Among these anionic associative polymers, polymers formed from 20 to 60% by weight of acrylic acid and/or methacrylic acid, from 5 to 60% by weight of C alkyl (meth)acrylates are particularly preferred. ₁ -C ₄ , from 2 to 50% by weight of fatty chain allyl ether of formula (I'), and from 0 to 1% by weight of a crosslinking agent which is preferably a copolymerizable polyethylenic unsaturated monomer , such as diallyl phthalate, allyl (meth)acrylate, divinylbenzene, (poly)ethylene glycol dimethacrylate or methylene-bis-acrylamide.

We particularly prefer crosslinked terpolymers of methacrylic acid, ethyl acrylate, polyethylene glycol (10 EO) and stearyl alcohol ether (Steareth 10), in particular that sold by the company BASF under the name SALCARE SC 80 which is a 30% aqueous emulsion of a crosslinked terpolymer of methacrylic acid, ethyl acrylate and steareth-10-allyl ether (40/50/10), with the INCI name Steareth-10 Allyl Ether/Acrylates Copolymer.

- (B) those comprising at least one hydrophilic unit of the olefinic unsaturated carboxylic acid type, and at least one hydrophobic unit of the (C ₁₀ -C ₃₀ ) alkyl ester type of unsaturated carboxylic acid.

Preferably, these polymers are chosen from those whose hydrophilic unit of unsaturated olefinic carboxylic acid type corresponds to the monomer of formula (II) below:

in which R ₁ denotes H, CH ₃ or C ₂ H ₅ , and whose hydrophobic unit of alkyl ester type (C ₁₀ -C ₃₀ ) of unsaturated carboxylic acid corresponds to the monomer of formula (III) following:

in which R ₂ denotes H, CH ₃ or C ₂ H ₅ , and R ₃ denotes a C ₁₀ -C ₃₀ , preferably C ₁₂ -C ₂₂ , alkyl radical.

Alkyl esters (C ₁₀ -C ₃₀ ) of unsaturated carboxylic acids according to the invention include, for example, lauryl acrylate, stearyl acrylate, decyl acrylate, isodecyl acrylate , dodecyl acrylate, and the corresponding methacrylates, lauryl methacrylate, stearyl methacrylate, decyl methacrylate, isodecyl methacrylate and dodecyl methacrylate.

Among these anionic associative polymers, polymers formed from a mixture of monomers comprising: (i) (meth)acrylic acid, (ii) an ester of formula (III) described above and in which R ₂ denotes H or CH ₃ , R ₃ denotes an alkyl radical having 12 to 22 carbon atoms, and optionally (iii) a crosslinking agent, which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, allyl (meth)acrylate, divinylbenzene, (poly)ethylene glycol dimethacrylate, and methylene-bis-acrylamide.

Among this type of anionic associative polymers, those consisting of 95 to 60% by weight of (meth)acrylic acid, 4 to 40% by weight of C ₁₀ -C ₃₀ alkyl acrylate, and 0 are more particularly preferred. at 6% by weight of crosslinking polymerizable monomer, or those consisting of 98 to 96% by weight of (meth)acrylic acid, 1 to 4% by weight of C ₁₀ -C ₃₀ and 0 alkyl acrylate, 1 to 0.6% by weight of crosslinking polymerizable monomer such as those described above.

We can in particular cite the products sold by the company LUBRIZOL under the trade names PEMULEN TR1, PEMULEN TR2, CARBOPOL 1382, CARBOPOL ETD 2020, CARBOPOL ULTREZ 20, CARBOPOL ULTREZ 21, with the name INCI Acrylates/C10-30 Alkyl Acrylate Crosspolymer, and again more preferably PEMULEN TR1 and CARBOPOL 1382.

- (C) maleic anhydride/C ₃₀ -C ₃₈ α-olefin/alkyl maleate terpolymers such as the maleic anhydride/C ₃₀ -C ₃₈ α-olefin/isopropyl maleate copolymer, in particular that sold under the name PERFORMA V 1608 by the company NEWPHASE TECHNOLOGIES (INCI name: C30-38 Olefin/Isopropyl Maleate/MA Copolymer).

- (D) acrylic terpolymers comprising (a) 20 to 70% by weight of a carboxylic acid with α, β-monoethylenically unsaturated, (b) 20 to 80% by weight of a monomer with α, β-monoethylenically unsaturated non-surfactant other than (a), and (c) 0.5 to 60% by weight of a non-ionic mono-urethane which is the reaction product of a monohydric surfactant with a monoethylenically unsaturated monoisocyanate.
Mention may in particular be made of the methacrylic acid/methyl acrylate/dimethyl metaisopropenyl benzyl isocyanate of ethoxylated behenyl alcohol terpolymer (40 EO), particularly in aqueous dispersion at 25% such as the product VISCOPHOBE DB1000 sold by the company AMERCHOL (DOW CHEMICAL) of INCI name Polyacrylate-3.

- (E) copolymers comprising among their monomers (i) a carboxylic acid with α, β-monoethylenic unsaturation, such as acrylic or methacrylic acid, and (ii) a carboxylic acid ester with α, β-monoethylenic unsaturation , in particular acrylic or methacrylic, and fatty alcohol in particular oxyalkylenated C8-C32, in particular comprising 2 to 100 moles of ethylene oxide, in particular 4 to 50, or even 10 to 40 EO.

Mention may in particular be made as monomers of behenyl or stearyl (meth)acrylate, comprising 10 to 40 EO, in particular 18 to 30 EO.

Preferably these compounds also comprise as monomer an ester of α, β-monoethylenically unsaturated carboxylic acid and C1-C4 alcohol, in particular a C1-C4 alkyl (meth)acrylate.

Preferably, these copolymers comprise at least one (meth)acrylic acid monomer, at least one C1-C4 alkyl (meth)acrylate monomer and at least one C8-C32 alkyl (meth)acrylate monomer, oxyethylenated comprising 2 to 100 moles EO, in particular 4 to 50 EO, or even 10 to 40 EO.

As examples, we can cite ACULYN 22 sold by the company ROHM and HAAS, which is a methacrylic acid/ethyl acrylate/oxyalkylenated stearyl methacrylate terpolymer (INCI name Acrylates/Steareth-20 Methacrylate Copolymer), or also ACULYN 28 sold by ROHM and HAAS, which is a methacrylic acid/ethyl acrylate/oxyalkylenated behenyl methacrylate terpolymer (INCI name Acrylates/Beheneth-25 Methacrylate Copolymer), as well as NOVETHIX L-10 POLYMER sold by Lubrizol.

- (F) associative polymers comprising at least one ethylenically unsaturated monomer with a sulfonic group, in free or partially or totally neutralized form and comprising at least one hydrophobic part.

Among the polymers of this type, we can cite more especially
-crosslinked or non-crosslinked copolymers, neutralized or not, comprising from 15 to 60% by weight of AMPS units (2-acrylamido-2-methylpropanesulfonic acid or salt) and from 40 to 85% by weight of units (C8-C16) alkyl(meth)acrylate relative to the polymer, as described in application EP-A-750899
-terpolymers comprising from 10 to 90 mole% of acrylamide units, from 0.1 to 10 mole% of AMPS units and from 5 to 80 mole% of n-(C6-C8)alkylacrylamide units, such as those described in patent US5089578
- copolymers of totally neutralized AMPS and dodecyl methacrylate as well as non-crosslinked and crosslinked copolymers of AMPS and n-dodecylmethacrylamide
- copolymers consisting of AMPS units and steareth-25 methacrylate units such as ARISTOFLEX HMS marketed by the company CLARIANT, (INCI name Ammonium Acryloyldimethyltaurate / Steareth-25 Methacrylate Crosspolymer) or beheneth-25 methacrylate, such as ARISTOFLEX HMB (INCI name Ammonium Acryloyldimethyltaurate/Beheneth-25 Methacrylate Crosspolymer) marketed by the company CLARIANT, or steareth-8 methacrylate, such as ARISTOFLEX SNC from CLARIANT (INCI name ammonium acryloyldimethyltaurate/steareth-8 methacrylate copolymer).

- (G) associative polymers comprising at least one vinyllactam monomer and at least one carboxylic acid monomer with α, β-monoethylenic unsaturation such as the terpolymers of vinylpyrrolidone, acrylic acid and C ₁ -C ₂₀ alkyl methacrylate , for example lauryl, such as that marketed by the company ISP under the name ACRYLIDONE ^® LM (INCI name VP/Acrylates/Lauryl Methacrylate Copolymer).

Among the cationic associative polymers, we can cite:
- (A') cationic associative polyurethanes, which can be represented by the following general formula (Ia): RX-(P) _n -[L-(Y) _m ] _r -L'-(P') _p -X '-R'
in which :
R and R', identical or different, represent a hydrophobic group or a hydrogen atom;
X and X', identical or different, represent a group comprising an amine function carrying or not a hydrophobic group, or the group L";
L, L' and L", identical or different, represent a group derived from a diisocyanate;
P and P', identical or different, represent a group comprising an amine function carrying or not a hydrophobic group;
Y represents a hydrophilic group;
r is an integer included between 1 and 100 inclusively, preferably between 1 and 50 inclusively and in particular between 1 and 25 inclusively,
n, m, and p are each independently of the others between 0 and 1000 inclusive;
the molecule containing at least one protonated or quaternized amine function and at least one hydrophobic group.

Preferably, the only hydrophobic groups are the groups R and R' at the chain ends.

A preferred family of cationic associative polyurethanes is that corresponding to formula (Ia) described above in which:
R and R' both independently represent a hydrophobic group,
X, X' each represent a group L'',
n and p are integers which are inclusively between 1 and 1000 and
L, L', L'', P, P', Y and m have the meaning indicated above.

Another preferred family of cationic associative polyurethanes is that corresponding to formula (Ia) above in which:
n=p=0 (the polymers do not contain units derived from an amine-functional monomer, incorporated into the polymer during polycondensation),
the protonated amine functions result from the hydrolysis of excess isocyanate functions at the end of the chain, followed by the alkylation of the primary amine functions formed by alkylating agents with a hydrophobic group, that is to say compounds of type RQ or R'Q, in which R and R' are as defined above and Q designates a leaving group such as a halide, a sulfate, etc.

Yet another preferred family of cationic associative polyurethanes is that corresponding to formula (Ia) above in which:
R and R' both independently represent a hydrophobic group,
X and X' both independently represent a group comprising a quaternary amine,
n = p = 0, and
L, L', Y and m have the meanings indicated above.

The number average molecular mass (Mn) of the cationic associative polyurethanes is preferably between 400 and 500,000 inclusive, in particular between 1000 and 400,000 inclusive and ideally between 1000 and 300,000 inclusive.

Preferably, the hydrocarbon group comes from a monofunctional compound.

For example, the hydrophobic group can come from a fatty alcohol such as stearyl alcohol, dodecyl alcohol, decyl alcohol. It can also designate a hydrocarbon polymer such as for example polybutadiene.

When X and/or X' designate a group comprising a tertiary or quaternary amine, X and/or X' may represent one of the following formulas:
in which :
R ₂ represents an alkylene radical having from 1 to 20 carbon atoms, linear or branched, comprising or not a saturated or unsaturated ring, or an arylene radical, one or more of the carbon atoms being able to be replaced by a heteroatom chosen from N, S, O, P;
R ₁ and R ₃ , identical or different, designate a linear or branched C ₁ -C ₃₀ alkyl or alkenyl radical, an aryl radical, at least one of the carbon atoms being able to be replaced by a heteroatom chosen from N, S, O, P;
A ^- is a physiologically acceptable anionic counterion such as a halide such as a chloride or bromide, or a mesylate.

The groups L, L' and L" represent a group of formula:
in which :
Z represents –O-, -S- or –NH-; And
R ₄ represents an alkylene radical having from 1 to 20 carbon atoms, linear or branched, comprising or not a saturated or unsaturated ring, an arylene radical, one or more of the carbon atoms being able to be replaced by a heteroatom chosen from N, S , O and P.

The groups P and P', comprising an amine function, can represent at least one of the following formulas:

in which :
R ₅ and R ₇ have the same meanings as R ₂ defined previously;
R ₆ , R ₈ and R ₉ have the same meanings as R ₁ and R ₃ defined previously;
R ₁₀ represents an alkylene group, linear or branched, optionally unsaturated and which may contain one or more heteroatoms chosen from N, O, S and P,
and A ^- is a physiologically acceptable anionic counterion such as halide such as chloride or bromide or mesylate.

With regard to the meaning of Y, the term hydrophilic group means a water-soluble polymeric or non-polymeric group.

By way of example, we can cite, when it is not a question of polymers, ethylene glycol, diethylene glycol and propylene glycol.

When it is a hydrophilic polymer, mention may be made, by way of example, of polyethers, sulfonated polyesters, sulfonated polyamides, or a mixture of these polymers. Preferably, the hydrophilic compound is a polyether and in particular a poly(ethylene oxide) or poly(propylene oxide).

The cationic associative polyurethanes of formula (Ia) according to the invention are formed from diisocyanates and different compounds having labile hydrogen functions. The labile hydrogen functions can be alcohol, primary or secondary amine or thiol functions giving, after reaction with the diisocyanate functions, polyurethanes, polyureas and polythioureas respectively. The term "polyurethanes" of the present invention encompasses these three types of polymers, namely polyurethanes themselves, polyureas and polythioureas as well as copolymers thereof.

A first type of compound used in the preparation of the polyurethane of formula (Ia) is a compound comprising at least one amine function unit. This compound can be multifunctional, but preferably the compound is difunctional, that is to say that according to a preferred embodiment, this compound comprises two labile hydrogen atoms carried for example by a hydroxyl function, primary amine, secondary amine or thiol. It is also possible to use a mixture of multifunctional and difunctional compounds in which the percentage of multifunctional compounds is low.

As indicated previously, this compound may contain more than one amine-functional unit. It is then a polymer carrying a repetition of the amine function unit.

This type of compounds can be represented by one of the following formulas:
HZ-(P) _n -ZH, or HZ-(P') _p -ZH, in which Z, P, P', n and p are as defined above.

By way of example, mention may be made of N methyldiethanolamine, N-tert-butyl-diethanolamine and N-sulfoethyldiethanolamine.

The second compound used in the preparation of the polyurethane of formula (Ia) is a diisocyanate corresponding to the formula: O=C=NR ₄ -N=C=O in which R ₄ is defined above.

By way of example, mention may be made of methylenediphenyl-diisocyanate, methylenecyclohexanediisocyanate, isophoronediisocyanate, toluenediisocyanate, naphthalenediisocyanate, butanediisocyanate, hexanediisocyanate.

A third compound used in the preparation of the polyurethane of formula (Ia) is a hydrophobic compound intended to form the terminal hydrophobic groups of the polymer of formula (Ia).

This compound consists of a hydrophobic group and a labile hydrogen function, for example a hydroxyl, primary or secondary amine, or thiol function.

For example, this compound may be a fatty alcohol, such as stearyl alcohol, dodecyl alcohol, decyl alcohol. When this compound comprises a polymer chain, it may for example be alpha-hydroxy hydrogenated polybutadiene.

The hydrophobic group of the polyurethane of formula (Ia) can also result from the quaternization reaction of the tertiary amine of the compound comprising at least one tertiary amine unit. Thus, the hydrophobic group is introduced by the quaternizing agent. This quaternizing agent is a compound of type RQ or R'Q, in which R and R' are as defined above and Q designates a leaving group such as a halide, a sulfate, etc.

The cationic associative polyurethane may further comprise a hydrophilic sequence. This sequence is provided by a fourth type of compound used in the preparation of the polymer. This compound may be multifunctional. It is preferably difunctional. We can also have a mixture where the percentage of multifunctional compound is low.

The labile hydrogen functions are alcohol, primary or secondary amine, or thiol functions. This compound may be a polymer terminated at the ends of the chains by one of these labile hydrogen functions.

By way of example, we can cite, when it is not a question of polymers, ethylene glycol, diethylene glycol and propylene glycol.

