FR2973371B1 - PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS - Google Patents

PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS

Info

Publication number
FR2973371B1
FR2973371B1 FR1152888A FR1152888A FR2973371B1 FR 2973371 B1 FR2973371 B1 FR 2973371B1 FR 1152888 A FR1152888 A FR 1152888A FR 1152888 A FR1152888 A FR 1152888A FR 2973371 B1 FR2973371 B1 FR 2973371B1
Authority
FR
France
Prior art keywords
optionally substituted
compound
formula
preparation
formamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1152888A
Other languages
French (fr)
Other versions
FR2973371A1 (en
Inventor
Thibault Cantat
Christophe Gomes
Olivier Jacquet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1152888A priority Critical patent/FR2973371B1/en
Priority to JP2014503260A priority patent/JP2014517815A/en
Priority to PCT/IB2012/051667 priority patent/WO2012137152A2/en
Priority to EP12717879.6A priority patent/EP2694469B1/en
Priority to US13/805,899 priority patent/US8877971B2/en
Publication of FR2973371A1 publication Critical patent/FR2973371A1/en
Application granted granted Critical
Publication of FR2973371B1 publication Critical patent/FR2973371B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C07D295/104—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/108—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C07D211/76—Oxygen atoms attached in position 2 or 6
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C07D233/60—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with hydrocarbon radicals, substituted by oxygen or sulfur atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Preparing a formamide compound (I), comprises reacting an amine compound (II) with carbon dioxide in the presence of a catalyst and silane compound (III). Preparing a formamide compound of formula (H-C(=O)-N((R1)(R2))) (I), comprises reacting an amine compound of formula (H-N((R1)(R2))) (II) with carbon dioxide in the presence of a catalyst and a silane compound of formula (H-Si((R3)(R4)(R5))) (III). Either R1, R2 : H, alkyl, alkenyl, alkynyl, (hetero)aryl, heterocyclic, silyl, siloxy or amino (all optionally substituted); or R1R2+N : heterocycle (optionally substituted); and either R3-R5 : alkyl, alkenyl, alkynyl, alkoxy, silyl, siloxy, aryl, amino (all optionally substituted), H, halo or OH; or R3R4+Si : silylated heterocycle (optionally substituted).
FR1152888A 2011-04-04 2011-04-04 PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS Active FR2973371B1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1152888A FR2973371B1 (en) 2011-04-04 2011-04-04 PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS
JP2014503260A JP2014517815A (en) 2011-04-04 2012-04-04 Method for producing formamide compound
PCT/IB2012/051667 WO2012137152A2 (en) 2011-04-04 2012-04-04 Method for preparing formamide compounds
EP12717879.6A EP2694469B1 (en) 2011-04-04 2012-04-04 Method for preparing formamide compounds
US13/805,899 US8877971B2 (en) 2011-04-04 2012-04-04 Method for preparing formamide compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1152888A FR2973371B1 (en) 2011-04-04 2011-04-04 PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS

Publications (2)

Publication Number Publication Date
FR2973371A1 FR2973371A1 (en) 2012-10-05
FR2973371B1 true FR2973371B1 (en) 2013-05-10

Family

ID=44512947

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1152888A Active FR2973371B1 (en) 2011-04-04 2011-04-04 PROCESS FOR THE PREPARATION OF FORMAMIDE COMPOUNDS

Country Status (1)

Country Link
FR (1) FR2973371B1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3012050B1 (en) 2013-10-17 2016-01-01 Capsum METHOD OF FORMING A DISPERSION COMPRISING DROPS, AND APPARATUS THEREFOR
CN114989031B (en) * 2022-05-30 2024-08-20 湖南工程学院 Preparation method for synthesizing unsaturated amide by carbon dioxide and alkyne

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB783582A (en) * 1954-11-09 1957-09-25 Rohm & Haas Improvements in preparation of formamides
JPS5236617A (en) * 1975-09-17 1977-03-22 Mitsui Petrochem Ind Ltd Process for preparation of formamide derivatives
JPS5699450A (en) * 1980-11-28 1981-08-10 Sagami Chem Res Center Preparation of n-acyl-n-substituted formamide derivative
JPS62255456A (en) * 1986-04-30 1987-11-07 Idemitsu Petrochem Co Ltd Production of diethylformamide
DK0652202T3 (en) * 1993-11-04 1997-12-22 Japan Res Dev Corp Process for the preparation of formic acid or derivatives thereof

Also Published As

Publication number Publication date
FR2973371A1 (en) 2012-10-05

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