FR3124702A1 - Composition comprising propane-1,3-diol and at least one fatty substance and one or more alkaline agents and/or one or more colorants. - Google Patents

Abstract

The subject of the present invention is a cosmetic composition for the treatment of keratin fibres, in particular human keratin fibers such as the hair, comprising propane-1,3-diol, at least one fatty substance other than fatty acids in a content such as defined below, and one or more alkaline agents and/or one or more dyes. The present invention also relates to a process for dyeing and/or lightening keratin fibres, such as the hair, in which the composition as described above is applied to said fibres. The present invention also relates to a process for dyeing keratin fibres, such as the hair, in which the composition as described above, and comprising at least one dye, preferably chosen from oxidation dyes, direct dyes and their mixtures, is applied to said fibers. A subject of the present invention is also the use of the composition according to the invention for coloring and/or lightening, preferably coloring keratin fibers such as the hair.

Description

Composition comprising propane-1,3-diol and at least one fatty substance and one or more alkaline agents and/or one or more colorants.

The subject of the present invention is a cosmetic composition for the treatment of keratin fibres, in particular human keratin fibers such as the hair, comprising propane-1,3-diol, at least one fatty substance other than fatty acids in a content such as defined below, and one or more alkaline agents and/or one or more dyes.

The present invention also relates to a process for dyeing and/or lightening keratin fibres, such as the hair, in which the composition as described above is applied to said fibres.

In particular, the present invention also relates to a process for dyeing keratin fibres, such as the hair, in which the composition as described previously, and comprising at least one dye, preferably chosen from oxidation dyes, dyes direct and mixtures thereof, is applied to said fibers.

A subject of the present invention is also the use of the composition according to the invention for coloring and/or lightening, preferably coloring keratin fibers such as the hair.

In processes for dyeing keratin fibres, it is known to dye keratin fibers by various techniques using direct dyes for non-permanent dyes or oxidation dye precursors for permanent dyes.

Non-permanent coloring or direct coloring consists in dyeing the keratin fibers with dye compositions containing direct dyes. These dyes are colored and coloring molecules with an affinity for keratin fibres. They are applied to the keratin fibers for the time necessary to obtain the desired coloration, then rinsed off.

Some of these dyes can be used under lightening conditions, which makes it possible to obtain visible colorations on dark hair.

It is also known to dye keratin fibers permanently by oxidation dyeing. This coloring technique consists in applying to the keratin fibers a composition containing dye precursors such as oxidation bases and couplers. These precursors under the action of an oxidizing agent will form one or more colored species in the hair.

The performance of coloring and/or lightening compositions may not be entirely satisfactory in terms of dyeing properties such as power, chromaticity, selectivity or tenacity with respect to external agents such as light, perspiration, washes or rubs, or in terms of level of lightening.

Thus, there is a real need to provide a composition for coloring and/or lightening keratin fibres, in particular human keratin fibers such as the hair, and which does not have the drawbacks mentioned above, that is that is to say which is capable of leading to good performance, in particular in terms of color build-up, power and chromaticity when it comprises one or more dyes, while having low selectivity and good tenacity, or in terms lightening agent and which is capable of leading to good dyeing and/or lightening performance, even after a storage period, and good cosmetic properties, while having good qualities for use.

The subject of the present invention is therefore a composition comprising:
- one or more fatty substances different from the fatty acids present in a content greater than or equal to 20% by weight, preferably greater than or equal to 30% by weight, and more preferably greater than or equal to 40% by weight, relative to the weight composition total,
- propane-1,3-diol,
- one or more alkaline agents and/or one or more dyes.

The composition according to the invention makes it possible to achieve the above objectives, in particular in terms of increase in color, power of the coloring, chromaticity, selectivity, tenacity and/or lightening and qualities of use. .

The composition according to the invention also makes it possible to obtain powerful colorations and to lead to good cosmeticity, in particular in terms of shine, suppleness, a more natural touch, a smoother touch, comfort and while preserving the integrity fiber.

Furthermore, the composition according to the invention has good stability, in particular on storage. The composition may in particular comprise dyes and/or other compounds in the form of salts.

When the composition according to the invention is mixed with an oxidizing composition, the mixing is easy and rapid.

The ready-to-use composition has a texture allowing easy distribution on the hair.

The present invention also relates to a process for dyeing and/or lightening keratin fibres, in particular human keratin fibers such as the hair, in which is applied to said fibers a composition comprising:
- one or more fatty substances different from the fatty acids present in a content greater than or equal to 20% by weight, preferably greater than or equal to 30% by weight, and more preferably greater than or equal to 40% by weight, relative to the weight composition total,
- propane-1,3-diol,
- one or more alkaline agents and/or one or more dyes.

In particular, the present invention also relates to a process for dyeing keratin fibres, in particular human keratin fibers such as the hair, in which is applied to said fibers a composition comprising:
- one or more fatty substances different from the fatty acids present in a content greater than or equal to 20% by weight, preferably greater than or equal to 30% by weight, and more preferably greater than or equal to 40% by weight, relative to the weight composition total,
- propane-1,3-diol,
- one or more dyes,
- optionally one or more alkaline agents.

The present invention also relates to the use of the composition according to the invention for coloring and/or lightening, preferably coloring keratin fibres, in particular human keratin fibers such as the hair.

Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the example which follow.

In what follows, and unless otherwise indicated, the limits of a range of values are included in this range, in particular in the expressions “included between” and “ranging from … to …”.
Furthermore, the expression “at least one” used in the present description is equivalent to the expression “one or more”.

Fatty substances different from fatty acids
The composition according to the invention comprises one or more fatty substances in a total content greater than or equal to 20% by weight relative to the total weight of the composition.

The useful fatty substances according to the invention can be liquid fatty substances (or oils) and/or solid fatty substances. The term "liquid fatty substance" means a fatty substance having a melting point less than or equal to 25° C. and at atmospheric pressure (1.013.10 ⁵ Pa). The term “solid fatty substance” means a fatty substance having a melting point above 25° C. at atmospheric pressure (1.013.10 ⁵ Pa).

Within the meaning of the present invention, the melting point corresponds to the temperature of the most endothermic peak observed in thermal analysis (differential scanning calorimetry or DSC) as described in standard ISO 11357-3; 1999. The melting point can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name “MDSC 2920” by the company TA Instruments. In the present application, all the melting points are determined at atmospheric pressure (1.013.10 ⁵ Pa).

The term “fatty substance” is understood to mean an organic compound that is insoluble in water at 25° C. and at atmospheric pressure (1.013.10 ⁵ Pa) (solubility less than 5% by weight, and preferably less than 1% by weight, even more preferably less than 0.1% by weight). They have in their structure at least one hydrocarbon chain comprising at least 6 carbon atoms and/or a sequence of at least two siloxane groups. In addition, fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, such as chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran ( THF), vaseline oil or decamethylcyclopentasiloxane.

The fatty substances that can be used in the present invention are neither (poly)oxyalkylenated nor (poly)glycerolated.

Preferably, the fatty substances useful according to the invention are non-silicone.

“Non-silicone fatty substance” means a fatty substance containing no Si—O bonds and “silicone fatty substance” means a fatty substance containing at least one Si—O bond.

More particularly, the liquid fatty substance(s) according to the invention can be chosen from liquid C ₆ to C ₁₆ hydrocarbons, liquid hydrocarbons comprising more than 16 carbon atoms, non-silicone oils of animal origin, oils of triglyceride type of plant or synthetic origin, fluorinated oils, liquid fatty alcohols, liquid fatty acid and/or fatty alcohol esters other than triglycerides, silicone oils, and mixtures thereof.

It is recalled that the alcohols, esters and fatty acids have more particularly at least one hydrocarbon group, linear or branched, saturated or unsaturated, comprising from 6 to 40, better still from 8 to 30 carbon atoms, optionally substituted, in particular by a or more hydroxyl groups (in particular 1 to 4). If they are unsaturated, these compounds can comprise one to three carbon-carbon double bonds, conjugated or not.

As regards the C ₆ to C ₁₆ liquid hydrocarbons, the latter can be linear, branched, optionally cyclic, and are preferably chosen from alkanes. By way of example, mention may be made of hexane, cyclohexane, undecane, dodecane, isododecane, tridecane, isoparaffins such as isohexadecane, isodecane, and mixtures thereof.

The liquid hydrocarbons comprising more than 16 carbon atoms can be linear or branched, of mineral or synthetic origin, and are preferably chosen from paraffin or petroleum jelly oils, polydecenes, hydrogenated polyisobutene such as Parléam®, and their mixtures.

As hydrocarbon oils of animal origin, mention may be made of perhydrosqualene.

The triglyceride oils of plant or synthetic origin are preferably chosen from liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, such as triglycerides of heptanoic or octanoic acids or else, for example, sunflower, corn, soy, pumpkin, grapeseed, sesame, hazelnut, apricot, macadamia, arara, sunflower, castor, avocado, triglycerides of caprylic/capric acids such as those sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil, and mixtures thereof.

As regards the fluorinated oils, these may be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names “FLUTEC® PC1” and “FLUTEC® PC3” by the company BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names “PF 5050®” and “PF 5060®” by the company 3M, or else bromoperfluorooctyl sold under the name “FORALKYL®” by the company Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name “PF 5052®” by the company 3M.

The liquid fatty alcohols suitable for the implementation of the invention are more particularly chosen from saturated or unsaturated, linear or branched, preferably unsaturated or branched alcohols comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms. of carbon. These fatty alcohols are neither oxyalkylenated nor glycerolated. Mention may be made, for example, of octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, isostearyl alcohol, oleic alcohol, linolenic alcohol, ricinoleic alcohol, undecylenic alcohol or linoleic alcohol, and mixtures thereof.

As regards the liquid fatty acid and/or fatty alcohol esters, different from the triglycerides mentioned above, mention may be made in particular of the esters of saturated or unsaturated aliphatic mono or polyacids, linear in C ₁ to C ₂₆ or branched in C ₃ to C ₂₆ and saturated or unsaturated aliphatic mono or polyalcohols, linear C ₁ to C ₂₆ or branched C ₃ to C ₂₆ , the total carbon number of the esters being greater than or equal to 6, more advantageously greater than or equal at 10.

Preferably, for monoalcohol esters, at least one of the alcohol or acid is branched.

Among the monoesters, mention may be made of dihydroabietyl behenate; octyldodecyl behenate; isocetyl behenate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; isostearyl octanoate; isocetyl octanoate; octyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methyl acetyl ricinoleate; octyl isononanoate; 2-ethylhexyl isononate; octyldodecyl erucate; oleyl erucate; ethyl and isopropyl palmitates, such as ethyl-2-hexyl palmitate, 2-octyldecyl palmitate; alkyl myristates such as isopropyl myristate; isobutyl stearate; 2-hexyldecyl laurate, and mixtures thereof.

Preferably, among the monoesters of monoacids and monoalcohols, use will be made of ethyl and isopropyl palmitates, alkyl myristates such as isopropyl or ethyl myristate, isocetyl stearate, isononanoate of ethyl-2-hexyl, isodecyl neopentanoate, isostearyl neopentanoate, and mixtures thereof.

It is also possible to use esters of C ₄ to C ₂₂ di or tricarboxylic acids and C ₁ to C ₂₂ alcohols and esters of mono-, di-, or tricarboxylic acids and di-, tri-alcohols. -, tetra- or pentahydroxy C ₂ to C ₂₆ .

Mention may in particular be made of: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di n-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; polyethylene glycol distearates, and mixtures thereof.

The composition may also comprise, as fatty ester, esters and di-esters of sugars of C ₆ to C ₃₀ , preferably C ₁₂ to C ₂₂ , fatty acids. It is recalled that the term “sugar” is understood to mean oxygenated hydrocarbon compounds which have several alcohol functions, with or without an aldehyde or ketone function, and which contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides other than anionic polysaccharides as described below.

Suitable sugars include, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and derivatives thereof. in particular alkylated, such as methylated derivatives such as methylglucose.

The esters of sugars and of fatty acids can be chosen in particular from the group comprising the esters or mixtures of esters of sugars described previously and fatty acids C ₆ to C ₃₀ , preferably C ₁₂ to C ₂₂ , linear or branched, saturated or unsaturated. If they are unsaturated, these compounds can comprise one to three carbon-carbon double bonds, conjugated or not.

The esters can also be chosen from mono-, di-, tri- and tetra-esters, polyesters and mixtures thereof.

These esters can be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonate, or their mixtures such as in particular the mixed oleo-palmitate, oleo-stearate, palmito-stearate esters.

More particularly, the mono- and di-esters and in particular the mono- or di-oleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, of sucrose, of glucose or of methylglucose, and mixtures thereof, are used.

Mention may be made, by way of example, of the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.

Preferably, a liquid ester of monoacid and monoalcohol will be used.

The silicone oils which can be used in the composition according to the present invention can be volatile or non-volatile, cyclic, linear or branched, modified or not by organic groups, and preferably have a viscosity of 5.10-6 to 2.5 m2/s at 25° C., and preferably 1.10 −5 at 1 m2/s.

Preferably, the silicone oils are chosen from polydialkylsiloxanes, in particular polydimethylsiloxanes (PDMS), and liquid polyorganosiloxanes comprising at least one aryl group.

These silicone oils can also be organomodified. The organomodified silicone oils that can be used in accordance with the invention are preferably liquid silicones as defined above and comprising in their structure one or more organofunctional groups fixed via a hydrocarbon group, for example chosen from amino groups and alkoxy groups.

The organopolysiloxanes are defined in more detail in the work by Walter NOLL “Chemistry and Technology of Silicones” (1968), Academie Press. They can be volatile or non-volatile.

