FR2969697A1 - Dual catalytic nitrogen oxide trap integrated exhaust line desulfating method for lean-burn diesel engine of motor vehicle, involves determining progression of desulfation phase based on temperature of nitrogen oxide trap remote from engine - Google Patents

Dual catalytic nitrogen oxide trap integrated exhaust line desulfating method for lean-burn diesel engine of motor vehicle, involves determining progression of desulfation phase based on temperature of nitrogen oxide trap remote from engine Download PDF

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Publication number
FR2969697A1
FR2969697A1 FR1061001A FR1061001A FR2969697A1 FR 2969697 A1 FR2969697 A1 FR 2969697A1 FR 1061001 A FR1061001 A FR 1061001A FR 1061001 A FR1061001 A FR 1061001A FR 2969697 A1 FR2969697 A1 FR 2969697A1
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Prior art keywords
temperature
trap
engine
nitrogen oxide
remote
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FR1061001A
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French (fr)
Inventor
Morvan Pierre Yves Le
Xavier Descamps
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Renault SAS
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Renault SAS
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Priority to FR1061001A priority Critical patent/FR2969697A1/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0093Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are of the same type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/085Sulfur or sulfur oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • F01N3/0885Regeneration of deteriorated absorbents or adsorbents, e.g. desulfurization of NOx traps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2900/00Details of electrical control or of the monitoring of the exhaust gas treating apparatus
    • F01N2900/06Parameters used for exhaust control or diagnosing
    • F01N2900/16Parameters used for exhaust control or diagnosing said parameters being related to the exhaust apparatus, e.g. particulate filter or catalyst
    • F01N2900/1602Temperature of exhaust gas apparatus

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

The method involves triggering operation of a lean-burn internal combustion engine of a vehicle in a desulfation phase alternating with rich and lean periods. Progression of the desulfation phase is determined based on temperature of a nitrogen oxide trap (3) arranged remote from the engine, where a richness value during rich period of the desulfation phase takes a first value ranging from 1.03 to 1.05 if the temperature of the trap is greater than threshold, and takes a second value of 1.15 if the temperature of the trap is lower than the threshold. An independent claim is also included for a device for treating pollutant emission from a lean-burn engine of a vehicle,.

Description

DESULFATLAUQNNE LIGNE tYECHAPPEMENT A EEEEEEEEEEEEE OXYDE D'AZOTE bE MQIE.VS, MELANg.fAUVRE LInVen iàn se. situe dans le. d.eenaine :du part-traitenent. de 'éMiSSiOnS pelkiantèe: à réchappeffient dé.. Motees à :combueioh. interne -fonctionnant habitûelleMee en Mélange pauvre,. notaniMent les moteurs diesel équipant des Véhiet,iles autee.bilèe. .... . Plue precisement elle concerne lé procédé. de désulfatetion de pièges ta Cat:alytiqteis oxydes dkiedé. (NOx) èquiixxit la ligne d4chappement de. tels caner ne égaleinenl diepositif. de traitement de émissions pallnantee crie inotei.e'sutiliseit W1 tel procédé. Lee" Mo4elire modernes fOnCtianhant. herWellemehl neege. pauvre, c'est-à-e e aVeC Egin rappOrt: de le qUenfité. de torburont su la uarttité d'air 1 5. inférieur -au. rapport stoachiaMétrique, sont parfais équipée. d'Une ligne. déchappeMeiit «en:portent uh piège cetalytique A..oxydes eaeote, pour limiter tes rejets elahs rat Mosphère de. cette espèce. nocive à la santé et à l'environnement Un -tel piège fOnctionne usuellement :de 'manière séquentielle II stocke les. éMiesions de NOx pendant WS phase-de 'fonctionnement habituel du moteur .:en. . . . mélange pauvre, be teinpe eh