FR2984149A1 - Noncoloring and nonoxidizing composition, useful for conditioning keratinous matters, comprises sulfates or sulfonates anionic surfactant having specified fatty chains, solid fatty alcohols, solid fatty esters and liquid fatty substance - Google Patents

Abstract

Noncoloring and nonoxidizing composition comprises one or more sulfates or sulfonates anionic surfactant, one or more solid fatty alcohols, one or more solid fatty esters, and optionally one or more liquid fatty substance, where the surface-active anion sulfates or sulfonates comprises at least 50 wt.% comprising fatty chains having a number of carbon atoms of >= 14. An independent claim is included for conditioning keratinous materials, preferably keratinous fibers, comprising applying the composition on the keratinous material, and an optionally rinsing after a possible exposure time.

Description

The present invention relates to a composition, in particular for the conditioning of keratin materials, in particular keratinous fibers, comprising at least one anionic sulfate surfactant. or particular sulphonate, at least one solid fatty alcohol, at least one solid fatty ester and optionally at least one particular fatty substance, the use of said composition for conditioning keratin materials, in particular keratin fibers, as well as a method implementation of said composition. In the field of conditioners, a conditioning agent is generally associated which may be a cationic surfactant, a cationic polymer, a silicone, an oil, a fatty substance or a mixture thereof. These conditioning agents are used to improve the disentangling and softness of wet and dried hair but may tend to weigh down the hair and tarnish it.

The use of insoluble conditioning agents is severely limited: on the one hand, because of the difficulties of stabilization in compositions, on the other hand, because of the cosmetic defects in terms of weighting, loading and relubrication keratin materials related to coarse or heterogeneous dispersions.

Insoluble conditioning agents, in particular fatty alcohols, are known and used in hair compositions, for example in documents JP2002-20791, JP9-30938, US2009 / 005449 and US2009 / 005460.

However, these compositions do not exhibit high-level cosmetic performance in terms of disentangling and smoothing, without charging or weighing the hair and maintaining the level of the qualities of use.

The Applicant has now discovered that the use of compositions comprising at least one particular sulfate or sulphonate anionic surfactant, at least one solid fatty alcohol, at least one solid fatty ester and optionally at least one liquid fatty substance, makes it possible to obtain a composition having very good cosmetic properties and in particular smoothing, softness, flexibility, shine are improved, especially on sensitized hair. In the case of curly and / or frizzy hair, there is a decrease in volume allowing better control of the hair.

The compositions according to the invention also provide color protection to washes of artificially colored hair. The subject of the invention is therefore a non-coloring and non-oxidizing cosmetic composition, in particular for conditioning keratinous substances, in particular human keratinous fibers, comprising one or more anionic sulphate or sulphonate surfactants, one or more solid fatty alcohols, one or more esters. solid fats and optionally one or more liquid fatty substances, the at least one anionic sulphate or sulphonate surfactant being such that at least 50% by weight of them contain fatty chains having a carbon number equal to or greater than 14. Another object of the invention is the use of said composition for conditioning keratin materials, in particular human keratinous fibers, and more particularly hair. The subject of the invention is also a process for conditioning keratin materials using the composition according to the invention.

Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and the various examples which follow. According to the present invention, the term "non-coloring composition" is intended to mean a composition which does not contain a dye for keratinous fibers, such as direct dyes or oxidation dye precursors (bases and couplers). If they are present, their content does not exceed 0.005% by weight relative to the total weight of the composition. Indeed, at such a content, only the composition would be tinted, that is to say, one would not observe staining effect of keratin fibers.

By non-oxidizing composition is meant according to the present invention a composition containing no oxidizing agent usually used in the treatment of keratin fibers such as hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors, alkali or alkaline-earth metal percarbonates and peracids and their precursors. If they are present, their content does not exceed 0.005% by weight relative to the total weight of the composition.

In the present application, an entity is described as being "anionic" when it possesses at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the compositions of the invention ( medium, pH for example) and not comprising a cationic charge. The anionic sulphate or sulphonate surfactants of the invention are anionic surfactants comprising at least one sulphate function (-OSO3H or -OSO3) and / or a sulphonate function (-SO3H or -SO3). said anionic sulphate or sulphonate surfactants being such that at least 50% by weight of them contain fatty chains having a number of carbon atoms equal to or greater than 14. The anionic surfactants which can be used in the composition are especially chosen from salts, in particular alkali metal salts such as sodium salts, ammonium salts, amine salts, aminoalcohol salts or alkaline earth metal salts, for example from magnesium, of the following types: alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkyl aryl polyether sulphates, monoglyceride sulphates; alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, the alkyl and acyl groups of all these compounds preferably having from 14 to 30 carbon atoms, more preferably 16 to 22 carbon atoms, and the aryl group preferably denotes a phenyl or benzyl group.

