FR2939668A1 - Powdery composition, useful for makeup and/or care of skin, comprises powdery phase comprising filler and composite pigment comprising inorganic core, organic binder and partial coating of an organic dye - Google Patents

Abstract

Powdery composition (I) comprises: at least one powdery phase comprising filler (at least 60 wt.%); and at least one composite pigment comprising an inorganic core, at least one organic binder and at least one partial coating of at least one organic dye. An independent claim is included for cosmetic set comprising: a container delimiting at least one compartment, where the container is closed by a closure element; and the composition is placed inside the compartment. ACTIVITY : Dermatological. MECHANISM OF ACTION : None given.

Description

The field of the invention relates to makeup compositions and / or care of the skin in the form of powder, with a radiance effect of the complexion.

The present invention relates in particular to a powdery make-up and / or skincare composition comprising: a) at least one pulverulent phase comprising at least 60% by weight of filler relative to the total weight of the composition, and b) at least a composite pigment comprising an inorganic core, and at least one at least partial coating of at least one organic dyestuff.

The invention also relates to a process for making up or caring for the skin of a human being comprising applying the composition to the skin.

The makeup composition according to the invention is in particular a makeup composition for the skin, such as a foundation, an eyeshadow, a blush, a concealer, a powder of the face and body, a body makeup product. More particularly, the invention relates to a foundation composition.

The skin care composition may be a facial care product, a body care product, a deodorant powder.

The skin makeup compositions are commonly used to bring an aesthetic color to the skin, especially to the face, but also to hide skin imperfections such as redness, blemishes, wrinkles.

Some makeup compositions are in the form of powdery, free-powder or compacted powder compositions. These compositions generally comprise a high powders content, especially at least 80% by weight, relative to the total weight of the composition. Depending on the type of powders used, the cosmetic properties of the makeup product can be very variable. Moreover, the presence of certain powders (eg pigments, fillers) can give, after application to the skin, a whitish or grayish complexion. It is known from the prior art to use lacquers and / or nacres to impart a brighter and brighter complexion. But the addition of lacquers in large quantities has the effect of increasing transparency and therefore loss of coverage and fidelity of color. On the other hand, the addition of nacres confers more pearlescent effect (reflection of light) rather than the desired light effect and also generates compaction problems compositions containing them.

There is therefore still a need for a powdery make-up or skin care composition, especially in the form of a loose or compact powder having good properties of softness when applied to the skin and making it possible to obtain a deposit, in particular a makeup, camouflaging the imperfections of the relief of the skin like the microreliefs, the wrinkles, the wrinkles, while giving a natural and luminous complexion to the skin.

However, the inventors have shown that a pulverulent composition, especially in the form of a free or compact powder comprising a composite pigment comprising an inorganic core and at least a partial coating of at least one organic dyestuff, makes it possible to meet this need. This composite pigment also makes it possible to confer coverage and color fidelity properties.

The composition according to the invention is particularly advantageous for the makeup and / or care of ethnic skin, especially dark skin, on which the application of powders tends to give a whitish and / or grayish (ashy) complexion. The greyish or ashy effect results in an increase in the clarity L * (the composition becomes lighter in the mass) and a decrease in the saturation C * (the intensity of the color is decreased, which results in a loss of brightness of the color), after adding white fillers to make (for example) a cosmetic powder; L * and C * being the chromatic coordinates measured with a spectrocolorimeter. Dark skin is encountered, for example, among the African, Afro-American, Hispano-American, Indian and Maghrebi populations.

These skins can still be classified on the basis of their reactivity to the effects of solar radiation according to the scale proposed by FITZPATRICK.

According to this scale, the different existing ethnic skins can be distinguished according to the following types: Type Reactivity of the skin Origin I Burns always, never tans Celtic Burns always, little bronze Germanic III Burns moderately, progressively bronze European IV Burns slightly, bronze very easily Mediterranean V Burns rarely, intensely bronze Middle East - South American VI Never burns, strongly pigmented African The dark skin especially referred to in the present invention belong to types IV to VI.

The present invention therefore relates to a powdery make-up and / or skin care composition comprising: a) at least one pulverulent phase comprising at least 60% by weight of filler relative to the total weight of the composition, and b) at least a composite pigment comprising an inorganic core, and at least one at least partial coating of at least one organic dyestuff.

According to one particular embodiment, the pulverulent make-up and / or skincare composition according to the invention comprises: a) at least one pulverulent phase comprising at least 60% by weight of filler relative to the total weight of the composition, and b) at least one composite pigment comprising an inorganic core, at least one organic binder and at least one at least partial coating of at least one organic dyestuff.

According to another particular embodiment, the powdery makeup and / or skincare composition according to the invention comprises: a) at least one pulverulent phase comprising at least 60% by weight of filler relative to the total weight of the composition, and b) at least one composite pigment comprising an inorganic core, at least one at least partial coating of at least one organic dyestuff, the refractive index of said inorganic nucleus being greater than or equal to 2, or greater than or equal to at 2.1 or 2.2.

The composition according to the invention may be in particular in the form of a loose powder or a compact powder. A compact powder refers to a powder pressed using a manual or mechanical press.

Preferably, it will be a compact powder.

COMPOSITE PIGMENT Structure A composite pigment according to the invention may be composed in particular of particles comprising: - an inorganic core, - at least one at least partial coating of at least one organic dyestuff.

At least one binder can advantageously contribute to the fixing of the organic dyestuff on the inorganic nucleus. This binder can advantageously act without the formation of covalent bonds. The composite pigment particles may have various shapes. These particles may in particular be platelet-shaped or globular, in particular spherical, and may be hollow or solid. Platelet-shaped means particles whose ratio of the largest dimension to the thickness is greater than or equal to 5. A composite pigment according to the invention may have for example a specific surface area of between 1 and 1000 m 2 / g, especially between 10 and 600 m2 / g, and in particular between 20 and 400 m2 / g. The specific surface is the value measured by the BET method. The composition may comprise only one or more composite pigments as defined above or alternatively comprise one or more other composite pigments as well as pigments having a non-composite structure, in particular inorganic, interferential pigments, lacquers or organic pigments. The composition may in particular be devoid of uncoated TiO 2 particles.