When it is a hydrophilic polymer, mention may be made, by way of example, of polyethers, sulfonated polyesters, sulfonated polyamides, or a mixture of these polymers. Preferably, the hydrophilic compound is a polyether and in particular a poly(ethylene oxide) or poly(propylene oxide).

The hydrophilic group denoted Y in formula (Ia) is optional. Indeed, the units with quaternary or protonated amine function can be sufficient to provide the solubility or hydrodispersibility necessary for this type of polymer in an aqueous solution.

Although the presence of a hydrophilic Y group is optional, cationic associative polyurethanes comprising such a group are preferred.

- (B') quaternized cellulose derivatives, and in particular:
- i) quaternized celluloses modified by groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl, linear or branched alkylaryl groups comprising at least 8 carbon atoms, or mixtures thereof ;

- ii) quaternized hydroxyethylcelluloses modified by groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl, linear or branched alkylaryl groups comprising at least 8 carbon atoms, or mixtures thereof ;

- iii) hydroxyethylcelluloses of formula (Ib):

in which :
R and R', identical or different, represent an ammonium group R _a R _b R _c N ⁺ -, Q ^- in which R _a , R _b , R _c , identical or different represent a hydrogen atom, an alkyl group, linear or branched, in C ₁ -C ₃₀ preferably C ₁ -C ₂₀ , such as methyl or dodecyl; and Q- represents an anionic counterion such as a halide such as a chloride or bromide; And
n, x and y, identical or different, represent an integer between 1 and 10000.

The alkyl radicals carried by the celluloses i) or quaternized hydroxyethylcelluloses ii) above preferably contain from 8 to 30 carbon atoms. Aryl radicals preferably designate phenyl, benzyl, naphthyl or anthryl groups.

As examples of quaternized alkylhydroxyethyl celluloses with C ₈ -C ₃₀ fatty chains, we can indicate the product QUATRISOFT LM 200, marketed by the company AMERCHOL/DOW CHEMICAL (INCI name Polyquaternium-24) and the CRODACEL QM products (INCI name PG-Hydroxyethylcellulose Cocodimonium Chloride), CRODACEL QL (C ₁₂ alkyl) (INCI name PG-Hydroxyethylcellulose Lauryldimonium Chloride) and CRODACEL QS (C18 alkyl) (INCI name PG-Hydroxyethylcellulose Stearyldimonium Chloride) marketed by the company CRODA.

Mention may also be made of hydroxyethylcelluloses of formula (Ib) in which R represents trimethylammonium halide and R' represents dimethyldodecylammonium halide more preferably R represents trimethylammonium chloride Cl ^- , (CH ₃ ) ₃ N ⁺ - and R ' represents dimethyl dodecylammonium chloride Cl ^- , (CH ₃ ) ₂ (C ₁₂ H ₂₅ )N ⁺ -. This type of polymer is known under the trade names SOFTCAT POLYMER SL® such as SL-100, SL-60, SL-30 and SL-5 from the company AMERCHOL /DOW CHEMICAL with the INCI name Polyquaternium-67.

More particularly, the polymers of formula (Ib) are those whose viscosity is inclusively between 2000 and 3000 cPs. Preferably the viscosity is inclusively between 2700 and 2800 cPs. Typically SOFTCAT POLYMER SL-5 has a viscosity of 2500 cPs, SOFTCAT POLYMER SL-30 has a viscosity of 2700 cPs, SOFTCAT POLYMER SL-60 has a viscosity of 2700 cPs and SOFTCAT POLYMER SL-100 has a viscosity of 2800 cps.

- (C') cationic polyvinyllactams, in particular those comprising:
- a) at least one monomer of vinyllactam or alkylvinyllactam type;
- b) at least one monomer of the following structures (Ic) or (IIc):

in which :
X designates an oxygen atom or an NR6 radical,
R1 and R6 designate, independently of each other, a hydrogen atom or a linear or branched C1-C5 alkyl radical,
R2 designates a linear or branched C1-C4 alkyl radical,
R3, R4 and R5 designate, independently of one another, a hydrogen atom, a linear or branched C1-C30 alkyl radical or a radical of formula (IIIc):
in which :
Y, Y1 and Y2 designate, independently of each other, a linear or branched C2-C16 alkylene radical,
R7 denotes a hydrogen atom, or a linear or branched C1-C4 alkyl radical or a linear or branched C1-C4 hydroxyalkyl radical,
R8 designates a hydrogen atom or a linear or branched C1-C30 alkyl radical,
p, q and r designate, independently of each other, either the value zero or the value 1,
m and n designate, independently of each other, an integer ranging from 0 to 100 inclusively,
x designates an integer ranging from 1 to 100 inclusively,
Z designates an anionic counterion of an organic or mineral acid, such as a halide such as chloride or bromide or mesylate;
provided that :
- at least one of the substituents R3, R4, R5 or R8 designates a linear or branched C9-C30 alkyl radical,
- if m or n is different from zero, then q is equal to 1,
- if m or n are equal to zero, then p or q is equal to 0.

The cationic poly(vinyllactam) polymers according to the invention can be crosslinked or non-crosslinked and can also be block polymers.

Preferably the counterion Z- of the monomers of formula (Ic) is chosen from halide ions, phosphate ions, methosulfate ion, tosylate ion.

Preferably R3, R4 and R5 designate, independently of one another, a hydrogen atom or a linear or branched C1-C30 alkyl radical.

More preferably, monomer b) is a monomer of formula (Ic) for which, preferably, m and n are equal to zero.

The vinyllactam or alkylvinyllactam monomer is preferably a compound of structure (IVc):

in which s designates an integer ranging from 3 to 6; R9 designates a hydrogen atom or a linear or branched C1-C5 alkyl radical and R10 designates a hydrogen atom or a linear or branched C1-C5 alkyl radical, provided that at least one of the radicals R9 and R10 denotes a hydrogen atom.

Even more preferably, the monomer (IVc) is vinylpyrrolidone.

The cationic poly(vinyllactam) polymers according to the invention may also contain one or more additional monomers, preferably cationic or non-ionic.

As particularly preferred compounds, mention may be made of the following terpolymers comprising at least:
a)-a monomer of formula (IVc),
b)-a monomer of formula (Ic) in which p=1, q=0, R3 and R4 designate, independently of one another, a hydrogen atom or a C1-C5 alkyl radical and R5 designates a linear or branched C9-C24 alkyl radical and
c)-a monomer of formula (IIc) in which R3 and R4 designate, independently of one another, a hydrogen atom or a linear or branched C1-C5 alkyl radical.

Even more preferably, terpolymers comprising, by weight, 40 to 95% of monomer (a), 0.1 to 55% of monomer (c) and 0.25 to 50% of monomer (b) will be used. Such polymers are described in particular in patent application WO-00/68282.

As cationic poly(vinyllactam) polymers according to the invention, the following are used in particular:
- vinylpyrrolidone/dimethylaminopropylmethacrylamide/dodecyldimethylmethacrylamidopropylammonium tosylate terpolymers,
- vinylpyrrolidone/dimethylaminopropylmethacrylamide/cocoyldimethylmethacrylamidopropylammonium tosylate terpolymers,
- vinylpyrrolidone / dimethylaminopropylmethacrylamide / tosylate or lauryldimethylmethacrylamidopropylammonium chloride terpolymers.

The vinylpyrrolidone/dimethylaminopropyl methacrylamide/lauryl dimethylmethacrylamidopropylammonium chloride terpolymer is notably offered by the company ISP under the names Styleze W10 or Styleze W20L (INCI name Polyquaternium-55).

The molecular mass by weight (Mw) of the cationic poly(vinyllactam) polymers is preferably between 500 and 20,000,000, more particularly between 200,000 and 2,000,000 and preferably between 400,000 and 800,000.

- (D') cationic polymers obtained by polymerization of a mixture of monomers comprising one or more vinyl monomers substituted by one or more amino groups, one or more hydrophobic nonionic vinyl monomers, and one or more associative vinyl monomers, such as described in patent application WO2004/024779.

Among these polymers, mention may be made more particularly of the products of the polymerization of a mixture of monomers comprising:
- a di(C1-C4 alkyl)amino(C1-C6 alkyl) methacrylate,
- one or more C1-C30 alkyl esters and (meth)acrylic acid,
- a polyethoxylated C10-C30 alkyl methacrylate (20-25 moles of ethylene oxide unit),
- a 30/5 polyethylene glycol/polypropylene glycol allyl ether,
- a hydroxy methacrylate (C2-C6 alkyl), and
- an ethylene glycol dimethacrylate.

Such a polymer is for example the compound marketed by the company LUBRIZOL under the name CARBOPOL AQUA CC and which corresponds to the INCI name Polyacrylate-1 crosspolymer.

The nonionic associative polymers are preferably chosen from, alone or in mixture:

(1) Celluloses modified by groups comprising at least one fatty chain, in particular C8-C32 alkyl, better still C14-C28; preferably from:
- hydroxyethylcelluloses modified by groups comprising at least one fatty chain, in particular C8-C32 alkyl, better still C14-C28, such as alkyl, arylalkyl, alkylaryl groups, or mixtures thereof, and in which the alkyl groups are preferably in C ₈ -C ₂₂ , such as cetylhydroxyethyl cellulose sold in particular under the reference NATROSOL PLUS GRADE 330 CS (C ₁₆ alkyls) sold by the company Ashland, or the product Polysurf 67CS sold by the company Ashland,
- hydroxyethylcelluloses modified by polyalkylene glycol alkyl phenol ether groups, such as the product AMERCELL POLYMER HM-1500 (polyethylene glycol (15) nonyl phenol ether) sold by the company AMERCHOL,
- and their mixtures.

(2) Hydroxypropyl guars modified by groups comprising at least one fatty chain, in particular C8-C32 alkyl, better C14-C28, such as the product ESAFLOR HM 22 (C ₂₂ alkyl chain) sold by the company LAMBERTI, the products RE210-18 (C ₁₄ alkyl chain) and RE205-1 (C ₂₀ alkyl chain) sold by the company RHODIA.

(3) Copolymers of vinylpyrrolidone and hydrophobic monomers with fatty chains, in particular C8-C32 alkyl, better still C14-C28. We can cite as an example:
- the vinylpyrrolidone/hexadecene copolymer and in particular the ANTARON V216 or GANEX V216 products sold by the company ISP
- the vinylpyrrolidone/eicosene copolymer and in particular the ANTARON V220 or GANEX V220 products sold by the company ISP

(4) Copolymers of methacrylates or acrylates of C ₁ -C ₆ alkyls and amphiphilic monomers comprising at least one fatty chain, in particular C8-C32 alkyl, better still C14-C28 alkyl, such as for example the acrylate copolymer methyl/oxyethylenated stearyl acrylate sold by the company GOLDSCHMIDT under the name ANTIL 208.

(5) Copolymers of hydrophilic methacrylates or acrylates and hydrophobic monomers comprising at least one fatty chain, in particular C8-C32 alkyl, better still C14-C28, such as for example the polyethylene glycol methacrylate/lauryl methacrylate copolymer.

(6) Polyurethane polyethers comprising in their chain, both hydrophilic sequences of a most often polyoxyethylenated nature and hydrophobic sequences which can be aliphatic chains alone and/or cycloaliphatic and/or aromatic chains.

(7) Polymers with an aminoplast ether skeleton having at least one fatty chain, in particular C8-C32 alkyl, better still C14-C28, such as the PURE THIX compounds offered by the company SUD-CHEMIE.

Preferably, the polyurethane polyethers comprise at least two lipophilic hydrocarbon chains, having from 8 to 30 carbon atoms, separated by a hydrophilic sequence, the hydrocarbon chains possibly being pendant chains or chains at the end of the hydrophilic sequence. In particular, it is possible that one or more pendant chains are provided. In addition, the polymer may comprise a hydrocarbon chain at one end or at both ends of a hydrophilic sequence.

Polyurethane polyethers can be multiblocked, particularly in triblock form. The hydrophobic blocks can be at each end of the chain (for example: triblock copolymer with a hydrophilic central block) or distributed both at the ends and in the chain (multiblock copolymer for example). These same polymers can also be grafts or stars.

The nonionic polyurethane polyethers with a fatty chain can be triblock copolymers whose hydrophilic sequence is a polyoxyethylenated chain comprising from 50 to 1000 oxyethylenated groups. Non-ionic polyurethane polyethers have a urethane bond between the hydrophilic sequences, hence the origin of the name.

By extension, non-ionic polyurethane polyethers with a fatty chain also include those whose hydrophilic sequences are linked to the lipophilic sequences by other chemical bonds.

As examples of non-ionic polyurethane polyethers with a fatty chain which can be used in the invention, one can also use Rhéolate 205® with a urea function sold by the company RHEOX or even Rhéolates® 208, 204 or 212, as well as Acrysol RM 184®. We can also cite the product ELFACOS T210® with a C12-14 alkyl chain and the product ELFACOS T212® with a C18 alkyl chain from AKZO. The product DW 1206B® from ROHM & HAAS with a C20 alkyl chain and a urethane bond, offered at 20% dry matter in water, can also be used.

We can also use solutions or dispersions of these polymers, particularly in water or in a hydroalcoholic medium. By way of example, such polymers include RHEOLATE® 255, RHEOLATE® 278 and RHEOLATE® 244 sold by the company RHEOX. You can also use the product DW 1206F and DW 1206J offered by the company ROHM & HAAS.

The polyurethane polyethers which can be used according to the invention are in particular those described in the article by G. Fonnum, J. Bakke and Fk. Hansen - Colloid Polym. Sci. 271, 380,389 (1993).

Even more particularly, it is preferred to use a polyether polyurethane capable of being obtained by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 150 to 180 moles of ethylene oxide, (ii) stearyl alcohol or decyl alcohol and (iii) at least one diisocyanate.

Such polyether polyurethanes are sold in particular by the company ROHM & HAAS under the names ACULYN 46® and ACULYN 44® [ACULYN 46® is a polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, stearyl alcohol and methylene bis(4-cyclohexyl-isocyanate) (SMDI), at 15% by weight in a matrix of maltodextrin (4%) and water (81%); ACULYN 44® is a polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis(4-cyclohexylisocyanate) (SMDI), at 35% by weight in a mixture of propylene glycol ( 39%) and water (26%)].

Preferably, the composition comprises one or more nonionic associative polymers, preferably chosen from polyurethane polyethers.

Preferably, the associative polymer(s) are present in the composition in a total content ranging from 0.01 to 10% by weight, preferably 0.05 to 5% by weight, more preferably from 0.1 to 1.5% by weight. weight, relative to the total weight of the composition.

Preferably, the nonionic associative polymer(s) are present in the composition in a total content ranging from 0.01 to 10% by weight, preferably 0.05 to 5% by weight, more preferably from 0.1 to 1.5 % by weight, relative to the total weight of the composition.

Preferably, the nonionic associative polymer(s) chosen from polyurethane polyethers are present in the composition in a total content ranging from 0.01 to 10% by weight, preferably 0.05 to 5% by weight, more preferably 0. 1 to 1.5% by weight relative to the total weight of the composition.

Silicones

The composition used according to the invention may optionally comprise one or more silicones, which may in particular be chosen from aminated silicones, non-aminated silicones, and mixtures thereof.

The composition according to the invention can therefore comprise one or more non-amine silicones, which can be solid or liquid, preferably liquid (at 25°C, 1 atm), volatile or non-volatile.

The non-amine silicones which may be used may be soluble or insoluble in the composition according to the invention; they can be in the form of oil, wax, resin or gum; oils and silicone gums are preferred.

Silicones are described in detail in the work of Walter NOLL "Chemistry and Technology of Silicones" (1968), Academie Press.