C16-C18 alkyl sulphates and C16-18 alkyl ether sulphates and mixtures thereof are preferably used, in particular in the form of alkali metal or alkaline-earth metal salts, ammonium, amine or amine alcohol.

The anionic surfactant (s) according to the invention are preferably present in a total amount ranging from 0.5 to 20% by weight, preferably from 1 to 10% by weight, more preferably from 1 to 5% by weight relative to the weight. total composition SOLID FATTY ALCOHOLS "Solid fatty alcohols" are solid at room temperature (25 ° C) and at atmospheric pressure (780 mmHg), and insoluble in water (i.e., exhibit solubility in water less than 1% by weight and preferably less than 0.5% by weight). By fatty alcohol is meant a long-chain aliphatic alcohol comprising from 8 to 34 carbon atoms, and comprising at least one OH hydroxyl group. These fatty alcohols are neither oxyalkylenated nor glycerolated. Preferably the solid fatty alcohols are of R-OH structure with R denoting a linear alkyl group, optionally substituted with one or more hydroxy groups, comprising from 12 to 40, more preferably from 12 to 30 carbon atoms. The fatty alcohols solid at room temperature suitable for the implementation of the invention are more particularly chosen from: lauryl alcohol or lauryl alcohol (1 dodecanol); Myristic or myristyl alcohol, (1-tetradecanol); cetyl alcohol, (1-hexadecanol); stearyl alcohol, (1-octadecanol); arachidyl alcohol, (1-eicosanol); - behenyl alcohol, (1-docosanol); Lignocellulic alcohol, (1-tetracosanol); - Ceryl alcohol, (1-hexacosanol); - montanyl alcohol, (1-octacosanol); - myricylic alcohol, (1-triacontanol); 2,984,149 and their mixtures. Even more particularly, the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures thereof such as cetylstearyl or cetearyl alcohol. The fatty alcohols can be mixtures, which means that in a commercial product can coexist several species including different chain lengths, in the form of a mixture. The solid fatty alcohol (s) of the invention are generally present in an amount of from 0.01 to 30% by weight, preferably from 0.1 to 15% by weight and, more preferably, from 0.5 to 10% by weight. By weight relative to the total weight of the composition The weight ratio of solid fatty alcohol (s) / anionic surfactant (s) sulphate (s) or sulphonate (s) according to the invention is preferably from 1 to 15, more preferably 2 to 10. SOLID FATTY SOLIDS The composition of the invention comprises one or more solid fatty esters at room temperature (25 ° C) and at atmospheric pressure. Preferably, the solid fatty esters are esters of saturated carboxylic acids comprising at least 10 carbon atoms, and of saturated fatty monoalcohols containing at least 10 carbon atoms. Saturated acids or monoalcohols may be linear or branched. The saturated carboxylic acids preferably comprise from 10 to 30 carbon atoms and more particularly from 12 to 24 carbon atoms. They can be optionally hydroxylated. The saturated fatty monoalcohols preferably comprise from 10 to 30 carbon atoms and more particularly from 12 to 24 carbon atoms. Preferably, the solid fatty esters are chosen from myristyl, cetyl and stearyl myristates, myristyl, cetyl and stearyl palmitates, cetyl and stearyl myristyl stearates and mixtures thereof.

The said solid fatty ester (s) are present in an amount of between 0.1 and 10% by weight, and preferably in an amount of between 0.5 and 5% by weight relative to the total weight of the composition.

LIQUID FATTY BODY Fatty material means an organic compound which is insoluble in water at ordinary room temperature (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility less than 5% and preferably less than 1%). even more preferably at 0.1%). They have in their structure at least one hydrocarbon chain comprising at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as, for example, chloroform, ethanol, benzene, petroleum jelly or decamethylcyclopentasiloxane. are neither polyoxyethylenated nor polyglycerolated. The fatty substances according to the invention are liquid at room temperature (25 ° C.) and at atmospheric pressure (780 mmHg). They are chosen in particular from liquid fatty alcohols, liquid fatty esters, silicone oils, C6-C16 hydrocarbons, hydrocarbons having more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils from Triglycerides, synthetic triglycerides, fluorinated oils, "liquid fatty alcohols" are liquid at room temperature (25 ° C.) and at atmospheric pressure. Liquid fatty alcohols, in particular those containing C10-C34, have branched carbon chains or possess one or more (preferably 1 to 3) unsaturations. The liquid fatty alcohols according to the invention are preferably branched and / or unsaturated, and contain from 12 to 40 carbon atoms. The fatty alcohols of the invention are non-oxyalkylenated and non-glycerolated. The liquid fatty alcohols preferably have the R-OH structure, in which R preferably denotes a C12-C24 branched alkyl or C12-C24 alkenyl group. R may be substituted with one or more hydroxy groups. Preferably, R does not contain a hydroxyl group. By way of example, mention may be made of oleic alcohol, linoleic alcohol, linolenic alcohol, isocetyl alcohol, isostearyl alcohol, 2-octyl-1-dodecanol, 2-butyl octanol, 2- hexyl-1-decanol, 2-decyl-1-tetradecanol, 2-tetradecyl-1-ketanol and their mixture (s). Preferably, the liquid fatty alcohol of the invention is a branched saturated alcohol. Even more preferentially, the liquid fatty alcohol is 2-octyl-1-dodecanol. The fatty alcohols can be mixtures, which means that in a commercial product can coexist several species including different chain lengths, in the form of a mixture.