Inorganic core The inorganic nucleus may be of any form suitable for fixing particles of organic dyestuff, for example spherical, globular, granular, polyhedral, acicular, fusiform, flattened flake-like, rice grain, tortoiseshell, as well as a combination of these forms, this list not being limiting. Preferably, the ratio of the largest dimension of the core to its smallest dimension is between 1 and 50. The inorganic core may have an average size of between about 5 nm and about 100 nm, or between about 5 nm and about 75 nm. nm, for example between about 10 nm and about 50 nm, especially around 20 or 25 nm. By medium size, we denote the dimension given by the statistical size distribution to half of the population, called D50. The average size may be a number average size determined by image analysis (electron microscopy).

The inorganic nucleus may be made of a material chosen from the nonlimiting list comprising metal salts and metal oxides, in particular oxides of titanium, zirconium, cerium, zinc, iron, ferric blue, aluminum and aluminum. chromium, alumina, glasses, ceramics, graphite, silicas, silicates, especially aluminosilicates and borosilicates, synthetic mica, and mixtures thereof. According to a particular embodiment of the invention, the inorganic nucleus is a titanium oxide. The oxides of titanium, in particular TiO 2, of iron, in particular Fe 2 O 3, of cerium, of zinc and of aluminum, the silicates, in particular the aluminosilicates and the borosilicates, are very particularly suitable. The inorganic core may have a specific surface area, measured by the BET method, for example between about 1 m 2 / g and about 1000 m 2 / g, more preferably between about 10 m 2 / g and about 600 m 2 / g, for example between about 20 m 2 / g m2 / g and about 400 m2 / g.

The specific surface is for example between 30 and 70 m 2 / g, for example around 50 m 2 / g, especially in the case of TiO 2 cores of size close to 20 or 25 nm. The inorganic core can be colored, if necessary. The refractive index of the inorganic nucleus is advantageously greater than or equal to 2, or greater than or equal to 2.1 or 2.2. The mass proportion of the inorganic core within the composite pigment may exceed 50%, being for example between 50 and 70%, or 50 and 60%.

Organic dyestuff The organic dyestuff may be chosen for example from particulate compounds which are insoluble in the physiologically acceptable medium of the composition. The organic dyestuff may comprise, for example, organic pigments which may be chosen from the compounds below and their mixtures: cochineal carmine, organic pigments of azo, anthraquinone, indigo, xanthene, pyrenic, quinoline dyes fluoran triphenylmethane, - organic lakes or insoluble organic salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo dyes, anthraquinone dyes, indigoids , xanthéniques, pyréniques, quinoliniques, triphenylmethane, fluoran, these dyes may comprise at least one carboxylic or sulfonic acid group. Among the organic pigments, mention may be made of those known under the following names: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10, D & C Orange No. 11, D & C Red No. 6, D & C Red No. 7, D & C Red No. 17, D & C Red No. 21, D & C Red No. 22, D & C Red No. 27, D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow # 8, D & C Yellow # 10, D & C Yellow # 11, FD & C Blue # 1, FD & C Green # 3, FD & C Red # 40, FD & C Yellow # 5, FD & C Yellow # 6, D & C Black 2 ( carbon black) and phthalocyanine blue. According to one particular embodiment, the organic pigment D & C Red No. 7 is used.

According to another embodiment, the organic pigment D & C Red No. 28 is used. According to another particular embodiment, the FD & C Yellow No. 5 organic pigment is used. The organic dyestuff may comprise an organic lacquer supported on an organic support such as rosin or aluminum benzoate, for example.

Among the organic lakes, mention may be made in particular of the following denominations: D & C Red No. 2 Aluminum Lake, D & C Red No. 3 Aluminum Lake, D & C Red No. 4 Aluminum Lake, D & C Red No. 6 Aluminum Lake, D & C Red # 6 Barium Lake, D & C Red # 6 Barium / Strontium Lake, D & C Red # 6 Strontium Lake, D & C Red # 6 Potassium Lake, D & C Red # 7 Aluminum Lake, D & C Red # 7 Barium Lake, D & C Red # 7 Calcium Lake, D & C Red # 7 Calcium / Strontium Lake, D & C Red # 7 Zirconium Lake, D & C Red # 8 Sodium Lake, D & C Red # 9 Aluminum Lake, D & C Red # 9 Barium Lake, D & C Red # 9 Barium / Strontium Lake, D & C Red # 9 Zirconium Lake, D & C Red # 10 Sodium Lake, D & C Red # 19 Aluminum Lake, D & C Red # 19 Barium Lake, D & C Red # 19 Zirconium Lake, D & C Red # 21 Aluminum Lake, D & C Red # 21 Zirconium Lake, D & C Red # 22 Aluminum Lake, D & C Red # 27 Aluminum Lake, D & C Red # 27 Aluminum / Titanium / Zirconium Lake, D & C Red # 27 Barium Lake , D & C Red # 27 Calcium Lake, D & C Red # 27 Zirconium Lake, D & C Red # 28 Aluminum Lake, D & C Red # 30 Lake, D & C Red # 31 Calcium Lake, D & C Red # 33 Aluminum Lake, D & C Red # 34 Calcium Lake, D & C Red # 36 Lake, D & C Red # 40 Aluminum Lake, D & C Blue # 1 Aluminum Lake, D & C Green # 3 Aluminum Lake, D & C Orange # 4 Aluminum Lake, D & C Orange # 5 Aluminum Lake, D & C Orange # 5 Zirconium Lake, D & C Orange No. 10 Aluminum Lake, D & C Orange No. 17 Barium Lake, D & C Yellow No. 5 Aluminum Lake, D & C Yellow No. 5 Zirconium Lake, D & C Yellow No. 6 Aluminum Lake, D & C Yellow No. 7 Zirconium Lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red # 40 Aluminum Lake, FD & C Yellow # 5 Aluminum Lake, FD & C Yellow # 6 Aluminum Lake.

According to a particular mode, FD & C Blue organic lacquer No. 1 aluminum lake is used. According to another mode, FD & C Yellow No. 5 aluminum lake is used. The chemical compounds corresponding to each of the organic dyestuffs mentioned above are mentioned in the International Cosmetic Ingredient Dictionary and Handbook, Edition 1997, pages 371 to 386 and 524 to 528, published by The Cosmetic, Toiletry, and Fragrance Association, whose Content is incorporated herein by reference. The mass proportion of organic dyestuff may range from about 10 parts to about 500 parts by weight per 100 parts of the inorganic core, or from about 20 parts to about 250 parts by weight, for example, from about 40 parts to about 125 parts by weight. weight per 100 parts of the inorganic nucleus. In some exemplary embodiments, the total content of organic coloring matter of the composition is less than or equal to 10% by weight relative to the total weight of the composition.

