FR3131449B1 - Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode - Google Patents

Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode Download PDF

Info

Publication number
FR3131449B1
FR3131449B1 FR2114453A FR2114453A FR3131449B1 FR 3131449 B1 FR3131449 B1 FR 3131449B1 FR 2114453 A FR2114453 A FR 2114453A FR 2114453 A FR2114453 A FR 2114453A FR 3131449 B1 FR3131449 B1 FR 3131449B1
Authority
FR
France
Prior art keywords
electrode
porous
microbattery
manufacturing
porous electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2114453A
Other languages
English (en)
Other versions
FR3131449A1 (fr
Inventor
Fabien Gaben
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
I Ten SA
Original Assignee
I Ten SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2114453A priority Critical patent/FR3131449B1/fr
Application filed by I Ten SA filed Critical I Ten SA
Priority to PCT/IB2022/062522 priority patent/WO2023139429A1/fr
Priority to CA3242392A priority patent/CA3242392A1/fr
Priority to EP22839896.2A priority patent/EP4454030A1/fr
Priority to JP2024538219A priority patent/JP2025502735A/ja
Priority to KR1020247024458A priority patent/KR20240128033A/ko
Priority to IL313794A priority patent/IL313794A/en
Priority to TW111149163A priority patent/TW202339329A/zh
Publication of FR3131449A1 publication Critical patent/FR3131449A1/fr
Application granted granted Critical
Publication of FR3131449B1 publication Critical patent/FR3131449B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0409—Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0414—Methods of deposition of the material by screen printing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0421—Methods of deposition of the material involving vapour deposition
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/045—Electrochemical coating; Electrochemical impregnation
    • H01M4/0457—Electrochemical coating; Electrochemical impregnation from dispersions or suspensions; Electrophoresis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/13915—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne une électrode poreuse utilisable dans des batteries, telles qu’une une microbatterie à ions de lithium. Cette électrode poreuse comprend une couche poreuse d’au moins un matériau actif d’électrode P déposée sur un substrat, et un revêtement en matériau oxyde conducteur électronique présent sur et à l’intérieur des pores de ladite couche poreuse d’au moins un matériau actif d’électrode P.
FR2114453A 2021-12-23 2021-12-23 Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode Active FR3131449B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR2114453A FR3131449B1 (fr) 2021-12-23 2021-12-23 Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode
CA3242392A CA3242392A1 (fr) 2021-12-23 2022-12-20 Procede de fabrication d'une electrode poreuse, et batterie contenant une telle electrode
EP22839896.2A EP4454030A1 (fr) 2021-12-23 2022-12-20 Procede de fabrication d'une electrode poreuse, et batterie contenant une telle electrode
JP2024538219A JP2025502735A (ja) 2021-12-23 2022-12-20 多孔質電極およびこのような電極を含有する電池を製造する方法
PCT/IB2022/062522 WO2023139429A1 (fr) 2021-12-23 2022-12-20 Procede de fabrication d'une electrode poreuse, et batterie contenant une telle electrode
KR1020247024458A KR20240128033A (ko) 2021-12-23 2022-12-20 다공성 전극의 제조방법 및 이러한 전극을 포함하는 배터리
IL313794A IL313794A (en) 2021-12-23 2022-12-20 Method for manufacturing a porous electrode, and battery containing such an electrode
TW111149163A TW202339329A (zh) 2021-12-23 2022-12-21 多孔電極、包含該電極的電池、電子及電化學裝置、以及其製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2114453 2021-12-23
FR2114453A FR3131449B1 (fr) 2021-12-23 2021-12-23 Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode

Publications (2)

Publication Number Publication Date
FR3131449A1 FR3131449A1 (fr) 2023-06-30
FR3131449B1 true FR3131449B1 (fr) 2023-12-22

Family

ID=81325197

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2114453A Active FR3131449B1 (fr) 2021-12-23 2021-12-23 Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode

Country Status (1)

Country Link
FR (1) FR3131449B1 (fr)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3080862B1 (fr) * 2018-05-07 2022-12-30 I Ten Procede de fabrication d'anodes pour batteries a ions de lithium
FR3080957B1 (fr) 2018-05-07 2020-07-10 I-Ten Electrodes mesoporeuses pour dispositifs electrochimiques en couches minces
FR3109670B1 (fr) * 2020-04-28 2022-10-14 I Ten Procédé de fabrication d’un ensemble électrode poreuse et séparateur, un ensemble électrode poreuse et séparateur, et microbatterie contenant un tel ensemble
FR3109672B1 (fr) 2020-04-28 2022-10-14 I Ten Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode

Also Published As

Publication number Publication date
FR3131449A1 (fr) 2023-06-30

Similar Documents

Publication Publication Date Title
KR102570455B1 (ko) 보호된 음극을 갖는 전기 화학 전지
FR2885913A1 (fr) Element composite comprenant un substrat conducteur et un revetement metallique nanostructure.
FR3109670B1 (fr) Procédé de fabrication d’un ensemble électrode poreuse et séparateur, un ensemble électrode poreuse et séparateur, et microbatterie contenant un tel ensemble
FR3023418B1 (fr) Batterie entierement solide comprenant un electrolyte en materiau polymere solide reticule
WO2008015593A3 (fr) Source d'énergie électrochimique, dispositif électronique et procédé de fabrication d'une telle source d'énergie électrochimique
RU2012111663A (ru) Электрохромные устройства, блоки, содержащие электрохромные устройства, и/или способы их изготовления
JP2010509766A5 (fr)
FR3146761B1 (fr) Procede de fabrication de batteries, et batterie obtenue par ce procede
EP3183375B1 (fr) Métallisation pour un élément à couche mince, procédé pour sa fabrication et cible de pulvérisation
EP2975671B1 (fr) Structure de batterie à film mince et son procédé de fabrication
EP4014271A1 (fr) Unité d'électrode et cellule à flux redox
FR3131449B1 (fr) Procede de fabrication d’une electrode poreuse, et microbatterie contenant une telle electrode
FR3059157B1 (fr) Procede de fabrication d’une memoire resistive
JP2023532189A5 (fr)
FR3131450B1 (fr) Procede de fabrication d’une electrode poreuse, et batterie contenant une telle electrode
WO2008015619A3 (fr) Source d'énergie électrochimique et procédé de fabrication d'une telle source d'énergie électrochimique
WO2023019275A3 (fr) Anode prélithiée, batterie au lithium-ion la contenant et son procédé de production
MX2022015422A (es) Sensor de analitos y metodo para producir un sensor de analitos.
FR3096927B1 (fr) Film conducteur composite pour la réalisation d'accumulateurs d'énergie électrique, procédé de réalisation d'un tel film, et accumulateur électrique utilisant un tel film.
FR3082356B1 (fr) Procede de fabrication d'un module photovoltaique et module photovoltaique ainsi obtenu
KR20140127475A (ko) 전기화학센서용 기준전극 및 이를 포함하는 전기화학센서
FR3150644B1 (fr) Procede de fabrication d’une electrode poreuse, et batterie contenant une telle electrode
WO2022081545A8 (fr) Batterie à électrolyte solide contenant un séparateur d'électrolyte en vitrocéramique continu et cathode de batterie à électrolyte solide perforée et fritée
FR3060854B1 (fr) Procede de fabrication d'un module photovoltaique et module photovoltaique ainsi obtenu
CA3242814A1 (fr) Procede de fabrication d'electrode negative protegee et electrode negative ainsi produite

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20230630

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5