The liquid fatty esters that may be used according to the present invention may be esters of monoalcohols or of polyols with mono or polyacids, at least one of the alcohols and / or acids comprising at least one chain of more than 7 carbon atoms. Preferably, the liquid fatty ester according to the invention is chosen from fatty acid and monoalcohol esters. Preferably, at least one of the alcohols and / or acids is branched. As examples of liquid fatty esters according to the invention, mention may be made of isopropyl myristate, isopropyl palmitate, isononyl isononanoate, 2-ethylhexyl palmitate and 2-hexyldecyl laurate. , 2-octyldecyl palmitate, 2-octyldodecyl myristate. The silicones that can be used in accordance with the invention are in the form of oils.

Preferably, the silicone is chosen from polydialkylsiloxanes, in particular polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from amino groups and alkoxy groups. Organopolysiloxanes are further defined in Walter NOLL's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile. When volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and more particularly from cyclic polydialkylsiloxanes comprising from 3 to 7, preferably from 4 to at 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane marketed under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE ® 70045 V5 by RHODIA, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 sold by UNION CARBIDE, of the formula: ## STR2 ## O- with D ': Si-O-CH3 C8H17 Cyclic polydialkylsiloxane mixtures with organic compounds derived from silicon may also be mentioned, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and having a viscosity less than or equal to 5 × 10 -6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by Toray Silicone, silicones entering this class are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile polydialkylsiloxanes, polyorganosiloxanes modified with the above organofunctional groups, and mixtures thereof, are preferably used.

These silicones are more particularly chosen from polydialkylsiloxanes, among which may be mentioned mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of the silicones is measured at 25 ° C. according to ASTM Standard 445 Appendix C. Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of series 47 and 70,047 or MIRASIL oils ® marketed by RHODIA such as, for example 70 047 V 500 000 oil; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC.

Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA. In this class of polydialkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMIDT, which are polydialkyl (C1-C20) siloxanes. Particularly useful products according to the invention are mixtures such as: - mixtures formed from an end-hydroxylated polydimethylsiloxane or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such as the product Q2 1401 marketed by Dow Corning; The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. In addition to the silicones described above, the organomodified silicones may be polydiarylsiloxanes, especially polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized with the organofunctional groups mentioned above. The polyalkylarylsiloxanes are particularly chosen from polydimethyl / methylphenylsiloxanes, linear and / or branched polydimethyl / diphenylsiloxanes with a viscosity ranging from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes, mention may be made, by way of example, of the products sold under the following names: SILBIONE® oils of the 70 641 series from RHODIA; - the RHODORSIL® 70 633 and 763 RHODIA series of oils; - DOW CORNING 556 COSMETIC GRAD FLUID oil from Dow Corning; the silicones of the PK series of BAYER, such as the product PK20; The silicones of the PN, PH series of BAYER, such as the PN1000 and PH1000 products; certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: substituted or unsubstituted amino groups such as products sold under the name GP 4 Silicone Fluid and GP 7100 by the company GENESEE. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; Alkoxylated groups, such as the product marketed under the name "SILICONE COPOLYMER F-755" by SWS SILICONES. In one variant of the invention, the silicones are not organomodified.

As regards the C6-C16 hydrocarbons, the latter are linear, branched, optionally cyclic and preferably alkanes. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane. As hydrocarbon oils of animal origin, there may be mentioned perhydrosqualene. the triglyceride oils of vegetable or synthetic origin are preferably chosen from liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for instance triglycerides of heptanoic or octanoic acids or, for example, sunflower, corn, soy, squash, grape seeds, sesame, hazelnut, apricot, macadamia, arara, sunflower, pracaxi, argan, castor oil, avocado, triglycerides caprylic / capric acids such as those sold by Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil; The linear or branched hydrocarbons, of mineral or synthetic origin, of more than 16 carbon atoms, are preferably chosen from paraffin oils, petroleum jelly, vaseline oil, polydecenes, hydrogenated polyisobutene such as Parleam®. The fluorinated oils may be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTEC® PC1" and "FLUTEC® PC3" by the company BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or the bromoperfluorooctyl sold under the name "FORALKYL®" by the Atochem company; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M. Preferably, the liquid fatty substance according to the invention is chosen from silicone oils and liquid fatty alcohols. Even more preferentially, the liquid fatty substance is chosen from silicone oils. When they are present, the liquid fatty substance (s) of the invention are generally present in an amount ranging from 0.01% to 20% by weight, preferably from 0.1% to 10% by weight. by weight and, more preferably, from 0.5 to 5% by weight relative to the total weight of the composition. The composition may also further comprise at least one nonionic surfactant and / or at least one amphoteric surfactant.

