FR3113060B1 - PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING - Google Patents

PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING Download PDF

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Publication number
FR3113060B1
FR3113060B1 FR2008108A FR2008108A FR3113060B1 FR 3113060 B1 FR3113060 B1 FR 3113060B1 FR 2008108 A FR2008108 A FR 2008108A FR 2008108 A FR2008108 A FR 2008108A FR 3113060 B1 FR3113060 B1 FR 3113060B1
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FR
France
Prior art keywords
effluent
treatment
hydrocracked
oils including
hydrocracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2008108A
Other languages
French (fr)
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FR3113060A1 (en
Inventor
Wilfried Weiss
Jérôme Bonnardot
Sangüesa Iñigo Ribas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol SA
IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2008108A priority Critical patent/FR3113060B1/en
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to KR1020237005785A priority patent/KR20230044444A/en
Priority to AU2021318798A priority patent/AU2021318798A1/en
Priority to EP21751787.9A priority patent/EP4189038A1/en
Priority to CA3185358A priority patent/CA3185358A1/en
Priority to TW110127341A priority patent/TW202216968A/en
Priority to JP2023506170A priority patent/JP2023535638A/en
Priority to CN202180059087.8A priority patent/CN116194555A/en
Priority to BR112023001482A priority patent/BR112023001482A2/en
Priority to PCT/EP2021/070850 priority patent/WO2022023263A1/en
Priority to US18/018,494 priority patent/US20230287283A1/en
Publication of FR3113060A1 publication Critical patent/FR3113060A1/en
Application granted granted Critical
Publication of FR3113060B1 publication Critical patent/FR3113060B1/en
Active legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012Pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081Recycling aspects
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70Catalyst aspects

Abstract

La présente invention concerne un procédé de traitement d’une huile de pyrolyse de plastiques, comprenant : a) l’hydrogénation sélective de ladite charge pour obtenir un effluent hydrogéné; b) l’hydrotraitement dudit effluent hydrogéné pour obtenir un effluent d’hydrotraitement ; c) une première étape d’hydrocraquage dudit effluent hydrotraité pour obtenir un premier effluent hydrocraqué ; d) une séparation de l’effluent hydrocraqué en présence d’un flux aqueux, pour obtenir un effluent gazeux, un effluent liquide aqueux et un effluent liquide hydrocarboné ; e) un fractionnement de effluent liquide hydrocarboné pour obtenir au moins un flux gazeux et au moins une coupe naphta et une coupe plus lourde ; f) une deuxième étape d’hydrocraquage de la coupe plus lourde pour obtenir un deuxième effluent hydrocraqué ; g) un recyclage d’au moins une partie dudit deuxième effluent hydrocraqué dans l’étape d) de séparation.The present invention relates to a process for the treatment of an oil from the pyrolysis of plastics, comprising: a) the selective hydrogenation of said feedstock to obtain a hydrogenated effluent; b) hydrotreating said hydrogenated effluent to obtain a hydrotreating effluent; c) a first stage of hydrocracking said hydrotreated effluent to obtain a first hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, to obtain a gaseous effluent, an aqueous liquid effluent and a liquid hydrocarbon effluent; e) fractionation of liquid hydrocarbon effluent to obtain at least one gaseous stream and at least one naphtha cut and one heavier cut; f) a second stage of hydrocracking the heavier cut to obtain a second hydrocracked effluent; g) recycling at least a portion of said second hydrocracked effluent to step d) separation.

FR2008108A 2020-07-30 2020-07-30 PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING Active FR3113060B1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR2008108A FR3113060B1 (en) 2020-07-30 2020-07-30 PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING
BR112023001482A BR112023001482A2 (en) 2020-07-30 2021-07-26 PLASTICS PYROLYSIS OIL TREATMENT PROCESS INCLUDING A TWO-STEP HYDROCRACKING
EP21751787.9A EP4189038A1 (en) 2020-07-30 2021-07-26 Method for the treatment of plastic pyrolysis oils including two-stage hydrocracking
CA3185358A CA3185358A1 (en) 2020-07-30 2021-07-26 Method for the treatment of plastic pyrolysis oils including two-stage hydrocracking
TW110127341A TW202216968A (en) 2020-07-30 2021-07-26 Process for treating plastics pyrolysis oils including hydrocracking in two steps
JP2023506170A JP2023535638A (en) 2020-07-30 2021-07-26 Method for treating plastic pyrolysis oil involving two-step hydrocracking
KR1020237005785A KR20230044444A (en) 2020-07-30 2021-07-26 Method for processing plastic pyrolysis oil involving two-stage hydrocracking
AU2021318798A AU2021318798A1 (en) 2020-07-30 2021-07-26 Method for the treatment of plastic pyrolysis oils including two-stage hydrocracking
PCT/EP2021/070850 WO2022023263A1 (en) 2020-07-30 2021-07-26 Method for the treatment of plastic pyrolysis oils including two-stage hydrocracking
US18/018,494 US20230287283A1 (en) 2020-07-30 2021-07-26 Method for the treatment of plastic pyrolysis oils including two-stage hydrocracking
CN202180059087.8A CN116194555A (en) 2020-07-30 2021-07-26 Method for treating plastic pyrolysis oil comprising two-step hydrocracking

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2008108 2020-07-30
FR2008108A FR3113060B1 (en) 2020-07-30 2020-07-30 PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING

Publications (2)

Publication Number Publication Date
FR3113060A1 FR3113060A1 (en) 2022-02-04
FR3113060B1 true FR3113060B1 (en) 2023-04-28

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FR2008108A Active FR3113060B1 (en) 2020-07-30 2020-07-30 PROCESS FOR TREATMENT OF PLASTICS PYROLYSIS OILS INCLUDING TWO-STAGE HYDROCRACKING

Country Status (11)

Country Link
US (1) US20230287283A1 (en)
EP (1) EP4189038A1 (en)
JP (1) JP2023535638A (en)
KR (1) KR20230044444A (en)
CN (1) CN116194555A (en)
AU (1) AU2021318798A1 (en)
BR (1) BR112023001482A2 (en)
CA (1) CA3185358A1 (en)
FR (1) FR3113060B1 (en)
TW (1) TW202216968A (en)
WO (1) WO2022023263A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3133618A1 (en) 2022-03-17 2023-09-22 IFP Energies Nouvelles HYDROCONVERSION IN A BUBBLING BED OR BOILING-DRIVEN HYBRID WITH A FEED COMPRISING A FRACTION OF OIL FOR PYROLYSIS OF PLASTICS AND/OR RECOVERY SOLID FUELS
FR3135090A1 (en) * 2022-04-29 2023-11-03 IFP Energies Nouvelles METHOD FOR PROCESSING PLASTICS PYROLYSIS OIL INCLUDING AN H2S RECYCLING STEP
GB202208414D0 (en) * 2022-06-08 2022-07-20 Abundia Biomass To Liquids Ltd Process for producing naphtha and diesel from pyrolysis of plastics

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Publication number Publication date
KR20230044444A (en) 2023-04-04
CN116194555A (en) 2023-05-30
FR3113060A1 (en) 2022-02-04
TW202216968A (en) 2022-05-01
US20230287283A1 (en) 2023-09-14
BR112023001482A2 (en) 2023-04-11
AU2021318798A1 (en) 2023-02-09
CA3185358A1 (en) 2022-02-03
JP2023535638A (en) 2023-08-18
WO2022023263A1 (en) 2022-02-03
EP4189038A1 (en) 2023-06-07

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