When they are volatile, the silicone oils are more particularly chosen from those having a boiling point of between 60° C. and 260° C., and even more particularly from:
(i) cyclic polydialkylsiloxanes comprising from 3 to 7, preferably from 4 to 5 silicon atoms. These are, for example, octamethylcyclotetrasiloxane marketed in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane marketed under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE ® 70045 V5 by RHODIA, as well as their mixtures.
Mention may also be made of cyclocopolymers of the dimethylsiloxane/methylalkylsiloxane type, such as SILICONE VOLATILE® FZ 3109 marketed by the company UNION CARBIDE.
Mention may also be made of mixtures of cyclic polydialkylsiloxanes with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1'-(hexa -2,2,2',2',3,3'-trimethylsilyloxy)bis-neopentane;
(ii) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and exhibiting a viscosity less than or equal to 5×10 −6 m²/s at 25°C. This is, for example, decamethyltetrasiloxane marketed in particular under the name “SH 200” by the company TORAY SILICONE. Silicones falling into this class are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, P. 27-32 - TODD & BYERS “Volatile Silicone fluids for cosmetics”.

Preferably, non-volatile polydialkylsiloxanes are used.

These silicone oils are more particularly chosen from polydialkylsiloxanes, among which there may be mentioned mainly polydimethylsiloxanes containing trimethylsilyl end groups. The viscosity of silicones is measured at 25°C according to ASTM 445 Appendix C.

Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products:
- the SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA such as, for example, the oil 70 047 V 500 000;
- the oils of the MIRASIL® series marketed by the company RHODIA;
- 200 series oils from DOW CORNING such as DC200 having a viscosity of 60,000 mm 2 /s;
- VISCASIL® oils from GENERAL ELECTRIC and certain oils from the SF series (SF 96, SF 18) from GENERAL ELECTRIC.

Mention may also be made of polydimethylsiloxanes containing dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA.

The organomodified silicones which can be used in accordance with the invention are silicones as defined previously and comprising in their structure one or more organofunctional groups attached via a hydrocarbon group.

As regards the liquid polyorganosiloxanes comprising at least one aryl group, they can in particular be polydiphenylsiloxanes, and polyalkyl-arylsiloxanes functionalized with the organofunctional groups mentioned above.

The polyalkylarylsiloxanes are particularly chosen from polydimethyl/methylphenylsiloxanes, linear and/or branched polydimethyl/diphenylsiloxanes with a viscosity ranging from 1×10 −5 to 5×10 −2 m²/s at 25°C.

Among these polyalkylarylsiloxanes, mention may be made, by way of example, of the products marketed under the following names:
- SILBIONE® oils of the 70 641 series from RHODIA;
- oils of the RHODORSIL® 70 633 and 763 series from RHODIA;
- DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING;
- BAYER's PK series silicones such as the PK20 product;
- the silicones of the PN and PH series from BAYER such as the PN1000 and PH1000 products;
- certain oils from GENERAL ELECTRIC's SF series such as SF 1023, SF 1154, SF 1250, SF 1265.

Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising:
- amino groups, substituted or not, such as the products marketed under the names GP 4 Silicone Fluid and GP 7100 by the company GENESEE or the products marketed under the names Q2 8220 and DOW CORNING 929 or 939 by the company DOW CORNING. The substituted amino groups are in particular C ₁ to C ₄ aminoalkyl groups;
- alkoxylated groups,
- hydroxyl groups.

The solid fatty substances preferably have a viscosity greater than 2 Pa.s, measured at 25° C. and at a shear rate of 1 s ⁻¹ .

The solid fatty substance(s) are preferably chosen from solid fatty alcohols, solid fatty acid and/or fatty alcohol esters, waxes, ceramides, and mixtures thereof.

By “fatty alcohol”, is meant a long-chain aliphatic alcohol comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms and comprising at least one OH hydroxyl group. These fatty alcohols are neither oxyalkylenated nor glycerolated.

The solid fatty alcohols can be saturated or unsaturated, linear or branched, and contain from 8 to 40 carbon atoms, preferably from 10 to 30 carbon atoms. Preferably, the solid fatty alcohols have an R-OH structure with R denoting a linear alkyl group, optionally substituted by one or more hydroxy groups, comprising from 8 to 40, preferably from 10 to 30 carbon atoms, or even from 12 to 24 atoms, even better from 14 to 22 carbon atoms.

The solid fatty alcohols which can be used are preferably chosen from saturated or unsaturated, linear or branched, preferably linear and saturated (mono)alcohols, comprising from 8 to 40 carbon atoms, better still from 10 to 30, or even 12 to 24 atoms, even better 14 to 22 carbon atoms.

The solid fatty alcohols which can be used can be chosen from, alone or as a mixture: myristic or myristyl alcohol (or 1-tetradecanol); cetyl alcohol (or 1-hexadecanol); stearyl alcohol (or 1-octadecanol); arachidyl alcohol (or 1-eicosanol); behenyl alcohol (or 1-docosanol); lignoceryl alcohol (or 1-tetracosanol); cerylic alcohol (or 1-hexacosanol); montanyl alcohol (or 1-octacosanol); myricyl alcohol (or 1-triacontanol).

Preferably, the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol, behenyl alcohol, myristic alcohol, arachydic alcohol and mixtures thereof, such as cetyl stearyl or cetearyl alcohol. Particularly preferably, the solid fatty alcohol is cetylstearyl or cetearyl alcohol.

The solid fatty acid and/or fatty alcohol esters that can be used are preferably chosen from esters derived from a C ₉ -C ₂₆ carboxylic fatty acid and/or from a C ₉ -C fatty alcohol. ₂₆ .

Preferably, these solid fatty esters are saturated, linear or branched carboxylic acid esters, comprising at least 10 carbon atoms, preferably from 10 to 30 carbon atoms and more particularly from 12 to 24 carbon atoms, and from Saturated monoalcohol, linear or branched, comprising at least 10 carbon atoms, preferably from 10 to 30 carbon atoms and more particularly from 12 to 24 carbon atoms. The saturated carboxylic acids can optionally be hydroxylated, and are preferably monocarboxylic acids.

It is also possible to use esters of C ₄ -C ₂₂ di- or tricarboxylic acids and C ₁ -C ₂₂ alcohols and esters of mono-, di- or tricarboxylic acids and di-, tri-alcohols. -, tetra- or pentahydroxylated C ₂ -C ₂₆ .

Mention may in particular be made of octyldodecyl behenate, isocetyl behenate, cetyl lactate, stearyl octanoate, octyl octanoate, cetyl octanoate, decyl oleate, hexyl stearate, octyl stearate, myristyl stearate, cetyl stearate, stearyl stearate, octyl pelargonate, cetyl myristate, myristyl myristate, stearyl myristate, diethyl sebacate, diisopropyl sebacate, diisopropyl adipate, di n-propyl adipate, dioctyl adipate, dioctyl maleate, octyl palmitate, myristyl palmitate, cetyl palmitate, stearyl palmitate , and mixtures thereof.

Preferably, the solid fatty acid and/or fatty alcohol esters are chosen from C ₉ -C ₂₆ alkyl palmitates, in particular myristyl, cetyl and stearyl palmitates; C9-C26 alkyl myristates such as cetyl myristate, stearyl myristate and myristyl myristate; C9-C26 alkyl stearates, especially myristyl, cetyl and stearyl stearates; and their mixtures.

A wax, within the meaning of the present invention, is a lipophilic compound, solid at 25° C. and atmospheric pressure, with a reversible solid/liquid state change, having a melting temperature above approximately 40° C. and which can go up to at 200° C., and exhibiting an anisotropic crystalline organization in the solid state. In general, the size of the crystals of the wax is such that the crystals diffract and/or scatter the light, giving the composition which comprises them a more or less opaque cloudy appearance. By bringing the wax to its melting temperature, it is possible to make it miscible with oils and form a microscopically homogeneous mixture, but by bringing the temperature of the mixture back to room temperature, a recrystallization of the wax is obtained, which is microscopically detectable and macroscopically (opalescence).

In particular, the waxes suitable for the invention can be chosen from waxes of animal, plant or mineral origin, non-silicone synthetic waxes and mixtures thereof.

Mention may in particular be made of hydrocarbon waxes, such as beeswax, in particular of biological origin, lanolin wax, and Chinese insect waxes; Rice Bran Wax, Carnauba Wax, Candelilla Wax, Ouricury Wax, Alfa Wax, Berry Wax, Shellac Wax, Japan Wax, and Sumac Wax; Montan wax, orange and lemon waxes, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by the Fisher-Tropsch synthesis and waxy copolymers, as well as their esters.

Mention may also be made of C ₂₀ to C ₆₀ microcrystalline waxes, such as Microwax HW.

Mention may also be made of the polyethylene wax PM 500 marketed under the reference Permalen 50-L polyethylene.

Mention may also be made of the waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C ₈ to C ₃₂ fatty chains. Among these, mention may in particular be made of isomerized jojoba oil, such as trans isomerized partially hydrogenated jojoba oil, in particular that manufactured or marketed by the company Desert Whale under the trade reference Iso-Jojoba-50®, the hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil, hydrogenated lanolin oil, and di-(trimethylol-1,1,1 propane) tetrastearate, in particular that sold under the name of Hest 2T-4S® by the company HETERENE.

It is also possible to use the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, such as those sold under the names of Phytowax ricin 16L64® and 22L73® by the company SOPHIM.

As wax, it is also possible to use a C20 to C40 alkyl (hydroxystearyloxy)stearate (the alkyl group comprising from 20 to 40 carbon atoms), alone or as a mixture. Such a wax is in particular sold under the names “Kester Wax K 82 P®”, “Hydroxypolyester K 82 P®” and “Kester Wax K 80 P®” by the company KOSTER KEUNEN.

It is also possible to use microwaxes in the compositions of the invention; particular mention may be made of carnauba microwaxes, such as that marketed under the name MicroCare 350® by the company MICRO POWDERS, synthetic wax microwaxes, such as that marketed under the name MicroEase 114S® by the company MICRO POWDERS, microwaxes consisting of a mixture of carnauba wax and polyethylene wax, such as those marketed under the names Micro Care 300® and 310® by the company MICRO POWDERS, the microwaxes consisting of a mixture of carnauba wax and synthetic wax , such as that marketed under the name Micro Care 325® by the company MICRO POWDERS, polyethylene microwaxes, such as those marketed under the names Micropoly 200®, 220®, 220L® and 250S® by the company MICRO POWDERS and the polytetrafluoroethylene microwaxes, such as those marketed under the names Microslip 519® and 519 L® by the company MICRO POWDERS.

The waxes are preferably chosen from mineral waxes such as paraffin wax, petroleum jelly, lignite or ozokerite; vegetable waxes such as cocoa butter or cork or sugar cane fiber waxes, olive wax, rice wax, hydrogenated jojoba wax, Ouricoury wax, carnauba wax, candelila wax, Alfa wax, or absolute flower waxes such as essential blackcurrant flower wax sold by the company BERTIN (France); waxes of animal origin such as beeswax or modified beeswax (cerabellina), spermaceti, lanolin wax and lanolin derivatives; microcrystalline waxes; and their mixtures.

The ceramides or analogues of ceramides such as glycoceramides, capable of being used in the compositions according to the invention, are known; particular mention may be made of ceramides of classes I, II, III and V according to the DAWNING classification.

The ceramides or their analogues which may be employed preferably correspond to the following formula: R ³ CH(OH)CH(CH ₂ OR ² )(NHCOR ¹ ), in which:
R ¹ denotes an alkyl group, linear or branched, saturated or unsaturated, derived from C ₁₄ -C ₃₀ fatty acids, this group possibly being substituted by a hydroxyl group in the alpha position, or a hydroxyl group in the omega position esterified by a saturated or unsaturated C ₁₆ -C ₃₀ fatty acid;
R ² denotes a hydrogen atom, a (glycosyl)n group, a (galactosyl)m group or a sulfogalactosyl group, in which n is an integer varying from 1 to 4 and m is an integer varying from 1 to 8;
R ³ denotes a C ₁₅ -C ₂₆ hydrocarbon-based group, saturated or unsaturated in the alpha position, this group possibly being substituted by one or more C ₁ -C ₁₄ alkyl groups; it being understood that in the case of natural ceramides or glycoceramides, R ³ can also denote a C ₁₅ -C ₂₆ alpha-hydroxyalkyl group, the hydroxyl group being optionally esterified with a C ₁₆ -C ₃₀ alpha-hydroxy acid.

The more particularly preferred ceramides are the compounds for which R ¹ denotes a saturated or unsaturated alkyl derived from C ₁₆ -C ₂₂ fatty acids; R ² denotes a hydrogen atom and R ³ denotes a saturated linear C ₁₅ group.

Preferably, ceramides are used for which R ¹ denotes a saturated or unsaturated alkyl group derived from C ₁₄ -C ₃₀ fatty acids; R ² denotes a galactosyl or sulfogalactosyl group; and R ³ denotes a -CH=CH-(CH ₂ ) ₁₂ -CH ₃ group.

It is also possible to use the compounds for which R ¹ denotes a saturated or unsaturated alkyl radical derived from C ₁₂ -C ₂₂ fatty acids; R ² denotes a galactosyl or sulfogalactosyl radical and R ³ denotes a saturated or unsaturated C ₁₂ -C ₂₂ hydrocarbon radical and preferably a -CH=CH-(CH ₂ ) ₁₂ -CH ₃ group.

As particularly preferred compounds, mention may also be made of 2-N-linoleoylamino-octadecane-1,3-diol; 2-N-oleoylamino-octadecane-1,3-diol; 2-N-palmitoylamino-octadecane-1,3-diol; 2-N-stearoylamino-octadecane-1,3-diol; 2-N-behenoylamino-octadecane-1,3-diol; 2-N-[2-hydroxy-palmitoyl]-amino-octadecane-1,3-diol; 2-N-stearoyl amino-octadecane-1,3,4 triol and in particular N-stearoyl phytosphingosine 2-N-palmitoylamino-hexadecane-1,3-diol, N-linoleoyldihydrosphingosine, N-oleoyldihydrosphingosine, N-palmitoyldihydrosphingosine, N-stearoyldihydrosphingosine, and N-behenoyldihydrosphingosine, N-docosanoyl N-methyl-D-glucamine, N-(2-hydroxyethyl)-N-(3-cetyloxy-2-hydroxypropyl)amide cetyl acid and bis-(N-hydroxyethyl N-cetyl) malonamide; and their mixtures. Preferably, N-oleoyldihydrosphingosine will be used.

