FR2983853B1 - HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES - Google Patents

HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES

Info

Publication number
FR2983853B1
FR2983853B1 FR1161497A FR1161497A FR2983853B1 FR 2983853 B1 FR2983853 B1 FR 2983853B1 FR 1161497 A FR1161497 A FR 1161497A FR 1161497 A FR1161497 A FR 1161497A FR 2983853 B1 FR2983853 B1 FR 2983853B1
Authority
FR
France
Prior art keywords
benzyloxy
calix
arenes
high yield
yield synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1161497A
Other languages
French (fr)
Other versions
FR2983853A1 (en
Inventor
Vincent Germain Huc
Cyril Martini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universite Paris Sud Paris 11
Original Assignee
Universite Paris Sud Paris 11
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universite Paris Sud Paris 11 filed Critical Universite Paris Sud Paris 11
Priority to FR1161497A priority Critical patent/FR2983853B1/en
Priority to PCT/FR2012/052877 priority patent/WO2013088056A1/en
Priority to US14/364,484 priority patent/US9255054B2/en
Priority to EP12816705.3A priority patent/EP2791097B1/en
Publication of FR2983853A1 publication Critical patent/FR2983853A1/en
Application granted granted Critical
Publication of FR2983853B1 publication Critical patent/FR2983853B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/92—Systems containing at least three condensed rings with a condensed ring system consisting of at least two mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic system, e.g. cyclophanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Preparing compounds comprising p-(benzyloxy)calix[6]arene and/or p-(benzyloxy)calix[7]arene, comprises contacting cesium hydroxide such as a base, with p(benzyloxy)phenol and paraformaldehyde, where the base has a concentration of 0.09-0.5 equivalent, relative to the p-(benzyloxy)phenol. An independent claim is included for the compound comprising p-(benzyloxy)calix[7]arene in cesium monosalt form obtained by the process.
FR1161497A 2011-12-12 2011-12-12 HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES Expired - Fee Related FR2983853B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1161497A FR2983853B1 (en) 2011-12-12 2011-12-12 HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES
PCT/FR2012/052877 WO2013088056A1 (en) 2011-12-12 2012-12-11 High‑yield synthesis of p-(benzyloxy)calix[6, 7, 8]arenes
US14/364,484 US9255054B2 (en) 2011-12-12 2012-12-11 High-yield synthesis of p-(benzyloxy)calix[6, 7,8]arenes
EP12816705.3A EP2791097B1 (en) 2011-12-12 2012-12-11 High yield synthesis of p-(benzyloxy)calix[6,7,8]arenes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1161497A FR2983853B1 (en) 2011-12-12 2011-12-12 HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES

Publications (2)

Publication Number Publication Date
FR2983853A1 FR2983853A1 (en) 2013-06-14
FR2983853B1 true FR2983853B1 (en) 2013-12-20

Family

ID=45524864

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1161497A Expired - Fee Related FR2983853B1 (en) 2011-12-12 2011-12-12 HIGH YIELD SYNTHESIS OF P (BENZYLOXY) CALIX [6,7,8] ARENES

Country Status (1)

Country Link
FR (1) FR2983853B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113880707A (en) * 2021-10-22 2022-01-04 燕山大学 Preparation method and application of calix [ octaquinone ]

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2797442B1 (en) * 1999-08-13 2003-10-03 Commissariat Energie Atomique CALIXARENES ACETAMIDO DERIVATIVES, THEIR PREPARATION AND THEIR USE FOR THE EXTRACTION OF STRONTIUM

Also Published As

Publication number Publication date
FR2983853A1 (en) 2013-06-14

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