tempe,. calculateur. :du moteur déclenche le beeenleinent de ce dernier tiens un mode. de fonctionnement en: .mélege riche,: c'est-à-dire. avec un excès de carburant par rapport à. Vair, comparativement :aux conditions. etoeChioMétriquee. Le: piège catalytique est alors purgé: il réduit les molécules. d'Oxydes (NOx) en moiéeutes d'ezote (N2). inoffensives gi:ii sont 25 rejetées Mans l'dtrnospl3ar.re.. DESULFATLAUQNNE LINE EXHAUST EEEEEEEEEEEEEEE NITROGEN OXIDE BE MQIE.VS, MELANg.fAUVRE LInVen iàn se. located in the. d.eenaine: on the part-treatenent. of Pelkiantèe eMiSSiOn: to rechappie d .. Motees to: combueioh. internally -operating in poor, poor mixing. Notably the diesel engines fitted to Vehiet, the United States. .... More precisely, it concerns the process. desulfation of traps Cat: alytiqteis oxides of time. (NOx) equals the exhaust line of. such caner is not equal in any way. This process is used in the case of palliative creep emissions inotei. The modern world is a poor one, that is to say, with respect to the quality of the air in the air, which is lower than the stoachia metric ratio, are perfectly equipped. A line can be found in a chemical trap, which can be used to limit the emissions of this species to the health and the environment. stores the NOx emissions during the usual engine operation phase: in lean mixture, beeweled in the engine, the engine starts the engine of the engine, and It is a rich mixture, that is to say, with an excess of fuel compared to Vair, in comparison with the chemical and chemical conditions: the catalytic trap is then purged: it reduces the molecules of oxides (NOx). ) in meeutes of ezote (N2), inoffensive gi: ii are rejected 25 Mans the dtrnospl3ar.re ..

Un problème connu- des piéges catalytiques. à oxyde eezote est leur empoisonnement progressif par le soufre contenu des le:carburant et dame Les moiéCLiles de soufre tendent à se stocker. sur. le. piège, et elles en diminuent progressivement la capacité de stockage de. NOxi ce qui peut conduire,. à ;30. rapprocher et ri. multiplier les phases de purge, ço(ltgusee en. carburant Pour lutter contre cet empoisonnement du piège et lui conserver toute son efficacité, le calculateur du moteur déclenche une phase de régénération, dite de désaifatation, qui consiste a alterner des périodes de fonctionnement du moteur en mélange riche et en mélange pauvre, le piège ayant une température supérieure à un seuil minimum, typiquement de l'ordre de 650'C. Cette température peut être déterminée par mesure grace à un capteur, ou par Un modèle de calcul intégré au calculateur, Elle peut être atteinte, par exemple, en maintenant assez longtemps !a durée de la première période de fonctionnement en mélange riche du moteur pendant la phase de désulfatation, ou par l'utilisation de moyens de chauffage additionnels. La valeur de la richesse choisie pendant les périodes de fonctionnement en mélange riche de Io phase de déseatation est comprise entre environ 1,03 et 1,05. Il y a un excès d'environ 3 à 5 % de carburant sur Fair par rapport à Id quantité stoechiométrique. Cette valeur est le résultat dun compromis, qui permet de rejeter le soufre essentiellement sous la forme d'oxyde de. soufre (SO2), composé inoffensif, Eh dessous de cette plage de richesse, le soufre ne parvient pas à être désorbé convenablement du piège. Au dessus, le soufre peut être évacué plus rapidement du piège. Cependant, les rejets contiennent alors non seulement des oxydes de soufre (SO2), mais SUrtOUt du Se Ure d'hydrogène «I-12S) qui est un composé particulièrement malodorant, La proportion de H25 est d'autant plus grande que la richesse est élevée, tes pièges catalytiques à oxydes d'azote connus ont un rendement limité, Un moyen de réduire les rejets de NOx dans l'atmosphère consiste à équiper la ligne d'échappement d'un moteur de deux pièges catalytiques à oxydes d'azote placés en série, de manière à augmenter le rendement de l'ensemble, les deux pièges étant régulièrement purgés de leurs 1\10x et désulfatés, La publication U5 2009 0229249 présente un tel