FR2987362B1 - A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS - Google Patents

A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS

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Publication number
FR2987362B1
FR2987362B1 FR1251809A FR1251809A FR2987362B1 FR 2987362 B1 FR2987362 B1 FR 2987362B1 FR 1251809 A FR1251809 A FR 1251809A FR 1251809 A FR1251809 A FR 1251809A FR 2987362 B1 FR2987362 B1 FR 2987362B1
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FR
France
Prior art keywords
equal
monomer
formula
less
glycerine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1251809A
Other languages
French (fr)
Other versions
FR2987362A1 (en
Inventor
Olivier Braun
Paul Mallo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Original Assignee
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
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Publication date
Application filed by Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA filed Critical Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Priority to FR1251809A priority Critical patent/FR2987362B1/en
Publication of FR2987362A1 publication Critical patent/FR2987362A1/en
Application granted granted Critical
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Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8188—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bonds, and at least one being terminated by a bond to sulfur or by a hertocyclic ring containing sulfur; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F228/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

Polyélectrolyte anionique issu de la polymérisation: a) d'une proportion massique supérieure ou égale à 80% et inférieure ou égale à 99,5% d'unités monomériques issues d'un monomère à fonction acide fort ; b) d'une proportion massique supérieure ou égale à 0,5% et inférieure ou égale à 20%, - Soit d'un monomère de formule (la) : R-(CH ) -Si(CH ) -[O-Si(CH ) -] O-Si(CH ) -(CH ) -R (la), dans laquelle R représente le radical monovalent : -(O-CH -CH -) [O-CH -CH(CH )-] O-C(=O)-CH=CH , ledit monomère de formule (la) ayant un poids moléculaire supérieur ou égal à 1.500 et inférieur ou égal à 7.000 ; - Soit d'un monomère de formule (Ib) : Si(CH ) -[O-Si(CH ) -] [O-Si(CH )[(CH ) -R]-] O-Si(CH ) (Ib), dans laquelle R représente un radical monovalent de formule : -(O-CH -CH -)x[O-CH -CH(CH )-] O-C(=O)-CH=CH , ledit monomère de formule (Ib) ayant un poids moléculaire supérieur ou égal à 1.000 et inférieur ou égal à 4.000 ; c) optionnellement d'une proportion massique supérieure à 0% et inférieure ou égale à 5%, d'unités monomériques issues d'au moins un monomère de formule (II) : R -C(=O)-O-[(CH -CH(R )-O] -R (II), d) optionnellement d'une proportion massique supérieure à 0% et inférieure ou égale à 5% d'au moins un monomère de réticulation diéthylénique ou polyéthylénique ; son procédé pour sa préparation et son utilisation comme épaississant dans les compositions topiques.Anionic polyelectrolyte resulting from the polymerization: a) in a proportion by mass greater than or equal to 80% and less than or equal to 99.5% of monomer units resulting from a monomer containing a strong acid function; b) a proportion by mass greater than or equal to 0.5% and less than or equal to 20%, - Either of a monomer of formula (la): R- (CH) -Si (CH) - [O-Si (CH) -] O-Si (CH) - (CH) -R (la), in which R represents the monovalent radical: - (O-CH -CH -) [O-CH -CH (CH) -] OC (= O) -CH = CH, said monomer of formula (Ia) having a molecular weight greater than or equal to 1,500 and less than or equal to 7,000; - Or a monomer of formula (Ib): Si (CH) - [O-Si (CH) -] [O-Si (CH) [(CH) -R] -] O-Si (CH) (Ib ), in which R represents a monovalent radical of formula: - (O-CH -CH -) x [O-CH -CH (CH) -] OC (= O) -CH = CH, said monomer of formula (Ib) having a molecular weight greater than or equal to 1,000 and less than or equal to 4,000; c) optionally in a proportion by mass greater than 0% and less than or equal to 5%, of monomer units resulting from at least one monomer of formula (II): R -C (= O) -O - [(CH -CH (R) -O] -R (II), d) optionally in a proportion by mass greater than 0% and less than or equal to 5% of at least one diethylene or polyethylene crosslinking monomer; its process for its preparation and its use as a thickener in topical compositions.

FR1251809A 2012-02-28 2012-02-28 A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS Active FR2987362B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR1251809A FR2987362B1 (en) 2012-02-28 2012-02-28 A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1251809A FR2987362B1 (en) 2012-02-28 2012-02-28 A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS

Publications (2)

Publication Number Publication Date
FR2987362A1 FR2987362A1 (en) 2013-08-30
FR2987362B1 true FR2987362B1 (en) 2014-09-12

Family

ID=46551690

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1251809A Active FR2987362B1 (en) 2012-02-28 2012-02-28 A NEW SILICONE ACRYLATE POLYMER THAT IS THICKENING AND REDUCING THE TACKING CHARACTER OF GLYCERINE-BASED COSMETIC FORMULAS

Country Status (1)

Country Link
FR (1) FR2987362B1 (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10059831A1 (en) * 2000-12-01 2002-06-13 Clariant Gmbh Silicon-modified comb polymers based on acryloyldimethyltauric acid

Also Published As

Publication number Publication date
FR2987362A1 (en) 2013-08-30

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