FR3079446A1 - Procede de renforcement de plaque thermoplastique - Google Patents
Procede de renforcement de plaque thermoplastique Download PDFInfo
- Publication number
- FR3079446A1 FR3079446A1 FR1870348A FR1870348A FR3079446A1 FR 3079446 A1 FR3079446 A1 FR 3079446A1 FR 1870348 A FR1870348 A FR 1870348A FR 1870348 A FR1870348 A FR 1870348A FR 3079446 A1 FR3079446 A1 FR 3079446A1
- Authority
- FR
- France
- Prior art keywords
- thermoplastic
- reinforcing
- plate
- joinery
- solar panels
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 52
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 16
- 230000003014 reinforcing effect Effects 0.000 title claims description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 11
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 9
- 238000005452 bending Methods 0.000 claims abstract description 8
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- 230000009466 transformation Effects 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims description 10
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- 238000011084 recovery Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000005538 encapsulation Methods 0.000 abstract description 2
- 239000012780 transparent material Substances 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 description 10
- 239000011347 resin Substances 0.000 description 9
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- 238000003466 welding Methods 0.000 description 8
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- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
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- -1 Setacryl Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
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- 239000004744 fabric Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
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- 229920000642 polymer Polymers 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
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- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
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- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
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- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
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- B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/74—Moulding material on a relatively small portion of the preformed part, e.g. outsert moulding
- B29C70/76—Moulding on edges or extremities of the preformed part
- B29C70/763—Moulding on edges or extremities of the preformed part the edges being disposed in a substantial flat plane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00278—Lenticular sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/26—Scrap or recycled material
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
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- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
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Abstract
Une plaque thermoplastique (9) est renforcée en flexion par thermocompression ou thermo-estampage puis fusion avec des profilés pultrudés thermoplastiques (7) à fibres longues ou continues et fabriqués avec une résine thermoplastique à faible viscosité. A des fins de légèreté, lesdits profilés pultrudés thermoplastiques (7) sont limités en masse et en volume. Ladite plaque thermoplastique (9), une fois renforcée en flexion, peut être soumise à transformation ou déformation, du fait de sa thermosoudabilité, de son emboutissabilité et de sa pliabilité à chaud. Ladite résine thermoplastique à faible viscosité peut être obtenue par des polymérisations différentielles du monomère methylméthacrylate MMA et générer un matériau hautement transparent. Lesdites plaques (9) en PMMA peuvent être destinées aux menuiseries (fenêtres, porte-fenêtres, meubles) et aux dispositif d'encapsulation de panneaux solaires, y compris à concentration. Le procédé de l'invention apporte un plus haut débit de fabrication de plaques thermoplastiques renforcées que le placement de fibres robotisé.
Description
INTRODUCTION
Une plaque thermoplastique peut manquer de résistance à la flexion et à la torsion.
La plupart du temps, la méthode de renfort consiste à la rendre solidaire d'une armature métallique, comme à chaque fois que l'on veut renforcer une plaque, de quelque nature qu'elle soit.
Deux besoins notoires concernent le renforcement de menuiseries (fenêtres, porte fenêtres, meubles) de grandes dimensions ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions.
A côté des renforts métalliques, les propriétés mêmes des matériaux thermoplastiques permettent d'envisager des solutions alternatives, d'une part du fait de leur thermosoudabilité, emboutissabilité et pliabilité à chaud, et d'autre part du fait qu'il existe désormais au moins une résine thermoplastique à faible viscosité. Celle-ci est à base de Methylmethacrylate, génère un matériau transparent, et, de façon singulière, est compatible avec certaines méthodes de fabrication de profilés composites, comme la pultrusion.
Par ailleurs, la demande de brevet « FR1771321 Panneaux thermoplastiques à hautes performances thermiques et lumineuses », émanant des mêmes demandeurs que les auteurs du présent document, décrit des plaques et des caissons en Methylmethacrylate et renforcés de fibres. Toutefois, cette demande de brevet ne décrit pas le présent procédé de renfort de ces plaques et caissons thermoplastiques en Plexiglas ou PolyMethylmethacrylate.
Le Plexiglas ou PolyMethylmethacrylate
Le Polymethyl Méthacrylate ou PM MA, est un polymère du methylmethacrylate. Ses autres noms commerciaux sont Plexiglass, Altuglas, Lucite, Perspex, Setacryl, Crystalite, Nudec, et bien d'autres. Le PMMA peut être moulé par compression, injection, coulée, soufflage et extrusion.