The organic dyestuff represents for example between 30 and 50% by weight of the composite pigment relative to the total weight thereof, for example between 30 and 40%.

Binder The binder can be of any type since it allows the organic dyestuff to adhere to the surface of the inorganic core. In a particular and preferred embodiment, the binder is organic.

The binder can in particular be chosen from a nonlimiting list comprising silicone compounds, polymeric, oligomeric or similar compounds, and in particular from organosilanes, fluoroalkyl organosilanes and polysiloxanes, for example polymethylhydrogenosiloxane, as well as various coupling agents, such as coupling agents based on silanes, titanates, aluminates, zirconates and mixtures thereof. The silicone compound may be chosen from a nonlimiting list comprising in particular: organosilanes (1) obtained from alkoxysilanes, polysiloxanes (2) modified or non-selected from a non-limiting list comprising: modified polysiloxanes (2A) ) comprising at least one radical chosen from, in particular, polyethers, polyesters and epoxy compounds (they will be called modified polysiloxanes), polysiloxanes (2B) bearing on a silicon atom located at the end of the polymer, at least a group selected from a nonlimiting list comprising carboxylic acids, alcohols or hydroxy groups, and - fluoroalkylated organosilane compounds (3) obtained from fluoroalkylsilanes. The organosilane compounds (1) can be obtained from alkoxysilane compounds represented by the formula (I): ## STR5 ## in which: R 'represents C 6 H 5 -, (CH 3) 2 CH-CH 2 - or a radical of type Cb H2b +, - (where b varies from 1 to 18), - X represents CH3O- or C2H5O-, and - a varies from 0 to 3. Specific examples of alkoxysilane compounds may include alkoxysilanes selected from: methyltriethoxysilane, dimethyldiethoxysilane, phenyltriethoxysilane, diphenyldiethoxysilane, methyltrimethoxysilane, dimethyldimethoxysilane, phenyltrimethoxysilane, diphenyldimethoxysilane, isobutyltrimethoxysilane, decyltrimethoxysilane, and the like, particularly from methyltriethoxysilane, phenyltriethoxysilane, methyltrimethoxysilane, dimethyldimethoxysilane, isobutyltrimethoxysilane, and most preferably methyltriethoxysilane, methyltrimethoxysilane and phenyltriethoxysilane. The polysiloxanes (2) may in particular satisfy formula (II):

Embedded image in which R 2 is H- or CH 3 - and d is from 15 to 450. Among these polysiloxanes, those for which R 2 is H are preferred. The modified polysiloxanes (2A) may especially correspond to the following formulas: - (a1) modified polysiloxanes bearing polyethers, represented by the formula (III) ## STR1 ## wherein R3 represents (CH2) h-; R4 represents (CH2); R5 is OH, -COOH, -CH = CH2, -C (CH3) = CH2 or ù (CH2); -CH3; R6 represents (CH2) k-CH3; g and h vary independently from 1 to 15; j and k varying independently from 0 to 15; e ranging from 1 to 50 and ranging from 1 to 300, (a2) polysiloxane-modified polysiloxanes, represented by the formula (IV): wherein R 7, R 8 and R 9 represent independently (CH2) q-; R10 represents OH; -COOH, -CH = CH2, -C (CH3) = CH2 or ù (CH2) r-CH3; R11 represents (CH2) S CH3; n and q varying independently from 1 to 15, r and s independently ranging from 0 to 15; e varying from 1 to 50 and f varying from 1 to 300, CH 3 CH 3

## STR5 ## wherein R 3 is a polysiloxane containing epoxy radicals represented by the formula ## STR1 ## formula CH (H 3 SiO Si)

CH CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3

Wherein R12 represents (CH2), -; v ranging from 1 to 15; t ranging from 1 to 50 and u ranging from 1 to 300; or their mixtures. Among the modified polysiloxanes (2A), modified polysiloxanes bearing polyethers of formula (III) are preferred. The modified polysiloxanes on the terminal part (2B) can correspond to the formula (VI): ## STR2 ## in which R 13 and R 14 can represent OH, R 16 -OH or R 17 -COOH independently of each other; R15 is CH3 or CH6H5; R16 and R17 represent (CH2) y-; y ranging from 1 to 15; w ranging from 1 to 200 and x varying from 0 to 100. Among these polysiloxanes modified on at least one end, those carrying at least one radical (R16 and / or R17) carrying a carboxylic acid group on at least one terminal silicon atom are still preferred. The fluoroalkylated organosilane compounds (3) can be obtained from fluoroalkyl silanes represented by the formula (VII):

CF3 (CF2) ZCH2CH2 (R18) to SiX4-a (VII) wherein: - R18 is CH3-, C2H5-, CH3O- or C2HSO-, -X is CH3O- or C2HSO-, - is from 0 to 15 and has a range of from 0 to 3. The fluoroalkylsilanes may be selected in a non limiting list trifluoropropyltrimethoxysilane, tridecafluorooctyltrimethoxysilane, heptadecafluorodecyltrimethoxysilane, the heptadécafluorodécylméthyldiméthoxysilane, trifluoropropyltriethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecylmethyldiethoxysilane and the like, in particular trifluoropropyltrimethoxysilane, tridecafluorooctyltrimethoxysilane and heptadecafluorodecyltrimethoxysilane, and most preferably trifluoropropyl trimethoxysilane and tridecafluorooctyltrimethoxysilane. The coupling agents based on silane may be chosen from a non-limiting list comprising in particular vinyltrimethoxysilane, vinyltriethoxysilane, y-aminopropyltriethoxysilane, γ-flycidoxypropyltrimethoxysilane, γ-mercaptopropyltrimethoxysilane, γ-methacryloxypropyltrimethoxysilane and N-13 (aminoethyl γ-aminopropyltrimethoxysilane, γ-glycidoxypropylmethyldimethoxysilane, γ-chloropropyltrimethoxysilane and the like. The titanate coupling agents may be chosen from the list comprising isopropylstearoyl titanate, isopropyltris titanate (dioctylpyrophosphate), isopropyltri (N-aminoethylaminoethyl) titanate, tetraoctylbis titanate (ditridecylphosphate), tetra (2,2-diaryloxymethyl-1-butyl) bis (diterridecyl) phosphate titanate, bis (dioctylpyrophosphate) oxyacetate titanate, bis (dioctylpyrophosphate) ethylene titanate, and the like.