The volatile silicones can be chosen from those having a boiling point of between 60 and 260°C (at atmospheric pressure), in particular from:

i) cyclic polydialkylsiloxanes containing 3 to 7 silicon atoms, preferably 4 to 5, such as

- octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5). We can cite the products marketed under the name "VOLATILE SILICONE 7207" by UNION CARBIDE or "SILBIONE 70045 V 2" by RHODIA, "VOLATILE SILICONE 7158" by UNION CARBIDE, "SILBIONE 70045 V 5" by RHODIA.

- cyclocopolymers of the dimethylsiloxane/methylalkylsiloxane type with chemical structure:

We can cite the “VOLATILE SILICONE FZ 3109” marketed by the company UNION CARBIDE.

- mixtures of cyclic silicones with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1'-(hexa-2, 2,2',2',3,3'-trimethylsilyloxy) bis-neopentane;

ii) linear polydialkylsiloxanes having 2 to 9 silicon atoms, which generally have a viscosity less than or equal to 5.10 ^-6 m ² /s at 25°C, such as decamethyltetrasiloxane.

Other silicones falling into this class are described in the article published in Cosmetics and toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics"; we can cite the product marketed under the name "SH 200" by the company TORAY SILICONE.

Among the non-volatile silicones, mention may be made, alone or in mixture, of polydialkylsiloxanes and in particular polydimethylsiloxanes (PDMS or dimethicone), polydiarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, as well as non-amine organopolysiloxanes (or polysiloxanes). organomodified silicones, or even organomodified silicones) which are polysiloxanes comprising in their structure one or more non-amine organofunctional groups, generally fixed via a hydrocarbon group, and preferably chosen from aryl groups, alkoxy groups and groups polyoxyethylene and/or polyoxypropylenated.

The organomodified silicones may be polydiarylsiloxanes, in particular polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized with the organofunctional groups mentioned above. The polyalkylarylsiloxanes are particularly chosen from polydimethyl/methylphenylsiloxanes, linear and/or branched polydimethyl/diphenylsiloxanes.

Among the organomodified silicones, mention may be made of organopolysiloxanes comprising:

- polyoxyethylene and/or polyoxypropylene groups optionally comprising C ₆ -C ₂₄ alkyl groups such as dimethicone-copolyols, and in particular those marketed by the company DOW CORNING under the name DC 1248 or SILWET ^® L 722, L 7500 oils , L 77, L 711 of the company UNION CARBIDE; or alternatively alkyl(C ₁₂ )-methicone-copolyols, and in particular those marketed by the company DOW CORNING under the name Q2-5200;

- thiol groups, such as the products marketed under the names “GP 72 A” and “GP 71” from GENESEE;

- alkoxylated groups, such as the product sold under the name "SILICONE COPOLYMER F-755" by SWS SILICONES and ABIL WAX ^® 2428, 2434 and 2440 by the company GOLDSCHMIDT;

- hydroxyl groups, such as polyorganosiloxanes with a hydroxyalkyl function;

- acyloxyalkyl groups such as the polyorganosiloxanes described in patent US-A-4957732.

- anionic groups of the carboxylic acid type, as for example described in EP186507, or of the alkyl-carboxylic type such as the product X-22-3701E from the company SHIN-ETSU; or of the 2-hydroxyalkylsulfonate or 2-hydroxyalkylthiosulfate type, such as the products marketed by the company GOLDSCHMIDT under the names “ABIL ^® S201” and “ABIL ^® S255”.

The silicones can also be chosen from polydialkylsiloxanes, among which we can mainly cite polydimethylsiloxanes with trimethylsilyl terminal groups (CTFA: dimethicone). Among these polydialkylsiloxanes, the following commercial products can be cited:

- SILBIONE® oils of the 47 and 70 047 series or MIRASIL® oils marketed by RHODIA such as, for example, oil 70 047 V 500 000;

- oils from the MIRASIL® series marketed by the company RHODIA;

- 200 series oils from the company DOW CORNING such as DC200 having viscosity 60,000 mm ² /s;

- VISCASIL® oils from GENERAL ELECTRIC and certain oils from the SF series (SF 96, SF 18) from GENERAL ELECTRIC.

We can also cite polydimethylsiloxanes with terminal dimethylsilanol groups (CTFA: dimethiconol) such as the 48 series oils from the company RHODIA.

In this class of polydialkylsiloxanes, we can also cite the products marketed under the names "ABIL WAX® 9800 and 9801" by the company GOLDSCHMIDT which are polydialkyl (C1-C20) siloxanes.

Products which can be used more particularly in accordance with the invention are mixtures such as:

- mixtures formed from a polydimethylsiloxane hydroxylated at the end of the chain, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such as the product Q2-1401 marketed by the company DOW CORNING.

The polyalkylarylsiloxanes are particularly chosen from polydimethyl/methylphenylsiloxanes, linear and/or branched polydimethyl/diphenylsiloxanes with viscosities ranging from 1.10 ^-5 to 5.10 ^-2 m²/s at 25°C.

Among these polyalkylarylsiloxanes, we can cite the products marketed under the following names:

- SILBIONE® oils from the 70 641 series from RHODIA;

- RHODORSIL® 70 633 and 763 series oils from RHODIA;

- DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING;

- silicones from the PK series from BAYER such as the PK20 product;

- silicones from the PN, PH series from BAYER such as the PN1000 and PH1000 products;

- certain oils from the SF series from GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265.

The non-amine silicones more particularly preferred according to the invention are polydimethylsiloxanes with trimethylsilyl terminal groups (CTFA: dimethicone).

The composition according to the invention may comprise one or more amino silicones.

Amino silicone means any silicone comprising at least one primary, secondary, tertiary amine or a quaternary ammonium group.

The amino silicones which can be used according to the present invention can be volatile or non-volatile, cyclic, linear or branched, and preferably have a viscosity ranging from 5*10 ^-6 to 2.5 m ² /s at 25°C. , for example from 1*10 ^-5 to 1 m ² /s.

Preferably, the amino silicone(s) are chosen from, alone or in mixtures, the following compounds:

A) polysiloxanes corresponding to formula (I):

in which x' and y' are integers such that the weight average molecular mass (Mw) is between 5000 and 500000 g/mol;

B) amino silicones corresponding to formula (II):

R' _a G _3-a -Si(OSiG ₂ ) _n -(OSiG _b R' _2-b ) _m -O-SiG _3-a' -R'_a' (II)

in which :

- G, identical or different, denotes a hydrogen atom, a phenyl, OH, C ₁ -C ₈ alkyl group, for example methyl or C ₁ -C ₈ alkoxy, for example methoxy,
- a, a' identical or different, designate 0 or an integer from 1 to 3, in particular 0, provided that at least one of a or a' is equal to zero,

- b designates 0 or 1, in particular 1,

- m and n are numbers such that the sum (n + m) varies from 1 to 2000, in particular from 50 to 150, n can designate a number from 0 to 1999, and in particular from 49 to 149 and m can designate a number from 1 to 2000, and in particular from 1 to 10; And

- R', identical or different, designates a monovalent radical of formula -C _q H _2q L in which q is a number ranging from 2 to 8, and L is an amine group optionally quaternized chosen from the groups: -NR''- QN(R'') ₂ , -N(R'') ₂ , -N ⁺ (R'') ₃ A ^- , -N ⁺ H(R'') ₂ A ^- , -N ⁺ H ₂ (R'') A ^- , -NR''-QN ⁺ (R'')H ₂ A ^- , -NR''-QN ⁺ (R'') ₂ HA ^- and -NR''-QN ⁺ (R'') ₃ A ^- , in which R'', identical or different, denotes hydrogen, phenyl, benzyl, or a monovalent saturated hydrocarbon radical, for example a C ₁ -C ₂₀ alkyl radical; Q designates a group of formula C _r H _2r , linear or branched, r being an integer ranging from 2 to 6, preferably from 2 to 4; and A ^- represents a cosmetically acceptable anion, in particular a halide such as fluoride, chloride, bromide or iodide.

Preferably, the amino silicones of formula (II) can be chosen from:

(i) “trimethylsilylamodimethicone” silicones corresponding to formula (III):

in which m and n are numbers such that the sum (n + m) varies from 1 to 2000, preferably from 20 to 1000, in particular from 50 to 600, better still from 50 to 150; n can designate a number from 0 to 1999, and in particular from 49 to 149 and m can designate a number from 1 to 2000, and in particular from 1 to 10.

(ii) silicones of formula (IV) following:

in which :

- m and n are numbers such that the sum (n + m) varies from 1 to 1000, in particular from 50 to 250 and more particularly from 100 to 200; n designating a number from 0 to 999 and in particular from 49 to 249 and more particularly from 125 to 175 and m designating a number from 1 to 1000, in particular from 1 to 10, more particularly from 1 to 5; And

- R ₁ , R ₂ , R ₃ , identical or different, represent a hydroxy or C ₁ -C ₄ alkoxy radical, at least one of the radicals R ₁ to R ₃ designating an alkoxy radical.

Preferably the alkoxy radical is a methoxy radical.

The hydroxy/alkoxy molar ratio preferably ranges from 0.2:1 to 0.4:1 and preferably from 0.25:1 to 0.35:1 and more particularly is equal to 0.3:1.

The weight average molecular mass (Mw) of these silicones preferably ranges from 2000 to 1000000 g/mol, more particularly from 3500 to 200000 g/mol.

(iii) silicones of formula (V) following:

in which :

- p and q are numbers such that the sum (p + q) varies from 1 to 1000, in particular from 50 to 350, and more particularly from 150 to 250; p designating a number from 0 to 999 and in particular from 49 to 349 and more particularly from 159 to 239 and q designating a number from 1 to 1000, in particular from 1 to 10 and more particularly from 1 to 5; And

- R ₁ , R ₂ , different, represent a hydroxy or C ₁ -C ₄ alkoxy radical, at least one of the R ₁ or R ₂ radicals designating an alkoxy radical.

Preferably the alkoxy radical is a methoxy radical.

The hydroxy/alkoxy molar ratio generally ranges from 1:0.8 to 1:1.1 and preferably from 1:0.9 to 1:1 and more particularly is equal to 1:0.95.

The weight average molecular mass (Mw) of the silicone preferably ranges from 2000 to 200000 g/mol, more preferably from 5000 to 100000 g/mol and in particular from 10000 to 50000 g/mol.

Commercial products comprising silicones of structure (IV) or (V) may include in their composition one or more other amino silicones whose structure is different from formulas (IV) or (V). A product containing amine silicones of structure (IV) is offered by the company WACKER under the name BELSIL® ADM 652. A product containing amine silicones of structure (V) is offered by WACKER under the name Fluid WR 1300®. Another product containing structural amino silicones (XIV) is offered by WACKER under the name Belsil ADM LOG 1®.

When these amino silicones are used, a particularly interesting embodiment is their use in the form of an oil-in-water emulsion. The oil-in-water emulsion may include one or more surfactants. The surfactants can be of any nature but preferably cationic and/or non-ionic. The number average size of the silicone particles in the emulsion generally ranges from 3 nm to 500 nanometers. Preferably, in particular as amino silicones of formula (V), microemulsions are used whose average particle size ranges from 5 nm to 60 nm (limits included) and more particularly from 10 nm to 50 nm (limits included). Thus, according to the invention, it is possible to use the amino silicone microemulsions of formula (V) offered under the names FINISH CT 96 E® or SLM 28020® by the company WACKER.

(iv) silicones of the following formula (VI):

in which :

- m and n are numbers such that the sum (n + m) varies from 1 to 2000 and in particular from 50 to 150, n designating a number from 0 to 1999 and in particular from 49 to 149 and m designating a number from 1 to 2000, and in particular from 1 to 10; And

- A designates a linear or branched alkylene radical having from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably linear.

The weight average molecular mass (Mw) of these aminated silicones preferably ranges from 2000 to 1000000 g/mol and more particularly from 3500 to 200000 g/mol.
A silicone meeting this formula is for example XIAMETER MEM 8299 EMULSION from DOW CORNING.

(v) silicones of the following formula (VII):

in which :

- m and n are numbers such that the sum (n + m) varies from 1 to 2000 and in particular from 50 to 150, n can designate a number from 0 to 1999 and in particular from 49 to 149 and m can designate a number from 1 to 2000, and in particular from 1 to 10; And

- A designates a linear or branched alkylene radical having from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably branched.

The weight average molecular mass (Mw) of these aminated silicones preferably ranges from 500 to 1000000 g/mol and more particularly from 1000 to 200000 g/mol.
A silicone meeting this formula is for example DC2-8566 Amino Fluid from DOW CORNING.

C) amino silicones corresponding to formula (VIII):

in which :

- R ₅ represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C ₁ -C ₁₈ alkyl radical, or C ₂ -C ₁₈ alkenyl, for example methyl;

- R ₆ represents a divalent hydrocarbon radical, in particular a C ₁ -C ₁₈ alkylene radical or a divalent C ₁ -C ₁₈ alkyleneoxy radical, for example C ₁ -C ₈ linked to Si by an SiC bond;

- Q ^- is an anion such as a halide ion, in particular chloride or an organic acid salt, in particular acetate;

- r represents an average statistical value ranging from 2 to 20, in particular from 2 to 8;

And
- s represents an average statistical value ranging from 20 to 200, in particular from 20 to 50.

D) quaternary ammonium silicones of formula (IX)

in which :

- R ₇ , identical or different, represent a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C ₁ -C ₁₈ alkyl radical, a C ₂ -C ₁₈ alkenyl radical or a cycle comprising 5 or 6 carbon atoms, for example methyl;

- R ₆ represents a divalent hydrocarbon radical, in particular a C ₁ -C ₁₈ alkylene radical or a divalent C ₁ -C ₁₈ alkyleneoxy radical, for example C ₁ -C ₈ linked to Si by an SiC bond;

- R ₈ , identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C ₁ -C ₁₈ alkyl radical, a C ₂ -C ₁₈ alkenyl radical , a radical -R ₆ -NHCOR ₇ ;

- X ^- is an anion such as a halide ion, in particular chloride or an organic acid salt, in particular acetate; And

- r represents an average statistical value ranging from 2 to 200, in particular from 5 to 100.
These silicones are for example described in application EP-A-0530974; we can in particular cite the silicone with the INCI name: QUATERNIUM 80.

Silicones falling into this class are the silicones marketed by the company GOLDSCHMIDT under the names ABIL QUAT 3270, ABIL QUAT 3272, ABIL QUAT 3474.

E) amino silicones of formula (X):

in which :

- R ₁ , R ₂ , R ₃ and R ₄ , identical or different, designate a C ₁ -C ₄ alkyl radical or a phenyl group,

- R ₅ denotes a C ₁ -C ₄ alkyl radical or a hydroxyl group,

- n is an integer varying from 1 to 5,

- m is an integer varying from 1 to 5, and

- x is chosen such that the amine index varies from 0.01 to 1 meq/g;

F) multiblock polyoxyalkylenated amino silicones, of type (AB) _n , A being a polysiloxane block and B being a polyoxyalkylenated block comprising at least one amine group.

Said silicones are preferably made up of repeating units of the following general formulas:

[-(SiMe ₂ O) _x SiMe ₂ -RN(R'')-R'-O(C ₂ H ₄ O) _a (C ₃ H ₆ O) _b -R'-N(H)-R-] or

[-(SiMe ₂ O) _x SiMe ₂ -RN(R'')-R'-O(C ₂ H ₄ O) _a (C ₃ H ₆ O) _b -]
in which :

- a is an integer greater than or equal to 1, preferably ranging from 5 to 200, more particularly ranging from 10 to 100;

- b is an integer between 0 and 200, preferably ranging from 4 to 100, more particularly between 5 and 30;

- x is an integer ranging from 1 to 10000, more particularly from 10 to 5000;

- R’’ is a hydrogen atom or a methyl;

- R, identical or different, represent a divalent C ₂ -C ₁₂ hydrocarbon radical, linear or branched, optionally comprising one or more heteroatoms such as oxygen; preferably, R, identical or different, denote an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a CH ₂ CH ₂ CH ₂ OCH ₂ CH(OH)CH ₂ - radical; preferably R designate a radical CH ₂ CH ₂ CH ₂ OCH ₂ CH(OH)CH ₂ -; And

- R', identical or different, represent a divalent C ₂ -C ₁₂ hydrocarbon radical, linear or branched, optionally comprising one or more heteroatoms such as oxygen; preferably, R', identical or different, denote an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a CH ₂ CH ₂ CH ₂ OCH ₂ CH(OH)CH ₂ - radical; preferably R' designate -CH(CH ₃ )-CH ₂ -.