arrangement, Pour des raisons d'encombrement, il est ement mpassible de loger sous ...le-capot 41un..véhieule. plus: d'un piège. Ça.talytiqueà oxydes. dlazote'. bans eas dlune:. ligne d'échappement équipée ..de deux piège e, le piège le plue éloigné du moteur doit e re logé. sous la caisse daa véhieule.,. à. une di-Stance. impertante, :du. piège le plus rapproché dei moteur, qui. est logé soaE~ le capote e. La distance -que se pare le piège éloigné. du MoteUe. rend ed. montée en température plus longue que celle du piège rapproché. Lorsque le calculateur du moteur lance une phase alternent des périodee riches et pauvres pour désulfater la ligne dlécheppeinent, le piège rapproché est désulfaté facilement -or sa montée en température au dessus du seuil de 650'C est très rapide après la mise en 10 marche du moteur, nuis, tant que la température dag piège éloigné est inférieure à ce m'élime seuil, les oxydes de soufre (SO2) désorbés du piège rapproché se stockent entièrement sur le piège éloigne, Globalement, la désulfatation de la ligne d'échappement échoue, Le carburant dédié à cette opération est perdu, L'invention vise à. améliorer l'efficacité globale du procédé de desulfatation 15 dîme ligne d'échappement à double piège à oxydes d'azote, ert proposant cale le déroulement de chaque phase de désulfatation soit déter Ilné en fonction de la température du piege le plUS éloigné du MOteUr. Plus précisément, elle. prévoit que le calculateur du moteur détermine une phdse de desulfatafion specffique lorsque la ternperature du piégé éloh né est 20 inférieure à un seuil de températures c'est-à-dire une phase différente de la phase de désulfatatioh classique du piège rapproché pris solément. Selon ün premier mode de réalisation de l'invention, la phase de désulfatation de la ligne d'échappement n'est autorisée par le calculateur que si la température du piège éloigné est eupérieure à un seuil de température donné. La 25 phage de chauffe de la ligne d'échappement qui précède la phase de désulfatation est prolongée jusqulà ce que le piège éloigné soit suffisamment chaud, Selon un deuxième mode, la phase de désulfatation de la ligne d'échappement est autorisée quelle que soit la température du piège éloigné, ,ét cette température est au dessus d'un seuil donné, les périodes de fonctionnement 1 du. moteur :en. mélange riche lors de la phase dg déSulfatation se: déroulent avec: première. valeur de richesse, typiquemen. de. l'ordre de 1,03 à. 1Q5.> 5i cette tempéra...ore est Qu. dessous du. seuil,. l'es périodes. de. : onctipnnernent. en mélange riche ont lieu avec une se:onde valee de richesse, supérieure:à. la pr~~r~i~re vateuri typiquement de l'ordre de 1,1 - 1>'ciutres caractéristiques avantages de. la prlésente: invention appareitrpnt clairement a. le lecture de la despriptioit suivante d'Un. mode de réelisation ripn: de pelle7ei., en se. reportant à.. la figure qui représente une. vue en perspective d'une ligne d'échappement comportant deux. :pièges 10. catalytiques à oxydes azote enpsérie:. Fri référence à: eefte. figure ligne. déchappetnent reçoit des d'échappement d'un moteur à. combustion interne non représenté) fonctionnant habituellement en mélange pauvrei par exemple. un motepp. diesel Muni d'an catalyseur d'oxydation. (non représenté). permettant 0e. traiter en continu l'oXyde de carbone :t les hydrocarbures imbrûlée contenue plane. les gaz par. le Moteur. ..C.ee ,qp;tz pénètrent dans la.pliane . eéphappetnent et en reseprtent après-traitement, dans le sens des flèches de la figure, La ligne d'échappement comporte un premier piège catalytique oxydes d'azote, pu piège rapproché 1, qui est monté au plus près du moteur pour avoir une montée en température rapide, après le démarrage de ce dernier> De façon non-limitative, ce piège rapproché 1 est logé, dans un même compartiment de le ligne d'échappements ati voisinage d'un filtre à particules qui traite les particules de suie émises per le moteur. 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(x N.) .?4.0ZOp $VpAXO. :SV" .5?.fre d. .'Xnpp $?]