FR3040170B1 - Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation - Google Patents

Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation Download PDF

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FR3040170B1
FR3040170B1 FR1557767A FR1557767A FR3040170B1 FR 3040170 B1 FR3040170 B1 FR 3040170B1 FR 1557767 A FR1557767 A FR 1557767A FR 1557767 A FR1557767 A FR 1557767A FR 3040170 B1 FR3040170 B1 FR 3040170B1
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Prior art keywords
imine
exchange reactions
exchangeable
aldehyde
composition
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FR1557767A
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FR3040170A1 (fr
Inventor
Ludwik Leibler
Renaud Nicolay
Max ROTTGER
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Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
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Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
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Priority to FR1557767A priority Critical patent/FR3040170B1/fr
Application filed by Ecole Superieure de Physique et Chimie Industrielles de Ville Paris filed Critical Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
Priority to EP16759992.7A priority patent/EP3337835B1/fr
Priority to CA3031551A priority patent/CA3031551A1/fr
Priority to PCT/EP2016/069483 priority patent/WO2017029311A1/fr
Priority to JP2018508727A priority patent/JP6908956B2/ja
Priority to US15/238,969 priority patent/US9994651B2/en
Priority to CN201680060814.1A priority patent/CN108431057B/zh
Publication of FR3040170A1 publication Critical patent/FR3040170A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/28—Condensation with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention a pour objet une composition comprenant (a) des polymères réticulés contenant des liaisons pendantes échangeables et des points de réticulation échangeables, par réactions d'échange aldéhyde-imine et/ou par réactions d'échange imine-imine, obtenu par réticulation de polymères linéaires ou branchés et (b) des aldéhydes libres monofonctionnels et/ou des imines libres monofonctionnelles. L'invention a également pour objet des procédés de préparation d'une telle composition et les utilisations de la composition. L'invention a aussi pour objet des combinaisons pour réticuler des polymères linéaires ou branchés, et leur utilisation pour former une composition comprenant des polymères réticulés contenant des liaisons pendantes échangeables et des points de réticulation échangeables par réactions d'échange aldéhyde-imine et/ou par réactions d'échange imine-imine. L'invention a enfin pour objet l'utilisation d'aldéhyde pour catalyser les réactions de métathèse imine-imine et les réactions d'échange imine-aldéhyde.
FR1557767A 2015-08-17 2015-08-17 Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation Active FR3040170B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1557767A FR3040170B1 (fr) 2015-08-17 2015-08-17 Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation
CA3031551A CA3031551A1 (fr) 2015-08-17 2016-08-17 Composition de polymeres reticules comprenant des liaisons laterales echangeables et des pontages echangeables, par l'intermediaire de reactions d'echange aldehyde-imine et/ou imi ne-imine, ses procedes de preparation et utilisation
PCT/EP2016/069483 WO2017029311A1 (fr) 2015-08-17 2016-08-17 Composition de polymères réticulés comprenant des liaisons latérales échangeables et des pontages échangeables, par l'intermédiaire de réactions d'échange aldéhyde-imine et/ou imine-imine, ses procédés de préparation et utilisation
JP2018508727A JP6908956B2 (ja) 2015-08-17 2016-08-17 アルデヒド−イミン及び／又はイミン−イミン交換反応によって交換可能なペンダント結合及び交換可能な架橋を含む架橋ポリマーの組成物、調製方法、並びに使用
EP16759992.7A EP3337835B1 (fr) 2015-08-17 2016-08-17 Composition de polymères réticulés comprenant des liaisons latérales échangeables et des pontages échangeables, par l'intermédiaire de réactions d'échange aldéhyde-imine et/ou imine-imine, ses procédés de préparation et utilisation
US15/238,969 US9994651B2 (en) 2015-08-17 2016-08-17 Composition of cross-linked polymers comprising pending exchangeable bonds and exchangeable cross-links, via aldehyde-imine and/or imine-imine exchange reactions, preparation processes and use
CN201680060814.1A CN108431057B (zh) 2015-08-17 2016-08-17 包含通过醛-亚胺和/或亚胺-亚胺交换反应可交换的侧挂的键和可交换的交联连接的交联聚合物的组合物、制备方法和用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1557767 2015-08-17
FR1557767A FR3040170B1 (fr) 2015-08-17 2015-08-17 Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation

Publications (2)

Publication Number Publication Date
FR3040170A1 FR3040170A1 (fr) 2017-02-24
FR3040170B1 true FR3040170B1 (fr) 2019-02-01

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FR1557767A Active FR3040170B1 (fr) 2015-08-17 2015-08-17 Composition de polymeres reticules contenant des liaisons pendantes echangeables et des points de reticulation echangeables, par reactions d'echange aldehyde-imine et/ou par reactions d'echange imine-imine, procedes de preparations et utilisation

Country Status (7)

Country Link
US (1) US9994651B2 (fr)
EP (1) EP3337835B1 (fr)
JP (1) JP6908956B2 (fr)
CN (1) CN108431057B (fr)
CA (1) CA3031551A1 (fr)
FR (1) FR3040170B1 (fr)
WO (1) WO2017029311A1 (fr)

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JP5999267B2 (ja) * 2014-04-25 2016-09-28 横浜ゴム株式会社 コンベヤベルト用コートゴム組成物
JP6661827B2 (ja) 2016-11-01 2020-03-11 エルジー・ケム・リミテッド 変性共役ジエン系重合体及びその製造方法
KR20210057071A (ko) * 2018-09-06 2021-05-20 말린다 고가공성 공유 네트워크 중합체 및 블렌드에 대한 무수 경로
US11214676B2 (en) * 2019-04-05 2022-01-04 Fina Technology, Inc. Polyenes for curable liquid rubber-based compositions
CN113930135A (zh) * 2020-07-14 2022-01-14 北京化工大学 一种自修复无溶剂型环氧防火涂料及制备方法
CN116410545A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 一种抗冲共聚聚丙烯树脂及其制备方法
CN116410546A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 一种聚丙烯树脂及其制备方法

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JP4338478B2 (ja) * 2003-09-04 2009-10-07 独立行政法人科学技術振興機構 固相担体およびそれを用いる液晶化合物の固相合成
FR2923834B1 (fr) * 2007-11-20 2011-01-21 Rhodia Operations Nouvelles compositions polysicocyanates hydrodispersibles.

Also Published As

Publication number Publication date
EP3337835A1 (fr) 2018-06-27
JP2018523743A (ja) 2018-08-23
EP3337835B1 (fr) 2021-12-01
CA3031551A1 (fr) 2017-02-23
WO2017029311A1 (fr) 2017-02-23
FR3040170A1 (fr) 2017-02-24
US20170051082A1 (en) 2017-02-23
JP6908956B2 (ja) 2021-07-28
US9994651B2 (en) 2018-06-12
CN108431057A (zh) 2018-08-21
CN108431057B (zh) 2021-06-18

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