The siloxane blocks preferably represent 50 and 95% by moles of the total weight of the silicone, more particularly 70 to 85% by moles.

The amine level is preferably between 0.02 and 0.5 meq/g of copolymer in a 30% solution in dipropylene glycol, more particularly between 0.05 and 0.2.

The weight average molecular mass (Mw) of the silicone is preferably between 5000 and 1000000 g/mol, more particularly between 10000 and 200000 g/mol.
We can in particular cite the silicones marketed under the names Silsoft A-843 or Silsoft A+ by Momentive.

G) amino silicones of formulas (XI) and (XII):

in which :

- R, R' and R'', identical or different, denote a C ₁ -C ₄ alkyl group or a hydroxyl group,

- A denotes a C ₃ alkylene radical; And

- m and n are numbers such that the weight average molecular mass of the compound is between 5000 and 500000.

in which :

- x and y are numbers ranging from 1 to 5000; preferably x ranges from 10 to 2000, and more preferably from 100 to 1000; preferably it goes from 1 to 100;

- R ₁ and R ₂ , identical or different, preferably identical, designate an alkyl group, linear or branched, saturated or unsaturated, comprising from 6 to 30 carbon atoms, preferably from 8 to 24 carbon atoms, and more preferably from 12 to 20 carbon atoms; And

- A designates a linear or branched alkylene radical having 2 to 8 carbon atoms.

Preferably, A comprises 3 to 6 carbon atoms, more preferably 4 carbon atoms; preferably A is branched. We can cite in particular the following divalent groups: -CH ₂ CH ₂ CH ₂ - and -CH ₂ CH(CH ₃ )CH ₂ -.

Preferably, R ₁ and R ₂ are independent saturated linear alkyl groups comprising 6 to 30 carbon atoms, preferably 8 to 24 carbon atoms and in particular 12 to 20 carbon atoms; in particular the dodecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl and eicosyl groups may be mentioned; and preferably, R ₁ and R ₂ , identical or different, are chosen from the hexadecyl (cetyl) and octadecyl (stearyl) groups.

Preferably, in the silicone of formula (XII), we have:

- x ranging from 10 to 2,000, and in particular from 100 to 1,000;

- going from 1 to 100;

- A comprising from 3 to 6 carbon atoms and in particular 4 carbon atoms; preferably, A is branched; and more particularly, A is chosen from the following divalent groups: -CH ₂ CH ₂ CH ₂ and -CH ₂ CH(CH ₃ )CH ₂ -; And

- R ₁ and R ₂ being independently saturated linear alkyl groups comprising from 6 to 30 carbon atoms, preferably from 8 to 24 carbon atoms and in particular from 12 to 20 carbon atoms; chosen in particular from the groups dodecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl and eicosyl; preferably, R ₁ and R ₂ , identical or different, being chosen from the hexadecyl (cetyl) and octadecyl (stearyl) groups.

A preferred silicone of formula (XII) is bis-cetearylamodimethicone. We can cite in particular the amino silicone sold under the name SILSOFT AX by Momentive.

H) polysiloxanes and in particular polydimethylsiloxanes, comprising primary amine groups at a single chain end or on the side chains, such as those of formula (XIV), (XV) or (XVI):

In formula (XIV), the values of n and m are such that the weight average molecular mass of the aminated silicone is between 1000 and 55000.
As examples of amino silicones of formula (XIV), we can cite the products sold under the names AMS-132, AMS-152, AMS-162, AMS-163, AMS-191 and AMS-1203 by the company Gelest and KF-8015 by the Shin Etsu company.

In formula (XV), the value of n is such that the weight average molecular mass of the aminated silicone is between 500 and 3000.

As an example of amino silicones of formula (XV), we can cite the products sold under the names MCR-A11 and MCR-A12 by the company Gelest.

In formula (XVI), the values of n and m are such that the weight average molecular mass of the aminated silicone is between 500 and 50,000.

As examples of amino silicones of formula (XVI), we can cite aminopropyl phenyl trimethicone sold under the name DC 2-2078 Fluid by the company Dow Corning.

The cosmetic composition according to the invention may also comprise as silicone, an amino silicone corresponding to the formula (XVIII) below:

in which :

- n is a number between 1 and 1000, preferably between 10 and 500, better still between 25 and 100, even better between 50 and 80;

- m is a number between 1 and 200, preferably between 1 and 100, better still between 1 and 10 and even better between 1 and 5;

- R''', identical or different, preferably identical, are linear or branched, saturated or unsaturated alkyl radicals, comprising from 8 to 30 carbon atoms, preferably 10 to 24 carbon atoms, in particular 12 to 18 carbon atoms carbon; said radicals optionally being able to be substituted by one or more OH hydroxyl groups;

- R' is a linear or branched divalent alkylene radical, having from 1 to 6 carbon atoms, in particular from 2 to 5 carbon atoms;

- R'' is a linear or branched divalent alkylene radical, having from 1 to 6 carbon atoms, in particular from 1 to 5 carbon atoms.

Preferably, the R''', identical or different, are saturated linear alkyl radicals comprising 8 to 30 carbon atoms, preferably 10 to 24 carbon atoms, in particular 12 to 18 carbon atoms; we can in particular cite the dodecyl, C13, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl radicals; preferably the R''', identical or different, are chosen from saturated linear alkyl radicals having 12 to 16 carbon atoms, in particular C13, C14, C15, alone or in mixture, and better represent a mixture of C13, C14 and C15.

Preferably, the R''' are identical.

Preferably, R' is a divalent linear or branched alkylene radical, preferably branched, comprising 1 to 6 carbon atoms, in particular 2 to 5 carbon atoms; in particular a radical -CH2-CH2-CH2-, -CH2-CH(CH3)-CH2- or –CH2-CH2-CH(CH3)-.

Preferably, R'' is a divalent linear alkylene radical comprising 1 to 6 carbon atoms, in particular 1 to 4 carbon atoms; in particular a radical -CH2-CH2-.

Preferably, the composition may comprise one or more silicones of formula (XVIII) in which:

- n is a number between 50 and 80;

- m is a number between 1 and 5;

- R''', identical, are saturated linear alkyl radicals comprising from 12 to 18 carbon atoms;

- R’ is a divalent alkylene radical having 2 to 5 carbon atoms,

- R'' is a divalent linear alkylene radical having 1 to 4 carbon atoms.

Even better, the composition may comprise one or more silicones of formula (XVIII) in which:

- n is a number between 50 and 80;

- m is a number between 1 and 5;

- R''', identical, are saturated linear alkyl radicals comprising from 13 to 15 carbon atoms;

- R' is a radical –(CH ₂ ) ₃ -, -CH2-CH(CH3)-CH2- or –CH2-CH2-CH(CH3)-, and

- R'' is a radical –(CH ₂ ) ₂ -.

A particularly preferred silicone of formula (XVIII) is Bis(C13-15 alkoxy) PG Amodimethicone (INCI name). We can in particular cite the silicone marketed under the name “DOWSIL 8500 Conditioning agent” by DOW.

Preferably, the amino silicone(s) are chosen from, alone or in a mixture,

- amino silicones of formula (II), preferably those in which G denotes a C1-C8 alkyl and a=a’=0; a particularly preferred silicone of formula (II) being aminopropyldimethicone, such as that marketed under the name X-22-9686 by SHIN ETSU;

- quaternary ammonium silicones of formula (IX) above;

- amino silicones of formula (XVIII) above, in particular those in which n is a number between 50 and 80; m is a number between 1 and 5; R''', identical, are saturated linear alkyl radicals comprising 13 to 15 carbon atoms; R’ is a radical –(CH2)3-, -CH2-CH(CH3)-CH2- or –CH2-CH2-CH(CH3)-, and R’’ is a radical –(CH2)2-.

Advantageously, the composition according to the present invention may comprise the silicone(s) in a total content preferably ranging from 0.3 to 5% by weight, better still from 0.4 to 4% by weight, preferably from 0.6 to 3%. by weight, and more preferably from 0.7 to 2.5% by weight, relative to the total weight of the composition.

Advantageously, the composition according to the present invention may comprise the aminated silicone(s) in a total content preferably ranging from 0.3 to 5% by weight, better still from 0.4 to 4% by weight, preferably from 0.6 to 3% by weight. % by weight, and even better from 0.7 to 2.5% by weight, relative to the total weight of the composition.

Cationic surfactants

The composition used according to the invention may optionally comprise one or more cationic surfactants.

Said cationic surfactants are non-silicone, that is to say they do not contain a Si-O group.

They are preferably chosen from primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, or their salts, quaternary ammonium salts, and mixtures thereof.

The composition may comprise one or more cationic surfactants chosen from, alone or in a mixture, the following compounds which are quaternary ammonium salts:

- compounds corresponding to the following general formula (II):
(II)
in which :

^- _{_ _ _ _ _ _} ;

the groups R ₁ to R ₄ , which may be identical or different, represent an aliphatic group, linear or branched, comprising from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R ₁ to R ₄ designating an aliphatic group, linear or branched, comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms.

The aliphatic groups can include heteroatoms such as oxygen, nitrogen, sulfur and halogens. The aliphatic groups are for example chosen from C ₁ -C ₃₀ alkyl, C ₁ -C ₃₀ alkoxy, polyoxyalkylene (C ₂ -C ₆ ), C ₁ -C ₃₀ alkylamide, alkyl (C ₁₂ -C ₂₂ )amido(C ₂ -C ₆ )alkyl, (C ₁₂ -C ₂₂ )alkylacetate, and C ₁ -C ₃₀ hydroxyalkyl.

Among the quaternary ammonium salts of formula (II), tetraalkylammonium salts are preferred, such as dialkyldimethylammonium or alkyltrimethylammonium salts in which the alkyl group contains approximately 12 to 22 carbon atoms, in particular behenyltrimethylammonium salts, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium; as well as palmitylamidopropyltrimethylammonium salts, stearamidopropyltrimethylammonium salts, stearamidopropyldimethylcetearylammonium salts, or stearamidopropyldimethyl-(myristylacetate)-ammonium salts such as those marketed under the name CERAPHYL® 70 by the company VAN DYK.

It is particularly preferred to use the chloride, bromide or methyl sulfate salts of these compounds.

- quaternary ammonium salts of imidazoline, such as those of formula (III):
(III)
in which R ₅ represents an alkenyl or alkyl group comprising 8 to 30 carbon atoms, for example derived from tallow fatty acids, R ₆ represents a hydrogen atom, a C ₁ -C ₄ alkyl group or an alkenyl group or alkyl comprising from 8 to 30 carbon atoms, R ₇ represents a C ₁ -C ₄ alkyl group, R ₈ represents a hydrogen atom, a C ₁ -C ₄ alkyl group, X ^- is an anion chosen from the group of halides, phosphates, acetates, lactates, alkyl sulfates, alkyl- or alkylaryl sulfonates whose alkyl and aryl groups preferably comprise respectively from 1 to 20 carbon atoms and from 6 to 30 carbon atoms.

Preferably, R ₅ and R ₆ designate a mixture of alkenyl or alkyl groups comprising 12 to 21 carbon atoms, for example derived from tallow fatty acids, R ₇ designates a methyl group, R ₈ designates a hydrogen atom.

Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO.

- quaternary di- or tri-ammonium salts in particular of formula (IV):
(IV)
in which

R ₉ designates an alkyl radical comprising approximately 16 to 30 carbon atoms optionally hydroxylated and/or optionally interrupted by one or more oxygen atoms,

R ₁₀ is chosen from hydrogen or an alkyl radical containing 1 to 4 carbon atoms or a group (R _9a )(R _10a )(R _11a )N-(CH ₂ ) ₃ , with R _9a , R _10a , R _11a , R ₁₁ , R ₁₂ , R ₁₃ and R ₁₄ , identical or different, chosen from hydrogen or an alkyl radical containing 1 to 4 carbon atoms, and
^- _{_ _ _ _ _ _} in particular methyl sulfate and ethyl sulfate.

Such compounds are for example Finquat CT-P offered by the company FINETEX (Quaternium 89), Finquat CT offered by the company FINETEX (Quaternium 75).

- quaternary ammonium salts containing at least one ester function, such as those of formula (V) below:
(V)
in which :

R ₁₅ is chosen from C ₁ -C ₆ alkyl groups and C ₁ -C ₆ hydroxyalkyl or dihydroxyalkyl groups;

R ₁₆ is chosen from the group R19-C(O)-; the R ₂₀ groups which are C ₁ -C ₂₂ hydrocarbon groups, linear or branched, saturated or unsaturated, the hydrogen atom,

R ₁₈ is chosen from the group R21-C(O)-; the R ₂₂ groups which are C ₁ -C ₆ hydrocarbon groups, linear or branched, saturated or unsaturated; the hydrogen atom;

R ₁₇ , R ₁₉ and R ₂₁ , identical or different, are chosen from C ₇ -C ₂₁ hydrocarbon groups, linear or branched, saturated or unsaturated;

r, s and t, identical or different, are integers valued from 2 to 6;

y is an integer from 1 to 10;

x and z, identical or different, are integers ranging from 0 to 10;

X ^- is a simple or complex, organic or inorganic anion;

provided that the sum x + y + z is from 1 to 15, that when x is 0 then R ₁₆ designates R ₂₀ and that when z is 0 then R ₁₈ designates R ₂₂ .

The R ₁₅ alkyl groups can be linear or branched and more particularly linear. Preferably, R ₁₅ denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group.

Advantageously, the sum x + y + z is worth 1 to 10.

When R ₁₆ is a hydrocarbon R ₂₀ group, it can be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms.

When R ₁₈ is a hydrocarbon R ₂₂ group, it preferably has 1 to 3 carbon atoms.

Advantageously, R ₁₇ , R ₁₉ and R ₂₁ , identical or different, are chosen from C ₁₁ -C ₂₁ hydrocarbon groups, linear or branched, saturated or unsaturated, and more particularly from C ₁₁ -C alkyl and alkenyl groups. ₂₁ , linear or branched, saturated or unsaturated.

Preferably, x and z, identical or different, are 0 or 1.

Advantageously, y is equal to 1.

Preferably, r, s and t, identical or different, are worth 2 or 3, and even more particularly are equal to 2.

The anion X ^- is preferably a halide (chloride, bromide or iodide) or an alkyl sulfate, more particularly methyl sulfate. However, methanesulfonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function can be used. The anion X ^- is even more particularly chloride or methyl sulfate.

It is possible to use more particularly in the composition according to the invention, the ammonium salts of formula (V) in which R ₁₅ denotes a methyl or ethyl group, x and y are equal to 1; z is equal to 0 or 1; r, s and t are equal to 2;
R ₁₆ is chosen from the group R19-C(O)-, methyl, ethyl or C ₁₄ -C ₂₂ hydrocarbon groups, the hydrogen atom;
R ₁₈ is chosen from the group R21-C(O)- and the hydrogen atom;
R ₁₇ , R ₁₉ and R ₂₁ , identical or different, are chosen from C ₁₃ -C ₁₇ hydrocarbon groups, linear or branched, saturated or unsaturated, and preferably from C ₁₃ -C ₁₇ alkyl and alkenyl groups, linear or branched, saturated or unsaturated.

Advantageously, the hydrocarbon groups are linear.