Les feuilles et plaques de PMMA sont facilement thermoformées. Elles peuvent être pleines ou alvéolées.
Certaines plaques de PMMA sont destinées aux panneaux solaires à concentration et intègrent des lentilles destinées à concentrer les rayons du soleil.
On peut facilement le métalliser. Le PMMA peut également être soudé par de nombreuses méthodes, par exemple par ultra-sons.
II existe une large gamme de compositions commerciales qui sont des copolymères avec différents co-monomères autres que le méthacrylate de méthyle.
Avec le développement rapide de la polymérisation radicalaire contrôlée (PRC), un grand nombre de co-polymères blocs comme avec des méthacrylates fluorés ont vu le jour.
Le Butyl méthacrylate parmi d'autres molécules peut être envisagé comme un co-monomère du polymethyl méthacrylate.
Une autre version polymérique du methymethacrylate, obtenue à partir de la résine ELIUM à faible viscosité de la société ARKEMA, ici dénommée résine PMMA-MMA, imprègne très facilement des fibres de renforts au prix de la perte de transparence. Cette résine permet des fabrications de composites avec des techniques telles que la pultrusion jusque-là réservées aux composites thermodurcissables.
Ladite résine thermoplastique à faible viscosité est obtenue par des polymérisations différentielles du monomère methylméthacrylate MMA, ladite résine PMMA-MMA étant décrite entre autres dans les brevets de la société ARKEMA WO2013056845A2, W02014013028A1, WO2014135815, WO2014135816 et WO 2017121750 Al. Ladite résine est commercialisée avec fibres, catalyseurs, additifs, activateurs, monomères de MMA, oligomères de MMA et homo-ou co-polymères de MMA.
Pultrusion et Thermo-compression
Parmi de nombreuses méthodes de fabrication de composites, le présent brevet utilise avant tout la pultrusion et la thermo-compression.
La pultrusion est une technique de fabrication en continu, destinée à créer des profilés de section quelconque et constante, qui consiste à imprégner de résine des fibres longues par passage dans un bain, puis à les tirer à travers une longue filière chauffée qui contrôle la teneur en résine et détermine la forme de la section, le passage dans la filière permettant d'écraser les fuseaux de mèches pré-imprégnées et d'obtenir une imprégnation régulière de la résine en éliminant l'air occlus dans lesdites fibres et à leur jonction, et donc sans les défauts dûs à une porosité ou un excès de résine.
le renfort (tissu, mat, fibres) étant conditionné en bobine,
La principale limitation du procédé, outre les contraintes sur la géométrie des pièces, porte sur les directions des renforts ainsi mis en place.
En effet, la pultrusion installe des renforts axiaux (ce qui conduit à des comportements fortement anisotropes, avec des propriétés mécaniques satisfaisantes en résistance à la flexion, mais non-optimales en ce qui concerne la résistance au fluage et à la compression). Une méthode de fabrication complémentaire existe, dénommée le « pull-winding ».
Le pull-winding consiste à effectuer un enroulement filamentaire autour d'une âme obtenue par pultrusion et permet donc d'obtenir deux directions de renforts.
Le thermo-estampage est une mise en forme selon un procédé discontinu par compression à une pression allant jusqu'à 20 bars, tandis que la thermo-compression est elle aussi une mise en forme selon un procédé discontinu par compression à des pressions de 100 à 300 bars en moyenne, avec un grand écart-type.
II est possible de thermo-comprimer des profilés thermoplastiques pultrudés, voire même des profilés thermoplastiques fabriqués par pull-winding ou enroulement filamentaire.
II est possible de thermo-comprimer des déchêts broyés de produits themoplastiques à fibres longues ou continues ou de valoriser des chutes de production de composites thermoplastiques par le procédé de thermo-compression .
