FR3116532B1 - Procede ameliore de recyclage de pet par methanolyse - Google Patents
Procede ameliore de recyclage de pet par methanolyse Download PDFInfo
- Publication number
- FR3116532B1 FR3116532B1 FR2012085A FR2012085A FR3116532B1 FR 3116532 B1 FR3116532 B1 FR 3116532B1 FR 2012085 A FR2012085 A FR 2012085A FR 2012085 A FR2012085 A FR 2012085A FR 3116532 B1 FR3116532 B1 FR 3116532B1
- Authority
- FR
- France
- Prior art keywords
- pet
- recycling
- methanolysis
- relates
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004064 recycling Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000006140 methanolysis reaction Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 abstract 2
- 229920003023 plastic Polymers 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine group Chemical group NC(=N)N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000007530 organic bases Chemical class 0.000 abstract 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/28—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/14—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with steam or water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La présente invention a trait au domaine du recyclage des plastiques de type PET couramment utilisés pour la fabrication de bouteilles en plastiques jetables, barquettes alimentaires, textile... Plus particulièrement, elle concerne un procédé permettant le recyclage du PET en dimethyl téréphtalate ou téréphtalate de diméthyle (DMT) en quelques heures (moins de 5h) par la mise en œuvre d’une réaction complète résultant en un produit dénué d’impuretés. L’étape de dépolymérisation a lieu en présence de méthanol, ainsi que d’une base organique à motif guanidine et d’une deuxième base qui peut être soit inorganique, soit un éther oxyde. Ces deux bases sont présentes en quantités catalytiques par rapport à la quantité de PET à traiter.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2012085A FR3116532B1 (fr) | 2020-11-24 | 2020-11-24 | Procede ameliore de recyclage de pet par methanolyse |
JP2023531578A JP2023553315A (ja) | 2020-11-24 | 2021-11-24 | アルコール分解によってペットをリサイクルするための改良された方法 |
PCT/FR2021/052085 WO2022112715A1 (fr) | 2020-11-24 | 2021-11-24 | Procede ameliore de recyclage de pet par alcoolyse |
US18/253,439 US20230399485A1 (en) | 2020-11-24 | 2021-11-24 | Improved method for recycling pet by alcoholysis |
CA3199380A CA3199380A1 (fr) | 2020-11-24 | 2021-11-24 | Procede ameliore de recyclage de pet par alcoolyse |
EP21823983.8A EP4251603A1 (fr) | 2020-11-24 | 2021-11-24 | Procede ameliore de recyclage de pet par alcoolyse |
CN202180078952.3A CN116685572A (zh) | 2020-11-24 | 2021-11-24 | 通过醇解法回收pet的改进方法 |
KR1020237021316A KR20230129010A (ko) | 2020-11-24 | 2021-11-24 | 알코올 분해에 의한 pet를 재활용하는 개선된 방법 |
ZA2023/05504A ZA202305504B (en) | 2020-11-24 | 2023-05-22 | Improved method for recycling pet by alcoholysis |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2012085A FR3116532B1 (fr) | 2020-11-24 | 2020-11-24 | Procede ameliore de recyclage de pet par methanolyse |
FR2012085 | 2020-11-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3116532A1 FR3116532A1 (fr) | 2022-05-27 |
FR3116532B1 true FR3116532B1 (fr) | 2022-10-28 |
Family
ID=74095899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2012085A Active FR3116532B1 (fr) | 2020-11-24 | 2020-11-24 | Procede ameliore de recyclage de pet par methanolyse |
Country Status (9)
Country | Link |
---|---|
US (1) | US20230399485A1 (fr) |
EP (1) | EP4251603A1 (fr) |
JP (1) | JP2023553315A (fr) |
KR (1) | KR20230129010A (fr) |
CN (1) | CN116685572A (fr) |
CA (1) | CA3199380A1 (fr) |
FR (1) | FR3116532B1 (fr) |
WO (1) | WO2022112715A1 (fr) |
ZA (1) | ZA202305504B (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114890892B (zh) * | 2022-06-04 | 2023-09-15 | 浙江理工大学 | 一种降膜流动醇解聚酯的方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8541477B2 (en) | 2011-03-04 | 2013-09-24 | International Business Machines Corporation | Methods of depolymerizing terephthalate polyesters |
US10252976B1 (en) | 2017-09-15 | 2019-04-09 | 9449710 Canada Inc. | Terephthalic acid esters formation |
CN117326941A (zh) | 2018-06-25 | 2024-01-02 | 9449710加拿大公司 | 对苯二甲酸酯的形成 |
FR3089983B1 (fr) | 2018-12-18 | 2021-11-05 | Raouf Medimagh | Procédé de recyclage de déchets de plastiques PET |
US11248103B2 (en) | 2019-03-20 | 2022-02-15 | 9449710 Canada Inc. | Process for the depolymerization of polyethylene terephthalate (PET) |
-
2020
- 2020-11-24 FR FR2012085A patent/FR3116532B1/fr active Active
-
2021
- 2021-11-24 US US18/253,439 patent/US20230399485A1/en active Pending
- 2021-11-24 KR KR1020237021316A patent/KR20230129010A/ko unknown
- 2021-11-24 CA CA3199380A patent/CA3199380A1/fr active Pending
- 2021-11-24 WO PCT/FR2021/052085 patent/WO2022112715A1/fr active Application Filing
- 2021-11-24 CN CN202180078952.3A patent/CN116685572A/zh active Pending
- 2021-11-24 EP EP21823983.8A patent/EP4251603A1/fr active Pending
- 2021-11-24 JP JP2023531578A patent/JP2023553315A/ja active Pending
-
2023
- 2023-05-22 ZA ZA2023/05504A patent/ZA202305504B/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN116685572A (zh) | 2023-09-01 |
EP4251603A1 (fr) | 2023-10-04 |
WO2022112715A1 (fr) | 2022-06-02 |
KR20230129010A (ko) | 2023-09-05 |
CA3199380A1 (fr) | 2022-06-02 |
FR3116532A1 (fr) | 2022-05-27 |
JP2023553315A (ja) | 2023-12-21 |
US20230399485A1 (en) | 2023-12-14 |
ZA202305504B (en) | 2024-02-28 |
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Legal Events
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PLFP | Fee payment |
Year of fee payment: 2 |
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PLSC | Publication of the preliminary search report |
Effective date: 20220527 |
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PLFP | Fee payment |
Year of fee payment: 3 |
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PLFP | Fee payment |
Year of fee payment: 4 |