The nonionic surfactants that can be used in the compositions of the present invention are well-known compounds per se (see in particular in this connection "Handbook of Surfactants" by MR PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116- 178). They are chosen in particular from alcohols, alpha-diols, alkyl (Ci-20) phenols, these compounds being polyethoxylated, polypropoxylated or polyglycerolated, and having a fatty chain comprising, for example, from 8 to 30 carbon atoms, preferably from 8 to 22, the number of ethylene oxide or propylene oxide groups ranging from 2 to 50 and the number of glycerol groups ranging from 2 to 30.

It is also possible to mention the condensates of ethylene oxide and of propylene oxide on fatty alcohols; the polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, the polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4, the fatty acid esters of sorbitan polyethoxylated ethers having preferably from 2 to 40 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, (C6-24) alkyl polyglycosides, N- (lower alkyl) derivatives, C6_24) glucamine, amine oxides such as (C18-C14 alkyl) amine oxides or N- (C10-C14) -aminopropylmorpholine oxides. Of the nonionic surfactants mentioned above, C 8-24 alkyl polyglycosides, and more particularly C 8 48 alkyl polyglycosides, fatty acid esters of polyethoxylated sorbitan, polyethoxylated fatty alcohols, are preferably used. The amphoteric surfactants which can be used in the present invention can be in particular derivatives of secondary or tertiary aliphatic amines, in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms and containing at least one group. anionic such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. In particular, mention may be made of (C 8 -C 28) betaines, sulfobetaines, (C 8-20 alkyl) amido (C 2-8 alkyl) betaines or (C 8-20 alkyl) amido (C 2-8 alkyl) sulfobetaines. Among the amine derivatives, mention may be made of the products sold under the name Miranoc, as described in US Pat. No. 2,528,378 and US Pat. No. 2,781,354, and classified in the CTFA dictionary, 3rd edition, 1982, under the names Amphocarboxy. glycogen and Amphocarboxypropionate of respective structures (1) and (2): Ra-CONHCH2CH2-N (Rb) (R1) (CH2C00-) (1) wherein: Ra represents an alkyl group derived from an acid Ra -COOH in hydrolyzed coconut oil, heptyl, nonyl or undecyl, Rb is beta-hydroxyethyl, and R is carboxymethyl; and Ra'-CONHCH2CH2-N (B) (C) (2) wherein: B represents -CH2CH2OX ', C represents - (CH2), - Y', with z = 1 or 2, X 'represents the group - CH 2 CH 2 -COOH or a hydrogen atom, Y 'represents -COOH or the group -CH 2 -CHOH-503H, Ra' represents an alkyl group of an acid Ra'-COOH present in coconut oil or in the hydrolyzed linseed oil, a saturated or unsaturated C7-C23 alkyl group, especially C17, and its iso form, an unsaturated C17 group.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate di-sodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium , lauroamphodipropionic acid, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate sold by RHODIA under the trade name MIRANOC C2M concentrate. Of the amphoteric surfactants mentioned above, C 8-20 alkylbetaines, C 8-20 alkylamido (C 2-8 alkyl) betaines, alkylamphodiacetates and mixtures thereof are preferably used. The nonionic and / or amphoteric surfactants are preferably present in the composition according to the invention in an amount ranging from 0 to 10% by weight, more preferably from 0.5 to 5% by weight relative to the total weight of the composition. composition. The total amount of surfactants is preferably from 1 to 20% by weight, more preferably from 1 to 10% by weight, and more preferably from 1 to 5% by weight relative to the total weight of the composition. The composition according to the invention may in particular further comprise one or more cationic polymers. The cationic polymers that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair, in particular those described in the patent application EP-A-0 337 354 and in the French patents FR-A-2,270,846, 2,383,660, 2,598,611, 2,470,596 and 2,519,863. More generally, within the meaning of the present invention, the term "cationic polymer" refers to any polymer comprising cationic groups and / or ionizable groups in cationic groups.

The preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that may either be part of the main polymer chain or may be carried by a lateral substituent directly connected thereto. The cationic polymers used generally have an average molecular weight in number or in weight of between about 500 and 5 × 10 6, and preferably between about 103 and 3 × 10 6.

Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products.