The aluminate-based coupling agents may be chosen from acetoalkoxyaluminum diisopropylate, aluminum diisopropoxymonoethylacetoacetate, aluminum triethylacetoacetate, aluminum triacetylacetonate and the like. The zirconate coupling agents may be chosen from a list comprising, in particular, zirconium tetrakisacetylacetonate, zirconium dibutoxybisacetylacetonate, zirconium tetrakisethylacetoacetate, zirconium tributoxymonoethylacetoacetate, zirconium tributoxyacetylacetonate and the like. The binder compounds may in particular have a molar mass which may vary between 300 and 100,000. To obtain a layer covering the inorganic cores uniformly, the binder is preferably in a liquid state or soluble in water or in different solvents. In a particular embodiment, the organic binder is a polymethylhydrogenosiloxane.

The amount of binder can vary from 0.01 to 15%, especially from 0.02 to 12.5% and in particular from 0.03 to 10% by weight (calculated with respect to C or Si) relative to the weight of the particles comprising the core and the binder. For further details on how to calculate the relative amount of the binder, reference can be made to application EP 1 184 426 A2. The relative mass proportion of binder may be less than or equal to 5%, or even 3%, relative to the total weight of the composite pigment.

Preparation of the composite pigment The composite pigment can be prepared anywhere suitable process, for example a chemical-mechanical process or a solution precipitation process, with dissolution of an organic coloring substance and precipitation on its surface of the core. The composite pigment can be produced for example by one of the methods described in European Patent Applications EP 1 184 426 and EP 1 217 046, the contents of which are incorporated herein by reference, advantageously by the method described in EP 1 184,426.

In an exemplary implementation, it starts by mixing the particles intended to form the inorganic core with the binder. In order that the binder adheres uniformly to the surface of the inorganic core, it is preferable to pass these particles beforehand into a mill, so as to de-agglomerate them.

The mixing and stirring conditions are chosen so that the core is uniformly covered with binder. These conditions can be controlled so that the linear load is between 19.6 and 19160 N / cm, in particular between 98 and 14170 N / cm and better still between 147 and 980 N / cm; the treatment time is in particular between 5 minutes and 24 hours and better from 10 minutes to 20 hours; the speed of rotation can be between 2 and 1000 rpm, in particular between 5 and 1000 rpm and better still between 10 and 800 rpm. After the binder has coated the inorganic core, the organic coloring material is added and mixed with agitation to adhere to the binder layer. The addition methods may be, for example, a large amount, continuously, or in small amounts. Mixing and stirring, whether inorganic cores with the binder or organic dyestuff with binder-bound inorganic cores, can be performed using an apparatus that can apply spatular cutting and / or compression force to the mixture. of powders. Such devices are for example wheeled kneaders, blades and the like. Wheel kneaders are particularly suitable. A list of suitable devices is given in the application EP 1 184 426 A2.

Another method of manufacturing a composite pigment is disclosed in JP 3286463, which discloses a solution precipitation process. The organic dyestuff is dissolved in ethanol, the inorganic nuclei are then dispersed in this ethanolic solution.

Then, an aqueous alkaline solution of sodium or potassium carbonate is added slowly to these mixtures, then, slowly, an ethanolic solution of calcium chloride is added, all with stirring.

As examples of composite pigments that may be used according to the invention, alone or in a mixture, mention may be made in particular of: titanium dioxide (C177891), blue FD & C blue lake aluminum lake (C142090) and polymethylhydrogensiloxane (58.1 / 40.7 / 1.2) - titanium dioxide (C177891), D & C Red No. 7 (C115850) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3) - titanium dioxide (C177891), D & C Red No. 28 (C145410) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3) - titanium dioxide (C177891), yellow lacquer FD & C Yellow Aluminum lake (C1191140) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3) According to one particular embodiment, the composition according to the invention comprises a composite pigment. By way of example, the composite pigment comprising titanium dioxide (C177891), FD & C blue aluminum lake (C142090) and polymethylhydrogensiloxane (58.1 / 40.7 / 1.2) is used.

According to another particular embodiment, the composition according to the invention comprises at least two distinct composite pigments. By way of example, it comprises a mixture of yellow composite pigment (titanium dioxide (C177891), FD & C yellow aluminum lake yellow lacquer (C1191140) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3) and red composite pigment (titanium dioxide). (C177891), D & C Red No. 7 (C115850) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3).

The composite pigment (s) according to the invention may be present in said composition in a content ranging from 0.01% to 70% by weight relative to the total weight of the composition, in particular from 0.1% to 50% by weight, of preferably from 0.5 to 20% by weight relative to the total weight of said composition.

PULVERULENT PHASE

The pulverulent phase according to the invention comprises at least fillers, which may be of organic or inorganic nature, as well as dyestuffs.

Preferably, the fillers represent at least 60% by weight relative to the total weight of said composition.

By charge is meant colorless or white, solid particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition. Of mineral or organic nature, they make it possible to impart body or stiffness to the composition and / or softness, and uniformity to makeup.