The solid fatty substances are preferably chosen from solid fatty alcohols and mixtures thereof.

Preferably, the composition according to the invention comprises one or more liquid fatty substances, preferably chosen from liquid C ₆ to C ₁₆ hydrocarbons, liquid hydrocarbons comprising more than 16 carbon atoms, non-silicone oils of animal origin, oils of the triglyceride type of plant or synthetic origin, fluorinated oils, liquid fatty alcohols, liquid esters of fatty acids and/or fatty alcohols other than triglycerides, silicone oils, and mixtures thereof.

According to a particularly preferred embodiment, the composition according to the invention comprises one or more liquid fatty substances chosen from liquid hydrocarbons comprising more than 16 carbon atoms, more preferably vaseline oil.

Advantageously, the total content of the fatty substance(s) other than fatty acids is greater than or equal to 25% by weight, preferably greater than or equal to 30% by weight, more preferably greater than or equal to 40% by weight, even more preferably greater than or equal to 50% by weight, relative to the total weight of the composition.

Advantageously, the total content of the fatty substance(s) other than fatty acids varies from 20 to 85% by weight, preferably from 30 to 80% by weight, more preferably varies from 40 to 70% by weight, relative to the total weight of the composition.

Advantageously, the total content of the liquid fatty substance(s) is greater than or equal to 20% by weight, preferably greater than or equal to 30% by weight, even more preferably greater than or equal to 40% by weight, better still greater than or equal at 50% by weight relative to the total weight of the composition.

Advantageously, the total content of the liquid fatty substance(s) varies from 20 to 85% by weight, preferably from 30 to 80% by weight, more preferably varies from 40 to 70% by weight, relative to the total weight of the composition

Propane-1,3-diol
The composition according to the invention further comprises propane-1,3-diol.

Advantageously, the total propane-1,3-diol content varies from 0.5 to 15% by weight, preferably from 1 to 10% by weight, preferably varies from 2 to 8% by weight, more preferably from 2.5 at 6% by weight, relative to the total weight of the composition.

The composition according to the present invention also comprises one or more alkaline agents and/or one or more dyes chosen from direct dyes, oxidation dyes and mixtures thereof, as defined below.

alkaline agent
The composition according to the present invention may also comprise one or more alkaline agent(s) chosen from inorganic, organic or hybrid alkaline agents.

Preferably, the composition according to the present invention comprises one or more alkaline, mineral(s), organic(s) or hybrid agent(s).

Within the meaning of the present invention, the terms “alkaline agent” or “alkalizing agent” are used interchangeably.

The inorganic alkalizing agent(s) are preferably chosen from ammonia, alkali metal carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali metal or alkaline metal phosphates. earth metals such as sodium phosphates or potassium phosphates, sodium or potassium hydroxides, silicates or metasilicates of alkali or alkaline earth metals such as sodium metasilicate and mixtures thereof.

The organic basifying agent(s) are preferably chosen from alkanolamines, amino acids, organic amines other than alkanolamines, oxyethylenated and/or oxypropylenated ethylenediamines, 1,3 diaminopropane, 1,3 diamino 2 propanol, spermine, spermidine and mixtures thereof.

By alkanolamine is meant an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C ₁ -C ₈ alkyl groups carrying one or more hydroxyl radicals.

The organic amines chosen from alkanolamines such as mono-, di- or tri-alkanolamines, comprising one to three C ₁ -C ₄ hydroxyalkyl radicals, which may or may not be identical, are particularly suitable for carrying out the invention.

In particular, the alkanolamine(s) are chosen from monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N,N-dimethylethanolamine, 2-amino-2-methyl-1 -propanol, triisopropanol-amine, 2-amino-2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylamino- methane and their mixtures.

Advantageously, the amino acids are basic amino acids comprising an additional amine function. Such basic amino acids are chosen, preferably, from histidine, lysine, arginine, ornithine, citrulline.

The organic amine can also be chosen from organic amines of the heterocyclic type. Mention may in particular be made, in addition to the histidine already mentioned in the amino acids, of pyridine, piperidine, imidazole, triazole, tetrazole, benzimidazole. The organic amine can also be chosen from amino acid dipeptides. As amino acid dipeptides which can be used in the present invention, mention may in particular be made of carnosine, anserine and balenine. The organic amine can also be chosen from compounds comprising a guanidine function. As amines of this type different from arginine which can be used in the present invention, mention may in particular be made of creatine, creatinine, 1,1-dimethylguanidine, 1,1-diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidinopropionic acid, 4-guanidinobutyric acid and 2-([amino(imino)methyl]amino)ethane-1-sulfonic acid.)

As hybrid compounds, it is possible in particular to use guanidine carbonate or monoethanolamine hydrochloride.

The alkaline agent(s) useful according to the invention is (are) preferably chosen from alkanolamines such as monoethanolamine, diethanolamine, triethanolamine; ammonia, carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali or alkaline earth metal silicates or metasilicates such as sodium metasilicate and mixtures thereof, plus preferably from ammonia, alkanolamines, alkali or alkaline earth metal silicates or metasilicates, better still from alkanolamines and alkali metal or alkaline earth metal silicates or metasilicates, even better from monoethanolamine and sodium metasilicate,

According to a particularly preferred embodiment, the alkaline agent is monoethanolamine.

When the composition comprises at least one alkaline agent, the total content of the alkaline agent(s) preferably varies from 1 to 15% by weight, preferably from 2 to 10% by weight, better still from 3 to 8% by weight, or even from 4 at 6% by weight relative to the total weight of the composition.

Preferably, the basifying agents are organic.

In a particular embodiment, the composition according to the invention is free of ammonia.

When the composition comprises at least one alkaline agent chosen from alkanolamines, preferably monoethanolamine, the total content of alkanolsmine(s) preferably varies from 1 to 15% by weight, preferably from 2 to 10% by weight, better still from 3 to 8% by weight, or even from 4 to 6% by weight relative to the total weight of the composition.

According to one embodiment, the pH of the composition according to the invention is between 8 and 13; preferably between 9.0 and 12.

The pH of the composition can be adjusted to the desired value by means of acidic or alkaline agent(s) usually used in dyeing keratin fibres, such as those described above, or even using buffer systems known to those skilled in the art.

Dyes
The composition according to the present invention may comprise one or more dyes.

Preferably, the composition according to the present invention comprises one or more dyes chosen from oxidation dyes, direct dyes and mixtures thereof, in particular oxidation dyes.

Dyes: oxidation dyes
The oxidation dyes can be chosen from one or more oxidation bases, optionally combined with one or more couplers.

Preferably, the oxidation dye or dyes comprise one or more oxidation bases.

Preferably, the composition according to the invention comprises one or more oxidation bases.

Oxidation bases can be present as salts, solvates and/or solvates of salts.

The oxidation bases can be chosen from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts, their solvates and the solvates of their salts.

The addition salts of the oxidation bases present in the composition according to the invention are chosen in particular from addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, methanesulfonates, phosphates and acetates, and addition salts with a base such as sodium hydroxide, potassium hydroxide, ammonia, amines or alkanolamines.

Furthermore, the solvates of the oxidation bases more particularly represent the hydrates of said oxidation bases and/or the combination of said oxidation bases with a linear or branched C ₁ to C ₄ alcohol such as methanol, ethanol, isopropanol, n-propanol. Preferably, the solvates are hydrates.

Among the paraphenylenediamines, mention may be made, by way of example, of paraphenylenediamine, paratoluylenediamine, 2-chloroparaphenylenediamine, 2,3-dimethyl paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2 ,5-dimethyl paraphenylenediamine, N,N-dimethyl paraphenylenediamine, N,N-diethyl paraphenylenediamine, N,N-dipropyl paraphenylenediamine, 4-amino N,N-diethyl 3-methyl aniline, N,N-bis -(β-hydroxyethyl) paraphenylenediamine, 4-N,N-bis-(β-hydroxyethyl)amino 2-methyl aniline, 4-N,N-bis-(β-hydroxyethyl)amino 2-chloro aniline, 2 -β-hydroxyethyl para-phenylenediamine, 2-methoxymethyl-para-phenylenediamine, 2-γ-hydroxypropyl-para-phenylenediamine, 2-fluoro para-phenylenediamine, 2-isopropyl para-phenylenediamine, N-(β-hydroxypropyl) para-phenylenediamine, 2 -hydroxymethyl paraphenylenediamine, N,N-dimethyl 3-methyl paraphenylenediamine, N,N-(ethyl, β-hydroxyethyl) paraphenylenediamine, N- (β,γ-dihydroxypropyl) paraphenylenediamine, N-(4'-aminophenyl) paraphenylenediamine, N-phenyl paraphenylenediamine, 2-β-hydroxyethyloxy paraphenylenediamine, 2-β-acetylaminoethyloxy paraphenylenediamine, N-(β-methoxyethyl) paraphenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, 2-β hydroxyethylamino 5-amino toluene, 3-hydroxy 1-(4'-aminophenyl)pyrrolidine and their addition salts, solvates and solvates of their salts.

Among the para-phenylenediamines mentioned above, para-phenylenediamine, para-toluylenediamine, 2-isopropyl para-phenylenediamine, 2-β-hydroxyethyl para-phenylenediamine, 2-methoxymethyl-para-phenylenediamine, 2-γ-hydroxypropyl-para-phenylenediamine, 2 -β-hydroxyethyloxy paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, N,N-bis-(β-hydroxyethyl) paraphenylenediamine, 2-chloro paraphenylenediamine, 2-β-acetylaminoethyloxy paraphenylenediamine, and their addition salts, their solvates and the solvates of their salts are particularly preferred.

Among the bis-phenylalkylenediamines, mention may be made by way of example of N,N'-bis-(β-hydroxyethyl) N,N'-bis-(4'-aminophenyl) 1,3-diamino propanol, N ,N'-bis-(β-hydroxyethyl) N,N'-bis-(4'-aminophenyl) ethylenediamine, N,N'-bis-(4-aminophenyl)tetramethylenediamine, N,N'-bis-( β-hydroxyethyl) N,N'-bis-(4-aminophenyl)tetramethylenediamine, N,N'-bis-(4-methyl-aminophenyl)tetramethylenediamine, N,N'-bis-(ethyl)N,N' -bis-(4'-amino, 3'-methylphenyl) ethylenediamine, 1,8-bis-(2,5-diaminophenoxy)-3,6-dioxaoctane, and their addition salts, solvates and solvates of their salts.

Among the para-aminophenols, mention may be made, by way of example, of para-aminophenol, 4-amino 3-methyl phenol, 4-amino 3-fluoro phenol, 4-amino-3-chlorophenol, 4- amino 3-hydroxymethyl phenol, 4-amino 2-methyl phenol, 4-amino 2-hydroxymethyl phenol, 4-amino 2-methoxymethyl phenol, 4-amino 2-aminomethyl phenol, 4-amino 2-(β -hydroxyethyl aminomethyl) phenol, 4-amino 2-fluoro phenol, and their addition salts, their solvates and the solvates of their salts.

Among the ortho-aminophenols, mention may be made, by way of example, of 2-amino phenol, 2-amino 5-methyl phenol, 2-amino 6-methyl phenol, 5-acetamido 2-amino phenol, and their addition salts, their solvates and the solvates of their salts.

Among the heterocyclic bases, mention may be made, by way of example, of pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.

Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1,026,978 and GB 1,153,196, such as 2,5-diamino pyridine, 2-(4-methoxyphenyl)amino 3-amino pyridine, 3,4-diamino pyridine, and their addition salts, their solvates and the solvates of their salts.

Other useful pyridine oxidation bases in the present invention are the 3-amino pyrazolo-[1,5-a]-pyridine oxidation bases or their addition salts described for example in patent application FR 2801308. By way of example, mention may be made of pyrazolo[1,5-a]pyridin-3-ylamine; 2-acetylamino pyrazolo-[1,5-a]pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo[1,5-a]pyridin-3-ylamine; 3-amino-pyrazolo[1,5-a]pyridin-2-carboxylic acid; 2-methoxy-pyrazolo[1,5-a]pyridin-3-ylamino; (3-amino-pyrazolo[1,5-a]pyridin-7-yl)-methanol; 2-(3-amino-pyrazolo[1,5-a]pyridin-5-yl)-ethanol; 2-(3-amino-pyrazolo[1,5-a]pyridin-7-yl)-ethanol; (3-amino-pyrazolo[1,5-a]pyridin-2-yl)-methanol; 3,6-diamino-pyrazolo[1,5-a]pyridine; 3,4-diamino-pyrazolo[1,5-a]pyridine; pyrazolo[1,5-a]pyridine-3,7-diamine; 7-morpholin-4-yl-pyrazolo[1,5-a]pyridin-3-ylamine; pyrazolo[1,5-a]pyridine-3,5-diamine; 5-morpholin-4-yl-pyrazolo[1,5-a]pyridin-3-ylamine; 2-[(3-amino-pyrazolo[1,5-a]pyridin-5-yl)-(2-hydroxyethyl)-amino]-ethanol; 2-[(3-amino-pyrazolo[1,5-a]pyridin-7-yl)-(2-hydroxyethyl)-amino]-ethanol; 3-amino-pyrazolo[1,5-a]pyridin-5-ol; 3-amino-pyrazolo[1,5-a]pyridin-4-ol; 3-amino-pyrazolo[1,5-a]pyridin-6-ol; 3-amino-pyrazolo[1,5-a]pyridin-7-ol; 2-[(3-amino-pyrazolo[1,5-a]pyridin-2-yl)oxy ethanol as well as their addition salts, their solvates and the solvates of their salts.

Among the pyrimidine derivatives, mention may be made of the compounds described for example in patents DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetra-aminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, 2 ,4-dihydroxy 5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and their tautomeric forms, when a tautomeric equilibrium exists.