. - g - gZ L69696Z 2969697 - 6 - supérieure à la richesse r par exemple de l'ordre de 1,15 , alors due la température du piège éloigné 3 est inférieure au seuil 5, le soufre se désorbe du piège rapproché 1 sous !a forme de H25 et se eestocke sur le piège éloigné 3, Puis, après que le température du piège éloigné 3 a dépassé le seuil 5., lorsqu'une phase de désulfatation est lancée avec des périodes riches de richesse ri , les molécules de H2S adsorbées par le piège éloigné 3 s'en désorbent sous forme de 502, En résumé, l'invention propose, pour une I'gne d'échappement a double piège à oxydes d'azote 1,3 de moteur à combustion interne fonctionnant usuellement en mélange pauvres d'optimiser le procédé de désulfatation de la ligne, 9race à un deroulement de chaque phase de désulfatetion qui soit déterminé par le calculateur en fonction de la températ e du piege le plus éloigné du moteur 3. Selon un premier mode de réalisation de l'invention, une phase de désulfatation de la ligne d'échappement est autorisée quand la température du piège éloi dépasse le seuil 5, 15 Selon un deuxième mode, une phase de désulfatation de ln ligne est lancée par une alternance de périodes de fonctionnement du moteur en régime riche et en régim.e pauvre, les périodes riches se déroulant avec une première valeur de richesse rl si la température du piège éloigné 3 est supérieure au seuil 5, ou avec une seconde valeur de richesse r2, supérieure a la première valeur si la 2 température du piege éloigné 3 est inférieure au seuil L'invention propose également un dispositif de traitement des émissions polluantes dIun moteur a mélange pauvre de véhicules comportant un double piège a oxydes d'azote (1,3) et un calculateur capable de provoquer le basculement du fonctionnement du moteur, dans une phase alternant des périodes riches e des 25 périodes pauvres. Selon l'invention, le dispositif comprend des moyens de détermination de la température associés au piège le plus éloigné du moteur (3), qui fournissent une valeur de ln température du piège éloigné 3 au calculateur, ce dernier faisant se dérouler chaque phase d'alternance de périodes riches et pauvres en fonction de cette valeur de température. A known problem - catalytic traps. With eezote oxide is their progressive poisoning by the sulfur contained in the fuel and the lady's sulfuric acids tend to store themselves. sure. the. trap, and they gradually decrease the storage capacity of. NOxi what can lead ,. to 30. get closer and laughed. multiply the purge phases, to avoid this poisoning of the trap and keep it all its efficiency, the engine calculator triggers a phase of regeneration, called désaifatation, which consists of alternating periods of engine operation in rich mixture and in lean mixture, the trap having a temperature above a minimum threshold, typically of the order of 650 ° C. This temperature can be determined by measurement by means of a sensor, or by a calculation model integrated into the calculator It can be reached, for example, by maintaining the duration of the first period of operation in rich engine mixture during the desulfation phase, or by the use of additional heating means. during periods of operation in rich mixture of Io phase deeatation is between about 1.03 and 1.05 There is an excess of enviro n 3 to 5% fuel on Fair compared to Id stoichiometric amount. This value is the result of a compromise, which makes it possible to reject the sulfur essentially in the form of oxide of. sulfur (SO2), harmless compound, below this range of richness, the sulfur does not manage to be properly desorbed from the trap. Above, the sulfur can be evacuated more quickly from the trap. However, the discharges then contain not only sulfur oxides (SO2), but also the hydrogen phase (I-12S), which is a particularly malodorous compound. The proportion of H25 is all the greater since the richness is higher. Nitrogen oxide catalytic traps are known to have a limited yield. One way of reducing NOx emissions into the atmosphere is to equip the exhaust line with an engine of two catalytic nitrogen oxide traps