Mention may be made, for example, of compounds of formula (V) such as the salts (notably chloride or methyl sulfate) of diacyloxyethyl-dimethylammonium, of diacyloxyethyl-hydroxyethyl-methyl-ammonium, of monoacyloxyethyl-dihydroxyethyl-methylammonium, of triacyloxyethylmethylammonium, of monoacyloxyethyl-hydroxyethyl -dimethylammonium and their mixtures. The acyl groups preferably have 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm or sunflower oil. When the compound contains several acyl groups, they may be the same or different.

These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on C ₁₀ -C ₃₀ fatty acids or on mixtures of C ₁₀ - fatty acids. C ₃₀ of plant or animal origin, or by transesterification of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide (preferably methyl or ethyl), a dialkyl sulfate (preferably methyl or ethyl), methyl, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin.

Such compounds are for example marketed under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.

The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts.

It is also possible to use the ammonium salts containing at least one ester function described in patents US-A-4874554 and US-A-4137180.

Behenoylhydroxypropyl-trimethylammonium chloride offered by KAO under the name Quatarmin BTC 131 can be used.

Preferably ammonium salts containing at least one ester function contain two ester functions.

Among the quaternary ammonium salts containing at least one usable ester function, it is preferred to use dipalmitoylethylhydroxyethyl-methylammonium salts.

The term “fatty amines” means a compound comprising at least one primary, secondary or tertiary amine function, optionally (poly)oxyalkylenated, or their salts and comprising at least one C ₆ -C ₃₀ hydrocarbon chain, preferably C ₈ -C ₃₀ .

Preferably, the fatty amines useful according to the invention are not (poly)oxyalkylenated.

As fatty amines, we can cite amidoamines. The amidoamines according to the invention can be chosen from fatty amidoamines, the fatty chain being able to be carried by the amine group or by the amido group.

Amidoamine means a compound comprising at least one amide function and at least one primary, secondary or tertiary amine function.

By fatty amidoamine is meant an amidoamine comprising, in general, at least one C ₆ -C ₃₀ hydrocarbon chain. Preferably, the fatty amidoamines useful according to the invention are not quaternized.

Preferably, the fatty amidoamines useful according to the invention are not (poly)oxyalkylenated.

Among the fatty amidoamines useful according to the invention, mention may be made of the following amidoamines of formula (VI): RCONHR’’N(R’)₂(VI)
in which :
-R represents a monovalent linear or branched hydrocarbon radical, saturated or unsaturated and substituted or unsubstituted, having from 5 to 29 carbon atoms, preferably from 7 to 23 carbon atoms, and in particular a C alkyl radical₅-VS₂₉, preferably in C₇-VS₂₃, linear or branched, or a C alkenyl radical₅-VS₂₉, preferably in C₇-VS₂₃linear or branched;
- R'' represents a divalent hydrocarbon radical having less than 6 carbon atoms, preferably 2 to 4 carbon atoms, better still, 3 carbon atoms; And
- R', identical or different, represent a monovalent hydrocarbon radical having less than 6 carbon atoms, preferably 1 to 4 carbon atoms, linear or branched, saturated or unsaturated and substituted or unsubstituted, preferably a methyl radical .

The fatty amidoamines of formula (VI) are, for example, chosen from oleamidopropyl dimethylamine, stearamidopropyl dimethylamine, in particular that marketed by the company INOLEX CHEMICAL COMPANY under the name LEXAMINE S13, isostearamidopropyl dimethylamine, stearamidoethyl dimethylamine, lauramidopropyl dimethylamine , myristamidopropyl dimethylamine, behenamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine, palmitamidopropyl dimethylamine, ricinoleamindopropyl dimethylamine, soyamidopropyl dimethylamine, avocadoamidopropyl dimethylamine, cocamidopropyl dimethylamine, minkamidopropyl dimethylamine, oatamidopropyl dimethylamine, sesamidopropyl dimethylamine, tallamidopropyl dimethyl amine , olivamidopropyl dimethylamine, palmitamidopropyl dimethylamine, stearamidoethyldiethylamine, brassicamidopropyl dimethylamine and mixtures thereof.

Preferably, the fatty amidoamines are chosen from oleamidopropyl dimethylamine, stearamidopropyl dimethylamine, brassicamidopropyl dimethylamine and mixtures thereof.

The cationic surfactant(s) are preferably chosen from those of formula (II) above, those of formula (V) above, those of formula (VI) above, and mixtures thereof; better among those of formula (II) above, those of formula (VI) above, and their mixtures; even better among those of formula (II) above.

Preferably, the cationic surfactant(s) may be chosen from salts such as chlorides, bromides or methosulphates, of tetraalkylammonium such as, for example, salts of dialkyldimethylammonium or alkyltrimethylammonium in which the alkyl group comprises approximately from 12 to 22 carbon atoms, in particular the salts of behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium; dipalmitoylethyl–hydroxyethylmethylammonium salts such as dipalmitoylethylhydroxyethyl–methylammonium methosulfate; and their mixtures.

Even more preferably, they are chosen from cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, dipalmitoylethylhydroxyethylmethylammonium methosulfate, and mixtures thereof.

When they are present, the total content of cationic surfactant(s) in the composition according to the invention preferably ranges from 0.1 to 10% by weight, in particular from 0.2 to 8% by weight, preferably from 0.3 to 7% by weight, better still from 0.5 to 5% by weight, relative to the total weight of the composition.

In a preferred embodiment of the invention, the weight ratio between the total content of cationic surfactant(s) and the total content of amino acid type compounds is greater than or equal to 1.

Cationic polymers

The composition used according to the invention may optionally comprise one or more cationic polymers, different from the associative polymers described above. This or these cationic polymers are therefore non-associative.

The term "cationic polymer" means any non-silicone polymer (not comprising a silicon atom) containing cationic groups and/or groups ionizable into cationic groups, and not containing anionic groups and/or groups ionizable into anionic groups.

The cationic polymers likely to be used preferably have a cationic charge density less than or equal to 5 milliequivalents/gram (meq/g), better still less than or equal to 4 meq/g.

The cationic charge density of a polymer corresponds to the number of moles of cationic charges per unit mass of polymer under conditions where it is completely ionized. It can be determined by calculation if we know the structure of the polymer, that is to say the structure of the monomers constituting the polymer and their molar or weight proportion. It can also be determined experimentally by the Kjeldahl method.

The cationic polymers capable of being used preferably have a weight average molar mass (Mw) of between approximately 500 and 5.10 ⁶ , preferably between approximately 10 ³ and 3.10 ⁶ .

The cationic polymers likely to be used are preferably non-associative.

Among the cationic polymers likely to be used, we can cite:

(1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formula:

in which:

- R3, identical or different, designate a hydrogen atom or a CH3 radical;

- A, identical or different, represent a divalent alkyl group, linear or branched, of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms;

- R4, R5, R6, identical or different, represent an alkyl group having 1 to 18 carbon atoms or a benzyl radical; preferably an alkyl group having 1 to 6 carbon atoms;

- R1 and R2, identical or different, represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, preferably methyl or ethyl;

- X designates an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide.

The copolymers of family (1) may also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1-C4) , acrylic or methacrylic acid esters, vinyl lactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.

Among these copolymers of family (1), we can cite:

- copolymers of acrylamide and dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company HERCULES,

- copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, such as those sold under the name BINA QUAT P 100 by the company CIBA GEIGY,

- the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, such as that sold under the name RETEN by the company HERCULES,

- vinylpyrrolidone/dialkylaminoalkyl acrylate or methacrylate copolymers, quaternized or not, such as products sold under the name "GAFQUAT" by the company ISP such as for example "GAFQUAT 734" or "GAFQUAT 755" or products called "COPOLYMER 845 , 958 and 937";

- dimethylaminoethyl methacrylate/vinylcaprolactam/vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP,

- vinylpyrrolidone/methacrylamidopropyldimethylamine copolymers, such as those marketed under the name STYLEZE CC 10 by ISP;

- quaternized vinylpyrrolidone/dimethylaminopropyl methacrylamide copolymers, such as the product sold under the name "GAFQUAT HS 100" by the company ISP,

- polymers, preferably crosslinked, of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts such as polymers obtained by homopolymerization of dimethylaminoethylmethacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethylmethacrylate quaternized with methyl chloride, the homo- or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylene bisacrylamide. It is more particularly possible to use a crosslinked acrylamide/methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name “SALCARE® SC 92” by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride comprising approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names “SALCARE® SC 95” and “SALCARE® SC 96” by the company CIBA.

(2) cationic polysaccharides, notably celluloses and cationic galactomannan gums.

Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers, cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.

Cellulose ether derivatives comprising quaternary ammonium groups are described in particular in FR1492597; they are also defined in the CTFA dictionary as quaternary ammonium hydroxyethylcellulose having reacted with an epoxide substituted with a trimethylammonium group.

We can in particular cite the polymers marketed under the name "UCARE POLYMER JR" (JR 400 LT, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by the AMERCHOL Company.

Cationic cellulose copolymers and cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described in particular in patent US4131576; we can cite hydroxyalkyl celluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyltrimethylammonium, methacrylamidopropyl trimethylammonium, or dimethyldiallylammonium. We can particularly cite quaternized hydroxyethyl celluloses, crosslinked or not, the quaternizing agent possibly being diallyldimethylammonium chloride; and particularly hydroxyethyl cellulose hydroxypropyltrimethylammonium

Among the commercial products meeting this definition, we can cite the products sold under the name "Celquat L 200" and "Celquat H 100" by the National Starch Company.

As a particularly preferred cationic cellulose, mention may in particular be made of the polymer with the INCI name POLYQUATERNIUM-10.

Cationic galactomannan gums are described in particular in patents US3589578 and US4031307; we can cite cationic guar gums, in particular those comprising cationic trialkylammonium groups, in particular trimethylammonium. We can thus cite guar gums modified with a salt (for example a chloride) of 2,3-epoxypropyl trimethylammonium.

Preferably, 2 to 30% by number of the hydroxyl functions of guar gums carry cationic trialkyammonium groups. Even more preferably, 5 to 20% of the number of hydroxyl functions of these guar gums are connected by cationic trialkyammonium groups. Among these trialkylammonium groups, mention may particularly be made of the trimethylammonium and triethylammonium groups. Even more preferably, these groups represent 5 to 20% by weight relative to the total weight of the modified guar gum. According to the invention, guar gums modified with 2,3-epoxypropyl trimethylammonium chloride can be used.

We can in particular cite the products with the INCI name “HYDRXYPROPYL GUAR HYDROXYPROPYLTRIMONIUM CHLORIDE” and “GUAR HYDROXYPROPYL-TRIMONIUM CHLORIDE”. Such products are marketed in particular under the names JAGUAR C13S, JAGUAR C15, JAGUAR C17 or JAGUAR C162 by the company Solvay.

Among the cationic polysaccharides likely to be used, we can also cite cationic derivatives of cassia gum, in particular those containing quaternary ammonium groups; in particular, we can cite the INCI name product “CASSIA HYDROXYPROPYLTRIMONIUM CHLORIDE”.

(3) polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene radicals with linear or branched chains, optionally interrupted by atoms of oxygen, sulfur, nitrogen or by aromatic or heterocyclic rings, as well as the products of oxidation and/or quaternization of these polymers.

(4) water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or even by an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, 'an epihalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mole per amine group of the polyaminoamide; these polyaminoamides can be alkylated or, if they contain one or more tertiary amine functions, quaternized.

(5) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with bifunctional agents. Mention may be made, for example, of adipic acid-diacoylaminohydroxyalkyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Among these derivatives, mention may be made more particularly of the adipic acid/dimethylaminohydroxypropyl/diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz.

(6) the polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio between the polyalkylene polyamine and the dicarboxylic acid preferably being between 0.8:1 and 1.4:1; the resulting polyaminoamide being reacted with the epichlorohydrin in a molar ratio of epichlorohydrin to the secondary amine group of the polyaminoamide preferably between 0.5:1 and 1.8:1. Polymers of this type are in particular marketed under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer. /epoxypropyl/diethylene-triamine.

(7) alkyl diallyl amine or dialkyl diallyl ammonium cyclopolymers such as homopolymers or copolymers comprising as main constituent of the chain units corresponding to formulas (I) or (II):

in which

- k and t are equal to 0 or 1, the sum k + t being equal to 1;

- R12 denotes a hydrogen atom or a methyl radical;

- R10 and R11, independently of each other, denote a C1-C6 alkyl group, a C1-C5 hydroxyalkyl group, a C1-C4 amidoalkyl group; or R10 and R11 can designate jointly with the nitrogen atom to which they are attached, a heterocyclic group such as piperidinyl or morpholinyl; R10 and R11, independently of each other, preferably denote a C1-C4 alkyl group;

- Y ^- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.

Mention may be made more particularly of the homopolymer of salts (for example chloride) of dimethyldiallylammonium (INCI name POLYQUATERNIUM-6), for example sold under the name "MERQUAT 100" by the company NALCO, and the copolymers of salts (for example chloride) of diallyldimethylammonium and acrylamide (INCI name POLYQUATERNIUM-7), marketed in particular under the name "MERQUAT 550" or "MERQUAT 7SPR".

(8) quaternary diammonium polymers comprising recurring units of formula:

in which :

- R13, R14, R15 and R16, identical or different, represent aliphatic, alicyclic, or arylaliphatic radicals comprising from 1 to 20 carbon atoms or C1-C12 hydroxyalkylaliphatic radicals,

or R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles possibly comprising a second heteroatom other than nitrogen

or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted by a nitrile, ester, acyl, amide or -CO-O-R17-D or -CO-NH-R17-D group where R17 is an alkylene and D is a quaternary ammonium group;

- A1 and B1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms, linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and

- X ^- denotes an anion derived from a mineral or organic acid;

it being understood that A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazin ring;

furthermore if A1 designates a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 can also designate a group (CH2)n-CO-D-OC-(CH2)p-, with n and p, identical or different, being integers varying from 2 to 20, and D designating:

a) a glycol residue of formula -O-Z-O-, where Z designates a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: -(CH2CH2O)x-CH2CH2- and -[CH2CH(CH3)O] y-CH2CH(CH3)- where x and y designate an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;

b) a bis-secondary diamine residue such as a piperazine derivative;

c) a bis-primary diamine residue of formula -NH-Y-NH- where Y designates a linear or branched hydrocarbon radical, or the divalent radical -CH2-CH2-S-S-CH2-CH2-;

d) a ureylene group of formula -NH-CO-NH-.

Preferably, X ^- is an anion such as chloride or bromide. These polymers have a number average molar mass (Mn) generally between 1000 and 100,000.

We can cite more particularly polymers which are made up of recurring units corresponding to the formula:

in which R1, R2, R3 and R4, identical or different, designate an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are integers varying from 2 to 20, and X- is an anion derived from 'a mineral or organic acid.

A particularly preferred compound of formula (IV) is that for which R1, R2, R3 and R4 represent a methyl radical, n=3, p=6 and X=Cl, called Hexadimethrine chloride according to the INCI (CTFA) nomenclature.

(9) quaternary polyammonium polymers comprising units of formula (V):

in which :

- R18, R19, R20 and R21, identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2(OCH2CH2)pOH radical, where p is equal to 0 or to an integer between 1 and 6, provided that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom,

- r and s, identical or different, are integers between 1 and 6,

- q is equal to 0 or an integer between 1 and 34,

- X- designates an anion such as a halide,

- A designates a divalent radical of a dihalide or preferably represents -CH2-CH2-O-CH2-CH2-.

We can for example cite the products "Mirapol® A 15", "Mirapol® AD1", "Mirapol® AZ1" and "Mirapol® 175" sold by the company Miranol.

(10) Quaternary polymers of vinylpyrrolidone and vinylimidazole such as, for example, the products marketed under the names Luviquat® FC 905, FC 550 and FC 370 by the company B.A.S.F.

(11) Polyamines such as Polyquart® H sold by COGNIS, referenced under the name "POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE" in the CTFA dictionary.

(12) polymers comprising in their structure:

(a) one or more reasons corresponding to the following formula (A):

(b) optionally one or more reasons corresponding to the following formula (B):

In other words, these polymers can be chosen in particular from homo- or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide.