Among the pyrazole derivatives, mention may be made of the compounds described in patents DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988 such as 4.5 -diamino 1-methyl pyrazole, 4,5-diamino 1-(β-hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino 1-(4'-chlorobenzyl) pyrazole, 4,5 -diamino 1,3-dimethyl pyrazole, 4,5-diamino 3-methyl 1-phenyl pyrazole, 4,5-diamino 1-methyl 3-phenyl pyrazole, 4-amino 1,3-dimethyl 5-hydrazino pyrazole , 1-benzyl 4,5-diamino 3-methyl pyrazole, 4,5-diamino 3-tert-butyl 1-methyl pyrazole, 4,5-diamino 1-tert-butyl 3-methyl pyrazole, 4, 5-diamino 1-(β-hydroxyethyl) 3-methyl pyrazole, 4,5-diamino 1-ethyl 3-methyl pyrazole, 4,5-diamino 1-ethyl 3-(4'-methoxyphenyl) pyrazole, 4 ,5-diamino 1-ethyl 3-hydroxymethyl pyrazole, 4,5-diamino 3-hydroxymethyl 1-methyl pyrazole, 4,5-diamino 3-hydroxymethyl 1-isopropyl pyrazole, 4,5-diamino 3-methyl 1 -isopropyl pyrazole, 4- amino 5-(2'-aminoethyl)amino 1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl 3,4,5-triamino pyrazole, 3,5-diamino 1-methyl 4 -methylamino pyrazole, 3,5-diamino 4-(β-hydroxyethyl)amino 1-methyl pyrazole, and their addition salts, their solvates and the solvates of their salts. It is also possible to use 4-5-diamino 1-(β-methoxyethyl)pyrazole.

Preferably, a 4,5-diaminopyrazole will be used and even more preferably 4,5-diamino-1-(β-hydroxyethyl)-pyrazole and/or one of its salts, solvates, solvates of its salts.

As pyrazolic derivatives, mention may also be made of the diamino N,N-dihydropyrazolopyrazolones and in particular those described in application FR-A-2 886 136 such as the following compounds and their addition salts: 2,3-diamino-6 ,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol -1-one, 2-amino-3-isopropylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-(pyrrolidin-1-yl) -6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 4,5-diamino-1,2-dimethyl-1,2-dihydro-pyrazol-3-one, 4 ,5-diamino-1,2-diethyl-1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-di-(2-hydroxyethyl)-1,2-dihydro-pyrazol-3 -one, 2-amino-3-(2-hydroxyethyl)amino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-dimethylamino-6, 7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H,6H-pyridazino[1,2-a] pyrazol-1-one, 4-amino-1,2-diethyl-5-(pyrrolidin-1-yl)-1,2-dihydro-pyrazol-3-one, 4-amino-5-(3-dimethylamino-pyrrolidin -1-yl)-1,2- diethyl-1,2-dihydro-pyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, their salts , their solvates and/or solvates of their salts.

It will be preferred to use 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or one of its salts, solvates or solvates of its salts.

As heterocyclic bases, 4,5-diamino-1-(β-hydroxyethyl)pyrazole and/or 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2- a]pyrazol-1-one and/or 2-[(3-amino-pyrazolo[1,5-a]pyridin-2-yl)oxy ethanol and/or one of their salts, solvates or solvates of its salts.

Preferably, the oxidation base(s) are chosen from para-phenylenediamines, in particular para-toluenediamine, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and salts of corresponding addition, their solvates and/or the solvates of their salts and their mixtures; more preferably from 2-methoxymethyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-γ-hydroxypropyl-para-phenylenediamine, and their addition salts, their solvates and/or the solvates of their salts and their mixtures.

In a particular embodiment, the composition according to the invention is free of oxidation bases chosen from para-phenylenediamine, para-toluenediamine, their addition salts, their solvates, and the solvates of their salts.

The oxidation dye(s) may also comprise one or more couplers, which may be chosen from the couplers conventionally used for dyeing keratin fibres.

Preferably, the composition according to the invention comprises one or more couplers.

Preferably, the couplers are chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene couplers, heterocyclic couplers as well as their addition salts and/or their solvates and/or the solvates of their salts.

By way of examples, mention may be made of 1,3-dihydroxy benzene, 1,3-dihydroxy-2-methyl benzene, 4-chloro-1,3-dihydroxy benzene, 1-hydroxy-3-amino benzene , 1-methyl-2-hydroxy-4-ß-hydroxyethylamino benzene, 4-amino-2-hydroxy toluene, 5-amino-6-chloro-2-methyl phenol, 2,4-diamino-1- (ß-hydroxyethyloxy) benzene, 2-amino-4-(ß-hydroxyethylamino)-1-methoxybenzene, 1,3-diamino benzene, 1,3-bis-(2,4-diaminophenoxy) propane, 3 -ureido aniline, 3-ureido-1-dimethylamino benzene, sesamol, 1-ß-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxy indole , 4-hydroxy indole, 4-hydroxy-N-methyl indole, 5-methoxy-6-hydroxy indole, 2-amino-3-hydroxy pyridine, 6-hydroxy benzomorpholine, 2-amino 4-hydroxyethylaminoanisole , 3-AMINO-6-METHOXY-2-METHYLAMINO PYRIDINE, 3,5-diamino-2,6-dimethoxypyridine, 1-N-(ß-hydroxyethyl)amino-3,4-methylene dioxybenzene, 2, 6-bis-(ß-hydroxyethylamino)toluene, 6-hydroxy i ndolin, 2,6-dihydroxy-4-methyl pyridine, 2-chloro-3,5-diaminopyridine, 2-chloro-3,5-diamino-6-methoxypyridine, 2-chloro-3,5-diamino -6-methylpyridine, 1-H-3-methyl pyrazol 5-one, 1-phenyl 3-methyl pyrazol 5-one, 4-(3,5-DIAMINOPYRIDIN-2-YL)-1-(2- HYDROXYETHYL)-1-METHYLPIPERAZIN-1-IUM CHLORIDE, 2,6-dimethyl pyrazolo-[1,5-b]-1,2,4-triazole, 2,4,6-trimethoxyaniline hydrochlorate, 2,6 -dimethyl-[3,2-c]-1,2,4-triazole, 6-methyl pyrazolo-[1,5-a]-benzimidazole, 2,6-diaminopyrazine, their addition salts and/or their solvates and/or the solvates of their salts, and mixtures thereof.

Preferably, the coupler(s) used in the invention are chosen from 1,3-dihydroxy benzene, 1,3-dihydroxy-2-methyl benzene, 4-chloro-1,3-dihydroxy benzene, 1-hydroxy-3-amino benzene, 1-methyl-2-hydroxy-4-ß-hydroxyethylamino benzene, 4-amino-2-hydroxy toluene, 5-amino-6-chloro-2-methyl phenol, 2,4-diamino-1-(ß-hydroxyethyloxy) benzene, α-naphthol, 6-hydroxy indole, 2-amino-3-hydroxy pyridine, 6-hydroxy benzomorpholine, 3-AMINO-6- METHOXY-2-METHYLAMINO PYRIDINE, 2-amino 4-hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino 5-ethylphenol, their addition salts and/or their solvates and/or the solvates of their salts, and mixtures thereof.

Even more preferably, the coupler(s) used in the invention are chosen from 3-AMINO-6-METHOXY-2-METHYLAMINO PYRIDINE, 6-hydroxy benzomorpholine, 2,4-diamino-1-(ß- hydroxyethyloxy) benzene, 2-amino-3-hydroxy pyridine, 5-amino-6-chloro-2-methyl phenol, 1-methyl-2-hydroxy-4-ß-hydroxyethylamino benzene, 2-amino 4- hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino 5-ethylphenol, 1-hydroxy 3-amino benzene, their addition salts and/or their solvates and/or the solvates of their salts and mixtures thereof .

In general, the addition salts of the couplers which can be used in the context of the invention are chosen in particular from addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates, and addition salts with a base such as soda, potash, ammonia, amines or alkanolamines.

Furthermore, the solvates more particularly represent the hydrates of these couplers and/or the association of these couplers with a linear or branched C ₁ to C ₄ alcohol such as methanol, ethanol, isopropanol, n- propanol. Preferably, the solvates are hydrates.

Preferably, the oxidation dyes chosen from couplers are chosen from 6-hydroxy benzomorpholine, 2,4-diamino-1-(β-hydroxyethyloxy) benzene, 2-amino-3-hydroxy pyridine, 5- amino-6-chloro-2-methyl phenol, 1-methyl-2-hydroxy-4-ß-hydroxyethylamino benzene, 2-amino 4-hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino 5 -ethylphenol, 1-hydroxy-3 aminobenzene, their addition salts, their salts and/or the solvates of their salts and their mixtures.

Better still, the coupler(s) is or are chosen from: 6-hydroxy benzomorpholine, its addition salts, its solvates and/or the solvates of its salts, hydroxyethyl-3-4-methylenedioxyaniline, its addition salts, its solvates and/or the solvates of its salts, 2-amino 5-ethylphenol, its addition salts, its solvates and/or the solvates of its salts and mixtures thereof.

Advantageously, when they are present, the oxidation dyes chosen from oxidation bases are present in a total content ranging from 0.0001 to 10% by weight, preferably from 0.005 to 7% by weight, more preferably from 0.1 to 4% by weight, relative to the total weight of the composition.

Advantageously, when they are present, the oxidation dyes chosen from couplers are present in a total content ranging from 0.0001 to 10% by weight, preferably from 0.005 to 7% by weight, more preferably from 0.1 at 4% by weight, relative to the total weight of the composition.

Advantageously, the oxidation dyes are present in a total content ranging from 0.0001 to 10% by weight, preferably from 0.005 to 7% by weight, more preferably from 0.1 to 4% by weight, relative to the weight composition total.

In a particular embodiment, the composition according to the invention is free of oxidation couplers chosen from resorcinol, 2-methyl resorcinol, 4-chloro resorcinol, their addition salts, their solvates, and the solvates of their salts.

Dyes: direct dyes
By "direct dye" is meant natural and/or synthetic dyes, different from oxidation dyes. These are dyes that will diffuse superficially on the fiber.

Synthetic direct dyes are for example chosen from those conventionally used in direct dyeing, and among which may be mentioned all the aromatic and/or non-aromatic dyes in common use such as nitrobenzene, azo, hydrazono, nitrated (hetero )aryl, tri(hetero)arylmethane, (poly)methine, carbonyl, azine, porphyrin, metalloporphyrin, quinone and in particular anthraquinone, indoamine, phthalocyanine and mixtures thereof.

Among the nitrobenzene direct dyes, mention may be made of: 1,4-diamino-2-nitrobenzene, 1-amino-2-nitro-4-β-hydroxyethylaminobenzene; 1-amino-2-nitro-4-bis(β-hydroxyethyl)-aminobenzene; 1,4-bis(β-hydroxyethylamino)-2-nitrobenzene; 1-β-hydroxyethylamino-2-nitro-4-bis-(β-hydroxyethylamino)-benzene; 1-β-hydroxyethylamino-2-nitro-4-aminobenzene; 1-β-hydroxyethylamino-2-nitro-4-(ethyl)(β-hydroxyethyl)-aminobenzene; 1-amino-3-methyl-4-β-hydroxyethylamino-6-nitrobenzene; 1-amino-2-nitro-4-β-hydroxyethylamino-5-chlorobenzene; 1,2-diamino-4-nitrobenzene; 1-amino-2-β-hydroxyethylamino-5-nitrobenzene; 1,2-bis-(β-hydroxyethylamino)-4-nitrobenzene; 1-amino-2-tris-(hydroxymethyl)-methylamino-5-nitrobenzene; 1-Hydroxy-2-amino-5-nitrobenzene; 1-Hydroxy-2-amino-4-nitrobenzene; 1-Hydroxy-3-nitro-4-aminobenzene; 1-Hydroxy-2-amino-4,6-dinitrobenzene; 1-β-hydroxyethyloxy-2-β-hydroxyethylamino-5-nitrobenzene; 1-Methoxy-2-β-hydroxyethylamino-5-nitrobenzene; 1-β-hydroxyethyloxy-3-methylamino-4-nitrobenzene; 1-β,γ-dihydroxypropyloxy-3-methylamino-4-nitrobenzene; 1-β-hydroxyethylamino-4-β,γ-dihydroxypropyloxy-2-nitrobenzene; 1-β,γ-dihydroxypropylamino-4-trifluoromethyl-2-nitrobenzene; 1-β-hydroxyethylamino-4-trifluoromethyl-2-nitrobenzene; 1-β-hydroxyethylamino-3-methyl-2-nitrobenzene; 1-β-aminoethylamino-5-methoxy-2-nitrobenzene; 1-Hydroxy-2-chloro-6-ethylamino-4-nitrobenzene; 1-Hydroxy-2-chloro-6-amino-4-nitrobenzene; 1-Hydroxy-6-bis-(β-hydroxyethyl)-amino-3-nitrobenzene; 1-β-hydroxyethylamino-2-nitrobenzene; 1-Hydroxy-4-β-hydroxyethylamino-3-nitrobenzene.

Azo direct dyes include: Basic Red 51, Basic Orange 31, Disperse Red 17, Acid Yellow 9, Acid Black 1, Basic Red 22, Basic Red 76, Basic Yellow 57, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 35, Acid Yellow 23, Acid Orange 24, Disperse Black 9, Basic Brown 16, Basic Brown 17.

Among the hydrazono direct dyes, we can mention: Basic Yellow 87.

Among the nitro aryl direct dyes, mention may be made of: HC Blue 2, HC Yellow 2, HC Red 3,4-hydroxypropylamino-3-nitrophenol, N, N′-bis-(2-hydroxyethyl)-2-nitro-phenylenediamine.

Among the triarylmethane direct dyes, mention may be made of: Basic Violet 1, Basic Violet 2, Basic Violet 3, Basic Violet 4, Basic Violet 14, Basic Blue 1, Basic Blue 7, Basic Blue 26, Basic green 1, Basic Blue 77 ( also called HC Blue 15), Acid Blue 1; Acid Blue 3; Acid Blue 7, Acid Blue 9; Acid Violet 49; Acid green 3; Acid green 5; Acid Green 50.