The fillers used in the compositions according to the present invention may be of lamellar, globular, spherical, fiber or any other intermediate form between these defined forms. The fillers according to the invention may or may not be superficially coated, and in particular they may be surface-treated with silicones, amino acids, fluorinated derivatives or any other substance which promotes dispersion and compatibility of the filler in the process. composition. Among the fillers that can be used in the compositions according to the invention, mention may notably be made of talc, natural or synthetic mica or alumino silicate, which may be chosen from muscovite, phlogopite, tiotite, sericite, lepidolite, paragonite. , margarite, roscoelite, artificial or synthetic mica having a fluorine atom substituting the hydroxyl group of natural mica, and the cooked or calcined products of these micas, silica, kaolin, bentone, calcium carbonate precipitate, magnesium carbonate and hydrogencarbonate, hydroxyapatite, boron nitride, polyamide (nylon), poly-13-alanine and polyethylene powders, tetrafluoroethylene polymer powders (Teflon), powders of polystyrene, polyester powders, lauroyl-lysine, starch, acrylic acid polymer powders, zinc and titanium oxides, zirconium or cerium oxides, hydroxyapatite, microbill Examples of silicone resin (such as TOSHIBA TOSPEARLS), hollow silica microspheres (such as 'SILICA BEADS SB 700 / HA' or 'SILICA BEADS SB 700' from MAPRECOS, SUNSPHERES H 33 'and' SUNSPHERES H-51 'from the company ASAHI GLASS), microspheres of acrylic polymers (such as those of crosslinked acrylate copolymer' POLYTRAP 6603 ADSORBER 'from the company RP SCHERRER, and those of polymethyl methacrylate MICROPEARL M 100 'from the company SEPPIC), polyurethane powders (such as hexamethylene diisocyanate copolymer powder and trimethylol hexyl lactone sold under the name PLASTIC POWDER D-400 by the company TOSHIKI), the microcapsules of glass or ceramic, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, in particular from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zirconium laurate. inc, magnesium myristate, microcapsules of polymers or copolymers of acrylate or methyl methacrylate, or copolymers of vinylidene chloride and acrylonitrile, such as I (Expancel from Expancel, and mixtures thereof.

The fillers may be present in the composition in a proportion of 10 to 95% by weight, relative to the total weight of the composition, preferably from 30 to 90% by weight, and better still from 60 to 80% by weight.

According to one particular embodiment, the fillers of a mineral nature are present in the composition in a content of at least 20% by weight relative to the total weight of said composition, more preferably at least 40% by weight relative to the weight. total of said composition.

According to a preferred embodiment, talc, mica or their mixture are used as mineral fillers. More preferably, a mixture of talc and mica is used.

The composition according to the invention may also comprise at least one organic filler. Preferably, a polyamide podure, such as nylon-12, will be used. The organic fillers may be present in the composition in an amount ranging from 5 to 25% by weight, preferably from 8 to 20% by weight relative to the total weight of said composition.

Dyestuff The pulverulent phase of the composition according to the invention may advantageously comprise, in addition to the composite pigments described above, at least one dyestuff chosen from organic or inorganic dyestuffs, in particular of the type of pigment or nacre conventionally used in the compositions cosmetics, liposoluble or water-soluble dyes, optically specific materials and mixtures thereof.

The term "pigments" is intended to mean white or colored particles, mineral or organic, insoluble in an aqueous solution, intended to color and / or opacify the resulting film. The pigments may be present in a proportion of from 0.1 to 40% by weight, in particular from 1 to 30% by weight, and in particular from 5 to 15% by weight, relative to the total weight of the cosmetic composition. As inorganic pigments that may be used in the invention, mention may be made of titanium, zirconium or cerium oxides, as well as zinc, iron or chromium oxides, ferric blue, manganese violet, ultramarine blue and Chromium hydrate. It may also be a pigment having a structure which may for example be sericite / brown iron oxide / titanium dioxide / silica. Such a pigment is marketed for example under the reference COVERLEAF NS or JS by CHEMICALS AND CATALYSTS and has a contrast ratio of about 30. Mention may also be made of BaSO4 / TiO2 / FeSO3 type pigment structures under the reference SILSEEM of Nihon Koken and silica-iron oxide XIRONA Merck's Red. The dyestuff may further comprise a pigment having a structure which may be, for example, silica microsphere type containing iron oxide.

An example of a pigment having this structure is that marketed by MIYOSHI under the reference PC BALL PC-LL-100P, this pigment consisting of silica microspheres containing yellow iron oxide. Among the organic pigments that can be used in the invention, mention may be made of carbon black, D & C type pigments, cochineal carmine, barium, strontium, calcium, aluminum or diketo pyrrolopyrrole (DPP) lacquers. ) described in EP-A-542 669, EP-A-787 730, EP-A-787 731 and WO-A-96/08537.

By nacres, it is necessary to understand colored particles of any shape, iridescent or not, in particular, produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. The nacres can be chosen from pearlescent pigments, such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. Mention may also be made, by way of example of nacres, of natural mica coated with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride. Among the nacres available on the market, mention may be made of mother-of-pearl TIMICA, FLAMENCO and DUOCHROME (based on mica) marketed by BASF, TIMIRON mother-of-pearl marketed by MERCK, mother-of-pearl containing PRESTIGE mica marketed by the company. ECKART; SUNPEARL natural mica mother-of-pearl from Sun Chemical, KTZ from Kobo and SUNPRIZMA from Sun Chemical; mother-of-pearl based on SUNSHINE and SUNPRIZMA synthetic mica marketed by the company SUN CHEMICAL, and nacres on synthetic mica base TIMIRON SYNWHITE marketed by the company MERCK. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection. As an illustration of pearlescent agents that can be used in the context of the present invention, mention may be made, in particular, of gold-colored mother-of-pearls, in particular sold by the company BASF under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres, in particular, sold by the company Merck under the names Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company BASF under the name Super Bronze (Cloisonne); orange nacres, in particular, sold by BASF under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); brown nacres, in particular, sold by BASF under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); pearl-reflective pearls, in particular, sold by BASF under the name Copper 340A (Timica); the red-colored pearlescent agents, in particular, marketed by MERCK under the name Sienna fine (17386) (Colorona); nacres with a yellow glint, in particular, sold by BASF under the name Yellow (4502) (Chromalite); gold-red nacres, in particular, marketed by BASF under the name Sunstone G012 (Gemtone); pink nacres, in particular, sold by the company BASF under the name Tan opal G005 (Gemtone); black pearls with gold glints, in particular, sold by the company BASF under the name Nu antique bronze 240 AB (Timica), blue pearls, in particular, sold by MERCK under the name Matte blue (17433) (Microna), white nacres with silvery reflection, in particular, sold by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl, in particular, marketed by MERCK under the name Indian summer (Xirona) and their mixtures.

The cosmetic composition according to the invention may also comprise water-soluble or fat-soluble dyes. Liposoluble dyes are, for example, Sudan Red, DC Red 17, DC Green 6, 13-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, Orange DC 5 and yellow quinoline, anthocyanins. The water-soluble dyes are, for example, beet juice and caramel.

