FR2882755A1 - GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM - Google Patents

GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM

Info

Publication number
FR2882755A1
FR2882755A1 FR0511111A FR0511111A FR2882755A1 FR 2882755 A1 FR2882755 A1 FR 2882755A1 FR 0511111 A FR0511111 A FR 0511111A FR 0511111 A FR0511111 A FR 0511111A FR 2882755 A1 FR2882755 A1 FR 2882755A1
Authority
FR
France
Prior art keywords
polyol
polyisocyanurate foam
glass fiber
fiber reinforced
glass fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0511111A
Other languages
French (fr)
Other versions
FR2882755B1 (en
Inventor
Marc Moerman
Bruno Guelton
Jacques Dhellemmes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gaztransport et Technigaz SA
Original Assignee
Gaztransport et Technigaz SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaztransport et Technigaz SA filed Critical Gaztransport et Technigaz SA
Priority to FR0511111A priority Critical patent/FR2882755A1/en
Priority to CA002534237A priority patent/CA2534237A1/en
Priority to EP06300101.0A priority patent/EP1698649B1/en
Priority to US11/348,273 priority patent/US20070015842A1/en
Priority to JP2006034546A priority patent/JP5303098B2/en
Priority to TW095104891A priority patent/TWI292408B/en
Priority to KR1020060020700A priority patent/KR101255607B1/en
Publication of FR2882755A1 publication Critical patent/FR2882755A1/en
Application granted granted Critical
Publication of FR2882755B1 publication Critical patent/FR2882755B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085—Use of fibrous compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Mousse de polyuréthanne/polyisocyanurate renforcée par des fibres de verre, étant obtenue :1) par la mise en contact :. d'un composant isocyanate. d'un composant polyol comportant un premier polyol et un deuxième polyol et un troisième polyol, en présence :. de catalyseurs. d'un agent d'expansion physique ou chimique,. d'un émulsifiant et. éventuellement d'un retardeur de flamme,2) par l'imprégnation, par la formulation issue de l'étape 1), d'un empilement de fibres de verre, et3) par l'expansion et la solidification de ladite formulation de façon à former un bloc de mousse renforcée contenant l'empilement de fibres de verre ;ledit bloc de mousse renforcée présentant une masse volumique moyenne comprise entre 115 et 135 kg/m<3>, et un indice isocyanate compris entre 100 et 180.Polyurethane / polyisocyanurate foam reinforced with glass fibers, being obtained: 1) by bringing into contact:. of an isocyanate component. of a polyol component comprising a first polyol and a second polyol and a third polyol, in the presence of :. catalysts. a physical or chemical blowing agent ,. an emulsifier and. optionally with a flame retardant, 2) by the impregnation, by the formulation resulting from step 1), of a stack of glass fibers, and 3) by the expansion and solidification of said formulation so as to forming a block of reinforced foam containing the stack of glass fibers; said block of reinforced foam having an average density of between 115 and 135 kg / m <3>, and an isocyanate number of between 100 and 180.

FR0511111A 2005-03-04 2005-10-28 GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM Granted FR2882755A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR0511111A FR2882755A1 (en) 2005-03-04 2005-10-28 GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM
CA002534237A CA2534237A1 (en) 2005-03-04 2006-01-25 Polyurethane/polyisocyanurate foam reinforced with glass fibres
EP06300101.0A EP1698649B1 (en) 2005-03-04 2006-02-02 Glassfiber-reinforced polyurethane-polyisocyanurate foam
US11/348,273 US20070015842A1 (en) 2005-03-04 2006-02-07 Glass fiber reinforced polyurethane/polyisocyanurate foam
JP2006034546A JP5303098B2 (en) 2005-03-04 2006-02-10 Glass fiber reinforced polyurethane-polyisocyanurate foam
TW095104891A TWI292408B (en) 2005-03-04 2006-02-14 Class fiber reinforced polyurethane/polyisocyanurate foam
KR1020060020700A KR101255607B1 (en) 2005-03-04 2006-03-04 Glass fiber reinforced polyurethane/polyisocyanurate foam

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0502227A FR2882756B1 (en) 2005-03-04 2005-03-04 FOAM OF POLYURETHAN-POLYISOCYANURATE REINFORCED WITH GLASS FIBERS
FR0511111A FR2882755A1 (en) 2005-03-04 2005-10-28 GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM

Publications (2)

Publication Number Publication Date
FR2882755A1 true FR2882755A1 (en) 2006-09-08
FR2882755B1 FR2882755B1 (en) 2007-04-27

Family

ID=35285410

Family Applications (2)

Application Number Title Priority Date Filing Date
FR0502227A Expired - Fee Related FR2882756B1 (en) 2005-03-04 2005-03-04 FOAM OF POLYURETHAN-POLYISOCYANURATE REINFORCED WITH GLASS FIBERS
FR0511111A Granted FR2882755A1 (en) 2005-03-04 2005-10-28 GLASS FIBER REINFORCED POLYURETHANE / POLYISOCYANURATE FOAM

Family Applications Before (1)

Application Number Title Priority Date Filing Date
FR0502227A Expired - Fee Related FR2882756B1 (en) 2005-03-04 2005-03-04 FOAM OF POLYURETHAN-POLYISOCYANURATE REINFORCED WITH GLASS FIBERS

Country Status (4)

Country Link
CN (1) CN100434451C (en)
FR (2) FR2882756B1 (en)
RU (1) RU2317307C2 (en)
TW (1) TWI292408B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020148339A1 (en) 2019-01-16 2020-07-23 Gaztransport Et Technigaz Process for preparing a block of polyurethane/polyisocyanurate foam of a slab for heat-insulating a tank

Families Citing this family (27)

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CN101191010B (en) * 2006-11-20 2011-06-15 中国船舶重工集团公司第七二五研究所 Fibre enhancement modifying method for polyurethane foam plastic
CN100485001C (en) * 2007-02-12 2009-05-06 江苏双良复合材料有限公司 Section material product of continuous glass-fiber reinforced hard polyurethane microfoam and coextrusion forming process
CN101029456B (en) * 2007-03-06 2010-05-19 天津工业大学 Non-woven elastic substrate and its production
US8940803B2 (en) * 2008-12-10 2015-01-27 Basf Se Water-blown rigid foams with improved mechanical properties at low temperatures
ITMI20100440A1 (en) * 2010-03-18 2011-09-19 Dow Global Technologies Inc PROCESS FOR THE PREPARATION OF POLYURETHANE REINFORCED WITH LONG FIBERS CONTAINING PARTICULAR FILLERS
CN101781395B (en) * 2010-03-30 2011-08-31 上海交通大学 Hard polyurethane adiabatic heat-insulation foam material and preparation method thereof
RU2465141C2 (en) * 2011-01-12 2012-10-27 Государственное образовательное учреждение высшего профессионального образования Балтийский государственный технический университет "ВОЕНМЕХ" им. Д.Ф. Устинова (БГТУ "ВОЕНМЕХ") Method of making gas-filled plastic reinforced by discrete elements
JP2013043374A (en) * 2011-08-24 2013-03-04 Nakagawa Sangyo Kk Manufacturing method of interior substrate for automobile
CN102504164B (en) * 2011-11-22 2013-10-16 中国农业大学 Manufacture method of enhanced corncob base polyurethane foam materials
TWI477552B (en) * 2012-06-28 2015-03-21 Fire-resistant polyurethane material and fire-resistant structure
FR2993270B1 (en) * 2012-07-12 2015-08-07 Rhodia Operations CHEMICAL FOAMING PROCESS IN THE PRESENCE OF REINFORCING LOADS
DK2885331T3 (en) * 2012-08-20 2019-12-09 Covestro Deutschland Ag FIBER ENHANCED COMPOSITION COMPONENTS AND THEIR PREPARATION
WO2014029700A1 (en) * 2012-08-20 2014-02-27 Bayer Materialscience Ag Polyurethane casting resins and potting compounds produced therefrom
CN103641984B (en) * 2013-11-13 2016-06-08 安徽金马海绵有限公司 A kind of enhancing sponge and preparation method thereof
CN107090074A (en) * 2016-02-17 2017-08-25 江苏雅克科技股份有限公司 A kind of high-fire-resistance fiberglass reinforced hard polyaminoester ultra-low temperature heat preservation material and its preparation method
CN107099018A (en) * 2016-02-22 2017-08-29 江苏雅克科技股份有限公司 A kind of halogen-free flame-retardant glass fiber of resistance to ultralow temperature enhancement type hard polyurethane insulation material of green-blowing agent production and preparation method thereof
TW201833164A (en) * 2016-05-04 2018-09-16 科思創德意志股份有限公司 Process for producing a composite polyisocyanurate material
CN108148166A (en) * 2016-12-05 2018-06-12 江苏雅克科技股份有限公司 Polyurethane heat-insulation composite material
CN107459617A (en) * 2017-07-11 2017-12-12 上海交通大学 A kind of LNG ship grad enhancement heat-insulating material and its short process making method
CN108997550A (en) * 2018-06-27 2018-12-14 扬中市天正合成材料研究中心 Environmental protection flame retardant foamed material and preparation method for tractor fuel tank
CN109503792A (en) * 2018-11-08 2019-03-22 青岛正能交通装备有限公司 A kind of polyurethane foam standard EMU operation bench mask and preparation method thereof
FR3088571B1 (en) * 2018-11-19 2021-12-17 Gaztransport Et Technigaz PROCESS AND SYSTEM FOR PREPARING A BLOCK OF POLYURETHANE / POLYISOCYANURATE FOAM FROM A THERMAL INSULATION MASS OF A TANK
FR3092837B1 (en) * 2019-02-18 2021-08-27 Gaztransport Et Technigaz METHACRYLATE COPOLYMERS, AND THEIR USES FOR THE PREPARATION OF POLYURETHANE FOAM
FR3094449B1 (en) 2019-03-26 2022-12-23 Gaztransport Et Technigaz Polyurethane/polyisocyanurate foam block for a thermal insulation block for a tank and process for its preparation
FR3094451B1 (en) 2019-03-26 2022-12-23 Gaztransport Et Technigaz Polyurethane/polyisocyanurate foam block for a thermal insulation block for a tank and process for its preparation
CN110699858A (en) * 2019-11-14 2020-01-17 江苏九鼎新材料股份有限公司 Method for producing a continuous glass fibre mat for polyurethane reinforcement and use thereof
WO2022268328A1 (en) 2021-06-24 2022-12-29 Gaztransport Et Technigaz Compositions of methacrylate copolymers and blowing agent, and uses thereof for the preparation of polyurethane foam