placed in the atmosphere. in series, so as to increase the efficiency of the assembly, the two traps being regularly purged of their 1 \ 10x and desulfated, the publication U5 2009 0229249 has such an arrangement, For reasons of space, it is eapable mpassible to sleep under ... the hood 41un..véhieule. more: a trap. This istalytic to oxides. dlazote. bans eas dlune :. exhaust system equipped with two traps, the most remote trap of the engine must be housed. under the body of the vehicle. at. a distance. impertant,: from. trap as close as possible to the engine, which. is housed soaE ~ the hood e. The distance-that is the distant trap. of the MoteUe. makes ed. temperature rise longer than that of the close trap. When the engine computer initiates an alternating phase of rich and poor periods to desulfate the line of escape, the close trap is desulfated easily -or its rise in temperature above the threshold of 650 ° C is very fast after the start of operation. engine, nuisance, as long as the temperature of the trapped trap is lower than this elime threshold, sulfur oxides (SO2) desorbed from the close trap are stored entirely on the trap away, Overall, the desulfation of the exhaust line fails The fuel dedicated to this operation is lost, The invention aims to. To improve the overall efficiency of the desulphatation process of a nitrogen oxide double trap exhaust line, it is proposed that the flow of each desulfation stage be determined as a function of the temperature of the trap away from the engine. More precisely, she. provides that the engine calculator determines a spectral desulfatafion phdse when the terernature of the trapped éloh né is lower than a threshold of temperatures that is to say a different phase of the desulphatati phase of the trap close taken solemnly. According to a first embodiment of the invention, the desulfation phase of the exhaust line is authorized by the computer only if the temperature of the remote trap is higher than a given temperature threshold. The heating phage of the exhaust line preceding the desulphatation phase is prolonged until the remote trap is sufficiently hot. In a second mode, the desulfation phase of the exhaust line is allowed irrespective of the temperature of the trap remote,, and this temperature is above a given threshold, the operating periods 1 of. motor: in. rich mixture during the de-sulphation phase: unfold with: first. wealth value, typically. of. the order of 1.03 to. This temperature is Qu. below. threshold,. the periods. of. : onctipnnernent. in rich mixture take place with a wave valee of wealth, superior: to. The prevailing value is typically of the order of 1.1 to 1. the present invention is clearly in accordance with the reading of the following despriptioit of Un. mode of realization ripn: of pelle7ei., in itself. referring to .. the figure representing a. perspective view of an exhaust line having two. : 10. Catalytic traps with nitrogen oxides. Fri reference to: eefte. line figure. unleashed receives exhaust from a motor to. internal combustion not shown) usually operating lean mixture for example. a motepp. diesel Equipped with an oxidation catalyst. (not shown) allowing 0e. continuously treat the carbon dioxide: unburned hydrocarbons contained flat. the gases by. engine. ..C.ee, qp; tz enter the .plana. The exhaust line comprises a first catalytic trap nitrogen oxides, pu close trap 1, which is mounted closer to the engine to have a rise in the air, in the direction of the arrows in the figure. rapid temperature, after the start of the latter> Without limitation, this close trap 1 is housed in a same compartment of the exhaust line in the vicinity of a particulate filter that treats the soot particles emitted by the engine. The close trap 1 and the particle filter 2 are, for example, housed under the hood of a vehicle (not shown) driven by the starter. The exhaust line is also equipped with a second catalytic trap, which is a trap. 3, separated from the perticle filter 2 by an exhaust pipe 4 'The downstream trap 3 is housed for example under