Preferably, these cationic polymers are chosen from polymers comprising, in their structure, from 5 to 100 mol% of units corresponding to formula (A) and from 0 to 95 mol% of units corresponding to formula (B). , preferably from 10 to 100 mole % of units corresponding to formula (A) and from 0 to 90 mole % of units corresponding to formula (B).

These polymers can be obtained for example by partial hydrolysis of polyvinylformamide. This hydrolysis can take place in an acidic or basic environment.

The weight average molecular mass of said polymer, measured by light diffraction, can vary from 1000 to 3,000,000 g/mole, preferably from 10,000 to 1,000,000 and more particularly from 100,000 to 500,000 g/mole.

Polymers comprising units of formula (A) and possibly units of formula (B) are sold in particular under the name LUPAMIN by the company BASF, such as for example, and without limitation, the products offered under the name LUPAMIN 9095 , LUPAMIN 5095, LUPAMIN 1095, LUPAMIN 9030 (or LUVIQUAT 9030) and LUPAMIN 9010.

Preferably, the cationic polymers capable of being used in the context of the invention are chosen from, alone or in mixture, polymers of family (1) and cationic polysaccharides, in particular cationic celluloses such as POLYQUATERNIUM-10 ; cationic galactomannan gums, in particular cationic guar gums; as well as their mixtures.

When they are present, the composition according to the invention may comprise the cationic polymer(s) in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0. 1 to 2% by weight, relative to the total weight of the composition.

When they are present, the composition according to the invention may comprise the cationic polysaccharide(s) in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0. 1 to 2% by weight, relative to the total weight of the composition.

Nonionic polysaccharides

The composition used according to the invention may optionally comprise one or more nonionic polysaccharides, different from the associative polymers described above. This or these non-ionic polysaccharides are therefore non-associative.

The nonionic polysaccharides are preferably chosen from, alone or in mixture, celluloses, starches, galactomannans, and their nonionic derivatives, in particular their ethers or esters.

These polymers can be modified physically or chemically. As a physical treatment, we can cite temperature; and as chemical treatment, we can cite esterification, etherification, amidification and oxidation reactions, to the extent that these treatments lead to polymers which are non-ionic.

As galactomannans likely to be used, mention may be made of non-ionic guar gums which can be modified by C1-C6 (poly)hydroxylakyl groups, in particular hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups.

These guar gums are well known from the state of the art and can for example be prepared by reacting corresponding alkene oxides such as for example propylene oxides with guar gum so as to obtain a guar gum. modified by hydroxypropyl groups.

The hydroxyalkylation rate preferably varies from 0.4 to 1.2 and corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum.

Such non-ionic guar gums possibly modified by hydroxyalkyl groups are for example sold under the trade names JAGUAR HP8, JAGUAR HP60, JAGUAR HP120, Jaguar HP105 SGI and Jaguar HP8 SGI by the company RHODIA CHIMIE.

The starch molecules which can be used in the present invention may have cereals or even tubers as botanical origins. Thus, the starches are for example chosen from corn, rice, cassava, barley, potato, wheat, sorghum and pea starches. Starches can be modified chemically or physically: in particular by one or more of the following reactions: pregelatinization, oxidation, crosslinking, esterification, etherification, amidification, heat treatments.

Starch molecules can come from all plant sources of starch such as corn, potatoes, oats, rice, tapioca, sorghum, barley or wheat. The hydrolysates of the starches mentioned above can also be used. The starch preferably comes from potatoes.

Nonionic polysaccharides can also be cellulosic polymers not having a C10-C30 fatty chain in their structure.

By “cellulosic” polymer is meant according to the invention any polysaccharide compound having in its structure sequences of glucose residues united by β-1,4 bonds; the cellulose polymers may be unsubstituted celluloses, and/or derivatives of non-ionic celluloses.

Thus, the cellulose polymers which can be used according to the invention can be chosen from unsubstituted celluloses, including in a microcrystalline form, and cellulose ethers. Among these cellulose polymers, we distinguish cellulose ethers, cellulose esters and cellulose ester-ethers.

Among the non-ionic cellulose ethers, mention may be made of (C1-C4)alkylcelluloses such as methylcelluloses and ethylcelluloses (for example Ethocel standard 100 Premium from DOW CHEMICAL); (poly)hydroxy(C1-C4)alkylcelluloses such as hydroxymethylcelluloses, hydroxyethylcelluloses (for example Natrosol 250 HHR offered by AQUALON) and hydroxypropylcelluloses (for example Klucel EF from AQUALON); mixed celluloses (poly)hydroxy(C1-C4)alkyl-(C1-C4)alkylcelluloses such as hydroxypropyl-methylcelluloses (for example Methocel E4M from DOW CHEMICAL), hydroxyethyl-methylcelluloses, hydroxyethyl-ethylcelluloses (for example Bermocoll E 481 FQ from AKZO NOBEL) and hydroxybutyl-methylcelluloses.

Preferably, the nonionic polysaccharides are chosen from, alone or in mixture, celluloses, galactomannans, and their nonionic derivatives, in particular their ethers; and even better among, alone or in a mixture, non-ionic guar gums optionally modified by C1-C6 (poly)hydroxylakyl groups, in particular hydroxypropyl; and/or celluloses, substituted or not, and cellulose ethers such as (C1-C4)alkylcelluloses and (poly)hydroxy(C1-C4)alkylcelluloses.

Preferably, the nonionic polysaccharides are chosen from, alone or in mixture, nonionic guar gums optionally modified by (poly)hydroxylakyl groups at C1-C6, in particular hydroxypropyl (INCI name: HYDROXYPROPYL GUAR).

When they are present, the composition according to the invention may comprise the nonionic polysaccharide(s) in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0 .1 to 2% by weight, relative to the total weight of the composition.

When present, the composition according to the invention may comprise the nonionic polysaccharide(s) chosen from celluloses, galactomannans, and their nonionic derivatives, in particular their ethers, and their mixtures, in a total quantity ranging from 0, 01 to 10% by weight, better still 0.05 to 5% by weight, even better 0.1 to 2% by weight, relative to the total weight of the composition.

In a preferred embodiment, the composition according to the invention may comprise one or more cationic polymers and one or more nonionic polysaccharides; in particular one or more cationic polysaccharides and one or more nonionic polysaccharides; even better, one or more cationic polysaccharides chosen from cationic guar gums and cationic celluloses, and one or more non-ionic guar gums.

Nonionic surfactants

The composition used according to the invention may optionally comprise one or more nonionic surfactants.

As examples of nonionic surfactants, the following compounds can be cited, alone or in mixture:

- alkyl (C ₈ -C ₂₄ ) oxyalkylenated phenols;

- C ₈ to C ₄₀ alcohols, saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated, they preferably contain one or two fatty chains;

- C ₈ to C ₃₀ fatty acid amides, saturated or unsaturated, linear or branched, oxyalkylenated;

- esters of C ₈ to C ₃₀ acids, saturated or unsaturated, linear or branched, and of polyethylene glycols;

- esters of C ₈ to C ₃₀ acids, saturated or unsaturated, linear or branched, and of sorbitol, preferably oxyethylenated;

- esters of fatty acids and sucrose,

- alkyl (poly) glycosides optionally oxyalkylenated (0 to 10 oxyalkylenated units) and which may comprise 1 to 15 glucose units,

- oxyethylenated vegetable oils, saturated or not;

- ethylene oxide and/or propylene oxide condensates;

- N-alkyl(C ₈ -C ₃₀ )glucamine and N-acyl(C ₈ -C ₃₀ )-methylglucamine derivatives;

- amine oxides.

The oxyalkylenated units are more particularly oxyethylenated, oxypropylenated units, or their combination, preferably oxyethylenated.

The number of moles of ethylene and/or propylene oxide preferably ranges from 1 to 250, more particularly from 2 to 100; better from 2 to 50; the number of moles of glycerol ranges in particular from 1 to 50, better still from 1 to 10.

Advantageously, the nonionic surfactants according to the invention do not comprise oxypropylenated units.

Preferably, they comprise a number of moles of ethylene oxide ranging from 1 to 250, in particular from 2 to 100, better still from 2 to 50.

As examples of glycerolated nonionic surfactants, C ₈ to C ₄₀ alcohols, mono- or polyglycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol, are preferably used.

We can cite lauryl alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauryl alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL -4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI Name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, cetearyl alcohol with 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol.

Among the glycerol alcohols, it is more particularly preferred to use C ₈ to C ₁₀ alcohol to one mole of glycerol, C ₁₀ to C ₁₂ alcohol to one mole of glycerol and C ₁₂ alcohol to 1.5 mole of glycerol.

Non-ionic surfactants of the alkyl (poly) glycoside type can in particular be represented by the following general formula: R1O-(R2O)t-(G)v in which:

- R1 represents a linear or branched alkyl or alkenyl radical comprising 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms, or an alkylphenyl radical whose linear or branched alkyl radical comprises 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms;

- R2 represents an alkylene radical containing 2 to 4 carbon atoms,

- G represents a sugar unit comprising 5 to 6 carbon atoms,

- t designates a value ranging from 0 to 10, preferably from 0 to 4,

- v designates a value ranging from 1 to 15, preferably from 1 to 4.

Preferably, the alkyl (poly) glycoside surfactants are compounds of formula described above in which:

- R1 designates a saturated or unsaturated, linear or branched alkyl radical containing 8 to 18 carbon atoms,

- R2 represents an alkylene radical containing 2 to 4 carbon atoms,

- t designates a value ranging from 0 to 3, preferably equal to 0,

- G designates glucose, fructose or galactose, preferably glucose;

- the degree of polymerization, that is to say the value of v, which can range from 1 to 15, preferably from 1 to 4; the average degree of polymerization being more particularly between 1 and 2.

The glucosidic bonds between the sugar units are generally of type 1-6 or 1-4, preferably of type 1-4. Preferably, the alkyl(poly)glycoside surfactant is an alkyl(poly)glucoside surfactant. We particularly prefer C8/C16-(poly)glucosides 1,4, and in particular decylglucosides and caprylyl/capryl glucosides.

Among the commercial products, we can cite the products sold by the company COGNIS under the names PLANTAREN® (600 CS/U, 1200 and 2000) or PLANTACARE® (818, 1200 and 2000); the products sold by the company SEPPIC under the names ORAMIX CG 110 and ORAMIX® NS 10; the products sold by the company BASF under the name LUTENSOL GD 70 or the products sold by the company CHEM Y under the name AG10 LK.

Preferably, C8/C16-(poly)glycoside 1,4 alkyl are used, in particular in a 53% aqueous solution, such as those marketed by COGNIS under the reference PLANTACARE® 818 UP.

The nonionic surfactant(s) used in the composition according to the invention are preferably chosen from, alone or in mixture:

- C ₈ to C ₄₀ alcohols, saturated or not, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide ethylene; they preferably contain one or two fatty chains;

- oxyethylenated vegetable oils, saturated or not, comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50;

- alkyl (C ₈ -C ₃₀ )(poly) glycosides, optionally oxyalkylenated, preferably from 0 to 10 moles of ethylene oxide, and comprising 1 to 15 glucose units;

- C ₈ to C ₄₀ alcohols, mono- or polyglycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol;

- amides of C ₈ to C ₃₀ fatty acids, saturated or unsaturated, linear or branched, oxyalkylenated;

- esters of C ₈ to C ₃₀ acids, saturated or unsaturated, linear or branched, and of polyethylene glycols;

- esters of C ₈ to C ₃₀ acids, saturated or unsaturated, linear or branched, and of sorbitol, preferably oxyethylenated.

More preferably, the nonionic surfactant(s) used in the composition according to the invention are chosen from, alone or in a mixture,:

- C ₈ to C ₄₀ alcohols, saturated or not, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide ethylene and comprising one or two fatty chains, in particular at least one C8-C20 alkyl chain, in particular C10-C18;

- esters of C ₈ to C ₃₀ acids, saturated or unsaturated, linear or branched, and of sorbitol, preferably oxyethylenated, and

- alkyl (C ₈ -C ₃₀ )(poly)glucosides, optionally oxyalkylenated, preferably comprising from 0 to 10 moles of ethylene oxide, and comprising 1 to 15 glucose units.

Preferably, the composition according to the invention comprises the nonionic surfactant(s) in a total content ranging from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, preferably from 0.2 to 3 % by weight, relative to the total weight of the composition according to the invention.

Fat body

The composition used according to the invention may optionally comprise one or more non-silicone fatty substances, which may be chosen from solid fatty substances, liquid fatty substances, and mixtures thereof.

The term “non-silicone fatty substance” means a fatty substance not containing Si-O bonds.

Solid fatty substance means a fatty substance having a melting point greater than 25°C, preferably greater than or equal to 28°C, preferably greater than or equal to 30°C at atmospheric pressure (1,013.105 Pa).

Advantageously, the solid fatty substances which can be used in the present invention are neither (poly)oxyalkylenated nor (poly)glycerolated.

The solid fatty substances can be chosen from solid fatty acids, solid fatty alcohols, solid esters of fatty acids and/or fatty alcohols, waxes and ceramides, and mixtures thereof.

By “fatty acids” is meant a long-chain carboxylic acid comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms. The solid fatty acids according to the invention preferably comprise from 10 to 30 carbon atoms and better still from 14 to 22 carbon atoms. These fatty acids are neither oxyalkylenated nor glycerolated. The solid fatty acids which can be used in the present invention are in particular chosen from myristic acid, cetyl acid, stearyl acid, palmitic acid, stearic acid, lauric acid, behenic acid, and their mixtures. Said fatty acids are different from the hydroxylated (poly)carboxylic acids, comprising 2 to 8 carbon atoms previously described.

By “fatty alcohol” is meant a long-chain aliphatic alcohol comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms and comprising at least one OH hydroxyl group. These fatty alcohols are neither oxyalkylenated nor glycerolated. Solid fatty alcohols can be saturated or unsaturated, linear or branched, and contain from 8 to 40 carbon atoms, preferably from 10 to 30 carbon atoms, better still from 12 to 30 carbon atoms. Preferably, the solid fatty alcohols are of structure R-OH with R denoting a linear alkyl group, optionally substituted by one or more hydroxy groups, comprising from 8 to 40, preferably from 10 to 30 carbon atoms, better still from 12 to 30 , even from 12 to 24 atoms, even better from 14 to 22 carbon atoms. The solid fatty alcohols capable of being used are preferably chosen from saturated (mono)alcohols, linear or branched, preferably linear and saturated, comprising from 8 to 40 carbon atoms, better still from 10 to 30, or even from 12 to 24 atoms, even better 14 to 22 carbon atoms.

The solid fatty alcohols that can be used can be chosen from, alone or in a mixture:

- myristic or myristyl alcohol (or 1-tetradecanol);

- cetyl alcohol (or 1-hexadecanol);

- stearyl alcohol (or 1-octadecanol);

- arachidyl alcohol (or 1-eicosanol);

- behenyl alcohol (or 1-docosanol);

- lignoceryl alcohol (or 1-tetracosanol);

- cerylic alcohol (or 1-hexacosanol);

- montanylic alcohol (or 1-octacosanol);

- myricylic alcohol (or 1-triacontanol).

Preferably, the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol, behenyl alcohol, myristic alcohol, arachidyl alcohol and their mixtures, such as cetylstearyl or cetearyl alcohol. Particularly preferably, the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol or their mixtures such as cetylstearyl alcohol, preferably the solid fatty alcohol is cetylstearyl alcohol.

The solid esters of fatty acid and/or fatty alcohol that can be used are preferably chosen from esters derived from C9-C26 carboxylic fatty acid and/or C9-C26 fatty alcohol.

