FR2958297B1 - METHOD FOR VALORIZING GASOLINE - Google Patents

METHOD FOR VALORIZING GASOLINE

Info

Publication number
FR2958297B1
FR2958297B1 FR1052318A FR1052318A FR2958297B1 FR 2958297 B1 FR2958297 B1 FR 2958297B1 FR 1052318 A FR1052318 A FR 1052318A FR 1052318 A FR1052318 A FR 1052318A FR 2958297 B1 FR2958297 B1 FR 2958297B1
Authority
FR
France
Prior art keywords
crystalline
catalyst
stream
olefins
gasoline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1052318A
Other languages
French (fr)
Other versions
FR2958297A1 (en
Inventor
Delphine Minoux
Donk Sander Van
Nikolai Nesterenko
Metin Bulut
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Marketing Services SA
Original Assignee
Total Raffinage Marketing SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Raffinage Marketing SA filed Critical Total Raffinage Marketing SA
Priority to FR1052318A priority Critical patent/FR2958297B1/en
Priority to PCT/EP2011/054824 priority patent/WO2011120968A2/en
Priority to US13/637,549 priority patent/US20130037446A1/en
Priority to EP11710517A priority patent/EP2553053A2/en
Priority to CN2011800167771A priority patent/CN102822320A/en
Publication of FR2958297A1 publication Critical patent/FR2958297A1/en
Application granted granted Critical
Publication of FR2958297B1 publication Critical patent/FR2958297B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates to a process allowing the tuning of the gasoline/diesel balance by converting an initial feedstock containing olefins from 4 to 20 carbon atoms using a crystalline catalyst with reduced diffusional limitations. The process comprises: processing a feedstock stream containing olefins from 4 to 20 carbon atoms with or without the presence of an aromatic containing stream, contacting said stream(s) with a catalyst at conditions effective to oligomerize a least a portion of the olefins and eventually alkylate at least a portion of the aromatics, wherein the catalyst is a crystalline compound with micro/mesoporous structure chosen among crystalline aluminosilicates, crystalline aluminophosphates, crystalline silico-aluminophosphates, crystalline zeolites, or the catalyst is a composite material comprising at least 20% wt of at least one of the above mentioned crystalline compounds, and wherein the mesoporous volume of the crystalline compound is at least 0.22 ml/g.
FR1052318A 2010-03-30 2010-03-30 METHOD FOR VALORIZING GASOLINE Expired - Fee Related FR2958297B1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1052318A FR2958297B1 (en) 2010-03-30 2010-03-30 METHOD FOR VALORIZING GASOLINE
PCT/EP2011/054824 WO2011120968A2 (en) 2010-03-30 2011-03-29 Gazoline upgrading process.
US13/637,549 US20130037446A1 (en) 2010-03-30 2011-03-29 Gazoline upgrading process
EP11710517A EP2553053A2 (en) 2010-03-30 2011-03-29 Gazoline upgrading process
CN2011800167771A CN102822320A (en) 2010-03-30 2011-03-29 Gazoline upgrading process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1052318A FR2958297B1 (en) 2010-03-30 2010-03-30 METHOD FOR VALORIZING GASOLINE

Publications (2)

Publication Number Publication Date
FR2958297A1 FR2958297A1 (en) 2011-10-07
FR2958297B1 true FR2958297B1 (en) 2013-11-29

Family

ID=43125488

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1052318A Expired - Fee Related FR2958297B1 (en) 2010-03-30 2010-03-30 METHOD FOR VALORIZING GASOLINE

Country Status (5)

Country Link
US (1) US20130037446A1 (en)
EP (1) EP2553053A2 (en)
CN (1) CN102822320A (en)
FR (1) FR2958297B1 (en)
WO (1) WO2011120968A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3009207B1 (en) * 2013-08-02 2021-04-30 Ifp Energies Now MODIFICATION OF EUO TYPE ZEOLITH AND ITS USE IN ISOMERIZATION OF C8 AROMATIC COMPOUNDS
KR102068312B1 (en) * 2013-10-18 2020-01-20 에스케이이노베이션 주식회사 Activated EU-2 Zeolite and Use Thereof
US9670425B2 (en) 2013-12-17 2017-06-06 Uop Llc Process for oligomerizing and cracking to make propylene and aromatics
US9732285B2 (en) 2013-12-17 2017-08-15 Uop Llc Process for oligomerization of gasoline to make diesel
WO2016205878A1 (en) * 2015-06-22 2016-12-29 Patrick James Cadenhouse-Beaty Process for producing transport fuel blendstock
US11149214B2 (en) 2018-12-17 2021-10-19 Saudi Arabian Oil Company Method and process to maximize diesel yield
CN115716651B (en) * 2021-08-25 2024-04-30 中国石油天然气股份有限公司 ZSM-35 molecular sieve and preparation method thereof, isomerization catalyst and preparation method thereof, and isomerization method

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4150062A (en) 1976-12-20 1979-04-17 Mobil Oil Corporation Light olefin processing
US4227992A (en) 1979-05-24 1980-10-14 Mobil Oil Corporation Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4482772A (en) 1983-11-03 1984-11-13 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4506106A (en) 1984-01-04 1985-03-19 Mobil Oil Corporation Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
US4543435A (en) 1985-01-17 1985-09-24 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle
DE3838710A1 (en) 1988-11-15 1990-05-17 Sued Chemie Ag CATALYST BASED ON CRYSTALLINE ALUMOSILICATES
US5601798A (en) 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
DE102005003109B4 (en) * 2005-01-22 2015-02-12 Air Liquide Global E&C Solutions Germany Gmbh Process for the preparation of synthetic fuels from oxygenates
US8299312B2 (en) * 2005-10-28 2012-10-30 Neste Oil Oyj Process for dimerizing olefins
FR2931708B1 (en) * 2008-05-28 2014-03-14 Inst Francais Du Petrole CATALYST BASED ON CRYSTALLIZED MATERIAL WITH HIERARCHISED AND ORGANIZED POROSITY AND USE IN OLIGOMERIZATION OF LIGHT OLEFINS
FR2931818B1 (en) * 2008-05-28 2012-11-30 Inst Francais Du Petrole METHOD FOR OLIGOMERIZING LIGHT OLEFINS USING A CATALYST BASED ON AMORPHOUS MATERIAL WITH HIERARCHISED AND ORGANIZED POROSITY

Also Published As

Publication number Publication date
WO2011120968A3 (en) 2012-06-07
CN102822320A (en) 2012-12-12
WO2011120968A2 (en) 2011-10-06
FR2958297A1 (en) 2011-10-07
EP2553053A2 (en) 2013-02-06
US20130037446A1 (en) 2013-02-14

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Effective date: 20151130