body, that is to say under the floor of the vehicle, Being further away from the engine than the close trap 1 , 1 rises more slowly than the latter, when the meter is switched on, 2: 4. oesotpp. opopop opopoo5 au.h oull.6pa ua 4.uavou .4diAlo.j ... pol, 19d sal mpd uo. 000uoi so 4o4ej.1hop .oËo4d on ls. .s.owasw. oiQ ...,., 'g o :. toeeel:, Otpou.cldO.i o60,1d .: hp? q4p5se: o..4noe..o.l 'if tho5s ho ojno.p9dn $. .45o g. 9u: 5!: O. "? A? Hhhhhhhh? .ed a 3d np. 9-q., at 4 o'clock o'clock o'clock o'clock o'clock. "DAO, 6h, Onb 000uol f, 5a, and Oh.aheDjed .00upfs.1p." A "dWoxo 4uppoad" .4a: euop oO.Uohbp4 9 .. un_o: "" InIp'.1.: Os ". ... o? .ouop9p: oae 4h-ad oub! l Op. 'UP "4.b4o.j4h.9p O's.o4d Ouh.,' ..woàOppOu, i 4 ... uaü, thereà" "no 4Jod eOdkIloun "Feo. H) am'eJpA1-1P a4nj.lhs- op 4hô.pne. ss "s s e e à sn sn sn sn sn sn sn:: p,,,,,,,,, 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44. eua.j.1 or! psodwoo "(zosg). oulnee op. opxo, p: ew.toj. ol. See also: http://www.youtube.com el a.poleA oflo.4 oun 'st :: i'.01 4o gal .. àJeo ..asudwoo. 4uOAhos sasosin 4.5o .at..te "j o6u.Pew wax oawauUo4nucij: op. ..to.o..p9d sas -4topple.d.F.w.). OseO.4olu .. he opeoleA 'atnO4.0ui np.ea.l.em.o tin .., oà59.1u .. "tep":. Sep oppouf uelà.e ojneàW. .A.pu. "WJo4; pp. .4nod oeto4duu.a4 o4on. .I, uppu.ad aldWaXO. ed. '-: S ~ t ~ as A: 4, .UD $$ Od9p. . S.a69A..d. xnop sep aan: ffia9tlWa.l .... to.e.e.e.e.o5no.eU .tao o4ap .o6uop.,. w ioe: 1, op. sopolà9 '. d. Oft pi) ossotid. ouh soop. op ... pOliloUüC ".. uu.4: el oetoq" p.gi'e'sdou.uou) eo..pw hp.. 1lopInosio puonb. Op. OqJpse.p.p to, Ë. " odAnod o6upe mo. 4usawolion4qo4 '.filo.eW puühb ..gs' sa Ed sas 'of s'qqoepo ..eo ou4noe HtO'. 4'u.aepad sojj.hôs cap 4, tà.oWelo6.9s. t: uel xnap UOU sap'.eW.dO.J.EN and) .UUH ') t .. $. POS trO.S sal .. 4Uoqto5 ".' uO 'oea obuo0sw. uo ..ap. 0W 'A Sep laIrT2. $' P'cI 0'1 pl: 4.be eee.ed taos F0, m: m4 o6uelo-w ... uo o.nuolpuol.,. Eoo.tu 'o "pen, b ., eo.Alos5o.a. (x N.).? 4.0ZOp $ VpAXO. For example, the value of the SV is higher than the richness r, for example, of the order of 1.15, then due to the temperature of the remote trap 3. is below the threshold 5, the sulfur is desorbed from the close trap 1 in the form of H25 and is attacked on the remote trap 3, Then, after the temperature of the remote trap 3 has exceeded the threshold 5., when a phase desulfation is launched with rich periods richness ri, the molecules of H2S adsorbed by the remote trap 3 desorbent in the form of 502, In summary, the invention provides for a 1'gne escape double trap with nitrogen oxides 1.3 of an internal combustion engine usually operating in a mixture poor to optimize the desulfation process of the line, 9race a unfolding of each desulphatetion phase which is determined by the calculator depending on the temperature of the trap farthest from the engine 3. According to a first mode of re According to a second embodiment, a phase of desulfation of the line is initiated by an alternation of periods of time of the invention, a phase of desulfation of the exhaust line is allowed when the temperature of the trap eli exceeds the threshold 5. operation of the engine in rich regime and poor regimen, the rich periods taking place with a first value of wealth rl if the temperature of the remote trap 3 is greater than the threshold 5, or with a second value of wealth r2, greater than the first value if the temperature of the remote trap 3 is lower than the threshold The invention also proposes a device for treating pollutant emissions of a lean-burn engine of vehicles comprising a double nitrogen oxide trap (1,3) and a calculator capable of causing the engine operation to switch, in a phase alternating between rich periods and poor periods. According to the invention, the device comprises temperature determination means associated with the trap farthest from the engine (3), which provide a value of 1n temperature of the remote trap 3 to the computer, the latter making each phase of alternation of rich and poor periods depending on this temperature value.