Quinone direct dyes include: Disperse Red 15, Solvent Violet 13, Acid Violet 43, Disperse Violet 1, Disperse Violet 4, Disperse Blue 1, Disperse Violet 8, Disperse Blue 3, Disperse Red 11, Acid Blue 62, Disperse Blue 7, Basic Blue 22, Disperse Violet 15, Basic Blue 99, as well as the following compounds: 1-N-methylmorpholiniumpropylamino-4-hydroxyanthraquinone, 1-aminopropylamino-4-methylaminoanthraquinone, 1-aminopropylamino-anthraquinone, 5-β-hydroxyethyl-1,4-diaminoanthraquinone, 2-aminoethylamino-anthraquinone, 1,4-bis-(β,γ-dihydroxypropylamino)-anthraquinone, Acid Blue 25, Acid Blue 43, Acid Blue 78, Acid Blue 129, Acid Blue 138, Acid Blue 140, Acid Blue 251, Acid Green 25, Acid Green 41, Acid Violet 42, Mordant Red 3, Acid Black 48, HC Blue 16.

Among the azine direct dyes, mention may be made of: Basic Blue 17, Basic Red 2.

Among the indoamine direct dyes are: 2-β-hydroxyethylamino-5-[bis-(β-4-hydroxyethyl)amino]anilino-1,4-benzoquinone, 2-β-hydroxyethylamino-5-(2-methoxy -4-amino)anilino-1,4-benzoquinone, 3-N(2'-chloro-4-hydroxy)phenyl-acetylamino-6-methoxy-1,4-benzoquinone imine, 3-N(3'-chloro- 4-Methylamino)phenyl-ureido-6-methyl-1,4-benzoquinone imine, 3-[4'-N-(ethyl,carbamylmethyl)-amino]-phenyl-ureido-6-methyl-1,4-benzoquinone imine .

The natural direct dyes are for example chosen from lawsone, juglone, indigo, leuco indigo, indirubine, isatin, hennotannic acid, alizarin, carthamine, morine, purpurin, l carminic acid, kermesic acid, laccaic acid, purpurogalline, protocatechaldehyde, curcumin, spinulosin, apigenidin, orceins, carotenoids, betanin, chlorophylls, chlorophyllins, monascus, polyphenols or orthodiphenols.

Among the useful ortho-diphenols according to the invention, mention may be made of: catechin, quercetin, brazilin, hematein, hematoxylin, chlorogenic acid, caffeic acid, gallic acid, L DOPA, cyanidin, (-)-epicatechin, (-)-epigallocatechin, (- )-Epigallocatechin 3-gallate (EGCG), Isoquercetin, Pomiferin, Aesculetin, 6,7-Dihydroxy-3-(3-hydroxy-2,4-dimethoxyphenyl)coumarin, Santalin A and B, Mangiferin, Butein, Maritimetin, Sulfuretin, Robteine, Betanidin, Pericampylinone A., Theaflavin, Proanthocyanidin A2, Proanthocyanidin B2, Proanthocyanidin C1, Procyanidins DP 4-8, Tannic Acid, Purpurogalline, 5,6-Dihydroxy-2-methyl-1,4-naphthoquinone, Alizarin, Wedelolactone and the natural extracts containing them.

When the composition comprises at least one direct dye, they are preferably present in a total content ranging from 0.001 to 20% by weight, preferably from 0.005 to 15% by weight, more preferably from 0.01 to 10 % by weight, better from 0.05 to 5%, even better from 0.1 to 3% by weight, relative to the weight of the composition.

The direct dye(s) may be present in a total content ranging from 0.001 to 20% by weight, preferably from 0.005 to 15% by weight relative to the total weight of the dye composition.

Preferably, the composition according to the invention comprises one or more dyes chosen from oxidation dyes and direct dyes, more preferably chosen from oxidation dyes.

In a particular embodiment, the composition according to the invention is free of oxidation couplers chosen from resorcinol, 2-methyl resorcinol, 4-chloro resorcinol, their addition salts, their solvates, and the solvates of their salts.

Preferably, the composition according to the invention comprises one or more alkaline agents and one or more dyes chosen from oxidation dyes, direct dyes, and mixtures thereof, in particular chosen from oxidation dyes.

Preferably, the composition according to the invention comprises:
- one or more fatty substances other than fatty acids, preferably liquid, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more alkaline agents and/or one or more colorants, preferably one or more alkaline agents, in particular chosen from alkanolamines, and one or more colorants, in particular chosen from oxidation dyes.

Surfactants

The composition according to the present invention may comprise one or more surfactants. These can be chosen from anionic surfactants, nonionic surfactants and cationic surfactants and/or mixtures thereof, preferably from anionic surfactants, nonionic surfactants and/or mixtures thereof.

Preferably, the composition according to the present invention comprises one or more surfactants.

Preferably, the surfactant or surfactants are chosen from anionic, nonionic and cationic surfactants and mixtures thereof.

Preferably, the surfactant or surfactants are chosen from anionic and nonionic surfactants, and mixtures thereof.

The term “ anionic surfactant ” is understood to mean a surfactant comprising, as ionic or ionizable groups, only anionic groups. These anionic groups are preferably chosen from the groups CO2H, CO2-, SO3H, SO3-, OSO3H, OSO3-, H2PO3, HPO3-, PO32-, H2PO2, HPO2-, PO22-, POH and PO-.

As examples of anionic surfactants that can be used in the composition according to the invention, mention may be made of alkyl sulfates, alkyl ether sulfates, alkylamidoether sulfates, alkylarylpolyether sulfates, monoglyceride-sulfates, alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-alkyl(C ₁ -C ₄ ) -N-acyltaurates, salts of alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, salts of D-galactoside-uronic acids, salts of alkyl ether-carboxylic acids, salts of alkyl aryl ether-carboxylic acids, salts of alkyl amido-ether-carboxylic acids; fatty acid salts, and the corresponding unsalified forms of all these compounds; the alkyl and acyl groups of all these compounds (unless otherwise mentioned) generally comprising from 6 to 24 carbon atoms and the aryl group generally designating a phenyl group.

These compounds can be oxyethylenated and then preferably contain from 1 to 50 ethylene oxide units.

The salts of C ₆ -C ₂₄ alkyl monoesters and of polyglycoside-polycarboxylic acids can be chosen from C ₆ -C 24 alkyl polyglycoside-citrates, C ₆ -C ₂₄ alkyl polyglycoside-tartrates ₂₄ and C ₆ -C ₂₄ alkyl polyglycoside sulfosuccinates.

When the anionic surfactant(s) are in salt form, they can be chosen from alkali metal salts such as sodium or potassium and preferably sodium salt, ammonium salts, amine salts and in particular of amino alcohols or salts of alkaline-earth metals such as the magnesium salt.

By way of example of aminoalcohol salts, mention may in particular be made of mono-, di- and triethanolamine salts, mono-, di- or tri-isopropanol-amine salts, 2-amino 2-methyl 1-propanol, 2-amino 2-methyl 1,3-propanediol and tris(hydroxymethyl)amino methane.

Salts of alkali or alkaline earth metals and in particular sodium or magnesium salts are preferably used.

Any anionic surfactants present may be mild anionic surfactants, that is to say without sulphate function.

As regards mild anionic surfactants, mention may be made in particular of the following compounds and their salts, as well as their mixtures: polyoxyalkylenated alkyl ether carboxylic acids; polyoxyalkylenated alkylaryl ether carboxylic acids; polyoxyalkylenated alkylamido ether carboxylic acids, in particular those comprising 2 to 50 ethylene oxide groups; alkyl D galactoside uronic acids; acylsarcosinates, acylglutamates; and carboxylic alkylpolyglycoside esters.

Very particularly, it is possible to use polyoxyalkylenated alkyl ether carboxylic acids such as, for example, lauryl ether carboxylic acid (4.5 EO) marketed for example under the name AKYPO RLM 45 CA from KAO.

The anionic surfactants optionally present may be carboxylic acids comprising at least 8 carbon atoms, also called fatty acids, optionally in salified form.

For the purposes of the present invention, fatty acid means an acid comprising at least one linear or branched, saturated or unsaturated hydrocarbon chain, such as alkyl or alkenyl, comprising at least 6 carbon atoms, preferably from 8 to 24 carbon atoms. of carbon, and better still from 10 to 22 carbon atoms.

The carboxylic acids comprising at least 6 carbon atoms (or fatty acids) according to the invention are neither (poly)oxyalkylenated nor (poly)glycerolated; in particular, they are not (poly)oxyethylene or (poly)oxypropylene.

They preferably have the structure R—COOH in which R denotes an alkyl or alkenyl group, linear or branched, C ₇ -C ₂₉ , preferably C ₉ -C ₂₃ , better still C ₉ -C ₁₇ .

Preferably, the fatty acid according to the invention is chosen from linear fatty acids, better still from linear unsaturated fatty acids, C ₁₀ -C ₂₂ , in particular C ₁₀ -C ₁₈ (R is a linear C ₉ alkenyl -C ₂₃ , even C ₉ -C ₁₇ ).

Mention may in particular be made of lauric, oleic, linoleic, linolenic, undecylenic, isocetyl, isostearyl, cetyl, stearyl and cetylstearyl acids, and mixtures thereof. Preferably, oleic acid is used.

Among the anionic surfactants mentioned above, use is preferably made of alkyl sulphates, alkyl ether sulphates, and mixtures thereof, fatty acids.

The nonionic surfactant(s) that can be used in the composition of the present invention are described in particular, for example, in “Handbook of Surfactants” by M.R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178.

As examples of nonionic surfactants, mention may be made of the following compounds, alone or as a mixture:
- oxyalkylenated (C ₈ -C ₂₄ )alkylphenols;
- C ₈ to C ₄₀ alcohols, saturated or not, linear or branched, oxyalkylenated or glycerolated, they preferably contain one or two fatty chains;
- C ₈ to C ₃₀ fatty acid amides, saturated or not, linear or branched, oxyalkylenated;
- esters of C ₈ to C ₃₀ acids, saturated or not, linear or branched, and of polyethylene glycols;
- esters of C ₈ to C ₃₀ acids, saturated or not, linear or branched, and of sorbitol, preferably oxyethylenated;
- fatty acid esters, in particular C ₈ -C ₂₄ , and preferably Ci ₆ -C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene
- esters of fatty acids and sucrose,
- (C ₈ -C ₃₀ )alkyl (poly)glucosides, (C ₈ -C ₃₀ )alkenyl (poly)glucosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising from 1 to 15 glucose units, esters of (C ₈ -C ₃₀ )alkyl (poly)glucosides,
- oxyethylenated vegetable oils, saturated or not;
- ethylene oxide and/or propylene oxide condensates;
- N -alkyl(C ₈ -C ₃₀ )glucamine and N -acyl(C ₈ -C ₃₀ )-methylglucamine derivatives;
- amine oxides.

They are chosen, in particular, from alcohols, alpha-diols, (C ₁ -C ₂₀ )alkylphenols, these compounds being ethoxylated, propoxylated or glycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups possibly ranging in particular from 1 to 200 and the number of glycerol groups possibly ranging in particular from 1 to 30.

Mention may also be made of condensates of ethylene oxide and of propylene oxide with fatty alcohols; ethoxylated fatty amides preferably having from 1 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4, fatty acid esters of sorbitan containing from 1 to 30 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, (C ₆ -C ₂₄ alkyl)polyglycosides, oxyethylenated vegetable oils, N-(C ₆ -C ₂₄ alkyl)glucamine derivatives, amine oxides such as (C10-C14 alkyl)amine oxides or N-(C ₁₀ -C ₁₄ acyl)- aminopropylmorpholine.

C ₈ to C ₃₀ fatty acid esters, in particular C ₈ -C ₂₄ , and preferably C ₁₆ -C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene, may comprise more than 10 oxyethylene and/or oxypropylene units, in particular from 15 to 200 units, better still from 15 to 100 oxyethylene and/or oxypropylene units).

C ₈ to C ₃₀ fatty acid esters, in particular C ₈ -C ₂₄ , and preferably C ₁₆ -C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene, are preferably chosen from polyoxyethylenated glyceryl monostearate containing 200 oxyethylene units, sold under the name Simulsol 220 TM® by the company SEPPIC; polyoxyethylenated glyceryl stearate with 30 oxyethylene units such as the product TAGAT S® sold by the company GOLDSCHMIDT, polyoxyethylenated glyceryl oleate with 30 oxyethylene units such as the product TAGAT O® sold by the company GOLDSCHMIDT, polyoxyethylenated glyceryl cocoate with 30 oxyethylene units such as the product VARIONIC LI 13® sold by the company SHEREX, the polyoxyethylene glyceryl isostearate with 30 oxyethylene units such as the product TAGAT L® sold by the company GOLDSCHMIDT and the polyoxyethylenated glyceryl laurate with 30 oxyethylene units such as the product TAGAT I® from GOLDSCHMIDT.

The esters (in particular mono, di, tri esters) of C ₈ -C ₃₀ fatty acids, preferably of C ₁₂ -C ₂₂ fatty acids, and of sorbitan can be chosen from:
Sorbitan Caprylate; Sorbitan Cocoate; Sorbitan Isostearate; Sorbitan Laurate; Sorbitan Oleate; Sorbitan Palmitate; Sorbitan Stearate; Sorbitan Diisostearate; Sorbitan Dioleate; Sorbitan Distearate; Sorbitan Sesquicaprylate; Sorbitan Sesquiisostearate; Sorbitan Sesquioleate; Sorbitan Sesquistearate; Sorbitan Triisostearate; Sorbitan Trioleate; Sorbitan Tristearate.