Cf. « Frédéric Ruch « Thermosaïc®, a Patented Technology for Thermoplastic Composite Materials Recycling » communications du CETIM et du CETIM-CERMAT au Salon JEC de Paris en mars 2017. » Cf « Julien Moothoo, Christian Garnier, Pierre Ouagne. Valorisation matière de chutes de production de composites thermoplastiques par le procédé de thermo-compression. Journées Nationales sur les Composites. 2017, Jun 2017, 77455 Champs-sur-Marne, France »
Thermosoudage des Thermoplastiques
L'Etat de l'Art du soudage thermoplastique se rapporte à des technologies diverses dont les principales sont * le soudage par ultra-sons, * le soudage par induction, * le soudage avec résistance, * le soudage par plaques chauffantes, * le soudage par gaz chaud, * le soudage par infra-rouge, * le soudage par laser.
ETAT DE L'ART
Une plaque thermoplastique peut manquer de résistance à la flexion et à la torsion.
Les propriétés mêmes des matériaux thermoplastiques permettent d'envisager des solutions alternatives d'une part du fait de leur thermosoudabilité, emboutissabilité et pliabilité à chaud. Ainsi le placement de fibres au moyen de robots permet d'appliquer des bandes fibreuses imprégnées de résine sur les parties à renforcer.
DESCRIPTION
L'invention met à profit le fait qu'il existe désormais au moins une résine thermoplastique à faible viscosité, et que celle-ci est compatible avec la pultrusion.
Selon l'invention, une plaque thermoplastique (9) est renforcée en flexion par thermocompression puis fusion avec des profilés pultrudés thermoplastiques (7) à fibres longues ou continues et fabriqués avec une résine thermoplastique à faible viscosité.
Le procédé de l'invention apporte un plus haut débit de fabrication de plaques thermoplastiques renforcées que le placement de fibres au moyen de robots, moins performant sur les surfaces planes (tandis que sa supériorité s'exprime plutôt sur des formes en 3D).
Selon une version de l'invention, afin que ladite plaque thermoplastique conserve sa légèreté, lesdits profilés pultrudés thermoplastiques (7) sont limités en masse et en volume.
Selon une version de l'invention, l'épaisseur desdits profilés pultrudés thermoplastiques (7) est inférieure à celle de ladite plaque (9), leur longueur totale additionnelle est limitée à 80% du périmètre de ladite plaque (9), leur surface à plat totale additionnelle est limitée à 15% de la surface totale de ladite plaque (9).
Selon une version de l'invention, des plats thermoplastiques composites à fibres pluri-directionnelles, de préférence issus de récupération et thermo-comprimés ou thermo-estampés accompagnent lesdits profilés pultrudés thermoplastiques (7).
Selon une version de l'invention, ladite plaque thermoplastique (9), une fois renforcée en flexion, est soumise à transformation ou déformation, du fait de sa thermosoudabilité, de son emboutissabilité et de sa pliabilité à chaud.
Selon une version de l'invention, ladite résine thermoplastique à faible viscosité est obtenue par des polymérisations différentielles du monomère methylméthacrylate MMA.
Selon une version de l'invention, lesdites plaques (9) en PMMA sont destinées aux panneaux solaires à concentration et intègrent, selon l'Etat de l'Art, des lentilles destinées à concentrer les rayons du soleil. http://www.totalplastics.com/products/650
FIGURES
La Figure IA représente une plaque thermoplastique (9) et quatre profilés pultrudés thermoplastiques (7) disposés en croix.
La Figure IB représente une plaque thermoplastique (9) et quatre profilés pultrudés thermoplastiques (7) parallèles aux bords de ladite plaque thermoplastique (9).
La Figure IC représente une plaque thermoplastique (9) et, quatre profilés pultrudés thermoplastiques (7) coupés en biseau et disposés de manière à former un cadre.
Les Figures IA, IB et IC montrent que lesdits quatre profilés pultrudés thermoplastiques (7) ont une longueur totale limitée à 80% du périmètre de ladite plaque thermoplastique (9), et une surface à plat totale est limitée à 15% de la surface totale de ladite plaque thermoplastique (9).
La Figure 2A représente une plaque thermoplastique (9), quatre profilés pultrudés thermoplastiques (7) coupés en biseau et disposés de manière à former un cadre, une plaque de thermo-compression (12), et un moule de thermocompression (22).
Les Figures 2A et 2B montrent que le moule de thermocompression (22) reçoit ladite plaque (9) surlaquelle sont disposés les quatre profilés (7).
Les Figures 2C et 2D montrent la thermocompression proprement dite avec application en pression de ladite plaque (12) de thermocompression.