Les moyens de détermination de la température du piège éloigné 3 sont constitués d'un capteur situé sur la ligne d'échappement du véhicule, à proximité du piège éloigné 3. Les moyens sont situés sous le plancher du véhicule. Cette invention présente l'avantage de réduire le nombre ou la durée des phases de désulfatation de la ligne d'échappement, et de limiter les quantités de carburant qui leur sont dédiées. The means for determining the temperature of the remote trap 3 consist of a sensor located on the exhaust line of the vehicle, near the remote trap 3. The means are located under the floor of the vehicle. This invention has the advantage of reducing the number or duration of the desulfation phases of the exhaust line, and to limit the amounts of fuel dedicated to them.

Claims (5)

REVENDICATIONS1. PrôeeW de déSeattitien dulie liee d'éChi44Wmueit 4 REVENDICATIONS1. PrôeeW de déSeattitien dulie liee d'éChi44Wmueit 4 doOO.ie pee 4 oxyde deote de. moteur à. a:embue:ion interne ctionnant ueUelleMènt eh. Mélenge pativre' par betulemeht du fonctionnement du Moteur dans phrase désulfotetion alternant des périodes riahes et des période pa(ivreS,-acire irisé eh ce Aue le déroulement de cheque phase est diterinihé en fonction de la tempéreture du piège (3. le plus éloigne . der tee.: : REVENDICATIONS1. WELCOME OF DETAINEES OF DULIA LINKED WITH SCHEME44WMUEIT 4 CLAIMS1. This is a good example of the Duletian dulie linked to the scale of 4 DOOO.ie pee 4 oxide deote of. engine to. a: fog: internal ion running uh eMeNt eh. Melenge patiently betrays the operation of the engine in a desulfotetion phrase alternating periods of time and periods of drunkenness, iridescent acid, while the course of each phase is diterinated as a function of the temperature of the trap (the furthest away. der tee .:: 2. Procédé.. selon là revendication. 1, caractérisé . ae que le déclenchement «une :phase de. desulfetetion est autorisé si là température du. piège éldigné..(3) est supérieure a. un seuil (SI 2. Process according to the claim. 1, characterized. that the trigger "a: phase of. Desulfetetion is allowed if there temperature. elongated trap .. (3) is greater than. a threshold (SI 3. Procédé. selon la-revehdieetioit 1 caractérisé en ce que. lavaleur de :la 15 richesse ors des périodes riahes «une phase de. désulfeetion prend ine premiere valeur 04.) e ie température du plage éloigné (.3) est supérieure au seuil ( et une seconde veieur (rZ.. si le température du. piège élpigni (i. ) est inférieure eu sedil 3. Process. according to the revehdieetioit 1 characterized in that. the value of: the 15 wealth ors of the riahes periods a phase of. Desulfideion takes the first value 04.) the temperature of the far range (.3) is greater than the threshold (and a second vessel (rZ .. if the temperature of the elepiated trap (i.) is lower than the sedil 4. Procédé selon. revendication caractérisé en ee que: seconde valeur 20 de richesse (rZ est supérieureà première. valeur (rl), 4. Method according to claim characterized in that: second value of wealth (rZ is greater than first value (r1), 5. bispositif de traitement des émissions polluantes «un moteur à. mélange pauvre de véhicule, emportant deux:pièges à oxydee d'azote (1,3) dispers~s en série dans 'là.. ligne déChappement du véhicale et un, calculateur capable de. tieculer le mode da. fonctionnement du. motegr dans .des phase-S. de désolfatation alternant .des périodes riches: :et des périe des, pauvres,. caractérisé. en cep :qu'il comprend des moyens de détermination ...a. température associés aupiège: le plus éloigné du moteur (3) .6., ).is.pasitif: selon: lc~ revendicetion. aaraetérisé. en :ce que détermine les phases d'alternance: de périodes. riches t paU.Vree 'en fonction de la température du piège éloigné (3). 