Preferably, these solid fatty esters are saturated, linear or branched carboxylic acid esters, comprising at least 10 carbon atoms, preferably 10 to 30 carbon atoms and more particularly 12 to 24 carbon atoms, and saturated monoalcohol, linear or branched, comprising at least 10 carbon atoms, preferably from 10 to 30 carbon atoms and more particularly from 12 to 24 carbon atoms. The saturated carboxylic acids can optionally be hydroxylated, and are preferably monocarboxylic acids.

Esters of C4-C22 di- or tricarboxylic acids and C1-C22 alcohols and esters of mono-, di- or tricarboxylic acids and di-, tri-, tetra-alcohols can also be used. or pentahydroxylated at C2-C26.

Mention may in particular be made of octyldodecyl behenate, isocetyl behenate, cetyl lactate, stearyl octanoate, octyl octanoate, cetyl octanoate, decyl oleate, stearyl stearate, hexyl, octyl stearate, myristyl stearate, cetyl stearate, stearyl stearate, octyl pelargonate, cetyl myristate, myristyl myristate, stearyl myristate, diethyl sebacate, diisopropyl sebacate, diisopropyl adipate, di n-propyl adipate, dioctyl adipate, dioctyl maleate, octyl palmitate, myristyl palmitate, cetyl palmitate, stearyl palmitate , and their mixtures.

Preferably, the solid fatty acid and/or fatty alcohol esters are chosen from C9-C26 alkyl palmitates, in particular myristyl, cetyl and stearyl palmitates; C9-C26 alkyl myristates such as cetyl myristate, stearyl myristate and myristyl myristate; C9-C26 alkyl stearates, in particular myristyl, cetyl and stearyl stearates; and their mixtures.

Particularly preferably, the solid fatty acid and/or fatty alcohol esters are chosen from myristyl stearate, myristyl palmitate, and mixtures thereof.

A wax, within the meaning of the present invention, is a lipophilic compound, solid at 25°C and atmospheric pressure, with a reversible solid/liquid state change, having a melting temperature greater than approximately 40°C and which can go up to at 200°C, and presenting an anisotropic crystalline organization in the solid state. Generally speaking, the size of the wax crystals is such that the crystals diffract and/or diffuse light, giving the composition which comprises them a more or less opaque cloudy appearance. By bringing the wax to its melting temperature, it is possible to make it miscible with oils and to form a homogeneous mixture microscopically, but by reducing the temperature of the mixture to room temperature, we obtain a recrystallization of the wax, detectable microscopically and macroscopically (opalescence).

In particular, the waxes suitable for the invention can be chosen from waxes of animal, vegetable, mineral origin, non-silicone synthetic waxes and their mixtures.

We can in particular cite hydrocarbon waxes, such as beeswax or modified beeswaxes (cerabellina), lanolin wax and lanolin derivatives, spermaceti; cork or sugar cane fiber waxes, olive tree wax, rice bran wax, Carnauba wax, Candellila wax, Ouricury wax, Alfa wax, pine wax Berry, Shellac wax, Japanese wax and sumac wax, flower absolute waxes; Montan wax, orange and lemon waxes, microcrystalline waxes, paraffins, petroleum jelly, lignite and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers, as well as their esters.

We can also cite microcrystalline waxes in C2 to C60, such as Microwax HW.

We can also cite polyethylene wax PM 500 marketed under the reference Permalen 50-L polyethylene.

We can also cite waxes obtained by catalytic hydrogenation of animal or vegetable oils having fatty chains, linear or branched, at C8 to C32. Among these, we can in particular cite isomerized jojoba oil, such as trans isomerized partially hydrogenated jojoba oil, in particular that manufactured or marketed by the company Desert Whale under the commercial reference Iso-Jojoba-50®, l hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil, hydrogenated lanolin oil, and di-(1,1,1-trimethylol propane) tetrastearate, in particular that sold under the name of Hest 2T-4S® by the HETERENE company.

We can also use waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, such as those sold under the names Phytowax ricin 16L64® and 22L73® by the company SOPHIM.

As a wax, it is also possible to use a C20 to C40 alkyl (hydroxystearyloxy) stearate (the alkyl group comprising 20 to 40 carbon atoms), alone or as a mixture. Such a wax is sold in particular under the names “Kester Wax K 82 P®”, “Hydroxypolyester K 82 P®” and “Kester Wax K 80 P®” by the company KOSTER KEUNEN.

It is also possible to use microwaxes in the compositions of the invention; we can cite in particular carnauba microwaxes, such as that marketed under the name MicroCare 350® by the company MICRO POWDERS, synthetic wax microwaxes, such as that marketed under the name MicroEase 114S® by the company MICRO POWDERS, microwaxes made a mixture of carnauba wax and polyethylene wax, such as those marketed under the names Micro Care 300® and 310® by the company MICRO POWDERS, microwaxes consisting of a mixture of carnauba wax and synthetic wax , such as that marketed under the name Micro Care 325® by the company MICRO POWDERS, polyethylene microwaxes, such as those marketed under the names Micropoly 200®, 220®, 220L® and 250S® by the company MICRO POWDERS and polytetrafluoroethylene microwaxes, such as those marketed under the names Microslip 519® and 519 L® by the company MICRO POWDERS.

The waxes are preferably chosen from mineral waxes such as paraffin, vaseline, lignite or ozokerite wax; vegetable waxes such as cocoa butter, shea butter or cork or sugar cane fiber waxes, olive tree wax, rice bran wax, hydrogenated jojoba wax, Ouricoury wax , Carnauba wax, Candelila wax, Alfa wax, or absolute flower waxes such as blackcurrant flower essential wax sold by the company BERTIN (France); waxes of animal origin such as beeswax or modified beewax (cerabellina), spermaceti, lanolin wax and lanolin derivatives; microcrystalline waxes; and their mixtures.

Ceramides or ceramide analogues such as glycoceramides, which can be used in the compositions according to the invention, are known; we can cite in particular the ceramides of classes I, II, III and V according to the DAWNING classification.

The ceramides or their analogues likely to be used preferably correspond to the following formula:

in which :

- R1 designates an alkyl group, linear or branched, saturated or unsaturated, derived from C14-C30 fatty acids, this group being able to be substituted by a hydroxyl group in the alpha position, or a hydroxyl group in the omega position esterified by a fatty acid saturated or unsaturated in C16-C30;

- R2 denotes a hydrogen atom, a (glycosyl)n group, a (galactosyl)m group or a sulfogalactosyl group, in which n is an integer varying from 1 to 4 and m is an integer varying from 1 to 8;

- R3 designates a C15-C26 hydrocarbon group, saturated or unsaturated in the alpha position, this group may be substituted by one or more C1-C14 alkyl groups;

it being understood that in the case of natural ceramides or glycoceramides, R3 can also designate a C15-C26 alpha-hydroxyalkyl group, the hydroxyl group optionally being esterified with a C16-C30 alpha-hydroxyacid.

Preferably, ceramides are used for which R1 designates a saturated or unsaturated alkyl group derived from C14-C30 fatty acids; R2 represents a galactosyl or sulfogalactosyl group; and R3 denotes a group -CH=CH-(CH2)12-CH3.

The more particularly preferred ceramides are the compounds for which R1 denotes a saturated or unsaturated alkyl derived from C16-C22 fatty acids; R2 denotes a hydrogen atom and R3 denotes a saturated or unsaturated C15 linear group.

It is also possible to use compounds for which R1 denotes a saturated or unsaturated alkyl radical derived from C12-C22 fatty acids; R2 designates a galactosyl or sulfogalactosyl radical and R3 designates a saturated or unsaturated C12-C22 hydrocarbon radical and preferably a -CH=CH-(CH2)12-CH3 group.

As particularly preferred compounds, mention may also be made of 2-N-linoleoylamino-octadecane-1,3-diol; 2-N-oleoylamino-octadecane-1,3-diol; 2-N-palmitoylamino-octadecane-1,3-diol; 2-N-stearoylamino-octadecane-1,3-diol; 2-N-behenoylamino-octadecane-1,3-diol; 2-N-[2-hydroxy-palmitoyl]-amino-octadecane-1,3-diol; 2-N-stearoyl amino-octadecane-1,3,4 triol and in particular N-stearoyl phytosphingosine, 2-N-palmitoylamino-hexadecane-1,3-diol, N-linoleoyldihydrosphingosine, N-oleoyldihydrosphingosine, N-palmitoyldihydrosphingosine, N-stearoyldihydrosphingosine, and N-behenoyldihydrosphingosine, N-docosanoyl N-methyl-D-glucamine, N-(2-hydroxyethyl)-N-(3-cetyloxy-2-hydroxypropyl)amide cetyl acid and bis-(N-hydroxyethyl N-cetyl) malonamide; and their mixtures. Preferably, N-oleoyldihydrosphingosine will be used.

As liquid fatty substances which may be used, mention may be made of liquid hydrocarbons, liquid fatty alcohols, liquid esters of fatty acids and/or fatty alcohols other than triglycerides, triglyceride type oils of vegetable origin or synthetic, mineral oils, and mixtures thereof.

Liquid fatty substances have a melting point less than or equal to 25°C, preferably less than or equal to 20°C, at atmospheric pressure (1,013.105 Pa). Advantageously, the liquid fatty substances are not (poly)oxyalkylenated.

It is recalled that alcohols, esters and fatty acids more particularly present at least one hydrocarbon group, linear or branched, saturated or unsaturated, comprising from 6 to 40, better still from 8 to 30 carbon atoms, optionally substituted, in particular by a or several hydroxyl groups (in particular 1 to 4). If they are unsaturated, these compounds can include one to three carbon-carbon double bonds, conjugated or not.

The liquid hydrocarbons can be C6 to C18, and be linear, branched, possibly cyclic; they are preferably chosen from C8-C16 alkanes, in particular C10-C14. By way of example, we can cite hexane, cyclohexane, undecane, dodecane, isododecane, tridecane, isoparaffins such as isohexadecane, isodecane, and their mixtures.

Liquid hydrocarbons can also be chosen from those comprising more than 16 carbon atoms, which can be linear or branched, of mineral or synthetic origin; we can cite paraffin or vaseline oils, polydecenes, hydrogenated polyisobutene such as Parléam®, and their mixtures.

The triglyceride oils of vegetable or synthetic origin can be chosen from liquid triglycerides of fatty acids comprising from 6 to 30 carbon atoms such as the triglycerides of heptanoic or octanoic acids or, for example, sunflower oils, corn oils, soy, squash, grape seeds, sesame, hazelnut, apricot, macadamia, arara, castor, avocado, triglycerides of caprylic/capric acids such as those sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil, and mixtures thereof.

The liquid fatty alcohols can be chosen from saturated or unsaturated, linear or branched, preferably unsaturated or branched alcohols comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms. Mention may be made, for example, of octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, isostearyl alcohol, oleic alcohol, linolenic alcohol, ricinoleic alcohol, undecylenic alcohol or linoleic alcohol, and mixtures thereof.

Liquid esters of fatty acids and/or fatty alcohols, different from the triglycerides mentioned above, include in particular esters of saturated or unsaturated aliphatic mono or polyacids, linear at C1 to C26 or branched at C3 to C26 and of mono or saturated or unsaturated aliphatic polyalcohols, linear at C1 to C26 or branched at C3 to C26, the total carbon number of the esters being greater than or equal to 6, more advantageously greater than or equal to 10.

Preferably, for monoalcohol esters, at least one of the alcohol or acid from which the esters of the invention are derived is branched.

Among the monoesters, we can cite dihydroabietyl behenate; octyldodecyl behenate; isocetyl behenate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; isostearyl octanoate; isocetyl octanoate; octyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; acetyl methyl ricinoleate; octyl isononanoate; 2-ethylhexyl isonate; octyldodecyl erucate; oleyl erucate; ethyl and isopropyl palmitates, such as ethyl-2-hexyl palmitate, 2-octyldecyl palmitate; alkyl myristates such as isopropyl, 2-octyldodecyl myristate; isobutyl stearate; 2-hexyldecyl laurate, and mixtures thereof.

Preferably among the monoesters of monoacids and monoalcohols, ethyl or isopropyl palmitate, alkyl myristates such as isopropyl or ethyl myristate, isocetyl stearate, isononanoate will be used. ethyl-2-hexyl, isodecyl neopentanoate, isostearyl neopentanoate, and mixtures thereof.

Still within the framework of this variant, esters of C4 to C22 di or tricarboxylic acids and C1 to C22 alcohols and esters of mono-, di-, or tricarboxylic acids and alcohols can also be used. di-, tri-, tetra- or pentahydroxy at C2 to C26.

We can in particular cite: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di n-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; polyethylene glycol distearates, and mixtures thereof.

The composition may also comprise, as fatty ester, sugar esters and diesters of C6 to C30 fatty acids, preferably C12 to C22. It is recalled that the term “sugar” means oxygenated hydrocarbon compounds which have several alcohol functions, with or without aldehyde or ketone functions, and which contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides.

As suitable sugars, mention may be made, for example, of sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and their derivatives. particularly alkylated, such as methylated derivatives such as methylglucose.

The esters of sugars and fatty acids may be chosen in particular from the group comprising the esters or mixtures of esters of sugars described above and of C6 to C30, preferably C12 to C22, linear or branched, saturated fatty acids. or unsaturated. If they are unsaturated, these compounds can include one to three carbon-carbon double bonds, conjugated or not.

The esters according to this variant can also be chosen from mono-, di-, tri- and tetra-esters, polyesters and mixtures thereof.

These esters can be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonate, or their mixtures such as in particular mixed oleo-palmitate, oleo-stearate, palmito-stearate esters.

More particularly, mono- and diesters are used and in particular mono- or di-oleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, of sucrose, glucose or methylglucose, and their mixtures.

As an example, we can cite the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.

Preferably, a liquid ester of monoacid and monoalcohol will be used.

Preferably, the fatty substances are chosen from triglyceride oils of vegetable or synthetic origin, liquid esters of fatty acids and/or fatty alcohols other than triglycerides, liquid C6-C18 hydrocarbons, solid fatty alcohols, solid esters of fatty acids and/or fatty alcohols, and mixtures thereof.

Preferably, the composition according to the invention may comprise the fatty substance(s) in a total quantity ranging from 0.1 to 20% by weight, better still from 1 to 18% by weight, preferably from 2 to 15% by weight, preferably another 5 to 12% by weight relative to the total weight of the composition.

Additional compounds

The composition used according to the invention advantageously comprises water, in particular at a concentration preferably ranging from 50 to 95% by weight, for example from 55 to 90% by weight, in particular from 60 to 85% by weight, better still from 65 to 85% by weight, relative to the total weight of the composition.

The pH of the composition can be between 2.5 and 8, preferably between 3 and 7, or even between 4 and 6.

The composition used according to the invention may optionally comprise one or more organic solvents, liquid at 25°C, 1 atm., preferably hydrophilic (soluble or miscible with water) which may be chosen from aliphatic C1-C6 monoalcohols. or aromatics, C2-C8 polyols, and C3-C7 polyol ethers. Advantageously, the organic solvent is chosen from C2-C4 mono-, di or tri-diols. It can advantageously be chosen from ethanol, isopropanol, benzyl alcohol, glycerol, propane 1,2-diol (propylene glycol) and their mixtures.

The composition used according to the invention may further comprise at least one or more usual cosmetic ingredients chosen in particular from thickeners, gelling agents, both different from the polymers described above; solar filters; anti-dandruff agents; antioxidant agents; chelating agents; reducing agents; oxidation bases, couplers, oxidizing agents, direct dyes; hair straightening agents; pearlescent and opacifying agents; micas, mother-of-pearl, glitter; plasticizing or coalescing agents; pigments; the charges; the perfumes; alkalizing or acidifying agents; silanes. Those skilled in the art will take care to choose the ingredients used in the composition, as well as their quantities, so that they do not harm the properties of the compositions of the present invention.