The polymers of the polyamine, polyamidoamide or quaternary polyammonium type which can be used in accordance with the present invention, which may be mentioned in particular, are those described in French Pat. Nos. 2,505,348 or 2,542,997. Among these polymers, mention may be made of: ) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formula: ## STR1 ## II X-IN 1: ZN + -R6 / \ 1 R2 ID '1 R5 125 R3 15 C-R3 1 C1 0 = C 0 = C 1 1 NH NH AXNA \ R2 N ± R6 R5 in which: R3, identical or different denote a hydrogen atom or a CH3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms; R1 and R2, identical or different, represent hydrogen or an alkyl group having 1 to 6 carbon atoms and preferably methyl or ethyl; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. The copolymers of the family (1) may further contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1-C4) , acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these copolymers of the family (1), mention may be made of: the copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company Hercules, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company Ciba Geigy; the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulphate sold under the name Reten by the company Hercules, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers quaternized or otherwise, such as the products sold under the name "GAFQUAT" by the company ISP such as "GAFQUAT 734" or "GAFQUAT 755 "or the products referred to as" COPOLYMER 845, 10 958 and 937 ". These polymers are described in detail in French Pat. Nos. 2,077,143 and 2,393,573, the terpolymers of dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone, such as the product sold under the name GAFFIX VC 713 by the company ISP, vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers sold in particular under the name STYLEZE CC 10 by ISP. quaternized dimethylaminopropyl vinylpyrrolidone / methacrylamide copolymers, such as the product sold under the name "GAFQUAT HS 100" by the company ISP, - preferably crosslinked polymers of methacryloyloxyalkyl (C 1 -C 4) trialkyl (C 1 -C 4) ammonium salts; such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized by methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by methyl chloride, the homo or copolymerization being followed by crosslinking with a compound of 25 olefinic unsaturation, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "SALCARE® 30 SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride comprising about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names "SALCARE® SC 95" and "SALCARE® SC 96" by the company CIBA. (2) Cationic polysaccharides, especially cationic celluloses and cationic galactomannans. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives containing quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums. The cellulose ether derivatives comprising quaternary ammonium groups described in French Patent 1,492,597, and in particular the polymers sold under the names "UCARE POLYMER JR" (JR 400 LT, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by the company AMERCHOL. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose reacted with an epoxide substituted with a trimethylammonium group.

Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in US Pat. No. 4 131 576, such as hydroxyalkyl celluloses, such as hydroxymethyl, hydroxyethyl or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyl trimethylammonium, methacrylmidopropyltrimethylammonium, dimethyl-diallylammonium. The marketed products corresponding to this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the company National Starch.

The cationic galactomannan gums are described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, in particular guar gums comprising cationic trialkylammonium groups. For example, guar gums modified with a salt (eg chloride) of 2,3-epoxypropyltrimethylammonium are used. Such products are marketed in particular under the trade names JAGUAR C13S, JAGUAR C15, JAGUAR C17 or JAGUAR C162 by RHODIA. (3) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are in particular described in French Patents 2,162,025 and 2,280,361; (4) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, or by an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halogenide, epilhalohydrin, diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polymaoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functions, quaternized. Such polymers are described in particular in French Patents 2,252,840 and 2,368,508; (5) polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid-diacoylaminohydroxyalkyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Such polymers are described in particular in French Patent 1,583,363. Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz. (6) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms . The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1; the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in the patents US 3,227,615 and 2,961,347. Polymers of this type are in particular sold under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / diethylenetriamine. (7) Cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium such as homopolymers or copolymers having as their main constituent of the chain units of formula (I) or (II): (CH2) kx - (CH2) ## STR2 ## ## STR2 ## ## STR2 ## ## STR2 ## ## STR2 ## R10 formulas wherein k and t are 0 or 1, the sum k + t being 1; R12 denotes a hydrogen atom or a methyl radical; R10 and R11, independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group ( C1-C4) or R10 and R11 may designate, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French Patent 2,080,759 and in its certificate of addition 2,190,406. R 10 and R 11, independently of one another, preferably denote an alkyl group having 1 to 4 carbon atoms. Among the polymers defined above, there may be mentioned more particularly the homopolymer of salts (for example chloride) dimethyldiallylammonium for example sold under the name "Merquat 100" by the company NALCO (and their counterparts of low molecular weight average weight ) and the copolymers of diallyldimethylammonium and acrylamide salts (for example chloride) marketed in particular under the name "MERQUAT 550" or "MERQUAT 7SPR". (8) quaternary diammonium polymers comprising repeating units corresponding to the formula: ## STR2 ## in which: R13, R14, R15 and R16, which may be identical or different, represent radicals; aliphatic, alicyclic, or arylaliphatic compounds comprising from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or else R13, R14, R15 and R16, together or separately, constitute, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile, ester, acyl, amide group or -CO-O-R17-D or -CO -NH20 R17-D where R17 is alkylene and D is a quaternary ammonium group; Al and B1 represent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- denotes an anion derived from a mineral or organic acid; A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 may also denote a (CH2) n -CO-D-OC- (CH2) n- group in which D denotes: a) a residue of glycol of formula: -O-Z-O-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: - (CH2-CH2-O) x-CH2-CH2- - [CH2 -CH (CH 3) -O] y-CH 2 -CH (CH 3) - where x and y denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing a degree of medium polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or alternatively the divalent radical -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula: -NH-CO-NH-; Preferably, X- is an anion such as chloride or bromide. These polymers have a number-average molecular weight generally of between 1,000 and 100,000. Polymers of this type are described in particular in French patents 2,320,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and the US Patents 2,273,780, 2,375,853, 2,388,614, 2,454,547, 3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 4,027,020. Polymers which consist of repeating units having the formula: + 3+ - N - (CH 2), - N- (CH 2) P - (IV) R 2 A R 4 in which R 1, R 2, R 3 can be used more particularly and R4, which may be identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are integers ranging from 2 to approximately 20 and X- is an anion derived from a mineral acid or organic.