The cosmetic composition according to the invention may also contain at least one material with a specific optical effect. This effect is different from a simple conventional hue effect, i.e. unified and stabilized as produced by conventional dyestuffs, such as, for example, monochromatic pigments. In the sense of the invention, stabilized means devoid of color variability effect with the angle of observation or in response to a change in temperature. For example, this material may be chosen from particles with a metallic sheen, goniochromatic coloring agents, diffractive pigments, thermochromic agents, optical brighteners, and especially interferential fibers. Of course, these different materials can be combined to provide the simultaneous manifestation of two effects, or even a new effect according to the invention. The particles with a metallic sheen that can be used in the invention are in particular chosen from: particles of at least one metal and / or at least one metal derivative, particles comprising an organic or inorganic substrate, monomaterial or multimaterial, at least partially covered by at least one metal-reflecting layer comprising at least one metal and / or at least one metal derivative, and - mixtures of said particles.

Among the metals that may be present in said particles, mention may be made, for example, of Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te. Se and their mixtures or alloys. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and mixtures or alloys thereof (e.g., bronzes and brasses) are preferred metals. The term "metal derivatives" denotes compounds derived from metals, in particular oxides, fluorides, chlorides and sulphides. As an illustration of these particles, mention may be made of aluminum particles, such as those sold under the names STARBRITE 1200. EAC by the company SIBERLINE and METALURE by the company ECKART. Mention may also be made of copper metal powders or mixtures of alloys, such as the references 2844 sold by the company Radium Bronze, metallic pigments, such as aluminum or bronze, such as those sold under the trade names ROTOSAFE 700 of ECKART company, the silica-coated aluminum particles marketed under the name VISIONAIRE BRIGHT SILVER by the company ECKART and the metal alloy particles, such as bronze powders (alloy copper and zinc) coated with silica marketed under the name of Visionaire Bright Natural Gold from Eckart. It may also be particles comprising a glass substrate such as those sold by the company NIPPON SHEET GLASS under the names MICROGLASS METASHINE, XIRONA from MERCK, RONASTAR from MERCK, REFLECKS from BASF, MIRAGE from the company BASF.

The goniochromatic coloring agent may be selected from, for example, interfering multilayer structures and liquid crystal coloring agents. Examples of symmetrical interferential multilayer structures that can be used in compositions produced in accordance with the invention are, for example, the following structures: Al / SiO 2 / Al / SiO 2 / Al, pigments having this structure being marketed by Du Pont de Nemours; Cr / MgF 2 / Al / MgF 2 / Cr, pigments having this structure being marketed under the name CHROMAFLAIR by the company FLEX; MoS2 / SiO2 / Al / SiO2 / MoS2 Fe2O3 / SiO2 / Al / SiO2 / Fe2O3, and Fe2O3 / SiO2 / Fe2O3 / SiO2 / Fe2O3, pigments having these structures being marketed under the name SICOPEARL by BASF MoS2 / SiO2 / mica -oxide / SiO2 / MoS2; Fe2O3 / SiO2 / mica-oxide / SiO2 / Fe2O3; TiO2 / SiO2 / TiO2 and TiO2 / Al2O3 / TiO2; SnO / TiO2 / SiO2 / TiO2 / SnO; Fe 2 O 3 / SiO 2 / Fe 2 O 3 SnO / mica / TiO 2 / SiO 2 / TiO 2 / mica / SnO, pigments having these structures being sold under the name XIRONA by the company Merck (Darmstadt). By way of example, these pigments may be the pigments of silica / titania / tin oxide structure sold under the name Xirona Magic by the company Merck, the silica / brown iron oxide structural pigments marketed under the name XIRONA. INDIAN SUMMER by the company MERCK and the silica / titanium oxide / mica / tin oxide structural pigments marketed under the name XIRONA CARRIBEAN BLUE by the company MERCK. Mention may also be made of the INFINITE COLORS pigments from SHISEIDO. Depending on the thickness and nature of the different layers, different effects are obtained. Thus, with the Fe.sub.2 O.sub.3 / SiO.sub.2 / Al.sub.2 / SiO.sub.2 / Fe.sub.2 O.sub.3 structure, grey-green to gray-red is passed for SiO.sub.2 layers of 320 to 350 nm; from red to golden for layers of SiO2 from 380 to 400 nm; from violet to green for SiO2 layers from 410 to 420 nm; from copper to red for SiO2 layers from 430 to 440 nm. Mention may be made, by way of example of pigments with a polymeric multilayer structure, those marketed by the company 3M under the name COLOR GLITTER. Mention may also be made of flakes from the polymeric multilayer DISCO structure of GLITTEREX, a MICROGLITTER company VENTURE CHEMICAL. As liquid crystal goniochromatic particles, it is possible to use, for example, those sold by CHENIX, as well as those marketed under the name HELICONE HC by WACKER.

The pulverulent dyestuff may generally be present in the composition in a content ranging from 0.5 to 35% by weight, especially from 1 to 25% by weight, and in particular from 2 to 15% by weight relative to the total weight of the composition. the composition.

The pulverulent phase (fillers, pigments) may be present in a content ranging from 30 to 99.5% by weight, relative to the total weight of the composition, preferably from 60 to 97% by weight, in particular from 75 to 95% by weight. in weight. FATTY PHASE The pulverulent composition according to the invention may also comprise a fatty phase. This fatty phase generally comprises at least one oil. Usable oils include soybean oil, common seed oil, sesame oil, corn oil, rapeseed oil, sunflower oil, oil, and the like. cotton, avocado oil, olive oil, castor oil, jojoba oil, peanut oil; hydrocarbon oils, such as paraffin oils, squalane, petroleum jelly, polydecene; fatty esters, such as isopropyl myristate, isopropyl palmitate, butyl stearate, isodecyl stearate, hexyl laurate, isononyl isononanoate, 2-ethylhexyl palmitate , 2-hexyl-decyl laurate, 2-25 octyl decyl palmitate, 2-octyl-dodecyl myristate or lactate, 2-diethylhexyl succinate, diisostearyl malate, glycerin triisostearate or diglycerol; silicone oils such as polymethylsiloxanes, polymethylphenylsiloxanes, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, fluorinated silicones, perfluorinated oils; oleic acid, linoleic acid, linolenic acid; higher fatty alcohols such as cetanol or oleic alcohol.

According to one particular embodiment, the composition according to the invention comprises at least one silicone oil such as polymethylsiloxanes, polymethylphenylsiloxanes, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes.