According to a preferred embodiment of the invention, the hair composition used in the process according to the invention may comprise:

- one or more compounds of the amino acid type corresponding to formula (I) as defined above, in which p=2 and R represents a hydrogen atom or a (C1-C4) alkyl group, linear or branched, saturated , optionally interrupted by an –S– heteroatom and/or optionally substituted by one or two groups chosen from hydroxyl, amino or –NH–C(NH)–NH2; better R represents a hydrogen atom;

preferably present in a total content of 0.5 to 10% by weight, in particular 0.7 to 8% by weight, better still 0.8 to 7% by weight, relative to the total weight of the composition;

- one or more hydroxylated (poly) carboxylic acids, comprising 4 to 6 carbon atoms, 1 to 3 OH groups and 2 or 3 COOH groups, and/or their salts, preferably present in a total content of 0.5 to 10% by weight, in particular from 1 to 8% by weight, better from 1.5 to 6% by weight,

- optionally one or more associative polymers, preferably non-ionic, better chosen from polyurethane polyethers;

preferably present in the composition in a total content ranging from 0.01 to 10% by weight, preferably 0.05 to 5% by weight, more preferably from 0.1 to 1.5% by weight relative to the total weight of the composition ;

- optionally one or more silicones, preferably chosen from amino silicones,

preferably present in a total content ranging from 0.3 to 5% by weight, better still from 0.4 to 4% by weight, preferably from 0.6 to 3% by weight, and more preferably from 0.7 to 2, 5% by weight, relative to the total weight of the composition;

- optionally one or more cationic surfactants preferably chosen from those of formula (II) above, those of formula (V) above, those of formula (VI) above, and their mixtures, preferably from those of formulas (II) and/or formula (VI) above;

preferably present in a total quantity ranging from 0.1 to 10% by weight, better still from 0.2 to 8% by weight, preferably from 0.3 to 7% by weight, better still from 0.5 to 5% by weight. weight relative to the total weight of the composition;

- optionally one or more cationic polysaccharides, in particular chosen from celluloses and/or cationic galactomannan gums; preferably present in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0.1 to 2% by weight, relative to the total weight of the composition;

- optionally one or more non-ionic polysaccharides, in particular chosen from alone or in mixture, non-ionic guar gums optionally modified by C1-C6 (poly)hydroxylakyl groups; preferably present in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0.1 to 2% by weight, relative to the total weight of the composition.

- optionally one or more nonionic surfactants; preferably present in a total content ranging from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, preferably from 0.2 to 3% by weight, relative to the total weight of the composition according to the invention.

The following examples serve to illustrate the invention without, however, being limiting in nature. All quantities are indicated, unless otherwise indicated, as a mass percentage of active ingredient (g% MA) relative to the total weight of the composition.

Example 1

The following compositions A according to the invention and A' comparative were prepared from the ingredients indicated in the tables below (g% MA):

Composition HAS HAS' CITRIC ACID 2.0 GLYCINE 1 BEHENTRIMONIUM CHLORIDE 3 3 HYDROXYPROPYL GUAR 0.15 0.15 AMINOPROPYL DIMETHICONE 0.4 0.4 BIS(C13-15 ALKOXY) PG-AMODIMETHICONE 0.3 0.3 PEG-150/DECYL ALCOHOL/SMDI COPOLYMER 0.15 0.15 BUTYROSPERMUM PARKII (SHEA) BUTTER 0.5 0.5 CETEARYL ALCOHOL 7 7 CETYL ESTERS 1.5 1.5 ISODODECANE 0.4 0.4 ISOPROPYL ALCOHOL 0.7 0.7 GLYCERIN 1 1 POLYQUATERNIUM-37 0.1 0.1 PROPYLENE GLYCOL 0.2 0.2 STEARETH-100 0.25 0.25 Conservatives Qs Qs Water Qsp 100% Qsp 100%

Composition A is in the form of a cream and can advantageously be used in rinse mode after or before shampooing. This composition can be used for detangling hair, providing care, shine and strength (a little less suppleness than classic body care treatments, and a massing effect).

Hair is soft, hydrated and shinier; they are considered stronger and less prone to breakage.

The composition therefore has strengthening properties and makes it possible to reduce the quantity of calcium contained in the hair fiber application after application.

Reinforcement is measured using the DSC technique.

(i) preparation of wicks

The measurements are carried out on strands previously bleached manually then treated five times (or ten times) according to the following protocol: the strand is washed with a neutral shampoo, then rinsed, 2 g of composition to be tested are applied per strand of hair 5.7g, leave the treatment on for 5 minutes then rinse again.

(ii) measurement method

The differential scanning calorimetry (DSC) technique is known to those skilled in the art as a method which makes it possible to quantify the reinforcement of proteins in the cortex of keratin fibers (Kinetics of the changes imparted to the main structural components of human hair by thermal treatment, F.-J. Wortmann and H. Deutz, J. Appl. Polym Sci., 48, 137 (1993). The principle of the test is to measure the denaturation temperature of proteins. It is widely recognized that the higher the protein denaturation temperature, the better the integrity of the cortex proteins, which reflects the reduction in fiber breakage.

The denaturation temperature is directly linked to the binding density of the keratin proteins present in the cortex. Thus, the lower the denaturation temperature, the lower the density of protein bonds between them, the disulfide bridges break and the cortex is damaged. A difference of 2°C is recognized by those skilled in the art as a significant modification.

The device used to carry out the measurements is a TA Instruments DSC Q20 reference device. This device measures the energy flow during heating of the sample. The temperature at which the energy flow is greatest represents the denaturation temperature.

(iii) results

The results of the measurements of the denaturation temperature (Td) of each of the wicks treated according to the protocol described above are summarized in the following table and correspond to the average of 3 measurements carried out per wick.

Td (°C) standard deviation Natural highlights (before bleaching treatment) 153.31 1.36 Untreated bleached strand 138.73 0.75 Discolored strand treated 5 times with composition A 155.80 0.17 Bleached strand treated 5 times with composition A’ 142.12 0.41 Bleached strand treated 10 times with composition A 162.55 0.34 Bleached strand treated 10 times with composition A’ 146.42 0.19

These results show that the use of the composition according to the invention increases the binding density of the keratin proteins present in the cortex of the treated hair, thus making it possible to repair damaged hair.

Furthermore, the denaturation temperature for the strands treated according to the present invention is better than that measured for natural and undamaged hair, thus showing that the hair is repaired.

This result is improved application after application.

Analysis of calcium by X-ray fluorescence using the RC-ANA-MET-1414 method.

These tests are carried out on strands previously bleached and then treated ten times according to the following protocol: the strand is washed with a neutral shampoo, then rinsed, 2g of composition to be tested is applied per 5.7g strand of hair, left apply the treatment for 5 minutes then rinse again.

We obtain the following results:

Calcium (concentration in ppm) Untreated bleached strand 16000 Bleached strand treated 10 times with composition A 6700 Bleached strand treated 10 times with composition A’ 13800

We therefore see that the calcium concentration decreases significantly for the locks treated with the invention.

Example 2

The composition according to the following invention was prepared from the ingredients indicated in the tables below (g% MA):

Composition B CITRIC ACID 3.0 GLYCINE 5 CETRIMONIUM CHLORIDE 0.5 QUATERNIUM-80 0.4 HYDROXYPROPYLTRIMONIUM HYDROLYZED WHEAT PROTEIN 1 GLYCERIN 15 PEG-40 HYDROGENATED CASTOR OIL 0.8 POLYSORBATE 20 0.8 POLYSORBATE 80 0.8 PROPYLENE GLYCOL 5 Conservatives Qs Water Qsp 100%

The composition is in the form of a lotion and can advantageously be used without rinsing before shampooing or after shampooing and before using a mask or conditioner without rinsing.

This composition can be used for detangling hair, providing care, shine and strength (body and mass effect).

Hair is soft, hydrated and shinier; they are considered stronger and less prone to breakage.

The composition therefore has strengthening properties and makes it possible to reduce the quantity of calcium contained in the hair fiber application after application.

The reinforcement is measured by DSC, according to the method described above.

The measurements are carried out on strands previously bleached manually then treated five (or ten) times according to the following protocol: the strand is washed with a conventional neutral shampoo, then rinsed, 2g of composition according to the invention is applied per strand of hair of 5.7g, then without rinsing we apply 2 g of a classic hair mask, we leave the mask on for 5 minutes then we rinse again.

This routine according to the invention is compared to the following comparative routine (without application of the composition of the invention): the strand is washed with a classic neutral shampoo, then it is rinsed, 2g of a classic hair mask is applied ( the same as in the routine according to the invention), we leave it on for 5 minutes then we rinse again.

The following results are obtained (average of 3 measurements per wick):

Td (°C) standard deviation Natural highlights (before bleaching treatment) 153.31 1.36 Untreated bleached strand 138.73 0.75 Bleached strand treated 5 times with the invention routine 159.7 1.40 Bleached strand treated 5 times with the comparative routine 140.8 0.32

These results show that the use of the composition according to the invention increases the binding density of the keratin proteins present in the cortex of the treated hair, thus making it possible to repair damaged hair.

Analysis of calcium by X-ray fluorescence using the RC-ANA-MET-1414 method.

These measurements are carried out on the locks treated according to the routine of the invention and according to the comparative routine described above.

We obtain the following results:

Calcium (concentration in ppm) Untreated bleached strand 10700 ± 1000 Bleached strand treated 5 times with the routine according to the invention 3974 ± 247 Bleached strand treated 5 times with the comparative routine 8542 ± 528 Bleached strand treated 10 times with the routine according to the invention 3127 ± 176 Bleached strand treated 10 times with the comparative routine 7896 ± 25

We therefore see that the calcium concentration decreases significantly for the locks treated according to the invention, application after application.

Claims (15)

Process for cosmetic treatment of hair, comprising at least two successive steps of applying a cosmetic composition comprising:
- one or more compounds of the amino acid type, present in a total content of at least 0.5% by weight relative to the total weight of the composition, and
- one or more hydroxylated (poly) carboxylic acids, comprising 2 to 8 carbon atoms, and/or their salts, present in a total content of at least 0.5% by weight relative to the total weight of the composition. Process according to the preceding claim, in which the compounds of the amino acid type are chosen from the compounds corresponding to formula (I) and/or their salts, in particular of alkali or alkaline earth metals, or of zinc:

in which p is an integer equal to 1 or 2, it being understood that:
- when p = 1, R forms with the nitrogen atom a saturated heterocycle comprising from 5 to 8 members, preferably 5 members, this cycle possibly being substituted by one or more groups chosen from hydroxyl or (C ₁ -C ₄ ) alkyl;
- when p = 2, R represents a hydrogen atom or a (C ₁ -C ₁₂ ) alkyl group, preferably (C ₁ -C ₄ ) alkyl, linear or branched, saturated, optionally interrupted by one or more heteroatoms or groups chosen from –S–, –NH– or –C(NH)– and/or optionally substituted by one or more groups chosen from hydroxyl (OH), amino (NH2), -SH, -COOH, -CONH2 or –NH –C(NH)–NH ₂ ;
preferably in which p = 2 and R represents a hydrogen atom or a (C1-C4) alkyl group, linear or branched, saturated, optionally interrupted by an –S– heteroatom and/or optionally substituted by one or two chosen groups among hydroxyl, amino or –NH–C(NH)–NH2; better p=2 and R represents a hydrogen atom. Process according to one of the preceding claims, in which the amino acid type compound(s) are chosen from glycine, proline, methionine, serine, arginine, lysine, their salts in particular of alkali or alkaline earth metals , or zinc, and their mixtures; preferentially chosen from glycine, its salts in particular of alkali or alkaline earth metals, or of zinc, and their mixtures. Process according to one of the preceding claims, in which the total content of compound(s) of amino acid type ranges from 0.5 to 10% by weight, in particular from 0.7 to 8% by weight, better still from 0.8 to 7% by weight relative to the total weight of the composition. Process according to one of the preceding claims, in which the composition comprises one or more hydroxylated (poly) carboxylic acids, comprising 4 to 6 carbon atoms, 1 to 3 OH groups and 2 to 3 COOH groups; and/or their salts, in particular of alkali metals, alkaline earth metals or zinc; preferably chosen from lactic, glycolic, tartaric or citric acids, and their salts in particular of alkali or alkaline earth metals; very particularly citric acid and/or tartaric acid as well as their salts, in particular of alkali or alkaline earth metals such as sodium citrate and/or sodium tartrate; even better citric acid or its salts, in particular of alkali or alkaline earth metals such as sodium citrate. Process according to one of the preceding claims, in which the total content of hydroxylated (poly) carboxylic acids comprising a total of 2 to 8 carbon atoms, and/or their salts, ranges from 0.5 to 10% by weight, in particular from 1 to 8% by weight, better still 1.5 to 6% by weight, relative to the total weight of the composition. Method according to one of the preceding claims, in which the composition comprises one or more associative polymers, preferably non-ionic, preferably chosen from polyurethane polyethers; in particular in a total content ranging from 0.01 to 10% by weight, preferably 0.05 to 5% by weight, more preferably from 0.1 to 1.5% by weight, relative to the total weight of the composition. Method according to one of the preceding claims, in which the composition comprises one or more silicones, preferably chosen from aminated silicones; in particular in a total content ranging from 0.3 to 5% by weight, better still from 0.5 to 4% by weight, preferably from 0.6 to 3% by weight, and more preferably from 0.7 to 2.5% by weight, relative to the total weight of the composition. Process according to one of the preceding claims, in which the composition comprises one or more cationic surfactants, in particular in a total quantity ranging from 0.1 to 10% by weight, better still from 0.2 to 8% by weight, preferably from 0 .3 to 7% by weight, better still 0.5 to 5% by weight relative to the total weight of the composition. Process according to one of the preceding claims, in which the composition comprises one or more cationic polymers, preferably chosen from cationic polysaccharides, in particular cationic celluloses, cationic galactomannan gums, in particular cationic guar gums; as well as their mixtures; in particular in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0.1 to 2% by weight, relative to the total weight of the composition. Process according to one of the preceding claims, in which the composition comprises one or more non-ionic polysaccharides, in particular chosen from, alone or in mixture, celluloses, galactomannans, and their non-ionic derivatives, in particular their ethers; better among, alone or in mixture, non-ionic guar gums optionally modified by (poly)hydroxylakyl groups at C1-C6, in particular hydroxypropyl and/or celluloses, substituted or not, and cellulose ethers such as (C1 -C4)alkylcelluloses and (poly)hydroxy(C1-C4)alkylcelluloses; preferably, chosen from, alone or as a mixture, non-ionic guar gums optionally modified by C1-C6 (poly)hydroxylakyl groups, in particular hydroxypropyl; preferably in a total quantity ranging from 0.01 to 10% by weight, better still from 0.05 to 5% by weight, even better from 0.1 to 2% by weight, relative to the total weight of the composition. Process according to one of the preceding claims, in which the composition comprises one or more nonionic surfactants, in particular in a total content ranging from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, preferably from 0.2 to 3% by weight, relative to the total weight of the composition according to the invention. Process according to one of the preceding claims, in which the composition comprises one or more non-silicone fatty substances, preferably chosen from triglyceride oils of vegetable or synthetic origin, liquid esters of fatty acid and/or fatty alcohol different from triglycerides, liquid C6-C18 hydrocarbons, solid fatty alcohols, solid esters of fatty acids and/or fatty alcohols, and mixtures thereof; in particular in a total quantity ranging from 0.1 to 20% by weight, better still from 1 to 18% by weight, preferably from 2 to 15% by weight, better still from 5 to 12% by weight relative to the total weight of the composition. Method according to one of the preceding claims, comprising a rinsing step, for example with water or with a shampoo, after a possible exposure time, between each successive application step of the composition. Method according to one of the preceding claims, for the hair treatment, in particular washing and/or conditioning, of sensitized, weakened and/or damaged hair, or hair loaded with metals at levels of at least 100 ppm, better by at least 200 ppm; in particular loaded with copper, in particular at contents of at least 100 ppm, better still at least 200 ppm and/or loaded with calcium, notably at contents of at least 4000 ppm, better still at least 10,000 ppm.