The esters (in particular mono, di, tri esters) of C ₈ -C ₃₀ (preferably C ₁₂ -C ₁₈ ) fatty acids and of polyoxyethylenated sorbitan having in particular from 2 to 20 moles of ethylene oxide can be chosen from C ₁₂ -C ₁₈ fatty acid esters, in particular lauric, myristic, cetyl, stearic, polyoxyethylenated sorbitan acid having in particular from 2 to 30 moles of ethylene oxide, such as:
- polyoxyethylenated (4 EO) sorbitan monolaurate (POLYSORBATE-21),
- polyoxyethylenated (20 EO) sorbitan monolaurate (POLYSORBATE-20),
- polyoxyethylenated (20 EO) sorbitan monopalmitate (POLYSORBATE-40),
- polyoxyethylenated (20 EO) sorbitan monostearate (POLYSORBATE-60),
- polyoxyethylenated (4 EO) sorbitan monostearate (POLYSORBATE-61),
- polyoxyethylenated (20 EO) sorbitan monooleate (POLYSORBATE-80),
- polyoxyethylenated (5 EO) sorbitan monooleate (POLYSORBATE-81),
- polyoxyethylenated (20 EO) sorbitan tristearate (POLYSORBATE-65),
- polyoxyethylenated (20 EO) sorbitan trioleate (POLYSORBATE-85).

The polyoxyethylenated esters (in particular mono, di, tri, tetra esters) of C ₈ -C ₃₀ (preferably C ₁₂ -C ₁₈ ) fatty acids and of sorbitan, having in particular from 2 to 20 moles of ethylene, can be chosen from polyoxyethylenated esters having in particular from 2 to 20 moles of ethylene oxide, such as: C ₁₂ -C ₁₈ fatty acids, in particular lau-ric, myristic, cetyl, stearic acid, sorbitan, such as:
- the 20 EO polyoxyethylenated ester of sorbitan and cocoic acid (PEG-20 Sorbitan Cocoate)
- polyoxyethylenated esters (in particular having from to 2 to 20 EO) of sorbitan and of isostearic acid (such as PEG-2 Sorbitan Isostearate; PEG-5 Sorbitan Isostearate; PEG-20 Sorbitan Isostearate such as the product marketed under the denomination Nikkol TI 10 V by the Nikkol company),
- polyoxyethylenated esters (in particular having from 2 to 20 EO) of sorbitan and lauric acid (such as PEG-10 Sorbitan Laurate),
- polyoxyethylenated esters (in particular having from to 2 to 20 EO) of sorbitan and oleic acid with 10 oxyethylenated groups (such as PEG-6 Sorbitan Oleate; PEG-20 Sorbitan Oleate),
- polyoxyethylenated esters (in particular having 3 to 20 EO) of sorbitan and stea-ric acid (such as PEG-3 Sorbitan Stearate; PEG-4 Sorbitan Stearate; PEG-6 Sorbitan Stea-rate).

The nonionic surfactant(s) are preferably chosen from ethoxylated C ₈ -C ₂₄ fatty alcohols comprising from 1 to 200 ethylene oxide groups, ethoxylated C ₈ -C ₃₀ fatty acid esters of sorbitan having from 1 containing 30 ethylene oxide units, (C ₆ -C ₂₄ alkyl)polyglycosides, C ₈ to C ₃₀ fatty acid esters, in particular C ₈ -C ₂₄ , and preferably C ₁₆ - C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene, and mixtures thereof, better still from (C ₆ -C ₂₄ alkyl)polyglycosides, even better still from (C 6 -C ₆ -alkyl) C ₂₄ )polyglycosides such as: coco glucoside, caprylyl/capryl glucoside, lauryl glucoside, decyl glucoside and cetearyl glucoside.

The cationic surfactant(s) which can be used in the composition according to the invention are generally chosen from primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof.

The fatty amines generally comprise at least one C ₈ -C ₃₀ hydrocarbon chain. Among the fatty amines which can be used according to the invention, mention may be made, for example, of stearyl amidopropyl dimethylamine and distearylamine.

As quaternary ammonium salts, mention may in particular be made, for example:

- those corresponding to the general formula (X) next :
(X)
in which the groups R₈to R₁₁, which may be identical or different, represent an aliphatic group, linear or branched, comprising from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R₈to R₁₁comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms. The aliphatic groups can comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens.
The aliphatic groups are for example chosen from C1-C30 alkyl groups, C alkoxy groups₁-VS₃₀, polyoxyalkylene (C₂-VS₆), C-alkylamide₁-VS₃₀, alkyl(C₁₂-VS₂₂)amidoalkyl(C₂-VS₆), alkyl(C₁₂-VS₂₂)acetate, and hydroxy-C₁-VS₃₀,X ^- is an anion selected from the group consisting of halides, phosphates, acetates, lactates, alkyl(C₁-VS₄)sulfates, alkyl(C₁-VS₄)- or (C₁-VS₄)arylsulphonates.
Among the quaternary ammonium salts of formula (X), preference is given, on the one hand, to tetraalkylammonium chlorides such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group contains about 12 to 22 carbon atoms, in particular behenyltrimethylammonium, distearyldimethylammonium , cetyltrimethylammonium, benzyldimethylstearylammonium or, on the other hand, distearoylethylhydroxyethylmethylammonium methosulfate, dipalmitoylethylhydroxyethylammonium methosulfate or distearoylethylhydroxyethylammonium methosulfate, or, finally, palmitylamidopropyltrimethylammonium chloride or marketed stearamidopropyldimethyl-(myristylacetate)-ammonium chloride under the name CERAPHYL® 70 by the company VAN DYK.

- the quaternary ammonium salts of imidazoline, such as for example those of formula ( XI ) below:
(XI)
in which R12 represents an alkenyl or alkyl group having from 8 to 30 carbon atoms, for example derived from tallow fatty acids, R13 represents a hydrogen atom, a C ₁ -C ₄ alkyl group or an alkenyl or alkyl group containing from 8 to 30 carbon atoms, R14 represents a C ₁ -C ₄ alkyl group, R15 represents a hydrogen atom, a C ₁ -C ₄ alkyl group, X ^- is an anion chosen from the group of halides , phosphates, acetates, lactates, alkyl(C ₁ -C ₄ )sulfates, alkyl(C ₁ -C ₄ )- or alkyl(C ₁ -C ₄ )aryl sulfonates.
Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups comprising from 12 to 21 carbon atoms, for example derived from tallow fatty acids, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO.

- di- or tri-quaternary ammonium salts in particular of formula ( XII ) below:
( XII )
in which R16 denotes an alkyl group comprising approximately 16 to 30 carbon atoms optionally hydroxylated and/or interrupted by one or more oxygen atoms, R17 is chosen from hydrogen or an alkyl group comprising 1 to 4 carbon atoms or a -(CH2)3-N+(R16a)(R17a)(R18a), R16a, R17a, R18a, R18 , R19 , R20 and R21 group, which are identical or different, are chosen from hydrogen or an alkyl group comprising 1 to 4 carbon atoms, and X- is an anion selected from the group consisting of halides, acetates, phosphates, nitrates, alkyl(C1-C4)sulfates, alkyl(C1-C4)- or alkyl(C1-C4)aryl- sulfonates, in particular methyl sulfate and ethyl sulfate.
Such compounds are, for example, Finquat CT-P offered by the company FINETEX (Quaternium 89), Finquat CT offered by the company FINETEX (Quaternium 75).

- quaternary ammonium salts containing one or more ester functions, such as, for example, those of formula ( XIII ) below:
( XIII )
wherein: R22 is selected from C1-C6 alkyl groups and C1-C6 hydroxyalkyl or dihydroxyalkyl groups; R23 is chosen from: the –C(O)R26 group, C1-C22 hydrocarbon R27 groups, linear or branched, saturated or unsaturated, the hydrogen atom; R25 is chosen from: the –C(O)R28 group, C1-C6 hydrocarbon R29 groups, linear or branched, saturated or unsaturated, the hydrogen atom; R24, R26 and R28, which are identical or different, are chosen from C7-C21 hydrocarbon groups, linear or branched, saturated or unsaturated; r, s and t, identical or different, are integers ranging from 2 to 6; r1 and t1, identical or different, are 0 or 1; r2 + r1 = 2 r and t1 + t2 = 2 t, y is an integer ranging from 1 to 10, x and z, identical or different, are integers ranging from 0 to 10, X- is a simple or complex anion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 denotes R27 and that when z is 0 then R25 denotes R29.
The R22 alkyl groups can be linear or branched and more particularly linear.
Preferably, R22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group.
Advantageously, the sum x + y + z is from 1 to 10.
When R23 is a hydrocarbon R27 group, it can be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms.
When R25 is a hydrocarbon R29 group, it preferably has 1 to 3 carbon atoms.
Advantageously, R24, R26 and R28, identical or different, are chosen from C11-C21 hydrocarbon groups, linear or branched, saturated or unsaturated, and more particularly from C11-C21 alkyl and alkenyl groups, linear or branched, saturated. or unsaturated.
Preferably, x and z, identical or different, are worth 0 or 1.
Advantageously, y is equal to 1.
Preferably, r, s and t, which are identical or different, are equal to 2 or 3, and even more particularly are equal to 2.
The anion X- is preferably a halide, preferably chloride, bromide or iodide, an alkyl (C1-C4) sulphate, alkyl (C1-C4)- or alkyl (C1-C4) aryl-sulphonate. It is however possible to use methanesulfonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function.
The anion X − is even more particularly chloride, methyl sulphate or ethyl sulphate.
The ammonium salts of formula (XIII) in which: R ₂₂ denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, are more particularly used in the composition according to the invention, r, s and t are equal to 2; R ₂₃ is chosen from: the –C(O)R ₂₆ group, methyl, ethyl or C ₁₄ -C ₂₂ hydrocarbon groups, the hydrogen atom, R ₂₅ is chosen from: the –C(O) group R28, the hydrogen atom, R24, _R26 and R28, identical or different, are chosen from C ₁₃ -C ₁₇ hydrocarbon groups _, linear or branched _, saturated or unsaturated, and preferably from alkyl groups and C ₁₃ -C ₁₇ alkenyl, linear or branched, saturated or unsaturated.
Advantageously, the hydrocarbon groups are linear.
Mention may be made, for example, among the compounds of formula (XIII) of the salts, in particular the chloride or the methyl sulphate of diacyloxyethyldimethylammonium, of diacyloxyethylhydroxyethyl methylammonium, of monoacyloxyethyldihydroxyethylmethylammonium, of triacyloxyethylmethylammonium, of monoacyloxyethylhydroxyethyldimethylammonium, and mixtures thereof. The acyl groups preferably have 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm or sunflower oil. When the compound contains several acyl groups, the latter may be the same or different.
These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or optionally oxyalkylenated alkyldiisopropanolamine on fatty acids or on mixtures of fatty acids of vegetable or animal origin, or by transesterification of their methyl esters. This esterification is followed by quaternization using an alkylating agent, such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulfate, preferably methyl or ethyl, methyl methanesulfonate, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin.
Such compounds are for example marketed under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.
The composition according to the invention may contain, for example, a mixture of mono-, di- and triester quaternary ammonium salts with a majority by weight of diester salts.
It is also possible to use the ammonium salts containing at least one ester function described in patents US-A-4874554 and US-A-4137180.
It is also possible to use behenoylhydroxypropyltrimethylammonium chloride, for example, offered by the company KAO under the name Quartamin BTC 131.
Preferably, the ammonium salts containing at least one ester function contain two ester functions.
Among the cationic surfactants, it is more particularly preferred to choose cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethylhydroxyethylmethylammonium salts, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof.

Preferably, the surfactant(s) are chosen from anionic surfactants, nonionic surfactants and mixtures thereof, preferably from alkyl sulphates, alkyl ether sulphates, fatty acids, ethoxylated C ₈ -C ₂₄ fatty alcohols comprising from 1 to 200 ethylene oxide groups, ethoxylated C ₈ -C ₃₀ fatty acid esters of sorbitan having from 1 to 30 ethylene oxide units, (C ₆ -C ₂₄ alkyl)polyglycosides, esters of fatty acid C ₈ to C ₃₀ , in particular C ₈ -C ₂₄ , and preferably C ₁₆ -C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene, and mixtures thereof .

More preferentially, the surfactant(s) are chosen from alkyl sulphates, alkyl ether sulphates, ethoxylated C ₈ -C ₂₄ fatty alcohols comprising from 1 to 200 ethylene oxide groups, (C ₆ -C ₂₄ alkyl) polyglycosides, as well as mixtures thereof.

Preferably, the composition also comprises one or more surfactants, preferably chosen from anionic and nonionic surfactants and mixtures thereof, more preferably one or more nonionic surfactants.

When the composition comprises one or more surfactants, in particular chosen from anionic and nonionic surfactants and mixtures thereof, preferably, the total content of surfactant(s) in the composition preferably varies from 0.01 to 15% by weight. , more preferably from 0.1 to 10% by weight, better still from 0.5 to 8% by weight, even better still from 1 to 6% by weight relative to the total weight of the composition.

When the composition comprises one or more surfactants chosen from alkyl sulphates, alkyl ether sulphates, fatty acids, ethoxylated C ₈ -C ₂₄ fatty alcohols comprising from 1 to 200 ethylene oxide groups, (C ₆ - C ₂₄ ) polyglycosides, preferably, the total content of surfactants in the composition preferably varies from 0.01 to 15% by weight, more preferably from 0.1 to 10% by weight, better still from 0.4 to 8% by weight, even better from 1 to 6% by weight relative to the total weight of the composition.

Thickening agent
The composition according to the present invention may comprise one or more thickening agents .

Preferably, the composition according to the present invention comprises one or more thickening agents.

Within the meaning of the present invention, thickening agent means an agent which, by its presence in the composition, makes it possible to increase the viscosity of said composition from at least 10 cPs, preferably by at least 200 cPs, to 25 °C and at a shear rate of 1s ^-1 . This viscosity can be measured using a cone/plane viscometer (Haake R600 rheometer or the like).