A particularly preferred compound of formula (IV) is that for which R 1, R 2, R 3 and R 4 represent a methyl radical and n = 3, p = 6 and X = Cl, called Hexadimethrine chloride according to the INCI nomenclature (CTFA). (9) quaternary polyammonium polymers comprising units of formula (V): R 18 R 2, I - N + - (Cl - 12), - NH - CO - (Cl - 12) q - CO - NH - (CH 2 wherein R 18, R 19, R 20 and R 21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl or propyl radical, or hydroxyethyl, 13-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH, where p is 0 or an integer of 1 to 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, r and s, which may be identical or different, are integers between 1 and 6, q is 0 or an integer between 1 and 34, X- denotes an anion such as a halide, A denotes a radical of a dihalide or is preferably -CH2-CH2-O-CH2-CH2-. Such compounds are described in particular in the patent application EP-25 A-122 324. For example, the products "Mirapol® A 15", "Mirapol® AD1", "Mirapol® AZ1" and "Mirapol® 175" sold by the company Miranol. (10) Quaternary polymers of vinylpyrrolidone and vinylimidazole such as, for example, the products sold under the names Luviquat® FC 905, FC 550 and FC 370 by the company B.A.S.F. (11) Polyamines such as Polyquart® H sold by COGNIS, referenced under the name "POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE" in the CTFA dictionary.

Other cationic polymers which may be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives. Among the cationic polymers mentioned above, which are suitable in the invention, quaternary cellulose ether derivatives such as the products sold under the name "JR 400" by the company Amerchol, cationic cyclopolymers, may be preferably used. in particular homopolymers or copolymers of salts (for example chloride) dimethyldiallylammonium, sold under the names "MERQUAT 100", "MERQUAT 550" and "MERQUAT S" by the company NALCO and their homologues of low molecular weight by weight, the quaternary polymers vinylpyrrolidone and vinylimidazole, optionally crosslinked homopolymers or copolymers of methacryloyloxyalkyl (Ci -C4) trialkyl (Ci - C4) ammonium salts and mixtures thereof.

If they are present, the cationic polymers are generally present in concentrations ranging from 0.01 to 20%, preferably from 0.05 to 10% and more particularly from 0.1 to 5% by weight relative to the total weight. of the composition.

The composition according to the invention is preferably aqueous. It may also contain at least one organic solvent chosen from C1-C4 lower alcohols, such as ethanol, isopropanol, tert-butanol or n-butanol; polyols such as glycerol, propylene glycol and polyethylene glycols.

Preferably, the composition comprises from 70 to 95% by weight of water relative to the total weight of the composition.

The pH of the compositions according to the invention is generally between 2 and 11, preferably between 3 and 10 and more preferably between 4 and 8.

The composition according to the invention may furthermore comprise additives chosen from anionic polymers, nonionic polymers, amphoteric polymers, associative or non-associative polymeric thickeners, non-polymeric thickeners, pearlescent agents, opacifiers, dyes or pigments, perfumes, vitamins, UV filters, anti-radical agents, anti-dandruff, preservatives, pH stabilizers, solvents, anionic surfactants other than those of the invention and mixtures thereof. Those skilled in the art will take care to choose the possible additives and their amount so that they do not adversely affect the properties of the compositions of the present invention. These additives are generally present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.

The compositions may be packaged in various forms, in particular in flasks, pump-bottles or in aerosol containers in order to ensure application of the composition in vaporized form or in foam form. The compositions may also impregnate applicators, including gloves or wipes. The composition according to the invention may be applied after coloration, in particular oxidation dyeing, perming, straightening, or any other hair treatment, in particular treatments using one or more cationic polymers. In a preferred variant of the invention, the composition according to the invention may be applied after coloration, in particular oxidation dyeing.