The fatty phase may be present in a content ranging from 0.1% to 13% by weight, relative to the total weight of the composition, preferably ranging from 0.1% to 10% by weight, and preferably ranging from 0, 1% to 8% by weight.

ADDITIVES The composition may comprise other ingredients (adjuvants) usually used in cosmetics such as waxes, preservatives, cosmetic active agents, moisturizing agents, UV filters, thickeners, water, surfactants, perfumes.

Of course, one skilled in the art will take care to choose the optional adjuvant (s) added to the composition according to the invention in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not, or substantially not , altered by the envisaged addition.

The composition according to the invention may be an anhydrous composition, that is to say a composition containing less than 2% by weight of water, or even less than 0.5% of water, in particular water-free. water not being added during the preparation of the composition but corresponding to the residual water provided by the mixed ingredients.

The composition according to the invention, when it is in the form of a compact powder, may be prepared by mixing the ingredients of the powder phase (fillers and pigments) and then adding the binder with stirring, the mixture then being ground, sieved and then poured into a cup and compacted.

The mixture of the pulverulent phase and the binder, crushed and sieved can be compacted using a press, in particular by applying a pressure ranging from 0.5 MPa to 10 MPa, and preferably ranging from 1 MPa to 5 MPa. . The composition thus obtained is in the form of a compact powder. 5

COSMETIC ASSEMBLY In another aspect, the invention also relates to a cosmetic assembly comprising: i) a container defining at least one compartment, said container being closed by a closure element; and ii) a composition disposed within said compartment, the composition being in accordance with the invention.

The container may be in any suitable form. It can be in particular in the form of a pot, a case, a box, a bag or a case.

The closure element may be in the form of a removable cap, a lid, a lid, a tearable strip, or a capsule, in particular of the type comprising a body attached to the container and a cap. articulated on the body. It may also be in the form of an element ensuring the selective closure of the container, in particular a valve, or a valve. The container may be associated with an applicator, in particular in the form of a brush, as described, for example, in patent FR 2 722 380. The applicator may be in the form of a block of foam or elastomer, or felt, or spatula. The applicator may be free (puff or sponge) or integral with a rod carried by the closure member, as described for example in US Patent 5,492,426. The applicator may be integral with the container, as described for example the patent FR 2 761 959. The product may be contained directly in the container, or indirectly. By way of example, the product may be placed on an impregnated support, in particular in the form of a wipe or a tampon, and arranged (individually or in several) in a box or in a bag. Such a carrier incorporating the product is described for example in the application WO 01/03538.

The closure member may be coupled to the container by screwing. Alternatively, the coupling between the closure element and the container is other than by screwing, in particular via a bayonet mechanism, snap-fastening, clamping, welding, gluing, or magnetic attraction. By "latching" is meant in particular any system involving the crossing of a bead or a bead of material by elastic deformation of a portion, in particular of the closure element, then by return to the position not elastically constrained of said portion after crossing the bead or cord.

The container may be at least partly made of thermoplastic material. Examples of thermoplastic materials include polypropylene or polyethylene. Alternatively, the container is made of non-thermoplastic material, in particular glass or metal (or alloy).

The container may have rigid walls or deformable walls, in particular in the form of a tube or a tube flask.

The container may consist of a housing with a bottom defining at least one housing containing the composition, and a cover, in particular articulated on the bottom, and adapted to cover at least part of said bottom. Such a housing is described for example in the application WO 03/018423 or in the patent FR 2 791 042.

The contents of all patents or patent applications cited above are incorporated by reference in this application.

The composition of the invention may be in the form of a care product or preferably a make-up product, in particular a colored product, of the skin, more specifically of the face. It can be in the form of a foundation, a blush or eyeshadow, a concealer, a blush, or a body makeup product, or a semi-permanent tattoo product.

The invention is illustrated by the following nonlimiting examples. Unless otherwise indicated, the contents are indicated in% by weight relative to the total weight of the composition.

EXAMPLES Compact powder mica talc 35 Yellow composite pigment (1) 1.5 Red composite pigment (2) 0.5 Titanium dioxide 2.0 nylon 20 magnesium stearate 4.0 isodecyl neopentanoate 4.0 Polydimethylsiloxane (viscosity: Cst) (FLUID DC 200 10 CS from the company Dow Corning) 1.5 cetyl dimethicone 0.25 preservatives qs (1) = titanium dioxide (C177891), FD & C yellow lake yellow aluminum lake (C1191140) and polymethylhydrogensiloxane (65.8 /32.9/1.3) (2) = titanium dioxide (C177891), D & C Red No. 7 (C115850) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3) Said composition is conventionally prepared according to the following protocol: fillers and pigments are mixed in a ribbon blender; the oils (esters and silicones) and the preservative are added and mixed again. The blender assembly is ground by air jet or pin mill; the crushed mixture is compacted in a cup so that the product can be taken with an applicator, sponge type. The powder is applied to the face.

Eye shadow (compact powder) 30 Mica 20 Mica-titanium oxide 5 Talc 35 Kaolin 5 35 Titanium dioxide 5 Iron oxides 0.35 Composite pigment (3) 0.5% Zinc laureate 3 Zinc stearate 3,5Nylon 13 Polydimethylsiloxane (viscosity: 10 cst) (FLUID DC 200 10 CS of the company (3): titanium dioxide (C177891), blue FD & C blue lake aluminum lake (C142090) and polymethylhydrogensiloxane (58.1 / 40.7 / 1.2) Said composition is prepared conventionally according to the following protocol: the fillers and pigments are mixed in a ribbon blender, the oils (esters and silicones) and the preservative are added, and the mixture is blended again. or at the pin mixer, a sieving step is carried out and then the ground mixture is compacted in a dish so that the product can be taken with a sponge-type applicatuer.

The eye shadow thus prepared is applied to the face with a sponge. The presence of composite pigment in this composition makes it possible to bring more brightness to the hue, and a less dull effect, compared to similar compositions containing conventional pigments such as black iron oxides for example.

