FR3129955B1 - Procédé d’électro-oxydation d’un composé furanique - Google Patents

Procédé d’électro-oxydation d’un composé furanique Download PDF

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Publication number
FR3129955B1
FR3129955B1 FR2112957A FR2112957A FR3129955B1 FR 3129955 B1 FR3129955 B1 FR 3129955B1 FR 2112957 A FR2112957 A FR 2112957A FR 2112957 A FR2112957 A FR 2112957A FR 3129955 B1 FR3129955 B1 FR 3129955B1
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France
Prior art keywords
furan compound
oxidation
electro
aminoxyl radical
content
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Active
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FR2112957A
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English (en)
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FR3129955A1 (fr
Inventor
Nhat Tam Vo
David Pasquier
Kim Larmier
Quentin Cacciuttolo
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR2112957A priority Critical patent/FR3129955B1/fr
Priority to PCT/EP2022/084120 priority patent/WO2023099689A1/fr
Publication of FR3129955A1 publication Critical patent/FR3129955A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/042—Electrodes formed of a single material
    • C25B11/048—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/087—Recycling of electrolyte to electrochemical cell
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/05—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

La présente invention concerne un procédé d’électro-oxydation d’un composé furanique dans un solvant organique ou hydro-organique en présence d’un catalyseur homogène comprenant un radical aminoxyl, - avec un ratio molaire initial r1 (F/A) de la teneur initiale en composé furanique sur la teneur en radical aminoxyl supérieur ou égal à 20, - ledit procédé étant opéré dans un dispositif d’électrolyse qui est compartimenté en un compartiment anodique (3) où s’opère l’oxydation du composé furanique et qui contient ledit composé furanique, ledit solvant et ledit radical aminoxyl, et un compartiment cathodique (8), lesdits compartiments étant séparés par une membrane échangeuse d’ions (2). Figure pour l’abrégé : Fig 1
FR2112957A 2021-12-03 2021-12-03 Procédé d’électro-oxydation d’un composé furanique Active FR3129955B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2112957A FR3129955B1 (fr) 2021-12-03 2021-12-03 Procédé d’électro-oxydation d’un composé furanique
PCT/EP2022/084120 WO2023099689A1 (fr) 2021-12-03 2022-12-01 Procédé d'électro-oxydation d'un composé furanique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2112957A FR3129955B1 (fr) 2021-12-03 2021-12-03 Procédé d’électro-oxydation d’un composé furanique
FR2112957 2021-12-03

Publications (2)

Publication Number Publication Date
FR3129955A1 FR3129955A1 (fr) 2023-06-09
FR3129955B1 true FR3129955B1 (fr) 2023-11-17

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Family Applications (1)

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FR2112957A Active FR3129955B1 (fr) 2021-12-03 2021-12-03 Procédé d’électro-oxydation d’un composé furanique

Country Status (2)

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FR (1) FR3129955B1 (fr)
WO (1) WO2023099689A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117248225A (zh) * 2023-09-14 2023-12-19 浙江大学 酸碱不平衡耦联糠醛氧化双极电解制氢的装置及方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2669634B1 (fr) 1990-11-22 1994-06-10 Furchim Procede de fabrication d'acide 2-5-furane dicarboxylique.
WO2015197699A1 (fr) 2014-06-25 2015-12-30 Basf Se Procédé de préparation d'acide furane-2,5-dicarboxylique
US9598780B2 (en) 2015-01-08 2017-03-21 Wisconsin Alumni Research Foundation Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran
ES2781329T3 (es) 2015-07-22 2020-09-01 Basf Se Procedimiento para preparar ácido furan-2,5-dicarboxílico

Also Published As

Publication number Publication date
FR3129955A1 (fr) 2023-06-09
WO2023099689A1 (fr) 2023-06-08

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