The present invention also relates to a process for conditioning keratin materials, in particular keratinous fibers, and more particularly the hair, which consists in applying an effective amount of a composition as described above to keratinous materials, optionally to carry out a keratinous material. rinsing for example with water after a possible exposure time. Preferably, rinsing is carried out after a possible exposure time.

The following examples are illustrative of the present invention. All quantities indicated are in% by weight unless otherwise indicated. EXAMPLES 1 The following conditioner composition was prepared: COMPOSITION 1 Cetylstearyl alcohol (C16 / C18 50/50 by weight) (LANETTE O OR FLAKES-COGNIS) 7% myristate / palmitate / myristyl stearate / cetyl / stearyl blend 1.5% (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) (PELLET LANTERN - COGNIS) 3% MA Silicone amine 20% by weight in polydimethylsiloxane 20 cst (KF 8020 -SHIN ETSU 0.5% Citric acid qs pH 5 Preservatives 0.33% Water qs 100% MA: active ingredient Examples 2 The following conditioner composition was prepared: COMPOSITION 2 Cetylstearyl alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES - COGNIS) 7% Myristate / Palmitate / Myristyl Stearate / Cetyl / Stearyl 1.5% Blend (CRODAMOL MS-V-CRODA) 15 2 984 14 9 26 Cetostearyl Sodium Sulphate (C16 / C18 50/50) (LANETTE E) GRANULES - COGNIS) 3% aminosilicone 20% by weight in polydimethylsiloxane 20 cst (KF 8020 -SHIN ETSU) 3.5% Citric Acid pH 5 Conser 0.33% Water qs 100% Examples 3 The following conditioner composition was prepared: COMPOSITION 3 Cetylstearyl Alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 10% Myristate / Palmitate / Blend Myristyl / cetyl / stearyl stearate 1 (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) (GRANULES LANTERN - COGNIS) 1% MA Silicone amine at 20% by weight in polydimethylsiloxane 20 cst (KF 8020 -SHIN ETSU) 3.5% Citric acid pH 5 Preservative 0.33% Water qs 100% Examples 4 The following conditioner composition was prepared: COMPOSITION 4 Cetylstearyl alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 10% Myristate / Palmitate / Myristyl / cetyl / stearyl 2% (CRODAMOL MS-V-CRODA) mixture Sodium cetostearyl sulphate (C16 / C18 50/50) 5% MA 5 10 2 984 149 27 (LANETTE E GRANULES - COGNIS) Silicone amine 20% by weight in polydimethylsiloxane 20 cst (KF 8020 -SHIN ETSU) 3.5% Citric acid pH 5 Preservative 0.33% Water qs 100% EXAMPLES The following conditioner composition was prepared: COMPOSITION Cetyl stearyl alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 5% Myristate / Palmitate / Stearate Blend myristyl / cetyl / 1.5% stearyl (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) (LANETTE E GRANULES - COGNIS) 1% MA Silicone amine 20% by weight in polydimethylsiloxane Cst (KF 8020 -SHIN ETSU) 0.5% Citric acid pH 5 Preservative 0.33% Water qs 100% Examples 6 The following conditioner composition was prepared: COMPOSITION 6 Cetylstearyl alcohol (C16 / C18 50 / 50) (LANETTE O OR FLAKES-COGNIS) 10% Myristate / Palmitate / Myristyl / cetyl / stearyl 1 mixture (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) 1% MA 5 10 2 984 14 9 28 (LANTERN E GRANULES - COGNIS) Dimethicone (DOW CORNING 200 FLUID 500000CS - Dow Corning) 0.65% Dimethicone 1.95% (MIRASIL DM 50-BLUESTAR) Citric acid pH 5 C 0.33% Water qs 100% Examples 7 The following conditioner composition was prepared: COMPOSITION 7 Cetylstearyl Alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 10% Myristate / Palmitate / Blend Myristyl / cetyl stearate / stearoyl 2% (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) (LANETTE E GRANULES - COGNIS) 5% MA Dimethicone (Dow Corning 200 Fluid 500000CS - Dow Corning) 0.65% Dimethicone 1.95% (MIRASIL DM 50-BLUESTAR) Citric acid pH 5 Preservative 0.33% Water qs 100% Examples 8 The following conditioner composition was prepared: COMPOSITION 8 Cetyl stearyl alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 5% Myristate / Palmitate / Stearate Blend 1.5% 5 10 2 984 14 9 29 myristyl / cetyl / stearyl (CRODAMOL MS-V-CRODA) Sodium cetostearyl sulphate (C16 / C18 50/50) (PELLET LANTERN - COGNIS) 1% MA Dimethicone (Dow Corning 200 Fluid 500000CS - Dow Corning) 0.65% Dimethicone 1.95% (MIRASIL DM 50-BLU ESTAR) Citric acid pH 5 Preservative 0.33% Water qs 100% Examples 9 The following conditioner composition was prepared: COMPOSITION 9 Cetylstearyl alcohol (C16 / C18 50/50) (LANETTE O OR FLAKES-COGNIS) 5% Mixture Myristate / Palmitate / Myristyl Stearate / Cetyl / 1.5% Stearyl (CRODAMOL MS-V-CRODA) Sodium Cetostearyl Sulfate (C16 / C18 50/50) (LANETTE E GRANULES - COGNIS) 1% MA Octydodecanol 2% (ETANOL G - COGNIS) Citric acid pH 5 Preservative 0.33% Water qs 100% The compositions are stable. If the sodium cetostearyl sulphate is replaced by sodium lauryl sulphate in composition 1, the composition is not stable. The wet and dried hair treated with the compositions of Examples 1 to 9 have very good cosmetic properties, especially in terms of smoothing.