The thickening agent(s) may, in particular, be chosen from sodium chloride, fatty acid amides obtained from C ₁₀ -C ₃₀ carboxylic acid (monoisopropanol-, diethanol- or monoethanol-amide of copra, monoethanolamide of oxyethylenated alkyl ether carboxylic acid), thickening polymers chosen in particular from polysaccharides such as cellulose polymers (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), guar gum and its nonionic derivatives (hydroxypropylguar), gums microbial origin (xanthan gum, scleroglucan gum), crosslinked or non-crosslinked homo- and copolymers based on acrylic acid, methacrylic acid or acrylamidopropanesulfonic acid and mixtures thereof.

According to a preferred embodiment, the thickening agent is chosen from thickening polysaccharides, preferably guar gums.

The guar gums that can be used according to the invention can be nonionic or cationic.

According to the invention, chemically modified or unmodified nonionic guar gums can be used.

Unmodified nonionic guar gums are, for example, the products sold under the name VIDOGUM GH 175 by the company UNIPECTINE and under the names MEYPRO-GUAR 50 and JAGUAR C by the company RHODIA CHIMIE.

The modified nonionic guar gums that can be used according to the invention are preferably modified with C1-C6 hydroxyalkyl groups.

Among the hydroxyalkyl groups, mention may be made, by way of example, of the hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups.

These guar gums are well known in the state of the art and can for example be prepared by reacting corresponding alkene oxides, such as for example propylene oxides, with guar gum so as to obtain a gum guar modified with hydroxypropyl groups.

The hydroxyalkylation rate, which corresponds to the number of molecules of alkylene oxide consumed by the number of free hydroxyl functions present on the guar gum, preferably varies from 0.4 to 1.2.

Such non-ionic guar gums optionally modified with hydroxyalkyl groups are for example sold under the trade names JAGUAR HP8, JAGUAR HP60 and JAGUAR HP120, JAGUAR DC 293 and JAGUAR HP 105 by the company MEYHALL, or under the name GALACTASOL 4H4FD2 by the company AQUALON.

Also suitable are non-ionic guar gums modified with hydroxyalkyl, more especially hydroxypropyl, groups modified with groups comprising at least one C ₆ -C ₃₀ fatty chain. By way of example of such compounds, mention may be made, inter alia, of the product ESAFLOR HM 22® (C ₂₂ alkyl chain) sold by the company LAMBERTI, the products RE210-18® (C ₁₄ alkyl chain) and RE205- 1® (C ₂₀ alkyl chain) sold by RHONE POULENC.

Preferably, a nonionic guar gum is used and, among these nonionic guar gums, more particularly guar gums modified with hydroxyalkyl groups.

According to one embodiment, the thickening polysaccharides are chosen from anionic polysaccharides.

By “ polysaccharides ” is meant polymers which contain at least 11 monosaccharide units. Preferably, the polysaccharides of the invention comprise between 20 and 100,000 monosaccharide units.

The anionic polysaccharides according to the invention comprise one or more anionic or anionizable groups, and do not comprise a cationic or cationizable group.

The anionic polysaccharides useful according to the invention can be chosen from those derived from the following sugars: glucose; galactose; arabinose; rhamnose; mannose; xylose; fucose; anhydrogalactose; galacturonic acid; glucuronic acid; mannuronic acid; galactose sulphate; anhydrogalactose sulphate.

The polymers with sugar units of the invention can be natural or synthetic.

According to a particular embodiment, the anionic polysaccharides useful according to the invention are chosen from native gums such as:
• tree or shrub exudates including: gum arabic (branched polymer of galactose, arabinose, rhamnose and glucuronic acid); ghatti gum (polymer derived from arabinose, galactose, mannose, xylose and glucuronic acid); karaya gum (polymer derived from galacturonic acid, galactose, rhamnose and glucuronic acid); tragacanth (or tragacanth) gum (polymer of galacturonic acid, galactose, fucose, xylose and arabinose);
• gums from algae such as: alginates (polymers of mannuronic acid and glucuronic acid); carrageenans and furcellerans (polymers of galactose sulphate and anhydrogalactose sulphate);
• microbial gums such as: xanthan gums (polymer of glucose, mannose acetate, mannose/pyruvic acid and glucuronic acid); gellan gums (polymer of partially acylated glucose, rhamnose and glucuronic acid).

Within the meaning of the present invention, the term " microbial gums " means substances synthesized by fermentation of sugars by microorganisms.

According to a preferred embodiment, the anionic polysaccharides useful according to the invention are chosen from anionic gums, better still from anionic microbial gums, more preferably from xanthan gums .

When they are present, the total content of thickening agents preferably varies from 0.01% to 10% by weight relative to the total weight of the composition, preferably from 0.05 to 8% by weight, better still 0.1 to 5% by weight relative to the total weight of the composition.

When they are present, the total content of thickening polysaccharides as defined above preferably varies from 0.01% to 10% by weight relative to the total weight of the composition, preferably from 0.05 to 8% by weight, better still from 0.1 to 5% by weight relative to the total weight of the composition.

The total content of microbial gums as defined above, when present, preferably varies from 0.01% to 10% by weight relative to the total weight of the composition, preferably from 0.05 to 5% by weight, better still from 0.1 to 2% by weight relative to the total weight of the composition.

The total content of guar gums as defined above, when they are present, preferably varies from 0.01% to 10% by weight relative to the total weight of the composition, preferably from 0.05 to 5 % by weight, better still from 0.1 to 2% by weight relative to the total weight of the composition

Sequestrants
The composition according to the invention may comprise at least one sequestering (or chelating) agent.

The definition of a “sequestering agent” (or “chelating agent”) is well known to those skilled in the art and refers to a compound or a mixture of compounds capable of forming a chelate with a metal ion. A chelate is an inorganic complex in which a compound (the sequestering or chelating agent) is coordinated with a metal ion, i.e. it forms one or more bonds with the metal ion (formation of a cycle including the metal ion).

A sequestering (or chelating) agent generally comprises at least two electron donor atoms which allow the formation of bonds with the metal ion.

In the context of the present invention, the sequestering agent(s) can be chosen from carboxylic acids, preferably aminocarboxylic acids, phosphonic acids, preferably aminophosphonic acids, polyphosphoric acids, preferably linear polyphosphoric acids, their salts and derivatives.

The salts include alkali metal, alkaline earth, ammonium and substituted ammonium salts.

Examples of chelating agents based on carboxylic acids include the following compounds: diethylenetriamine pentaacetic acid (DTPA), ethylenediamine disuccinic acid (EDDS) and trisodium ethylenediamine disuccinate such as Octaquest E30 from OCTEL, ethylenediaminetetraacetic acid (EDTA ), and its salts such as disodium EDTA, tetrasodium EDTA, ethylenediamine-N,N'-diglutaric acid (EDDG), glycinamide-N,N'-disuccinic acid (GADS), glycinamide-N,N'-disuccinic acid (GADS ), 2-hydroxypropylenediamine-N,N'-disuccinic acid (HPDDS), ethylenediamine-N-N'-bis(ortho-hydroxyphenyl acetic acid) (EDDHA), N,N'-bis(2-hydroxybenzyl)ethylenediamine- N,N'-diacetic acid (HBED), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA), N-2-hydroxyethyl N,N diacetic acid and glyceryl imino diacetic acid (as described in EP- A-317,542 and EP-A-399,133), iminodiacetic acid-N-2-hydroxypropyl sulfonic acid and aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid d (as described in EP-A-516,102), beta-alanine-N,N'-diacetic acid, aspartic acid-N,N'-diacetic acid, aspartic acid-N-monoacetic acid (described in EP-A -509,382), chelating agents based on iminodisuccinic acids (IDSA) (as described in EP-A-509,382), ethanoldiglycine acid, phophonobutane tricarboxylic acid such as the compound sold by Bayer under the reference Bayhibit AM, the N,N-dicarboxymethyl glutamic acid and its salts such as tetrasodium glutamate diacetate (GLDA) such as Dissolvine GL38 or 45S from Akzo Nobel.

Examples of chelating agents based on mono or polyphosphonic acid include the following compounds: diethylenetriamine-penta (methylene phosphonic acid) (DTPMP), ethane-1-hydroxy-1,1,2-triphosphonic acid ( E1HTP), ethane-2-hydroxy-1,1,2-triphosphonic acid (E2HTP), ethane-1-hydroxy-1,1-triphosphonic acid (EHDP), ethan-1,1,2-triphosphonic acid (ETP) , ethylenediaminetetramethylene phosphonic acid (EDTMP), hydroxyethane-1,1 diphosphonic acid (HEDP, or etidronic acid)., and salts such as disodium etidronate, tetrasodium etidronate.

By way of example of chelating agents based on polyphosphoric acid, the following compounds may be mentioned: sodium tripolyphosphate (STP), tetrasodium diphosphate, hexametaphophoric acid, sodium metaphosphate, phytic acid.

According to one embodiment, the sequestering agent(s) useful according to the invention are phosphorus sequestering agents, that is to say sequestering agents which comprise one or more phosphorus atoms, preferably at least two phosphorus atoms.

The phosphorus sequestering agent(s) used in the composition according to the invention are preferably chosen from:
- inorganic phosphorus derivatives preferably chosen from alkali or alkaline-earth metal phosphates and pyrophosphates, preferably alkali metals such as sodium pyrophosphate, potassium pyrophosphate, sodium pyrophosphate decahydrate; and polyphosphates of alkali or alkaline-earth metals, preferably of alkali metals, such as sodium hexametaphosphate, sodium polyphosphate, sodium tripolyphosphate, sodium trimetaphosphate; optionally hydrated, and mixtures thereof;
- organic phosphorus derivatives, such as organic (poly)phosphates and (poly)phosphonates, such as etidronic acid and/or its alkali or alkaline-earth metal salts such as tetrasodium etidronate, disodium etidronate and mixtures thereof.

Preferably, the phosphorus sequestering agent(s) is (are) chosen from linear or cyclic compounds comprising at least two phosphorus atoms bonded together covalently by at least one linker L comprising at least one oxygen atom and/or at least one carbon atom.

The phosphorus sequestering agent(s) may be chosen from inorganic phosphorus derivatives, preferably comprising at least 2 phosphorus atoms. More preferably, the phosphorus sequestrant(s) is (are) chosen from alkali metal or alkaline-earth metal pyrophosphates, better still from alkali metal pyrophosphates, in particular sodium pyrophosphate (also called tetrasodium pyrophosphate).

The phosphorus sequestering agent(s) may be chosen from organic phosphorus derivatives, preferably comprising at least 2 phosphorus atoms. More preferentially, the phosphorus sequestrant(s) is (are) chosen from etidronic acid (also called 1-hydroxyethane 1,1-diphosphonic acid) and/or its alkali or alkaline metal salts. -earth metals, preferably alkali metals such as tetrasodium etidronate and disodium etidronate.

Thus, preferably, the phosphorus sequestering agent(s) are chosen from alkali metal pyrophosphates, etidronic acid and/or its alkali metal salts, and a mixture of these compounds.

Particularly preferably, the phosphorus sequestering agent(s) are chosen from tetrasodium etidronate, disodium etidronate, etidronic acid, tetrasodium pyrophosphate and a mixture of these compounds.

According to the present invention, the sequestering agents are preferably chosen from diethylenetriaminepentaacetic acid (DTPA) and its salts, diethylenediaminetetraacetic acid (EDTA) and its salts, ethylenediamine disuccinic acid (EDDS) and its salts, etidronic acid and its salts, N,N-dicarboxymethyl glutamic acid and its salts (GLDA) and mixtures thereof.

More preferentially, the sequestering agent(s) are chosen from N,N-dicarboxymethyl glutamic acid and its salts (GLDA) and mixtures thereof.

Among the salts of these compounds, the alkali metal salts, and in particular the sodium or potassium salts, are preferred.

When the composition comprises one or more sequestrants, the total content of the sequestrant(s) preferably varies from 0.001 to 15% by weight, more preferably from 0.005 to 10% by weight, better still from 0.01 to 8% by weight. weight, even better from 0.05 to 5% by weight relative to the total weight of the composition.

Solvents
The composition according to the invention may also comprise at least one organic solvent other than propane-1,3-diol.

As an organic solvent, mention may be made, for example, of alkanols, linear or branched, C ₂ to C ₄ , such as ethanol, propanol and isopropanol, polyols different from propane-1,3-diol and polyol ethers such as 2-butoxyethanol, dipropylene glycol, propylene glycol monomethyl ether, glycerol, diethylene glycol monoethyl ether and diethylene glycol monomethyl ether, as well as aromatic alcohols or ethers such as benzyl alcohol or phenoxyethanol, and mixtures thereof.

The organic solvent(s) may be present in an amount ranging from 0.01 to 30% by weight, preferably ranging from 2 to 25% by weight, relative to the total weight of the composition.

Furthermore, preferably, the composition according to the invention is an aqueous composition. Preferably, the composition comprises water in an amount greater than or equal to 5% by weight, preferably greater than or equal to 10% by weight, by weight relative to the total weight of the composition.

Preferably, the water content ranges from 15 to 80% by weight, preferentially from 30 to 70% by weight, better still from 40 to 60% by weight.

Chemical oxidizing agents
The composition according to the invention may optionally also comprise one or more chemical oxidizing agents.

According to a particular embodiment, the composition according to the invention comprises one or more chemical oxidizing agents.

According to another particular embodiment, the composition according to the invention does not comprise chemical oxidizing agents.

According to this embodiment, the composition according to the invention is preferably mixed at the time of use with at least one composition comprising one or more chemical oxidizing agents.

By “chemical oxidizing agent” is meant, within the meaning of the present invention, an oxidizing agent different from the oxygen in the air.

The chemical oxidizing agent(s) (or bleaching agents) that can be used in the present invention can be chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, persalts such as perborates and persulfates, in particular sodium persulphate, potassium persulphate and ammonium persulphate, peracids and oxidase enzymes (with their possible cofactors) among which mention may be made of peroxidases, 2-electron oxidoreductases such as uricases and 4-electron oxygenases such as laccases, and mixtures thereof; more preferably, the chemical oxidizing agent(s) are chosen from hydrogen peroxide, persalts, and mixtures thereof, more preferably hydrogen peroxide.