Les Figures 2E et 2F montrent, respectivement avant et après ébarbage, le résultat de thermocompression/fusion, à savoir la plaque (19) qui résulte de la fusion de ladite plaque (9) et des quatre profilés pultrudés (7).
Claims (6)
1) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, caractérisée en ce qu' une plaque thermoplastique (9) est renforcée en flexion par thermocompression puis fusion avec des profilés pultrudés thermoplastiques (7) à fibres longues ou continues et fabriqués avec une résine thermoplastique à faible viscosité.
2) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, selon la revendication 1, caractérisée en ce que, afin que ladite plaque thermoplastique (9) renforcée conserve sa légèreté, lesdits profilés pultrudés thermoplastiques (7) sont limités en masse et en volume.
L'épaisseur desdits profilés pultrudés thermoplastiques (7) est inférieure à celle de ladite plaque (9), leur longueur totale additionnelle est limitée à 80% du périmètre de ladite plaque (9), leur surface à plat totale additionnelle est limitée à 15% de la surface totale de ladite plaque (9).
3) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, selon les revendications 1 et 2, caractérisée en ce que des plats thermoplastiques composites à fibres pluri-directionnelles, de préférence issus de récupération, et thermo-comprimés ou thermo-estampés, accompagnent lesdits profilés pultrudés thermoplastiques (7).
4) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, selon la revendication 1, caractérisée en ce que ladite plaque thermoplastique (9), une fois renforcée en flexion, est soumise à transformation ou déformation, du fait sa thermosoudabilité, son emboutissabilité et sa pliabilité à chaud.
5) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, selon la revendication 1, caractérisée en ce que ladite résine thermoplastique à faible viscosité est obtenue par des polymérisations différentielles du monomère methylméthacrylate MMA.
6) Procédé de renforcement de plaque thermoplastique, par exemple pour le renforcement de menuiseries ou des dispositifs d'encapsulation de panneaux solaires de grandes dimensions, selon la revendication 5, lesdites plaques (9) en PMMA sont destinées aux panneaux solaires à concentration et intègrent, selon l'Etat de l'Art, des lentilles destinées à concentrer les rayons du soleil.
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FR1870348A FR3079446A1 (fr) | 2018-03-27 | 2018-03-27 | Procede de renforcement de plaque thermoplastique |
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FR1870348A FR3079446A1 (fr) | 2018-03-27 | 2018-03-27 | Procede de renforcement de plaque thermoplastique |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5213889A (en) * | 1981-01-21 | 1993-05-25 | Imperial Chemical Industries Plc | Fibre-reinforced compositions and methods for producing such compositions |
US20020094427A1 (en) * | 2001-01-16 | 2002-07-18 | Edwards Christopher M. | Thermoplastic composite reinforced thermoform and blow-molded article |
EP1342623A1 (fr) * | 2002-03-08 | 2003-09-10 | N.V. Bekaert S.A. | Poutre de choc renforcé |
DE102015013915A1 (de) * | 2015-10-27 | 2017-04-27 | Florian Eichenhofer | Maschinensystem zur Herstellung eines Hybridbauteils |
CN107222153A (zh) * | 2017-07-05 | 2017-09-29 | 武汉理工大学 | 一种高倍聚光太阳能热电、光电复合联产组件及组装装置 |
-
2018
- 2018-03-27 FR FR1870348A patent/FR3079446A1/fr not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5213889A (en) * | 1981-01-21 | 1993-05-25 | Imperial Chemical Industries Plc | Fibre-reinforced compositions and methods for producing such compositions |
US5213889B1 (en) * | 1981-01-21 | 1996-10-29 | Kawasaki Chem Holding | Fibre-reinforced compositions and methods for producing such compositions |
US20020094427A1 (en) * | 2001-01-16 | 2002-07-18 | Edwards Christopher M. | Thermoplastic composite reinforced thermoform and blow-molded article |
EP1342623A1 (fr) * | 2002-03-08 | 2003-09-10 | N.V. Bekaert S.A. | Poutre de choc renforcé |
DE102015013915A1 (de) * | 2015-10-27 | 2017-04-27 | Florian Eichenhofer | Maschinensystem zur Herstellung eines Hybridbauteils |
CN107222153A (zh) * | 2017-07-05 | 2017-09-29 | 武汉理工大学 | 一种高倍聚光太阳能热电、光电复合联产组件及组装装置 |
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