Free powder

Mica-titanium dioxide 4,5 Synthetic Sericite Talc 22 Nylon 12 Iron oxide yellow 6 Composite pigment (1) 2,8 Polydimethylsiloxane (10cst) 3 Copolymers of vinylidene chloride / acrylonitrile / methyl methacrylate copolymer DOW CORNING 6, Cetyl dimethicone 1.0 Preservatives expanded with isobutane (Expancel 551 DE 20 D60 from Expancel) 1 Silica 5 Bismuth oxychloride 10 (1) = titanium dioxide (C177891), FD & C yellow lacquer Yellow Aluminum lake ( C1191140) and polymethylhydrogensiloxane (65.8 / 32.9 / 1.3)

Said composition is prepared according to the following standard procedure: the charges and pigments are mixed in a ribbon mixer; the oils (silicones) are added and mixed again; the blender assembly is ground by air jet or pin mill; the mixture obtained is poured into a casing provided with a sieve. The powder is applied to the houpette or with a brush on the face, by sampling through the sieve.

Claims (17)

REVENDICATIONS1. A pulverulent make-up and / or skincare composition comprising a) at least one pulverulent phase comprising at least 60% by weight of filler relative to the total weight of the composition, and b) at least one composite pigment comprising a core inorganic, at least one organic binder, and at least one at least partial coating of at least one organic dyestuff. 2. Composition according to the preceding claim, characterized in that the organic coloring material is chosen from an organic pigment or lacquer. 3. Composition according to any one of the preceding claims, characterized in that the inorganic core has a mean size of between about 1 nm and about 100 nm. 4. Composition according to any one of the preceding claims, characterized in that the inorganic core comprises a material selected from a metal salt, a metal oxide, an alumina, a glass, a ceramic, a graphite, a silica, a silicate , a synthetic mica, and a mixture thereof. 5. Composition according to the preceding claim, characterized in that the inorganic core comprises a metal oxide selected from an oxide of titanium, zirconium, cerium, zinc, iron, ferric blue, chromium and aluminum. 6. Composition according to the preceding claim, characterized in that the metal oxide comprises titanium dioxide. 35 7. Composition according to any one of the preceding claims, characterized in that the mass proportion of organic dyestuff is between about 10 and about 500 parts by weight per 100 parts of the inorganic nucleus. 8. Composition according to any one of the preceding claims, characterized in that the organic coloring material is chosen from a carmine of cochineal, an organic pigment of azo dye, anthraquinone, indigo, xanthene, pyrenic, quinoline, triphenylmethane, fluoran, an organic lacquer, an insoluble salt of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dye. 9. Composition according to any one of the preceding claims, characterized in that the organic coloring material comprises an organic pigment having one of the following denominations: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5 , D & C Green # 6, D & C Orange # 4, D & C Orange # 5, D & C Orange # 10, D & C Orange # 11, D & C Red # 6, D & C Red # 7, D & C Red # 17, D & C Red No. 21, D & C Red No. 22, D & C Red No. 27, D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red ° 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40 , FD & C Yellow No. 5, FD & C Yellow No. 6. 10. Composition according to any one of the preceding claims, characterized in that the organic coloring material comprises an organic lacquer having one of the following denominations: D & C Red No. 2 Aluminum Lake, D & C Red No. 3 Aluminum Lake, D & C Red # 4 Aluminum Lake, D & C Red # 6 Aluminum Lake, D & C Red # 6 Barium Lake, D & C Red # 6 Barium / Strontium Lake, D & C Red # 6 Strontium Lake, D & C Red # 6 Potassium Lake, D & C Red # 7 Aluminum Lake, D & C Red # 7 Barium Lake, D & C Red # 7 Calcium Lake, D & C Red # 7 Calcium / Strontium Lake, D & C Red # 7 Zirconium Lake, D & C Red # 8 Sodium Lake, D & C Red # 9 Aluminum Lake, D & C Red # 9 Barium Lake, D & C Red # 9 Barium / Strontium Lake, D & C Red # 9 Zirconium Lake, D & C Red # 10 Sodium Lake, D & C Red # 19 Aluminum Lake, D & C Red # 19 Barium Lake, D & C Red # 19 Zirconium Lake, D & C Red # 21 Aluminum Lake, D & C Red # 21 Zirconium Lake, D & C Red # 22 Aluminum Lake, D & C Red 10 15 # 27 Aluminum lak e, D & C Red # 27 Aluminum / Titanium / Zirconium Lake, D & C Red # 27 Barium Lake, D & C Red # 27 Calcium Lake, D & C Red # 27 Zirconium Lake, D & C Red # 28 Aluminum Lake, D & C Red # 30 lake, D & C Red No. 31 Calcium Lake, D & C Red No. 33 Aluminum Lake, D & C Red No. 34 Calcium Lake, D & C Red No. 36 Lake, D & C Red No. 40 Aluminum Lake, D & C Blue No. 1 Aluminum Lake, D & C Green No. 3 Aluminum Lake, D & C Orange No. 4 Aluminum Lake, D & C Orange No. 5 Aluminum Lake, D & C Orange No. 5 Zirconium Lake, D & C Orange No. 10 Aluminum Lake, D & C Orange No. 17 Barium Lake, D & C Yellow # 5 Aluminum Lake, D & C Yellow # 5 Zirconium Lake, D & C Yellow # 6 Aluminum Lake, D & C Yellow # 7 Zirconium Lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red No. 40 Aluminum Lake, FD & C Yellow No. 5 Aluminum Lake, FD & C Yellow No. 6 Aluminum Lake. 11. Composition according to any one of the preceding claims, characterized in that the organic binder of said composite pigment is selected from silicone compounds, polymeric compounds, oligomeric compounds, coupling agents, and mixtures thereof. 20 25 30 12. Composition according to any one of the preceding claims, characterized in that said composite pigment is present in a content ranging from 0.01 to 70% by weight relative to the total weight of the composition, in particular from 0.1 to 50% by weight, preferably from 0.5 to 20% by weight relative to the total weight of said composition. 13. Composition according to any one of the preceding claims, characterized in that the pulverulent phase comprises at least 40% by weight of mineral fillers, in particular chosen from talc, mica, and mixtures thereof. 14. Composition according to any one of the preceding claims, characterized in that it further comprises at least one spherical organic filler, in particular a polyamide (nylon) powder. 35 15. Composition according to any one of the preceding claims, characterized in that it is a loose powder or a compact powder. 16. A cosmetic process for making up and / or caring for the skin, comprising the application to said skin of a composition in powder form as described in any one of claims 1 to 15. Cosmetic assembly comprising: i) a container delimiting at least one compartment, said container being closed by a closure element; and ii) a composition disposed within said compartment, the composition being defined according to any one of claims 1 to 15.15