FR3095445B1 - Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate - Google Patents

Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate Download PDF

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Publication number
FR3095445B1
FR3095445B1 FR1904357A FR1904357A FR3095445B1 FR 3095445 B1 FR3095445 B1 FR 3095445B1 FR 1904357 A FR1904357 A FR 1904357A FR 1904357 A FR1904357 A FR 1904357A FR 3095445 B1 FR3095445 B1 FR 3095445B1
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France
Prior art keywords
thermoplastic elastomer
hexamethylene diisocyanate
binder
polyurethane thermoplastic
elastomer based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1904357A
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English (en)
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FR3095445A1 (fr
Inventor
Rémi Perrin
Pierre Etienne Bindschedler
Christine Robach
Frédéric Loup
François Olard
Raïssa Gallu
Florent Dalmas
Jean-François Gerard
Françoise Mechin
Jean-Pierre Pascault
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
Institut National des Sciences Appliquees de Lyon
Soprema SAS
Universite Jean Monnet Saint Etienne
Eiffage Infrastructures SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
Institut National des Sciences Appliquees de Lyon
Soprema SAS
Universite Jean Monnet Saint Etienne
Eiffage Infrastructures SAS
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Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite Claude Bernard Lyon 1 UCBL, Institut National des Sciences Appliquees de Lyon , Soprema SAS, Universite Jean Monnet Saint Etienne, Eiffage Infrastructures SAS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1904357A priority Critical patent/FR3095445B1/fr
Priority to EP20754308.3A priority patent/EP3959250A1/fr
Priority to CA3134960A priority patent/CA3134960A1/fr
Priority to US17/603,875 priority patent/US20220195183A1/en
Priority to PCT/FR2020/050686 priority patent/WO2020217021A1/fr
Priority to AU2020263978A priority patent/AU2020263978A1/en
Publication of FR3095445A1 publication Critical patent/FR3095445A1/fr
Application granted granted Critical
Publication of FR3095445B1 publication Critical patent/FR3095445B1/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0895Manufacture of polymers by continuous processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
    • C08G18/24Catalysts containing metal compounds of tin
    • C08G18/244Catalysts containing metal compounds of tin tin salts of carboxylic acids
    • C08G18/246Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/73Polyisocyanates or polyisothiocyanates acyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00Acoustic or vibration damping material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

La présente invention concerne un polyuréthane élastomère thermoplastique, une composition comprenant ledit polyuréthane et un liant, par exemple du bitume et/ou un liant biosourcé, ainsi que l’utilisation de la composition pour la préparation d’une membrane d’étanchéité, d’une membrane insonorisante, d’un système d’étanchéité liquide, d’un revêtement en enrobés bitumineux, d’un revêtement en asphalte coulé, d’un primaire, d’un vernis, d’un mastic, d’une colle ou d’une émulsion de liant.Figure de l’abrégé : aucune
FR1904357A 2019-04-25 2019-04-25 Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate Active FR3095445B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1904357A FR3095445B1 (fr) 2019-04-25 2019-04-25 Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate
EP20754308.3A EP3959250A1 (fr) 2019-04-25 2020-04-22 Polyuréthane élastomère thermoplastique à base d'hexaméthylène diisocyanate
CA3134960A CA3134960A1 (fr) 2019-04-25 2020-04-22 Polyurethane elastomere thermoplastique a base d'hexamethylene diisocyanate
US17/603,875 US20220195183A1 (en) 2019-04-25 2020-04-22 Polyurethane thermoplastic elastomer based on hexamethylene diisocyanate
PCT/FR2020/050686 WO2020217021A1 (fr) 2019-04-25 2020-04-22 Polyuréthane élastomère thermoplastique à base d'hexaméthylène diisocyanate
AU2020263978A AU2020263978A1 (en) 2019-04-25 2020-04-22 Polyurethane thermoplastic elastomer based on hexamethylene diisocyanate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1904357 2019-04-25
FR1904357A FR3095445B1 (fr) 2019-04-25 2019-04-25 Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate

Publications (2)

Publication Number Publication Date
FR3095445A1 FR3095445A1 (fr) 2020-10-30
FR3095445B1 true FR3095445B1 (fr) 2022-06-03

Family

ID=67875601

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1904357A Active FR3095445B1 (fr) 2019-04-25 2019-04-25 Polyuréthane élastomère thermoplastique à base d’hexaméthylène diisocyanate

Country Status (6)

Country Link
US (1) US20220195183A1 (fr)
EP (1) EP3959250A1 (fr)
AU (1) AU2020263978A1 (fr)
CA (1) CA3134960A1 (fr)
FR (1) FR3095445B1 (fr)
WO (1) WO2020217021A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114478976A (zh) * 2022-03-18 2022-05-13 福建农林大学 一种脂肪酸链悬挂的棕榈油基热塑性聚氨酯弹性体及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE758168A (fr) 1969-10-29 1971-04-28 Naphtachimie Sa Produits bitumeux contenant des polyurethanes
US5763036A (en) 1995-07-10 1998-06-09 Interface, Inc. Polyurethane-modified bitumen sheet material and method for protective moisture barrier
FR2787801B1 (fr) 1998-12-24 2001-03-23 Soprema Composition resineuse monocomposante a proprietes adhesives, notamment pour la realisation d'etancheites
US20030203771A1 (en) * 2002-04-26 2003-10-30 Ronald Rosenberg Polyurethane elastomers from HDI prepolymers with reduced content of free HDI monomers
FR2844283B1 (fr) 2002-09-11 2006-10-27 Soprema Membrane a base de liant bitumineux modifie polyrethanne et procede de fabrication
FR2941461B1 (fr) * 2009-01-29 2013-06-14 Colas Sa Obtention d'enrobe et de beton bitumeux a module eleve (eme et bbme)
FR3012812B1 (fr) * 2013-11-05 2015-11-20 Soprema Granule de bitume et de polyurethane elastomere thermoplastique, son procede de preparation et ses utilisations
US10907045B2 (en) * 2014-02-26 2021-02-02 Garland Industries, Inc. Active polymer modification of bitumen for use in roofing materials
FR3035113B1 (fr) 2015-04-14 2020-05-29 Soprema Liant d'origine vegetale, compositions le comprenant et methode pour diminuer la quantite de bitume petrolier
FR3035112B1 (fr) 2015-04-14 2020-05-29 Soprema Liant d'origine vegetale, compositions le comprenant et methode pour diminuer la quantite de bitume petrolier
EP3392285A1 (fr) * 2017-04-18 2018-10-24 Covestro Deutschland AG Polyuréthanes thermoplastiques aliphatiques, leur fabrication et leur utilisation

Also Published As

Publication number Publication date
WO2020217021A1 (fr) 2020-10-29
CA3134960A1 (fr) 2020-10-29
FR3095445A1 (fr) 2020-10-30
EP3959250A1 (fr) 2022-03-02
US20220195183A1 (en) 2022-06-23
AU2020263978A1 (en) 2021-11-04

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