7, Dispositif selon la revendication 5 ou 6, caractérisé en ce que les moyens de détermination de In température du piège éloigné (3) sont constituée d'un capteur situé sur la ligne d'échappement du véhicule, proximité du piège éloigne ) 8, Dispositif selon la revendication 5, 6 ou 7, aractérisé en e que les moyens de détermination de la température du piège éloigné (3) sont située sous le plemcher du véhicule.. 5. Bispositive treatment of pollutant emissions "a motor to. poor mixture of vehicle, carrying two: oxidation of nitrogen oxides (1,3) dispersed in series in 'there .. line exhaust of the vehicle and a calculator capable of. tune the da mode. operation of the. motegr in .des-S phase. of alternating periods of richness; and perishing of the poor. characterized. in that it includes means of determination ... a. temperature associated with the seat: the farthest from the engine (3) .6.)) ..Pasitive: according to: lc ~ claim. aaraetérisé. in: what determines the phases of alternation: of periods. rich paU.Vree 'depending on the temperature of the remote trap (3). 7, Device according to claim 5 or 6, characterized in that the means for determining the temperature of the remote trap (3) consist of a sensor located on the exhaust line of the vehicle, near the trap away) 8, Device according to claim 5, 6 or 7, characterized in that the means for determining the temperature of the remote trap (3) are located under the vehicle plemcher.
FR1061001A 2010-12-22 2010-12-22 Dual catalytic nitrogen oxide trap integrated exhaust line desulfating method for lean-burn diesel engine of motor vehicle, involves determining progression of desulfation phase based on temperature of nitrogen oxide trap remote from engine Pending FR2969697A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114718711A (en) * 2021-01-04 2022-07-08 广州汽车集团股份有限公司 Automobile exhaust treatment device and method

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DE19918756A1 (en) * 1999-04-24 2000-10-26 Volkswagen Ag Exhaust catalyst system includes three-way catalyst removing reductants carbon monoxide and hydrocarbons, followed by two nitrogen oxide storage catalysts optimized for operation at different temperatures
EP1519015A2 (en) * 2003-09-24 2005-03-30 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying system for internal combustion engine
FR2936564A1 (en) * 2008-09-26 2010-04-02 Peugeot Citroen Automobiles Sa Engine i.e. V-shaped six cylinder diesel engine, controlling method for vehicle, involves carrying out desulfation of nitrogen oxide trap of long conduit with two cylinder blocks respectively controlled in desulfation and normal modes

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19918756A1 (en) * 1999-04-24 2000-10-26 Volkswagen Ag Exhaust catalyst system includes three-way catalyst removing reductants carbon monoxide and hydrocarbons, followed by two nitrogen oxide storage catalysts optimized for operation at different temperatures
EP1519015A2 (en) * 2003-09-24 2005-03-30 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying system for internal combustion engine
FR2936564A1 (en) * 2008-09-26 2010-04-02 Peugeot Citroen Automobiles Sa Engine i.e. V-shaped six cylinder diesel engine, controlling method for vehicle, involves carrying out desulfation of nitrogen oxide trap of long conduit with two cylinder blocks respectively controlled in desulfation and normal modes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114718711A (en) * 2021-01-04 2022-07-08 广州汽车集团股份有限公司 Automobile exhaust treatment device and method
CN114718711B (en) * 2021-01-04 2023-04-07 广州汽车集团股份有限公司 Automobile exhaust treatment device and method

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