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FR2206292A1 (en) * 1972-11-13 1974-06-07 Daiki Sangyo Co Ltd
US4680214A (en) * 1986-03-12 1987-07-14 Polymetrics Corporation Reinforced foam composites
EP0248721A1 (en) * 1986-06-03 1987-12-09 Société Nouvelle Technigaz Thermally insulating wall structure of a fluid-tight container
US20030034578A1 (en) * 2001-07-05 2003-02-20 Han Kuk Fiber Glass Co., Ltd. Method for manufacturing polyurethane foam injected with strand mats and device for increasing volume of the strand mats

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JP2001247647A (en) * 2000-03-08 2001-09-11 Nkk Corp Raw liquid composition for rigid polyurethane foam, and process for preparation of thermal insulation panel for extremely low temperature

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2206292A1 (en) * 1972-11-13 1974-06-07 Daiki Sangyo Co Ltd
US4680214A (en) * 1986-03-12 1987-07-14 Polymetrics Corporation Reinforced foam composites
EP0248721A1 (en) * 1986-06-03 1987-12-09 Société Nouvelle Technigaz Thermally insulating wall structure of a fluid-tight container
US20030034578A1 (en) * 2001-07-05 2003-02-20 Han Kuk Fiber Glass Co., Ltd. Method for manufacturing polyurethane foam injected with strand mats and device for increasing volume of the strand mats

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020148339A1 (en) 2019-01-16 2020-07-23 Gaztransport Et Technigaz Process for preparing a block of polyurethane/polyisocyanurate foam of a slab for heat-insulating a tank

Also Published As

Publication number Publication date
RU2006106649A (en) 2007-09-10
FR2882755B1 (en) 2007-04-27
FR2882756A1 (en) 2006-09-08
CN100434451C (en) 2008-11-19
TWI292408B (en) 2008-01-11
TW200639202A (en) 2006-11-16
FR2882756B1 (en) 2007-04-27
RU2317307C2 (en) 2008-02-20
CN1834130A (en) 2006-09-20

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Legal Events

Date Code Title Description
ST Notification of lapse

Effective date: 20150630

CJ Change in legal form

Effective date: 20151022