Preferably, when they are present in the composition according to the invention, the chemical oxidizing agent(s) are present in a total content ranging from 0.1 to 35% by weight, more preferably from 0.5 to 25% by weight. , more preferably still from 1 to 15% by weight, relative to the weight of the composition.

According to a preferred embodiment, when they are present in the composition according to the invention, the chemical oxidizing agent(s) chosen from hydrogen peroxide, persalts, and mixtures thereof are present in a total content ranging from 0, 1 to 35% by weight, more preferably from 0.5 to 25% by weight, more preferably still from 1 to 15% by weight, relative to the weight of the composition.

Additives
The composition according to the invention may contain any adjuvant or additive usually used other than the compounds described previously.
Among the additives likely to be contained in the composition according to the invention, mention may be made of reducing agents, softeners, anti-foaming agents, moisturizing agents, UV filters, peptizers, solubilizers, perfumes, anionic, cationic, non-ionic, amphoteric polymers different from the thickening polymers described above, anti-dandruff agents, antiseborrheic agents, vitamins and pro-vitamins including panthenol, sun filters, plasticizers, solubilizing agents, acidifying agents , mineral thickeners, antioxidants, hydroxy acids, fragrances, and preservatives.
Of course, those skilled in the art will take care to choose this or these possible additional compounds in such a way that the advantageous properties inherently attached to the composition according to the invention are not, or substantially not, altered by the addition(s) envisaged. .
The above additives may generally be present in an amount comprised for each of them between 0 and 20% by weight, relative to the total weight of the composition.

Process
The present invention also relates to a process for dyeing and/or lightening keratin fibres, in particular human keratin fibers such as the hair, in which is applied to said fibers a composition comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more alkaline agents and/or one or more dyes.

In particular, the present invention also relates to a process for dyeing keratin fibres, in particular human keratin fibers such as the hair, in which is applied to said fibers a composition comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more dyes,
- optionally one or more alkaline agents.

In other words, the coloring process comprises at least the application of a composition according to the invention comprising one or more dyes. The dye(s) can be chosen from oxidation dyes, direct dyes and mixtures thereof, preferably chosen from oxidation dyes.

Preferably, the composition according to the invention comprises one or more surfactants as defined above, preferably chosen from anionic and nonionic surfactants and mixtures thereof.

In particular, the coloring process comprises at least one step of applying a composition as defined previously.

Preferably, the composition according to the invention is a composition for coloring keratin fibres, such as the hair. Thus, preferably, the composition according to the invention comprises one or more dyes chosen from oxidation dyes, direct dyes and their mixtures as described previously.

Preferably, the dyeing process comprises at least the application to said keratin fibers of at least one composition according to the invention comprising one or more dyes chosen from oxidation dyes, direct dyes and mixtures thereof, in the presence of one or more chemical oxidizing agents, as defined above, preferably hydrogen peroxide.

Preferably, the coloring process comprises at least the application of a composition according to the invention comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more surfactants, preferably chosen from anionic and nonionic surfactants and mixtures thereof,
- one or more dyes, as defined above,
- optionally one or more alkaline agents, as defined above,
- one or more oxidizing agents as defined above, preferably hydrogen peroxide.

According to a particular embodiment, the coloring and/or lightening process comprises at least the application to said fibers of a composition obtained by mixing at the time of use:

• at least one composition, as defined above, comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more alkaline agents, as defined above and/or one or more dyes, as defined above,
• at least one composition comprising one or more chemical oxidizing agents as described above, preferably hydrogen peroxide

According to a particular embodiment, the coloring process comprises at least the application to said fibers of a composition obtained by mixing at the time of use:

• at least one composition, as defined above, comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more dyes, as defined above,
- optionally one or more alkaline agents, as defined above,
• at least one composition comprising one or more chemical oxidizing agents as described above, preferably hydrogen peroxide.

The oxidizing composition is preferably an aqueous composition. In particular, it comprises more than 5% by weight of water, preferably more than 10% by weight of water, and even more advantageously more than 20% by weight of water.

The oxidizing composition also preferably comprises one or more acidifying agents. Among the acidifying agents, mention may be made, by way of example, of mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, lactic acid, sulphonic acids.

In addition, the oxidizing composition may comprise fatty substances such as those described above, preferably chosen from fatty alcohols, liquid hydrocarbons comprising more than 16 carbon atoms and their mixtures, surfactants, polymers.

Usually, the pH of the oxidizing composition, when it is aqueous, is less than 7.

Preferably, the oxidizing composition comprises hydrogen peroxide as oxidizing agent, in aqueous solution, the concentration of which varies, more particularly, from 0.1 to 30% by weight, more particularly from 1 to 20%, and even more preferably from 2 to 15% by weight relative to the weight of the oxidizing composition.

The present invention also relates to the use of the composition according to the invention as described above for coloring and/or lightening, preferably coloring keratin fibres, in particular human keratin fibers such as the hair.

The composition according to the invention can be applied to dry or wet keratin fibres, as well as to all types of fibres, light or dark, natural or colored, permed, bleached or straightened.

According to a particular embodiment of the method of the invention, the fibers are washed before application of the composition described above.

The composition of the invention can be applied to the keratin fibers by any conventional means, in particular by means of a comb, a brush or a brush.

The dyeing process, i.e. application of the dye composition to the keratin fibres, is generally carried out at ambient temperature (between 15 to 25°C).

The composition according to the invention can be applied to the keratin fibers according to an exposure time ranging from 30 to 60 minutes.

After application of the composition according to the invention, the keratin fibers can optionally undergo washing with a shampoo and/or be rinsed with water.

The present invention also relates to the use of the composition according to the invention as described above, preferably comprising at least one dye chosen from oxidation dyes, direct dyes and mixtures thereof, for dyeing keratin fibres, in in particular human keratin fibers such as the hair.

The present invention also relates to a ready-to-use composition, as defined above, comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more alkaline agents, as defined above and/or one or more dyes, as defined above,
- one or more chemical oxidizing agents as defined above, preferably hydrogen peroxide.

The present invention also relates to a ready-to-use composition, as defined above, comprising:
- one or more fatty substances other than fatty acids, in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propan-1,3-diol,
- one or more dyes, as defined above,
- optionally one or more alkaline agents, as defined above,
- one or more chemical oxidizing agents as defined above, preferably hydrogen peroxide.

The invention further relates to a multi-compartment device comprising at least a first compartment containing the composition according to the invention as described above and at least a second compartment containing one or more oxidizing agents as described above, preferably hydrogen peroxide.

The following examples serve to illustrate the invention without, however, being of a limiting nature.

Examples
Composition A2 and comparative compositions A1 and A3 were prepared from the ingredients described in the following table:

Layout A1 Composition A2 (invention) Layout A3 Ascorbic acid 0.12 0.12 0.12 Glycerin 5 5 5 Propylene glycol 2.5 - - Propane-1,3-diol - 2.5 - EDTA 0.2 0.2 0.2 Toluene-2,5-diamine 0.762 0.762 0.762 C20-C22 alcohols 4.6 4.6 4.6 Resorcinol 0.67 0.67 0.67 Ethanolamine 4.28 4.28 4.28 m-aminophenol 0.12 0.12 0.12 Sodium metabisulphite 0.22 0.22 0.22 Mineral oil 60 60 60 Carbomer 0.1 0.1 0.1 Oleth-10 1 1 1 Hydroxybenzomorpholine 0.033 0.033 0.033 2,4-diaminophenoxyethanol HCl 0.02 0.02 0.02 Deceth-5 1.08 1.08 1.08 Cetyl Palmitate 2 2 2 Ceteareth-60 myristyl glycol 0.01 0.01 0.01 Oleth-20 4 4 4 Water Qs 100 Qs 100 Qs 100

At the time of use, each of the compositions A1 to A3 is mixed with 1 times its weight of oxidant C1 (g%).

Composition C Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerin 0.5 Tetrasodium EDTA 0.00025 Cetearyl alcohol 6 Hexadimethrine chloride 0.15 Phosphoric acid Qs pH = 2.2 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0.03 Mineral oil 20 PEG-4 rapeseedamide 1.2 Steareth-20 5 Water Qs 100

Each of the mixtures is then applied to locks of 90% white natural hair, at the rate of 10 grams of mixture per g of hair.

After 35 minutes of pause on a plate thermostated at a temperature of 27° C., the hair is rinsed, washed with a standard shampoo and dried.

The colorimetric measurements were carried out using a Konica Minolta CM-3600A spectrocolorimeter (illuminant D65, angle 10°, specular components included) in the CIELab system.

L* represents lightness: the lower the value of L*, the more powerful the coloration obtained.

Power L*

Composition A1 A2 (invention) A3 I* 29.30 27.12 32.67

The composition according to the invention A2 comprising 1,3-propandediol leads to a lower L* value, therefore to a more powerful, intense coloring compared to the comparative compositions A1 and A3 comprising propylene glycol or without 1,3-propandediol respectively.

Claims (14)

Composition comprising:
- one or more fatty substances other than fatty acids in a content greater than or equal to 20% by weight relative to the total weight of the composition,
- propane-1,3-diol,
- one or more alkaline agents and/or one or more dyes. Composition according to Claim 1, characterized in that the fatty substances other than fatty acids are chosen from liquid fatty substances, solid fatty substances and mixtures thereof; preferably from liquid fatty substances. Composition according to Claim 1 or 2, characterized in that the fatty substances other than fatty acids are liquid fatty substances chosen from liquid C ₆ to C ₁₆ hydrocarbons, liquid hydrocarbons comprising more than 16 carbon atoms, oils not silicones of animal origin, oils of the triglyceride type of vegetable or synthetic origin, fluorinated oils, liquid fatty alcohols, liquid esters of fatty acids and/or fatty alcohols other than triglycerides, silicone oils, and mixtures thereof, preferably from liquid hydrocarbons comprising more than 16 carbon atoms, preferably petroleum jelly. Composition according to any one of the preceding claims, characterized in that the content of fatty substances other than fatty acids is greater than or equal to 30% by weight, preferably greater than or equal to 40% by weight, more preferably greater than or equal to 50% by weight, relative to the total weight of the composition. Composition according to any one of the preceding claims, characterized in that the total propane-1,3-diol content varies from 0.5 to 15% by weight, preferably from 1 to 10% by weight, preferably varies from 2 to 8% by weight, more preferably from 2.5 to 6% by weight, relative to the total weight of the composition. Composition according to any one of the preceding claims, characterized in that it comprises one or more alkaline agents, preferably chosen from alkanolamines such as monoethanolamine, diethanolamine, triethanolamine; ammonia, carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali or alkaline earth metal silicates or metasilicates such as sodium metasilicate and mixtures thereof, plus preferentially from ammonia, alkanolamines, silicates or metasilicates of alkali metals or alkaline earth metals, better still from alkanolamines and silicates or metasilicates of alkali metals or alkaline earth metals, better still from monoethanolamine and sodium metasilicate, better still monoethanolamine . Composition according to any one of the preceding claims, characterized in that it comprises one or more dyes chosen from oxidation dyes, direct dyes and mixtures thereof, preferably oxidation dyes, preferably from bases of oxidation possibly associated with one or more couplers. Composition according to any one of the preceding claims, characterized in that it additionally comprises one or more surfactants, preferably chosen from anionic and nonionic surfactants, and mixtures thereof. Composition according to any one of the preceding claims, characterized in that the surfactants are nonionic surfactants, preferably chosen from:
- oxyalkylenated (C ₈ -C ₂₄ )alkylphenols;
- C ₈ to C ₄₀ alcohols, saturated or not, linear or branched, oxyalkylenated or glycerolated, they preferably contain one or two fatty chains;
- C ₈ to C ₃₀ fatty acid amides, saturated or not, linear or branched, oxyalkylenated;
- esters of C ₈ to C ₃₀ acids, saturated or not, linear or branched, and of polyethylene glycols;
- esters of C ₈ to C ₃₀ acids, saturated or not, linear or branched, and of sorbitol, preferably oxyethylenated;
- fatty acid esters, in particular C ₈ -C ₂₄ , and preferably Ci ₆ -C ₂₂ , and (poly)oxyalkylenated glycerol ethers, in particular oxyethylenated and/or oxypropylene
- esters of fatty acids and sucrose,
- (C ₈ -C ₃₀ )alkyl (poly)glucosides, (C ₈ -C ₃₀ )alkenyl (poly)glucosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising from 1 to 15 glucose units, esters of (C ₈ -C ₃₀ )alkyl (poly)glucosides,
- oxyethylenated vegetable oils, saturated or not;
- ethylene oxide and/or propylene oxide condensates;
- derivatives of N -alkyl (C ₈ -C ₃₀ )glucamine and of N -acyl (C ₈ -C ₃₀ )-methylglucamine;
- amine oxides,
- and mixtures thereof. Composition according to any one of the preceding claims, characterized in that it comprises one or more chemical oxidizing agents, preferably chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, persalts such as perborates and persulphates, peracids and oxidase enzymes (with their possible cofactors), and mixtures thereof; preferably, the chemical oxidizing agent(s) are chosen from hydrogen peroxide, persalts, and mixtures thereof; more preferably hydrogen peroxide. Process for dyeing and/or lightening keratin fibres, in particular human keratin fibers such as the hair, comprising the application to the said fibers of a composition as defined according to any one of Claims 1 to 10. Process according to Claim 11, characterized in that it comprises at least the application to the said fibers of a composition obtained by mixing at the time of use:
• at least one composition as defined according to any one of claims 1 to 9,
• at least one composition comprising one or more chemical oxidizing agents as defined according to claim 10. Use of a composition according to any one of Claims 1 to 10 for coloring and/or lightening, preferably coloring keratin fibres, in particular human keratin fibers such as the hair. Device with several compartments comprising at least a first compartment containing the composition as defined according to any one of Claims 1 to 9 and at least a second compartment containing a composition comprising one or more chemical oxidizing agents as defined according to Claim 10.