Claims (18)

REVENDICATIONS1. Non-coloring and non-oxidizing composition, in particular for conditioning keratin materials, characterized in that it comprises: one or more sulphonated or sulphonated anionic surfactants, one or more solid fatty alcohols, one or more solid fatty esters, and optionally one or more liquid fatty substances, the at least one anionic sulphate or sulphonate surfactant being such that at least 50% by weight of them contain fatty chains having a number of carbon atoms equal to or greater than 14. 15 2. Composition according to the preceding claim characterized in that the sulfate or sulfonate anionic surfactant is selected from C16-C18 alkyl sulphates and C16-18 alkyl ether sulphates and mixtures thereof. 20 3. Composition according to one of the preceding claims, characterized in that the anionic surfactants sulfates or sulphonates are present in an amount ranging from 0.5 to 20% by weight, preferably from 1 to 10% by weight, more preferably 1 to 5% by weight relative to the total weight of the composition. 25 4. Composition according to any one of the preceding claims, characterized in that the solid fatty alcohols contain from 12 to 40 carbon atoms. 30 5. Composition according to the preceding claim, characterized in that the solid fatty alcohols have the structure R-OH, wherein R denotes a linear, optionally substituted, C12-C24 alkyl group. 6. Composition according to the preceding claim, characterized in that the solid fatty alcohols are chosen from cetyl alcohol, stearyl alcohol, behenyl alcohol and their mixture (s). 7. Composition according to any one of the preceding claims, characterized in that the solid fatty alcohol (s) are present in an amount ranging from 0.01 to 30, preferably from 0.1 to 15, more preferably from 0.5 to 10% by weight relative to the total weight of the composition. 8. Composition according to any one of the preceding claims, characterized in that the solid fatty esters are chosen from myristyl, cetyl and stearyl myristates, myristyl, cetyl and stearyl palmitates, myristyl stearates of cetyl and stearyl and mixtures thereof. 9. Composition according to any one of the preceding claims, characterized in that the solid fatty esters are present in an amount of between 0.1 and 10% by weight, and preferably in an amount of between 0.5 and 5%. by weight relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, characterized in that the liquid fatty substance or fats are chosen from liquid fatty alcohols, liquid fatty esters, silicone oils, C6-C16 hydrocarbons, hydrocarbons having more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, fluorinated oils. 11. Composition according to the preceding claim, characterized in that the liquid fatty substance or fats are chosen from liquid fatty alcohols and silicone oils, preferably silicone oils. 12. Composition according to any one of the preceding claims, characterized in that the liquid fat or fats are present in an amount ranging from 0.01 to 20%, preferably from 0.1 to 10%, and more preferably from 0 to 10%. , 5 to 5% by weight relative to the total weight of the composition. 13. Composition according to any one of the preceding claims, characterized in that it further comprises at least one nonionic surfactant and / or at least one amphoteric surfactant. 14. Composition according to any one of the preceding claims, characterized in that the composition further comprises water and optionally at least one organic solvent. 15. Composition according to any one of the preceding claims, characterized in that the composition further comprises at least one cationic polymer. 16. Use of the composition according to any one of the preceding claims, for the conditioning of keratin materials and in particular keratinous fibers. 17. A process for conditioning keratin materials and in particular keratin fibers, comprising applying an effective amount of a composition according to any one of claims 1 to 15, on keratin materials, and an optional rinsing after a possible exposure time, preferably with a rinse 18. A process for conditioning keratin materials and in particular keratin fibers according to claim 17, in which the application of a composition according to any one of claims 1 to 15 is carried out after a coloration, in particular a coloration. oxidation, perming, straightening, or any other hair treatment and preferably after coloring, in particular oxidation dyeing. 30